Issue 14, 2016
From the journal:

Polymer Chemistry

Polymerisation of 2-acrylamido-2-methylpropane sulfonic acid sodium salt (NaAMPS) and acryloyl phosphatidylcholine (APC) via aqueous Cu(0)-mediated radical polymerisation†

Vasiliki Nikolaou,a   Alexandre Simula,a   Martijn Droesbeke,a   Nuttapol Risangud,a   Athina Anastasaki,ab   Kristian Kempe,a   Paul Wilsonab  and  David M. Haddleton*ab  

* Corresponding authors

a University of Warwick, Chemistry Department, Library road, Coventry, UK
E-mail: d.m.haddleton@warwick.ac.uk

b ARC Centre of Excellence in Convergent Bio-Nano Science and Technology, Monash Institute of Pharmaceutical Sciences, Monash University (Parkville Campus), 399 Royal Parade, Parkville, Victoria 3152, Australia

Abstract

The scope of aqueous Cu(0)-mediated living radical polymerisation has been expanded with the preparation of poly(2-acrylamido-2-methylpropane sulfonic acid)sodium salt (P(NaAMPS)) and poly(acryloyl phosphatidycholine) (PAPC). Manipulation of the reaction conditions furnishes polymers capable of undergoing chain extension and supporting the synthesis of block copolymers at 0 °C.

Graphical abstract: Polymerisation of 2-acrylamido-2-methylpropane sulfonic acid sodium salt (NaAMPS) and acryloyl phosphatidylcholine (APC) via aqueous Cu(0)-mediated radical polymerisation

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Article information

DOI
https://doi.org/10.1039/C5PY02016F
Article type
Communication
Submitted
17 des. 2015
Accepted
04 mar. 2016
First published
07 mar. 2016

Polym. Chem., 2016,7, 2452-2456

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Polymerisation of 2-acrylamido-2-methylpropane sulfonic acid sodium salt (NaAMPS) and acryloyl phosphatidylcholine (APC) via aqueous Cu(0)-mediated radical polymerisation

V. Nikolaou, A. Simula, M. Droesbeke, N. Risangud, A. Anastasaki, K. Kempe, P. Wilson and D. M. Haddleton, Polym. Chem., 2016, 7, 2452 DOI: 10.1039/C5PY02016F

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