Issue 45, 2016

Finely tuning MOFs towards high performance in C2H2 storage: synthesis and properties of a new MOF-505 analogue with an inserted amide functional group

Abstract

Aiming to improve the acetylene (C2H2) storage capability of MOFs, we successfully designed NJU-Bai 17, a new analogue of MOF-505 with an inserted amide functional group which exhibits almost record high C2H2 uptakes of 222.4 cm3 g−1 at 296 K and 296 cm3 g−1 at 273 K under 1 bar. This result has been further supported by the determination of the heat of C2H2 adsorption and Grand Canonical Monte Carlo (GCMC) and first-principle calculations.

Graphical abstract: Finely tuning MOFs towards high performance in C2H2 storage: synthesis and properties of a new MOF-505 analogue with an inserted amide functional group

Supplementary files

Article information

Article type
Communication
Submitted
16 apr. 2016
Accepted
01 maí 2016
First published
04 maí 2016

Chem. Commun., 2016,52, 7241-7244

Finely tuning MOFs towards high performance in C2H2 storage: synthesis and properties of a new MOF-505 analogue with an inserted amide functional group

M. Zhang, B. Li, Y. Li, Q. Wang, W. Zhang, B. Chen, S. Li, Y. Pan, X. You and J. Bai, Chem. Commun., 2016, 52, 7241 DOI: 10.1039/C6CC03198F

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