Jump to main content
Jump to site search

Issue 6, 2016
Previous Article Next Article

Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

Author affiliations

Abstract

In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and 3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term “giant clusters” is used herein to denote metal clusters with nuclearity of 30 or greater. Many synthetic strategies towards such species have been developed and are discussed in this paper. Attempts are made to categorize some of the most successful methods to giant clusters, but it will be pointed out that the characteristics of the crystal structures of such compounds including nuclearity, shape, architecture, etc. are unpredictable depending on the specific structural features of the included organic ligands, reaction conditions and other factors. The majority of the described compounds in this review are of special interest not only for their fascinating nanosized structures but also because they sometimes display interesting magnetic phenomena, such as ferromagnetic exchange interactions, large ground state spin values, single-molecule magnetism behaviour or impressively large magnetocaloric effects. In addition, they often possess the properties of both the quantum and the classical world, and thus their systematic study offers the potential for the discovery of new physical phenomena, as well as a better understanding of the existing ones. The research field of giant clusters is under continuous evolution and their intriguing structural characteristics and magnetism properties that attract the interest of synthetic Inorganic Chemists promise a brilliant future for this class of compounds.

Graphical abstract: Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

Back to tab navigation

Publication details

The article was received on 29 júl. 2015 and first published on 15 jan. 2016


Article type: Review Article
DOI: 10.1039/C5CS00590F
Author version available: Download Author version (PDF)
Citation: Chem. Soc. Rev., 2016,45, 1597-1628
  •   Request permissions

    Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

    C. Papatriantafyllopoulou, E. E. Moushi, G. Christou and A. J. Tasiopoulos, Chem. Soc. Rev., 2016, 45, 1597
    DOI: 10.1039/C5CS00590F

Search articles by author

Spotlight

Advertisements