Journal cover: Organic Chemistry Frontiers

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Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00238E, Research Article
Allylic amination of allylic carbonates with ammonia gas or aqueous ammonia was successfully carried out using (SIPr)Pd(allyl)Cl as catalyst and Ph3P, which is essential for the reaction. The aqueous ammonia...
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QO00248B, Research Article
From themed collection Celebrating the 80th Birthday of Professor Ei-ichi Negishi
Oxidative C–H amination has proved to be an efficient strategy to construct pyrido[2′,1′:2,3]imidazo[4,5-b]indoles and their π-expanded analogs.
 
Tao Tu, Shuangliang Liu, Qinyue Deng, Weiwei Fang, Jun-Fang Gong, Mao-Ping Song and Mizhi Xu
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00253A, Research Article
By using a robust acenaphthoimidazolyidene palladium complex (Pd-NHC 1), a scalable approach to access a variety of chiral, pharmaceutical and structure intriguing N-substituted phthalimides via double aminocarbonylation has been established...
 
Arun Kumar Sinha, Bibhas Mondal, Mousumi Kundu, Biswajit Chakraborty and Ujjal Kanti Roy
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00235K, Research Article
Electrochemical synthesis, characterization and reactivity of a wire-shaped nano zinc architecture.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00161C, Review Article
The plants of the Trigonostemon genus (Euphorbiaceae family) comprising about 50 species are mainly distributed in tropical and subtropical Asia.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00223G, Research Article
Intramolecular annulations of allenes towards furans to give six-membered ring fused furans with gold and platinum catalysts have been developed.
 
Qingjiang Li, Xiao-Shui Peng and Henry N. C. Wong
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00242C, Research Article
From themed collection Celebrating the 80th Birthday of Professor Ei-ichi Negishi
A simple and efficient approach for the synthesis of disubstituted carbazoles has been developed from o-haloanilines and terminal alkynes using a two-step strategy, namely, Sonogashira coupling and intramolecular cyclization.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00229F, Research Article
A photoinduced highly efficient C–Si bond cleavage reaction of benzylsilanes under the catalysis of HBr was developed. The in situ generated benzyl radical intermediates were aerobically oxidized into benzoic acids highly chemoselectively.
 
See-Wing Lo, Edwin Law, Matthew Y. Lui, Xi-Guang Wei, Kai-Chung Lau, Chui Y. Ma, Margaret B. Murphy and István T. Horváth
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00192C, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
Nonafluoro-t-butyl propyl (1), allyl (2), and propargyl (3) ethers as well as bis(nonafluoro-t-butoxy) ethane (4), propane (5), and butane (6) were prepared by the reaction of sodium nonafluoro-t-butoxide (7) with the corresponding alkyl halides.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00214H, Research Article
The Pd-catalysed oxidation reactions of alcohols and their domino oxidation–arylation reactions using phenyl chloride as an oxidant have been computationally investigated.
 
Thanh Binh Nguyen, Ludmila Ermolenko, Mathilde Corbin and Ali Al-Mourabit
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00221K, Research Article
Fe/S clusters generated in situ from simple iron salts and sulfur S8 were found to be highly efficient to catalyze the decarboxylative redox condensation of arylacetic acids with nitroarenes in the presence of N-methylpiperidine as a basic additive.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00205A, Research Article
The copper-catalyzed direct C–H cyanation reaction of 2-phenylpyridines using O2 as the oxidant is realized. DMF participates as both the solvent and reagent which provides both the “C” and “N” units in the generated “CN” group in this cyanation transformation.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00208C, Review Article
From themed collection Celebrating the 80th Birthday of Professor Ei-ichi Negishi
Axially chiral allenes are an important class of molecules widely existing in nature and also valuable chiral building blocks for organic synthesis. With more and more new protocols for racemic allenes and new chiral ligands being developed, a wide variety of novel and challenging transformations have been recently unveiled for the synthesis of this type of highly versatile compounds. In this review, we present a critical account of the enantioselective synthesis of axially chiral allenes.
 
Louis Fensterbank and Corinne Aubert
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO90034K, Editorial
From themed collection In Celebration of Max Malacria’s 65th Birthday
Professor Max Malacria, Université Pierre et Marie Curie (UPMC), is celebrating his 65th birthday this year, and this themed collection marks this exciting occasion.
 
Paul A. Wender, Alison D. Axtman, Jennifer E. Golden, Jung-Min Kee, Lauren E. Sirois, Ryan V. Quiroz and Matthew C. Stevens
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00228H, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
We describe here step-economical, function-oriented strategies towards the syntheses of potent kinase inhibitors inspired by the natural product staurosporine.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00233D, Research Article
A robust catalyst derived from NiCl2·(DME) and acenaphthoimidazolium chloride exhibited high activity towards the challenging amination of bulky and heterocyclic aryl tosylates with secondary and primary amines under mild reaction conditions.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00196F, Research Article
Using an oxidizing directing group, a mild RuII-catalyzed direct coupling of N-phenoxypivalamide with internal alkynes was developed, generating the benzofurans in moderate to high yields.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00210E, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
The first example of the application of a chiral DMAP catalyst for allylic substitution of MBH carbonates.
 

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