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Mi-Na Zhao, Le Yu, Nan-Fang Mo, Zhi-Hui Ren, Yao-Yu Wang and Zheng-Hui Guan
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00809G, Research Article
An efficient iron-catalyzed cyclization of ketoxime acetates with N,N-dimethylaniline for the synthesis of symmetrical pyridines has been developed. A methyl carbon on N,N-dimethylaniline performed as a source of one carbon...
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00671J, Research Article
The rhodium-catalyzed intermolecular [3+2] cycloadditions of vinylaziridines with allenes represent an efficient method for the synthesis of biologically and pharmaceutically relevant chiral methylene pyrrolidines. In this report, the reaction mechanism...
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00654J, Research Article
The regioselective and highly efficient electrochemical method for direct acylation and carboxylation of a [60]fulleroindoline has been developed. By using inexpensive and readily available acyl chlorides and chloroformates, both keto...
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00865H, Research Article
A catalytic enantioselective hydroxyamination of α,β-unsaturated 2-acyl imidazoles with N-protected hydroxyl amines catalyzed by chiral-at-metal Rh (III) complex (0.5-2 mol%) have been developed. The approach affords valuable N-Boc protected β-amino...
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00867D, Research Article
From themed collection Novel π-electron molecular scaffolds
A new method based on the palladium-catalyzed tandem reaction for the fast construct of a dianthraceno[a,e]pentalene (DAP) framework is developed, which showed good functional group tolerance and gave a series...
 
Kui Lu, Ke Yang, Xiaoliang Jia, Xing Gao, Xia Zhao, Guojun Pan, Yantao Ma, Qiyao Huang and Peng Yu
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00726K, Research Article
The first total synthesis of I3,II8-biapigenin and ridiculuflavone A via key steps of regioselective iodination, Sonogashira reaction, and rhodium-catalyzed oxidative coupling with the overall yields of 31% and 22%, respectively,...
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00734A, Research Article
Cyclopropenones were first applied as potential 3C synthons in ring-opening formal cycloaddition with isatins via an organocatalytic C–C bond activation strategy.
 
V. M. Tsefrikas, A. K. Greene and L. T. Scott
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00831C, Research Article
From themed collection Novel π-electron molecular scaffolds
The first azacorannulene with a nitrogen on the rim, has been synthesized in seven steps from 4-bromoisoquinoline.
 
Yang Li, Dong Huai Tu, bo wangbo, juyou lu, Yao-Yu Wang, Zhao-Tie Liu, Zhong-Wen Liu and Jian Lu
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C7QO00001D, Research Article
By using N,N-dimethylformamide (DMF) as CO source, the cheap metal nickel-catalyzed carbonylation of arylboronic acids was demonstrated as an efficient and facile protocol for synthesis of diarylketones. Results indicated that...
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00871B, Research Article
From themed collection Novel π-electron molecular scaffolds
Naphtho[2,3-b]thiophene diimide (NTI) was found to be selectively thionated to afford naphtho[2,3-b]thiophene-4,9-dicarboxy-5,8-dithiocarboxydiimide (NTI-2S). By elucidating its electrochemical, optical, and structural properties, the effects of thionation on the molecular electronic structure...
 
Jun Huang, Linyong Li, Haoguo Chen, Tiebo Xiao, Yuwei He and Lei Zhou
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00813E, Research Article
A silver-catalyzed three-component reaction of diazoketones, anilines and NFSI is developed. The reaction provides a new method for gem-aminofluorination of acceptor diazo compounds with aniline as the nitrogen source and NFSI as the fluorine source.
 
José Almeida, António Aguiar, Andreia Leite, André M. N. Silva, Luís Cunha-Silva, Baltazar de Castro, Maria Rangel, Giampaolo Barone, Augusto C. Tomé and Ana M. G. Silva
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00771F, Research Article
Mixed bisadducts resulting from the sequential addition of a nitrone and an azomethine ylide to the porphyrin macrocycle were efficiently obtained, in a site selective approach.
 
