RSC Advances
Inorganic articles published in the last
6 months
Synthesis, characterization, and biomedical evaluation of ethylene-bridged tetra-NHC Pd(II), Pt(II) and Au(III) complexes, with apoptosis-inducing properties in cisplatin-resistant neuroblastoma cells
New ethylene-bridged N-heterocyclic carbene ligand systems and their respective transition metal complexes are characterized and the electronic properties are discussed.
RSC Adv., 2024,14, 10244-10254
https://doi.org/10.1039/D4RA01195C
In silico modelling of chelate stabilized tetrylene derivatives
The steric and electronic effects of specific ligands can play crucial roles in stabilizing unsaturated tetrylene species.
RSC Adv., 2024,14, 10161-10171
https://doi.org/10.1039/D4RA01515K
Recent advances in the fluorimetric and colorimetric detection of cobalt ions
Cobalt is an essential metal to maintain several functions in the human body and is present in functional materials for numerous applications.
RSC Adv., 2024,14, 9819-9847
https://doi.org/10.1039/D4RA00445K
Luminescence turn-on sensor for the selective detection of trace water and methanol based on a Zn(II) coordination polymer with 2,5-dihydroxyterephthalate
A Zn(II) coordination polymer containing free hydroxyl groups presents thermally and methanol induced reversible structural transformation, and high selectivity with water and methanol sensing by turn-on luminescent intensity.
RSC Adv., 2024,14, 9781-9790
https://doi.org/10.1039/D4RA00500G
Synthesis, structural, spectroscopic and electric/dielectric studies of a nanocrystalline Ni(II) complex based on [(1,3-diphenyl-1H-pyrazol-4-yl)methylene]thiocarbonohydrazide
A Ni2+ nanocomplex based on a heterocyclic ligand containing a pyrazole moiety was developed in this work, and its electric conductivity and dielectric characteristics were studied.
RSC Adv., 2024,14, 9747-9757
https://doi.org/10.1039/D4RA00665H
Design and application of metal organic frameworks for heavy metals adsorption in water: a review
The growing apprehension surrounding heavy metal pollution in both environmental and industrial contexts has spurred extensive research into adsorption materials aimed at efficient remediation.
RSC Adv., 2024,14, 9365-9390
https://doi.org/10.1039/D3RA08815D
Phenothiazine appended thiophene derivative: a trilateral approach to copper ion detection in living cells and aqueous samples
A novel phenothiazine-thiophene acetonitrile compound was synthesised through a Knoevenagel condensation reaction. The compound demonstrated selectivity towards Cu2+ and proved to have low cytotoxicity.
RSC Adv., 2024,14, 8885-8895
https://doi.org/10.1039/D3RA07608C
Antibacterial, antibiofilm, and antioxidant activities of two novel metal–organic frameworks (MOFs) based on 4,6-diamino-2-pyrimidinethiol with Zn and Co metal ions as coordination polymers
Two novel metal–organic frameworks (MOFs), synthesized from 4,6-diamino-2-pyrimidinethiol with Zn and Co metal ions, display antibacterial, antibiofilm, and antioxidant properties, serving multifunctionality in biological and environmental domains.
RSC Adv., 2024,14, 9080-9098
https://doi.org/10.1039/D4RA00545G
Machine learning guided tuning charge distribution by composition in MOFs for oxygen evolution reaction
We utilize machine learning (ML) to accelerate the synthesis of MOFs, starting by building a library of over 900 MOFs with different metal salts, solvent ratios and reaction tine, and then utilizing zeta potentials as target variables for ML training.
RSC Adv., 2024,14, 9032-9037
https://doi.org/10.1039/D3RA08873A
Crystal structure, Hirshfeld surface analysis, conduction mechanism and electrical modulus study of the new organic–inorganic compound [C8H10NO]2HgBr4
There has been a lot of interest in the development of a novel hybrid material based on mercury that has fascinating structural properties.
RSC Adv., 2024,14, 8971-8980
https://doi.org/10.1039/D4RA00689E
Viral peptide conjugates for metal-warhead delivery to chromatin
Chromatin-targeting viral peptide–gold(I) conjugates display cancer cell selectivity and localize to the nucleosome acidic patch, forming histone site-specific protein adducts.
RSC Adv., 2024,14, 8718-8725
https://doi.org/10.1039/D4RA01617C
Preparation of Co–Ni–Ce/TiC alloy coatings by double-pulse under a sulfamic acid system and a process mechanism study
To enhance the protective ability of copper crystallizers and extend their service life, this study explores the use of double pulse co-deposition under a sulfamic acid system to create protective coatings such as Co–Ni–Ce/TiC.
RSC Adv., 2024,14, 8526-8535
https://doi.org/10.1039/D4RA00896K
Heterocyclic (pyrazine)carboxamide Ru(II) complexes: structural, experimental and theoretical studies of interactions with biomolecules and cytotoxicity
The heterocyclic (pyrazine)carboxamide Ru(II) complexes interact with CT-DNA through minor groove binding and partial intercalation modes and exhibit significant cytotoxicity and selectivity against A549, PC-3, and Caco-2 cell lines.
