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Journal cover: Organic Chemistry Frontiers

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Wenju Chang, Jie Dai, Jingfu Li, yuan shi, Wen-Long Ren and Yian Shi
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C7QO00111H, Research Article
An effective palladium-catalyzed sequential carbonylation of olefins with formic acid is described. Ketones and the corresponding α,β-enones can be obtained with up to 90% yield. The reaction process is operationally...
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00636A, Research Article
A highly enantioselective bromohydroxylation of aryl olefins with flexible functionalities has been achieved with (DHQD)2PHAL as catalyst and H2O as nucleophile, giving a variety of optically active bromohydrins with up...
 
Xin He, Yi-zhu Xu, Ling-xuan Kong, Huan-huan Wu, De-zhong Ji, Zhi-bin Wang, Yun-gen Xu and Qi-hua Zhu
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00644B, Research Article
Direct regioselective halogenation of 8-amidoquinolines on the C5 position in the presence of NFSI and CuX under mild conditions.
 
Fen Zhao, Yaowen Liu, Shu Yang, Kai Xie and Jiang Jiang
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00834H, Research Article
Pd(OAc)2-catalyzed direct C–H arylation of arene triazole template has been explored using the triazole ring as a directing group. The N(3)-ortho C–H bond on C(4) aryl of 1,4-disubstituted 1,2,3-triazole can...
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00655H, Research Article
A simple and efficient method is established for the synthesis of perfluoroalkylated quinolines in the absence of any transition metal catalysts. The eco-friendly reaction reveals lower energy and time consumption....
 
Gang Li, Xulu Lv, Kexiao Guo, Ya Wang, suling yang, Liuyang Yu, Yantang Yu and Junjie Wang
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C7QO00004A, Research Article
We have developed meta-Selective CAr-H bond sulfonation of azoarenes with aryl sulfonyl chloride in the presence of the [Ru(p-cymene)Cl2]2 catalyst. Further reduction of the desired production provided meta-sulfonated aromatic amine....
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00042A, Research Article
Optically pure reagents that are able to deliver a trifluoromethylthio group with good to excellent enantioselectivities.
 
Yosuke Kimura, Ikumi Kawajiri, Masanori Ueki, Takayuki Morimoto, Jun-ichi Nishida, Hiroshi Ikeda, Mirai Tanaka and Takeshi Kawase
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00029D, Research Article
From themed collection Novel π-electron molecular scaffolds
A new fluorophore displays remarkable solvatofluorochromism, a CIEE effect, and an intense blue-green fluorescence in the presence of cyanide ions.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00806B, Research Article
A chiral ion-pair photoredox organocatalyst was reported to facilitate visible-light-meditated asymmetric anti-Markovnikov hydroetherification of alkenols with high reactivity and moderate enantioselectivity.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00820H, Research Article
A general and efficient approach to highly substituted butenolides through the annulation of keto acids and terminal alkynes is described.
 
Tian Li, Di Zhang, Ranran Wang, Yuanpeng Fan, Xinyan Guo, Shuai Liu, Yuguo Ma and Dahui Zhao
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00845C, Research Article
From themed collection Novel π-electron molecular scaffolds
A large π–conjugated macrocycle featuring a –[D–π–A]3– backbone is synthesized, exhibiting strongly solvent-dependent fluorescence and evident two-photon absorption ability.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00703A, Research Article
O-Homoallenylic α,β-unsaturated oximes were efficiently converted to the corresponding 2-alkenylpyridine derivatives by microwave irradiation.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00725B, Research Article
A copper(I)-catalyzed three-component reaction of sulfoximines, alkynes and azides is described, affording a variety of 1,2,3-triazolyl-5-sulfoximines in moderate to good yields.
 
Rafael Sandoval-Torrientes, Joaquín Calbo, David García-Fresnadillo, José Santos, Enrique Ortí and Nazario Martín
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00760K, Research Article
A series of new broad-absorbing rhodanine-fluorene dyes conjugated with triarylamines are presented. Spectroscopic and electrochemical characterizations, along with theoretical DFT calculations, unveil the electronic and optical properties of the dyes.
 
