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Issue 9, 2015
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Pyrrolophthalazine dione (PPD)-based donor–acceptor polymers as high performance electrochromic materials

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Abstract

A novel pyrrolophthalazine dione (PPD) acceptor was sophisticatedly designed and synthesized via an inverse electron demand Diels–Alder reaction, followed by aromatization with N-bromosuccinimide. The PPD moiety was incorporated into donor–acceptor type conjugated polymers through Stille coupling polymerization to yield a series of polymers P1–P3 with different linking groups, namely, thiophene, thieno[3,2-b]thiophene, and bithiophene. The polymers reveal excellent solubility in common organic solvents. Due to their low bandgaps of around 1.72–1.78 eV, the polymers show broad absorption that covers most of the visible region. All the polymers reveal electrochromism, switching between dark blue and transmissive sky blue states. In particular, P2 exhibits exceptional electrochromic properties with high optical contrasts of up to 34 and 71% in the visible and NIR regions, high coloration efficiencies of 471 and 651 cm2 C−1 respectively, as well as reasonable switching speeds and good long-term stability.

Graphical abstract: Pyrrolophthalazine dione (PPD)-based donor–acceptor polymers as high performance electrochromic materials

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Publication details

The article was received on 21 nóv. 2014, accepted on 03 des. 2014 and first published on 04 des. 2014


Article type: Paper
DOI: 10.1039/C4PY01608D
Author version available: Download Author version (PDF)
Citation: Polym. Chem., 2015,6, 1487-1494
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    Pyrrolophthalazine dione (PPD)-based donor–acceptor polymers as high performance electrochromic materials

    Q. Ye, W. T. Neo, T. Lin, J. Song, H. Yan, H. Zhou, K. W. Shah, S. J. Chua and J. Xu, Polym. Chem., 2015, 6, 1487
    DOI: 10.1039/C4PY01608D

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