RSC Advances  

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Biocatalysis articles published in the last 6 months

37 items - Showing page 1 of 2
Open Access Review Article

Synthetic pathways to create asymmetric center at C1 position of 1-substituted-tetrahydro-β-carbolines – a review

Chiral 1-substituted-THβC can be synthesized from L-tryptophan or tryptamine by Pictet–Spengler reaction and chiral auxiliary; also from substituted-DHβC by ATH reaction with chiral catalysts, asymmetric addition reaction, and enzymatic catalysis.

Graphical abstract: Synthetic pathways to create asymmetric center at C1 position of 1-substituted-tetrahydro-β-carbolines – a review
Open Access Paper

Influence of deposition conditions on performance of Ni3S2 as the bifunctional electrocatalyst in alkaline solutions by galvanostatic deposition

The electrodeposition method is a popular synthesis method due to its low cost, simplicity, and short synthesis time.

Graphical abstract: Influence of deposition conditions on performance of Ni3S2 as the bifunctional electrocatalyst in alkaline solutions by galvanostatic deposition
Open Access Review Article

Towards biotechnological production of bio-based low molecular weight esters: a patent review

Low molecular weight (LMW) esters are widespread bulk chemicals in many industries. This review presents the most significant patents and patent applications related to the biotechnological production of LMW esters.

Graphical abstract: Towards biotechnological production of bio-based low molecular weight esters: a patent review
Open Access Paper

Studies on the synergistic effect between corn straw and Canadian oil sands bitumen during the co-pyrolysis process

With the content of corn straw ranging from 0 to 40 wt%, the coke yield increased during the co-pyrolysis of corn straw and Canadian oil sands bitumen, while the yields of gas and oil showed a decreasing trend.

Graphical abstract: Studies on the synergistic effect between corn straw and Canadian oil sands bitumen during the co-pyrolysis process
Open Access Paper

Computational screening of transition metal atom doped ZnS and ZnSe nanostructures as promising bifunctional oxygen electrocatalysts

The computed OER and ORR overpotentials of pristine and TM doped ZnX (X = S and Se) nanostructures.

Graphical abstract: Computational screening of transition metal atom doped ZnS and ZnSe nanostructures as promising bifunctional oxygen electrocatalysts
Open Access Review Article

Biomass as an alternative feedstock to oleochemicals

Biomass upgrade to oleochemicals as petrochemical substitutes, including the utility, physical–chemical properties, reaction routes, affecting parameters and the future forecast.

Graphical abstract: Biomass as an alternative feedstock to oleochemicals
Open Access Review Article

Essential aspects of the CFD software modelling of biomass gasification processes in downdraft reactors

Different designs of downdraft gasifiers. Gasifier with open top (1), gasifier with closed (2).

Graphical abstract: Essential aspects of the CFD software modelling of biomass gasification processes in downdraft reactors
Open Access Review Article

A review on synthesis of MOF-derived carbon composites: innovations in electrochemical, environmental and electrocatalytic technologies

Carbon composites derived from Metal–Organic Frameworks (MOFs) have shown great promise as multipurpose materials for a range of electrochemical and environmental applications.

Graphical abstract: A review on synthesis of MOF-derived carbon composites: innovations in electrochemical, environmental and electrocatalytic technologies
Open Access Paper

Molybdenum tungsten hydrogen oxide doped with phosphorus for enhanced oxygen/hydrogen evolution reactions

The development of efficient electrocatalysts for hydrogen and oxygen evolution reactions (HER and OER) is pivotal for advancing cleaner and sustainable fuel production technologies.

Graphical abstract: Molybdenum tungsten hydrogen oxide doped with phosphorus for enhanced oxygen/hydrogen evolution reactions
Open Access Review Article

A comprehensive review of production, applications, and the path to a sustainable energy future with hydrogen

Green hydrogen, a versatile and sustainable energy carrier, has garnered increasing attention as a critical element in the global transition to a low-carbon economy.

Graphical abstract: A comprehensive review of production, applications, and the path to a sustainable energy future with hydrogen
From the themed collection: 2024 Reviews in RSC Advances
Open Access Paper

Investigating metal (M = Mn, Fe, and Ni)-doped Co(OH)2 nanofibers for electrocatalytic oxygen evolution and electrochemical biosensing performance

Metal (Mn, Fe, and Ni)-doped Co(OH)2 nanofibers for oxygen evolution through water splitting and electrochemical ascorbic acid sensing.

Graphical abstract: Investigating metal (M = Mn, Fe, and Ni)-doped Co(OH)2 nanofibers for electrocatalytic oxygen evolution and electrochemical biosensing performance
Open Access Paper

In situ growth of CaMoO4 on electropolymerized PANI as a hybrid electrocatalyst for enhanced oxygen evolution

Our studies demonstrate the potential of inorganic oxide/conductive polymer composite electrode prepared via binder-free growth for applications in electrochemical water splitting and energy conversion.

Graphical abstract: In situ growth of CaMoO4 on electropolymerized PANI as a hybrid electrocatalyst for enhanced oxygen evolution
Open Access Review Article

Recent advances in enzymatic carbon–carbon bond formation

Carbon–carbon (C–C) bond formation can be accomplished by various highly chemo-, regio- and/or stereoselective enzymatic reactions, sometimes through the catalytic promiscuity of enzymes.