Weilong Wu, Yun Xie, Pan Li, Xiuxiu Li, Yuanhua Liu, Xiu-Qin Dong and Xumu Zhang
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00810K, Research Article
We successfully applied f-amphox ligands to the Ir-catalyzed asymmetric hydrogenation of α-hydroxy ketones to afford chiral 1,2-diols with excellent results.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00533K, Research Article
AgNO3-catalyzed direct C–H arylation of quinolines by oxidative decarboxylation of aromatic carboxylic acids to afford aryl quinoline derivatives in moderate yields was described.
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00854B, Research Article
The AgNO3-catalyzed reactions of unactivated alkenes with acetic acid and Selectfluor reagent in aqueous solution afforded the corresponding γ-fluorinated carboxylic acids under mild conditions. The carbofluorination was not only efficient...
 
Dongdong Xu, Xiaotian Qi, Meng Duan, Zhaoyuan Yu, Lei Zhu, Chunhui Shan, Xiaoyu Yue, Ruopeng Bai and Yu Lan
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00841K, Research Article
Density functional theory (DFT) method M06-L was used to study the general mechanism of palladium-catalyzed C–S bond formation reactions. Our theoretical calculations revealed that this type of reaction starts with...
 
Yingqian Duan, Muliang Zhang, Rehanguli Ruzi, Zhongkai Wu and Chengjian Zhu
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00711B, Research Article
The direct decarboxylative allylation of N-arylglycine derivatives has been accomplished via visible-light photoredox catalysis.
 
Andreas Baur, Katelyn A. Bustin, Ellen Aguilera, Jeffrey L. Petersen and Jessica M. Hoover
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00678G, Research Article
A copper(II) benzoate complex is a viable intermediate for copper-catalyzed oxidative decarboxylative coupling reactions.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00775A, Research Article
A phosphine-mediated γ-umpolung/Wittig/γ-umpolung reaction between phthalimidomalonates and allenoates/but-2-ynoate furnishes highly functionalized pyrroloisoindolinone derivatives in synthetically useful yields.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00730A, Research Article
A highly site-selective oxidative C–H sulfonylation method for 8-acylaminoquinolines and anilides with sulfonyl chlorides has been developed, which provided C5-sulfonylated quinolines and para-sulfonylated anilides respectively.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00739B, Research Article
A new arylation/nucleophilic addition/fragmentation/C–S bond formation cascade was developed using isothiocyanates and diaryliodonium salts.
 
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00681G, Research Article
A one-pot approach with the substrate-driven selective and competitive reactivity of ortho-trifloxy, iodo or bromo functionalized gem-dibromovinylarenes was studied under Pd-catalyzed conditions.
 
Kwan Yin Cheung, Shuaijun Yang and Qian Miao
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00828C, Research Article
From themed collection Novel π-electron molecular scaffolds
Herein we report a new strategy to construct nano-rings of sp2 carbon by taking advantage of the “C” shape of syn-tetrabenzoheptafulvalene. This strategy led to successful synthesis of a sp2...
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00812G, Research Article
We describe the total synthesis of (±)-berkeleyamide D using a biosynthetically inspired strategy. The spirocyclic core of berkeleyamide D was constructed via sequential epoxidations and a late stage base mediated...
 
Org. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QO00677A, Research Article
A series of highly modular chiral axial-unfixed biphenyl phosphine-oxazoline ligands were developed via simple synthetic route using readily available (S)-(+)-2-phenylglycinol as starting material. Modular oxazoline motifs can be efficiently constructed...
 

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173 citations
In this review, a summary of transition metal-catalyzed C–H activation by utilizing the functionalities as directing groups is presented.
DOI: 10.1039/C5QO00004A
Published: 03 Jun 2015
56 citations
This review is focused on the recent advances in the transition metal-catalyzed direct remote C–H-functionalization of alkyl groups via C(sp3)–H bond activation. In general, carboxamide/ester-chelated β-functionalization reactions are summarized.
DOI: 10.1039/C4QO00207E
Published: 01 Dec 2014
20 citations
Primary alkyl bis-catecholato silicates have been successfully engaged with aryl and heteroaryl bromide substrates in photoredox/nickel dual catalysis to provide cross coupling products.
DOI: 10.1039/C6QO00014B
Published: 15 Feb 2016

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