RSC Advances
Biocatalysis articles published in the last
6 months
Synthetic pathways to create asymmetric center at C1 position of 1-substituted-tetrahydro-β-carbolines – a review
Chiral 1-substituted-THβC can be synthesized from L-tryptophan or tryptamine by Pictet–Spengler reaction and chiral auxiliary; also from substituted-DHβC by ATH reaction with chiral catalysts, asymmetric addition reaction, and enzymatic catalysis.
RSC Adv., 2024,14, 29827-29847
https://doi.org/10.1039/D4RA05961A
Influence of deposition conditions on performance of Ni3S2 as the bifunctional electrocatalyst in alkaline solutions by galvanostatic deposition
The electrodeposition method is a popular synthesis method due to its low cost, simplicity, and short synthesis time.
RSC Adv., 2024,14, 29800-29811
https://doi.org/10.1039/D4RA04667F
Towards biotechnological production of bio-based low molecular weight esters: a patent review
Low molecular weight (LMW) esters are widespread bulk chemicals in many industries. This review presents the most significant patents and patent applications related to the biotechnological production of LMW esters.
RSC Adv., 2024,14, 29472-29489
https://doi.org/10.1039/D4RA04131C
Studies on the synergistic effect between corn straw and Canadian oil sands bitumen during the co-pyrolysis process
With the content of corn straw ranging from 0 to 40 wt%, the coke yield increased during the co-pyrolysis of corn straw and Canadian oil sands bitumen, while the yields of gas and oil showed a decreasing trend.
RSC Adv., 2024,14, 29404-29412
https://doi.org/10.1039/D4RA05567E
Computational screening of transition metal atom doped ZnS and ZnSe nanostructures as promising bifunctional oxygen electrocatalysts
The computed OER and ORR overpotentials of pristine and TM doped ZnX (X = S and Se) nanostructures.
RSC Adv., 2024,14, 28998-29005
https://doi.org/10.1039/D4RA04011B
Biomass as an alternative feedstock to oleochemicals
Biomass upgrade to oleochemicals as petrochemical substitutes, including the utility, physical–chemical properties, reaction routes, affecting parameters and the future forecast.
RSC Adv., 2024,14, 28827-28843
https://doi.org/10.1039/D4RA04481A
Essential aspects of the CFD software modelling of biomass gasification processes in downdraft reactors
Different designs of downdraft gasifiers. Gasifier with open top (1), gasifier with closed (2).
RSC Adv., 2024,14, 28724-28739
https://doi.org/10.1039/D4RA04886E
A review on synthesis of MOF-derived carbon composites: innovations in electrochemical, environmental and electrocatalytic technologies
Carbon composites derived from Metal–Organic Frameworks (MOFs) have shown great promise as multipurpose materials for a range of electrochemical and environmental applications.
RSC Adv., 2024,14, 27575-27607
https://doi.org/10.1039/D4RA05183A
Molybdenum tungsten hydrogen oxide doped with phosphorus for enhanced oxygen/hydrogen evolution reactions
The development of efficient electrocatalysts for hydrogen and oxygen evolution reactions (HER and OER) is pivotal for advancing cleaner and sustainable fuel production technologies.
RSC Adv., 2024,14, 27928-27934
https://doi.org/10.1039/D4RA05023A
A comprehensive review of production, applications, and the path to a sustainable energy future with hydrogen
Green hydrogen, a versatile and sustainable energy carrier, has garnered increasing attention as a critical element in the global transition to a low-carbon economy.
RSC Adv., 2024,14, 26400-26423
https://doi.org/10.1039/D4RA04559A
Investigating metal (M = Mn, Fe, and Ni)-doped Co(OH)2 nanofibers for electrocatalytic oxygen evolution and electrochemical biosensing performance
Metal (Mn, Fe, and Ni)-doped Co(OH)2 nanofibers for oxygen evolution through water splitting and electrochemical ascorbic acid sensing.
RSC Adv., 2024,14, 26556-26567
https://doi.org/10.1039/D4RA04240A
In situ growth of CaMoO4 on electropolymerized PANI as a hybrid electrocatalyst for enhanced oxygen evolution
Our studies demonstrate the potential of inorganic oxide/conductive polymer composite electrode prepared via binder-free growth for applications in electrochemical water splitting and energy conversion.
RSC Adv., 2024,14, 26292-26301
https://doi.org/10.1039/D4RA03196B
Recent advances in enzymatic carbon–carbon bond formation
Carbon–carbon (C–C) bond formation can be accomplished by various highly chemo-, regio- and/or stereoselective enzymatic reactions, sometimes through the catalytic promiscuity of enzymes.