Graphical abstract: Recent advances in enzymatic carbon–carbon bond formation
From the themed collection: 2024 Reviews in RSC Advances
Open Access Paper

Cu-P@silica-CNT-based catalyst for effective electrolytic water splitting in an alkaline medium with hydrazine assistance

In this study, we prepared a potential catalyst as an electrode modifier for electrolytic water splitting.

Graphical abstract: Cu-P@silica-CNT-based catalyst for effective electrolytic water splitting in an alkaline medium with hydrazine assistance
Open Access Paper

Facile synthesis of MnO/NC nanohybrids toward high-efficiency ORR for zinc–air battery

The MnO/NC nanohybrids were synthesized via a facile hydrothermal-pyrolysis strategy, showing enhanced ORR activity and promising ZAB performance.

Graphical abstract: Facile synthesis of MnO/NC nanohybrids toward high-efficiency ORR for zinc–air battery
Open Access Paper

Coprecipitation and hydrothermal synthesis of CaO from dolomite in the presence of Sapindus rarak extract for biodiesel production: catalysts characterization and optimization

Saponin from Sapindus rarak can be applied as a surfactant to produce CaO with high purity and smaller particle size. Hydrothermal CaO showed enhanced catalytic activity in biodiesel production.

Graphical abstract: Coprecipitation and hydrothermal synthesis of CaO from dolomite in the presence of Sapindus rarak extract for biodiesel production: catalysts characterization and optimization
Open Access Paper

Catalytic effects of graphene structures on Pt/graphene catalysts

The nitrogen species of graphene supports play a more important role than the oxygen species, SSA and pore volume for Pt/graphene catalysts in providing accessible active sites for ORRs.

Graphical abstract: Catalytic effects of graphene structures on Pt/graphene catalysts
Open Access Paper

Cascade enzymatic synthesis of a statin side chain precursor – the role of reaction engineering in process optimization

Statins are an important class of drugs used to lower blood cholesterol levels and are often used to combat cardiovascular disease.

Graphical abstract: Cascade enzymatic synthesis of a statin side chain precursor – the role of reaction engineering in process optimization
Open Access Review Article

Photocatalytic systems: reactions, mechanism, and applications

The photocatalytic field revolves around the utilization of photon energy to initiate various chemical reactions using non-adsorbing substrates, through processes such as single electron transfer, energy transfer, or atom transfer.

Graphical abstract: Photocatalytic systems: reactions, mechanism, and applications
From the themed collection: 2024 Reviews in RSC Advances
Open Access Paper

Ruthenium-doped Ni(OH)2 to enhance the activity of methanol oxidation reaction and promote the efficiency of hydrogen production

Ru/Ni(OH)2/NF nanocomposites were in situ grown on nickel foam, which exhibits excellent electrocatalytic activity and high selectivity for methanol oxidation in an alkaline electrolyte.

Graphical abstract: Ruthenium-doped Ni(OH)2 to enhance the activity of methanol oxidation reaction and promote the efficiency of hydrogen production
Open Access Paper

3D flower-like bimetallic Ni–Co metal–organic framework as an electrocatalyst for the oxygen evolution reaction

3D flower-like bimetallic MOF (F-Ni1Co4-BTC) was successfully designed and synthesized and exhibited excellent OER activity. Moreover, fixed on the surface of a carbon cloth, F-Ni1Co4-BTC realized high OER activity and long-term durability.

Graphical abstract: 3D flower-like bimetallic Ni–Co metal–organic framework as an electrocatalyst for the oxygen evolution reaction
Open Access Paper

Tuning the high-entropy perovskite as efficient and reliable electrocatalysts for oxygen evolution reaction

This work reports a high-entropy perovskite La0.3Sr0.7(CrMnFeCoNi)0.2O3 as a high-performance OER electrocatalyst. Sr doping induces the formation of higher-valence Cr6+, Mn4+, Fe4+, Co4+ and Ni3+ responsible for the excellent OER activity.

Graphical abstract: Tuning the high-entropy perovskite as efficient and reliable electrocatalysts for oxygen evolution reaction
Open Access Paper

Optimization of the catalytic production of methyl stearate by applying response surface Box–Behnken design: an intensified green option for high-cetane biofuel manufacture

To enhance the efficiency of processes by decreasing the reaction severity and energy consumption and reducing the equipment size, facilities' space and operation cost, process intensification is an increasingly used option in the chemical industry.

Graphical abstract: Optimization of the catalytic production of methyl stearate by applying response surface Box–Behnken design: an intensified green option for high-cetane biofuel manufacture
Open Access Review Article

Advancements in enzyme immobilization on magnetic nanomaterials: toward sustainable industrial applications

Enzymes are widely used in biofuels, food, and pharmaceuticals.

Graphical abstract: Advancements in enzyme immobilization on magnetic nanomaterials: toward sustainable industrial applications
From the themed collection: 2024 Reviews in RSC Advances
Open Access Paper

Stereoselective Shi-type epoxidation with 3-oxo-4,6-O-benzylidene pyranoside catalysts: unveiling the role of carbohydrate skeletons

Sugar-derived chiral ketones are capable of reversing stereoselectivity in Shi-type epoxidation.

Graphical abstract: Stereoselective Shi-type epoxidation with 3-oxo-4,6-O-benzylidene pyranoside catalysts: unveiling the role of carbohydrate skeletons
37 items - Showing page 1 of 2

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