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Org. Chem. Front., 2016, Accepted Manuscript
DOI: 10.1039/C6QO00363J, Research Article
An efficient and facile method for the synthesis of ortho-cyanated diarylmethane by reaction of fluoroarene with arylacetonitrile in the presence of LDA (lithium diisopropylamide) at room temperature was developed. The...
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00237D, Research Article
Transition-metal-free, chemo- and regioselective aliphatic tertiary C–H bond azidation with good functional group tolerance is described.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00192K, Review Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
This review covers new developments in the transition metal-catalyzed allylic alkylations of non-stabilized enolates, preferentially generated from ketone, esters or amides.
 
Org. Chem. Front., 2016, Accepted Manuscript
DOI: 10.1039/C6QO00385K, Research Article
A highly efficient one-pot trifluoromethylation/cyclization reaction of conjugated enyne aldehydes and ketones was developed, which provide a modular access to highly substituted trifluoromethylated furans and 2,3-dihydrofurans. This method has the...
 
Rong Fu, Wen-Juan Hao, Ya-Nan Wu, Nan-Nan Wang, Shu-Jiang Tu, Guigen Li and Bo Jiang
Org. Chem. Front., 2016, Accepted Manuscript
DOI: 10.1039/C6QO00422A, Research Article
A new sulfonyl radical-triggered 6-endo-trig cyclization of unactivated 1,5-enynes under catalytic oxidation conditions for flexible synthesis of unprecedented unsymmetrical diaryl sulfones has been established. Using 2-arylalkynyl-1,1'-biphenyls, this transformation could also...
 
Org. Chem. Front., 2016, Accepted Manuscript
DOI: 10.1039/C6QO00318D, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
A highly efficient manganese-catalysed hydroperoxidation of carbon–carbon double bonds of enynes as well as styrene derivatives using N-hydroxyphthalimide, N-hydroxybenzotriazole or N-hydroxysuccinimide was developed. This reaction proceeded at room temperature through...
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00273K, Research Article
A substitutionally and configurationally inert octahedral chiral-at-metal iridium complex is reported to be an efficient catalyst for the enantioselective Friedel–Crafts alkylation of 2,5-disubstituted pyrroles at the β-position using nitroacrylates as electrophiles.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00206D, Review Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
Non-heteroatom-stabilized group 6 metal carbene complexes: versatile reagents or intermediates in stoichiometric or catalytic reactions in organic synthesis.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00215C, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
A new Pd-catalyzed alkene carboalkoxylation strategy for the preparation of 2,3-dihydrobenzofurans is described.
 
Org. Chem. Front., 2016, Accepted Manuscript
DOI: 10.1039/C6QO00304D, Research Article
A novel method to access triazole-fused spiro-guanidine from the reaction of isothiocyanate tethered N-sulfonyl-1,2,3-triazoles and amine has been developed. The reactions proceeded through a two-component tandem reaction including nucleophilic addition,...
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO90033J, Editorial
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
Honoring the 75th Birthday of Barry M. Trost.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00369A, Research Article
An effective and regioselective approach for C–H fluoroalkylation of 8-aminoquinoline amides with RfSO2Na is demonstrated herein.
 
Salvador Pérez-Estrada, Noel Sayar and Juan R Granja
Org. Chem. Front., 2016, Accepted Manuscript
DOI: 10.1039/C6QO00321D, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
Herein we report the facile construction of taxadiene precursors by ring closing dienyne metathesis (RCDEYM) of dienynes built on a cyclohexanenone with nantural configuration at C1 and its further transformation...
 
Fei-Hu Cui, Shi-Xia Su, Yan-li Xu, Ying Liang, Heng-shan Wang and Ying-Ming Pan
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00328A, Research Article
A sustainable strategy for the assembly of 4,5-disubstituted furan-2(5H)-ones directly from carbon dioxide from air was developed.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00261G, Highlight
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
Recent advances in ruthenium-catalysed hydrosilylation of C–C multiple bonds and its application to organic synthesis are highlighted.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00373G, Research Article
An isocyanide insertion approach to construct the pyrrolo[2,3-b]quinoline skeleton by an I2/CHP mediated reaction of aminome-thylenecyclo-propanes (amino-MCPs) is developed.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00367B, Research Article
We report herein a redox-neutral Cp*Co(III)-catalyzed cyclization of acetophenone N-Boc hydrazones with alkynes for streamlined synthesis of isoquinolines, accomplished via formation of a C–C and a C–N bond along with N–N bond cleavage.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00315J, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
A significant effect of the linker was observed on association chirality during the interpenetrative dimeric association of clothespin-shaped Pd complexes bearing either rigid or flexible linkers.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00255B, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
We describe the iron-catalyzed reductive cleavage of N–O-bonds in oxazines using malononitrile as reductant, which – in sequence with a [4 + 2]-cycloaddition – can be considered as an efficient way for the diastereoselective 1,4-aminohydroxylation of 1,3-dienes.
 
Carmine Gaeta, Paolo Della Sala, Carmen Talotta, Margherita De Rosa, Annunziata Soriente, Giovanna Brancatelli, Silvano Geremia and Placido Neri
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00336B, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
A resorcin[6]arene cavitand bearing sulfate bridges is herein reported. The host is able to interact with ammonium guests through the sulfate bridges.
 
Li Zhang, Changpeng Chen, Jian Han, Zhi-Bin Huang and Yingsheng Zhao
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00327C, Research Article
Ruthenium-catalysed C7-position alkynylation for indoline derivatives with various olefins was reported.
 
Fallia Aribi, Etienne Schmitt, Armen Panossian, Jean-Pierre Vors, Sergiy Pazenok and Frédéric R. Leroux
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00319B, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
The present work describes the unprecedented use of Fluoroalkyl Amino Reagents (FARs) to afford 2,4-bis(fluoroalkyl)-substituted quinoline derivatives in two steps under mild reaction conditions, in good yields and with a very good regioselectivity.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00275G, Research Article
6-Arylphenanthridines were synthesized in good to excellent yields from inexpensive and environmentally benign N-(2-aminoaryl)-diphenylmethanimine as a starting material under visible light-photocatalyzed conditions.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00249H, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
The oxidant–base bifunctionality of DEAD realized highly reliable cross dehydrogenative coupling of tetrahydroisoquinoline derivatives via aminal intermediates.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00320F, Research Article
Six thiostrepton (TSR) analogs, siomycin (SIO) and SIO-Dha2Ser were produced in the engineered TSR-producing strain by using a single “base”-based mutagenesis strategy.
 

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100 citations
In this review, a summary of transition metal-catalyzed C–H activation by utilizing the functionalities as directing groups is presented.
DOI: 10.1039/C5QO00004A
Published: 03 Jun 2015
44 citations
This review is focused on the recent advances in the transition metal-catalyzed direct remote C–H-functionalization of alkyl groups via C(sp3)–H bond activation. In general, carboxamide/ester-chelated β-functionalization reactions are summarized.
DOI: 10.1039/C4QO00207E
Published: 01 Dec 2014
11 citations
Primary alkyl bis-catecholato silicates have been successfully engaged with aryl and heteroaryl bromide substrates in photoredox/nickel dual catalysis to provide cross coupling products.
DOI: 10.1039/C6QO00014B
Published: 15 Feb 2016

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