RSC Adv., 2024,14, 25932-25974
https://doi.org/10.1039/D4RA03885A
Cu-P@silica-CNT-based catalyst for effective electrolytic water splitting in an alkaline medium with hydrazine assistance
In this study, we prepared a potential catalyst as an electrode modifier for electrolytic water splitting.
RSC Adv., 2024,14, 25830-25843
https://doi.org/10.1039/D4RA03998J
Facile synthesis of MnO/NC nanohybrids toward high-efficiency ORR for zinc–air battery
The MnO/NC nanohybrids were synthesized via a facile hydrothermal-pyrolysis strategy, showing enhanced ORR activity and promising ZAB performance.
RSC Adv., 2024,14, 24031-24038
https://doi.org/10.1039/D4RA04237A
Coprecipitation and hydrothermal synthesis of CaO from dolomite in the presence of Sapindus rarak extract for biodiesel production: catalysts characterization and optimization
Saponin from Sapindus rarak can be applied as a surfactant to produce CaO with high purity and smaller particle size. Hydrothermal CaO showed enhanced catalytic activity in biodiesel production.
RSC Adv., 2024,14, 23332-23340
https://doi.org/10.1039/D4RA03489A
Catalytic effects of graphene structures on Pt/graphene catalysts
The nitrogen species of graphene supports play a more important role than the oxygen species, SSA and pore volume for Pt/graphene catalysts in providing accessible active sites for ORRs.
RSC Adv., 2024,14, 22486-22496
https://doi.org/10.1039/D4RA02841D
Cascade enzymatic synthesis of a statin side chain precursor – the role of reaction engineering in process optimization
Statins are an important class of drugs used to lower blood cholesterol levels and are often used to combat cardiovascular disease.
RSC Adv., 2024,14, 21158-21173
https://doi.org/10.1039/D4RA01633E
Photocatalytic systems: reactions, mechanism, and applications
The photocatalytic field revolves around the utilization of photon energy to initiate various chemical reactions using non-adsorbing substrates, through processes such as single electron transfer, energy transfer, or atom transfer.
RSC Adv., 2024,14, 20609-20645
https://doi.org/10.1039/D4RA03259D
Ruthenium-doped Ni(OH)2 to enhance the activity of methanol oxidation reaction and promote the efficiency of hydrogen production
Ru/Ni(OH)2/NF nanocomposites were in situ grown on nickel foam, which exhibits excellent electrocatalytic activity and high selectivity for methanol oxidation in an alkaline electrolyte.
RSC Adv., 2024,14, 18695-18702
https://doi.org/10.1039/D4RA02181A
3D flower-like bimetallic Ni–Co metal–organic framework as an electrocatalyst for the oxygen evolution reaction
3D flower-like bimetallic MOF (F-Ni1Co4-BTC) was successfully designed and synthesized and exhibited excellent OER activity. Moreover, fixed on the surface of a carbon cloth, F-Ni1Co4-BTC realized high OER activity and long-term durability.
RSC Adv., 2024,14, 18367-18372
https://doi.org/10.1039/D4RA02280G
Tuning the high-entropy perovskite as efficient and reliable electrocatalysts for oxygen evolution reaction
This work reports a high-entropy perovskite La0.3Sr0.7(CrMnFeCoNi)0.2O3 as a high-performance OER electrocatalyst. Sr doping induces the formation of higher-valence Cr6+, Mn4+, Fe4+, Co4+ and Ni3+ responsible for the excellent OER activity.
RSC Adv., 2024,14, 18117-18125
https://doi.org/10.1039/D4RA02680B
Optimization of the catalytic production of methyl stearate by applying response surface Box–Behnken design: an intensified green option for high-cetane biofuel manufacture
To enhance the efficiency of processes by decreasing the reaction severity and energy consumption and reducing the equipment size, facilities' space and operation cost, process intensification is an increasingly used option in the chemical industry.
RSC Adv., 2024,14, 17990-18002
https://doi.org/10.1039/D4RA02750G
Advancements in enzyme immobilization on magnetic nanomaterials: toward sustainable industrial applications
Enzymes are widely used in biofuels, food, and pharmaceuticals.
RSC Adv., 2024,14, 17946-17988
https://doi.org/10.1039/D4RA02939A
Stereoselective Shi-type epoxidation with 3-oxo-4,6-O-benzylidene pyranoside catalysts: unveiling the role of carbohydrate skeletons
Sugar-derived chiral ketones are capable of reversing stereoselectivity in Shi-type epoxidation.
RSC Adv., 2024,14, 16778-16783
https://doi.org/10.1039/D4RA03011G
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