RSC Adv., 2024,14, 8322-8330
https://doi.org/10.1039/D4RA00525B
Accurate assembly of thiophene-bridged titanium-oxo clusters with photocatalytic amine oxidation activity
We synthesized a crystalline dumbbell-shaped Ti10, which effectively enhances charge transfer. As a result, it exhibits remarkably high conversion activity and selectivity in the photocatalytic oxidative coupling reaction of benzylamine.
RSC Adv., 2024,14, 7924-7931
https://doi.org/10.1039/D4RA00117F
Capture of mechanically interlocked molecules by rhodium-mediated terminal alkyne dimerisation
Active metal template synthesis of an enyne-based rotaxane and catenane.
RSC Adv., 2024,14, 7740-7744
https://doi.org/10.1039/D4RA00566J
Correction: Advances in metal–organic frameworks for water remediation applications
RSC Adv., 2024,14, 7640-7640
https://doi.org/10.1039/D4RA90018A
Tuning thermal and graphitization behaviors of lignin via complexation with transition metal ions for the synthesis of multilayer graphene-based materials
Transition metals affect thermal stabilization and graphitization of kraft lignin and further determine morphology and graphitic structures of multilayer graphene-based materials.
RSC Adv., 2024,14, 7592-7600
https://doi.org/10.1039/D3RA05881F
Coordination-induced and tunable layered rare-earth hydroxide-complex intercalated nanohybrid phosphorescent photosensitizer and therapy
Hydrotalcite intercalated nanohybrids have served as a vital phosphorescent photosensitizer owing to remarkable 1O2 quantum yield and high cell mortality performance.
RSC Adv., 2024,14, 7430-7439
https://doi.org/10.1039/D3RA07310F
Adsorption mechanism of Ca2+, Mg2+, Fe3+, and Al3+ ions in phosphoric acid–nitric acid solution on 001 × 7 and S957 resins
Under the influence of dihydrogen phosphate ions, Ca2+ and Mg2+ ions are adsorbed on the 001 × 7 resin through a sulfonic acid group, whereas Fe3+ and Al3+ ions are adsorbed on the S957 resin through a phosphonic acid group.
RSC Adv., 2024,14, 7234-7240
https://doi.org/10.1039/D3RA08791C
Alkyl chain functionalised Ir(III) complexes: synthesis, properties and behaviour as emissive dopants in microemulsions
Luminescent, alkyl chain functionalised Ir(III) complexes have been synthesised, characterised and studied in microemulsion environments showing retention of emissive behaviour.
RSC Adv., 2024,14, 6987-6997
https://doi.org/10.1039/D3RA06764E
Two new rare-earth oxyborates Ba4BiTbO(BO3)4 and Ba1.54Sr2.46BiTbO(BO3)4 and luminescence properties of the Ba4BiTb1−xEuxO(BO3)4 phosphors
Two new oxyborates Ba4BiTbO(BO3)4 and Ba1.54Sr2.46BiTbO(BO3)4 were synthesized and structurally characterized and luminescence properties of Ba4BiTb1−xEuxO(BO3)4 (0 ≤ x ≤ 0.2) were investigated.
RSC Adv., 2024,14, 6270-6284
https://doi.org/10.1039/D3RA08265B
Highly electron-deficient 1-propyl-3,5-dinitropyridinium: evaluation of electron-accepting ability and application as an oxidative quencher for metal complexes
Owing to enhanced electron-accepting/oxidizing abilities, a N-propylpyridinium derivative with two electron-withdrawing nitro groups efficiently quenched emission from Ru(II) and Ir(III) complexes by electron transfer.
RSC Adv., 2024,14, 5846-5850
https://doi.org/10.1039/D4RA00845F
Tandem manganese catalysis for the chemo-, regio-, and stereoselective hydroboration of terminal alkynes: in situ precatalyst activation as a key to enhanced chemoselectivity
The manganese(II) complex [Mn(iPrPNP)Cl2] (iPrPNP = 2,6-bis(diisopropylphosphinomethyl)pyridine) was found to catalyze the stereo- and regioselective hydroboration of terminal alkynes employing HBPin (pinacolborane).
RSC Adv., 2024,14, 5514-5523
https://doi.org/10.1039/D3RA08747F
Closed-shell d10–d10 mechanochromic [AuPh(CNPh)]n complex: quantum chemistry electronic and optical properties
[AuPh(CNPh)]2 complexes are modeled, and their electronic properties, optical properties, and solid state chemistry are studied.
RSC Adv., 2024,14, 5638-5647
https://doi.org/10.1039/D3RA08935E
The antibacterial activity of three zeolitic-imidazolate frameworks and zinc oxide nanoparticles derived from them
ZIF-4, ZIF-7 and ZIF-8 were synthesized and their antibacterial activity was evaluated. ZIF-8 showed the highest antibacterial property among the three types of MOFs and zinc oxide materials derived from them.
RSC Adv., 2024,14, 5601-5608
https://doi.org/10.1039/D4RA00447G
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