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Issue 26, 2017
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Sandwich rare earth complexes simultaneously involving aromatic phthalocyanine and antiaromatic hemiporphyrazine ligands showing a predominantly aromatic nature

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Abstract

Two mixed (phthalocyaninato)(hemiporphyrazinato) and two homoleptic bis(hemiporphyrazinato) rare earth double-decker complexes have been synthesized and structurally characterized. The EPR and NMR results clarified the protonated nature of these sandwich double-deckers. Spectroscopic and theoretical calculation results clearly reveal the predominantly aromatic nature of the mixed ring sandwich double-deckers.

Graphical abstract: Sandwich rare earth complexes simultaneously involving aromatic phthalocyanine and antiaromatic hemiporphyrazine ligands showing a predominantly aromatic nature

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Publication details

The article was received on 17 feb. 2017, accepted on 11 mar. 2017 and first published on 13 mar. 2017


Article type: Communication
DOI: 10.1039/C7CC01279A
Citation: Chem. Commun., 2017,53, 3765-3768
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    Sandwich rare earth complexes simultaneously involving aromatic phthalocyanine and antiaromatic hemiporphyrazine ligands showing a predominantly aromatic nature

    W. Liu, H. Pan, Z. Wang, K. Wang, D. Qi and J. Jiang, Chem. Commun., 2017, 53, 3765
    DOI: 10.1039/C7CC01279A

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