Dianpeng Chen, Gangdong Xing, Jinzhong Yao and Hongwei Zhou
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00675B, Research Article
A sequence of Sonogashira coupling, propargyl-allenyl isomerization, intramolecular addition and [3, 3] sigmatropic rearrangement affords thiophene derivatives.
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00851H, Research Article
Readily available triethylammonium thiolates were proven to be new and eco-friendly sulfenylating agents for the efficient and practical construction of sulfenylated indoles and pyrroles (48 examples) with good to excellent...
 
Lu-Ping Shao, Chang-Mei Si, Zhuo-Ya Mao, Wen Zhou, Tadeusz F. Molinski, Bang-Guo Wei and Guo-Qiang Lin
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00052A, Research Article
Symplocin A, a linear peptide has been synthesized for the first time employing our previously established ‘one-pot intramolecular tandem protocol’. Moreover, the stereochemistry of natural symplocin A was unambiguously revised through the confirmation by 1D NMR, 2D NMR, and HPLC comparisons with an authentic natural product.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00793G, Research Article
Synthetic and mechanistic studies on Rh-catalyzed C–H activation of amides with isocyanates, resulting in one of the unsymmetric diamine products showing promising anti-cancer activity.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00822D, Research Article
An iodine(III)-induced regioselective carbocyclization of functionally substituted terminal alkynes to afford 1,1-diiodomethylene substituted cyclic compounds is reported.
 
Lu Li, Bingbing Li, Chunli Li, Zhiying Ma, Li Xu and Hua Wang
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00754F, Research Article
The sequential lithiation mechanism for the selective deprotonation of tetra[3,4]thienylene (1) to form Li4-1 in the present of n-BuLi in THF is investigated.
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C7QO00075H, Research Article
Facile assembly of 3-((arylsulfonyl)methyl)indolin-2-ones via insertion of sulfur dioxide starting from anilines, N-arylacrylamides, and DABCO•(SO2)2 is developed. This one-pot reaction proceeds efficiently in dichloroethane, leading to sulfonated oxindoles in good...
 
Xiaolong Sun, Maria Odyniec , Adam C Sedgwick, Karel Lacina, Suying Xu, Taotao Qiang, Steven Bull, Frank Marken and Tony D. James
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00448B, Research Article
Based on the complexation of phenylboronic acid (PBA) with Alizarin Red S (ARS), we developed a new and valid chemosensor for the detection of hydrogen peroxide in an aqueous media....
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00713A, Research Article
Theoretical studies reveal the role of a dirhodium catalyst in the expansion reactions of azide tethered methylenecyclopropanes and account for the origin of product selectivity.
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C7QO00098G, Research Article
From themed collection Novel π-electron molecular scaffolds
Selective insertion of a CH2 or NH group at the 5,6-junction on the C59N skeleton is achieved through PCl5 induced reaction of a CH2OH or NHOH group on the cage...
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00785F, Research Article
A highly enantioselective synthesis of (−)-lamenallenic acid utilizing the recently developed EATA reaction and aerobic oxidation reaction has been accomplished.
 

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197 citations
In this review, a summary of transition metal-catalyzed C–H activation by utilizing the functionalities as directing groups is presented.
DOI: 10.1039/C5QO00004A
Published: 03 Jun 2015
34 citations
Recent advancements in the condensation of alcohols with pronucleophiles by the Mitsunobu reaction are described.
DOI: 10.1039/C5QO00016E
Published: 17 Mar 2015
22 citations
Primary alkyl bis-catecholato silicates have been successfully engaged with aryl and heteroaryl bromide substrates in photoredox/nickel dual catalysis to provide cross coupling products.
DOI: 10.1039/C6QO00014B
Published: 15 Feb 2016

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