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Journal cover: Organic Chemistry Frontiers

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Mariem Brahim, Imen Smari, Hamed Ben Ammar, Bechir Ben Hassine, Jean-François Soulé and Henri Doucet
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00093A, Research Article
The Pd-catalyzed arylation at the C5 position of N-protected pyrazole derivatives bearing bromo or iodo substituents at the C4 position is described.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO90028J, Correction
 
Zhi-Wei Jiao, Yong-Qiang Tu, Qing Zhang, Wen-Xing Liu, Shao-Hua Wang and Min Wang
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00109A, Research Article
An efficient formal synthesis of (−)-platensimycin was completed by using a tandem C–H oxidation/C–C coupling (cyclization)/rearrangement as the key step.
 
Qingquan Lu, Huamin Wang, Pan Peng, Chao Liu, Zhiyuan Huang, Yi Luo and Aiwen Lei
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00102A, Research Article
Spontaneous O2 fixation by just mixing activated alkenes and thiols at room temperature is rationally demonstrated.
 
Org. Chem. Front., 2015, Accepted Manuscript
DOI: 10.1039/C5QO00146C, Research Article
An efficient reductive Ugi-type reaction employing common secondary amides as starting material has been established. The reaction exhibited a broad substrate scope, good chemoselectivity and functional group tolerance and provides...
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00121H, Research Article
The mechanism and stereoselectivity of the NHC-catalyzed [4 + 2] annulation reaction of enals with azodicarboxylates have been investigated using the DFT method.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00110B, Research Article
A series of dirhodium complexes were synthesized and found to be effective chiral catalysts for nitrene and carbene transfer reactions.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00092K, Review Article
Recent progress in catalytic asymmetric synthesis of spirocyclopropyl oxindoles via organocatalysis and transition metal catalysis are summarized and discussed.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00096C, Research Article
A Pd-catalyzed intermolecular asymmetric hydroamination of styrenes was developed with pyridine-oxazoline as the chiral ligand.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00101C, Research Article
Chemoselective cleavage of the C(CO)–C(alkyl) bond in aryl ketones leading to azole amides is disclosed. Aryl ketones with a variety of long-chain alkyl groups have been demonstrated to be active substrates and mechanism studies suggested that molecular oxygen serves both as an oxidant and a reactant in this strategy.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00091B, Research Article
A palladium-catalyzed Heck cyclization and in situ hydrocarboxylation reaction was developed using chloroform as a one-carbon elongation reagent.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00106D, Research Article
The inexpensive Lewis acid AlCl3 was found to be an efficient catalyst for the O-alkylative Passerini reaction of isocyanides, cinnamaldehydes and alcohols.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00099H, Research Article
An efficient catalytic enantioselective Nazarov cyclization of divinyl ketoesters is developed using a BOX/Cu(II) catalyst, affording various optically active cyclopent-2-enone esters.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00127G, Research Article
An intramolecular rearrangement of vinylidenecyclopropanes to dimethylenecyclopropanes through C–C bond activation has been developed.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00049A, Research Article
C–C reductive coupling of rare five-coordinate rhodium(III) complexes has been studied in detail.
 
Bin Liu, Xuhu Huang, Xin Wang, Zemei Ge and Runtao Li
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00104H, Research Article
A palladium catalyzed ortho-acetoxylation of arenes is shown, using an amide-oxazoline as the directing group. The reactions are compatible with a variety of aryl and heteroaryl amides in moderate to good yields.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00108K, Research Article
A novel α-oxygenation reaction of carbonyl compounds was developed by utilizing the [1,2]-phospha-Brook rearrangement under Brønsted base catalysis.
 
Oana R. Luca, Jeffrey L. Gustafson, Sean M. Maddox, Aidan Q. Fenwick and Daryl C. Smith
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00075K, Review Article
The present review surveys current chemical understanding of catalysis by addition and removal of an electron.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO90023A, Correction
 
Lipeng Wu, Qiang Liu, Ralf Jackstell and Matthias Beller
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00071H, Research Article
The first ruthenium-catalyzed alkoxycarbonylation of alkenes with alcohols using carbon monoxide as carbonyl source is realized.
 
Xiaofei Zhang, Shuo Guo and Pingping Tang
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00095E, Research Article
A mild and practical unactivated aliphatic C–H fluorination reaction was reported without the use of transition metals.
 
Li Hui Lim and Jianrong (Steve) Zhou
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C5QO00015G, Research Article
A difficult Heck reaction of base-sensitive maleimides is realized by using a weak base in a carbonate solvent.
 

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