Issue 90, 2015

Novel comb polymers from alternating N-acylated poly(aminoester)s obtained by spontaneous zwitterionic copolymerisation

Abstract

N-Acylated poly(aminoester) (NPAE) macromonomers were synthesised via spontaneous copolymerisation of 2-oxazolines and acrylic acid. Inherent quantitative introduction of α-vinyl end-groups was observed, which enabled the preparation of a series of well-defined NPAE comb polymers through redox-initiated RAFT polymerisation. Investigations of the thermal properties of the comb polymers revealed similarities to poly(2-oxazoline) based systems.

Graphical abstract: Novel comb polymers from alternating N-acylated poly(aminoester)s obtained by spontaneous zwitterionic copolymerisation

Supplementary files

Article information

Article type
Communication
Submitted
28 ágú. 2015
Accepted
17 sep. 2015
First published
24 sep. 2015

Chem. Commun., 2015,51, 16213-16216

Novel comb polymers from alternating N-acylated poly(aminoester)s obtained by spontaneous zwitterionic copolymerisation

K. Kempe, P. A. J. M. de Jongh, A. Anastasaki, P. Wilson and D. M. Haddleton, Chem. Commun., 2015, 51, 16213 DOI: 10.1039/C5CC07247F

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