Journal cover: Organic Chemistry Frontiers

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Jianhui Chen, Tuo Xi, Xiang Ren, Biao Cheng, Jun Guo and Zhan Lu
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00295D, Research Article
The chiral iminopyridine oxazoline (IPO) ligands were designed, synthesized and utilized for the first cobalt-catalyzed highly regio- and enantioselective anti-Markovnikov hydroboration of 1,1-disubstituted aryl alkenes. This novel IPO ligands will...
 
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00245H, Review Article
This review highlights the recent applications of chiral N-tert-butanesulfinyl imines and chiral diene ligands, with bicyclo[3.3.0]octadiene and dicyclopentadiene skeletons, in asymmetric chemical transformations. The chiral sulfinamide-olefin products from allylation of...
 
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00246F, Research Article
Diaryldifluoromethanes constitute a distinct class of fluorinated compounds in medicinal chemistry. But only limited methods to access such a structural motif have been reported. Herein, we demonstrate the first example...
 
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00256C, Research Article
In this Article, we report the first examples of carbofluorination of unactivated alkenes. Under the catalysis of AgNO3, the reactions of unactivated alkenes with Selectfluor reagent and active methylene compounds...
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QO00251B, Research Article
Alkylarylation of N-arylacrylamides with alkyl halides through selective scission of the C(sp3)–H bond adjacent to halide atoms is presented.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QO00250D, Research Article
A novel one-step synthesis of both symmetric and unsymmetric 2,2′-bisoxazoles starting from simple acyclic α-isocyanoacetamides was achieved.
 
Jing-Rui Zhao, Xiaolong Yuan, Zhaoyan Wang, Zhan-Xin Zhang, Shi-Wu Chen and Weihua Xue
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00255E, Research Article
Cbz-protected N-benzyl-progargylamine is easily synthesized and described as a benzylating reagent. The treatment of the novel reagent with various alcohols in the presence of IPrAuNTf2 catalyst affords benzyl ethers in...
 
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00244J, Research Article
From themed collection Celebrating the 80th Birthday of Professor Ei-ichi Negishi
We describe a novel and useful method to provide 1H-indazoles via copper-catalyzed tandem reaction which is triggered by Ullmann-type reaction and followed by N-N bond formation. Arylamines, alkylamines and sulfonamides...
 
Yun-Long Ji, Jin-Hong Lin, Ji-Chang Xiao and Yu-Cheng Gu
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QO00240G, Research Article
Copper-catalyzed tandem trifluoromethylation/cyclization of internal alkynes with Umemoto's reagent leading to 3-trifluoromethyl-1,2-dihydronaphthalene derivatives in moderate to good yields is described.
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QO00243A, Research Article
Dicyclen–TPE conjugates were developed as novel fluorescent chemosensors for PPi sensing, which could selectively respond to PPi over other phosphate-based anions in 100% aqueous medium with a detection limit of 22.8 nm.
 
Shuangliang Liu, Qinyue Deng, Weiwei Fang, Jun-Fang Gong, Mao-Ping Song, Mizhi Xu and Tao Tu
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00253A, Research Article
A scalable approach to access various pharmaceutical and structurally intriguing N-substituted phthalimides via double aminocarbonylations has been established under atmospheric CO pressure with a robust Pd-NHC complex at a low catalyst loading.
 
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00238E, Research Article
Allylic amination of allylic carbonates with ammonia gas or aqueous ammonia was successfully carried out using (SIPr)Pd(allyl)Cl as catalyst and Ph3P, which is essential for the reaction. The aqueous ammonia...
 
Org. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QO00248B, Research Article
From themed collection Celebrating the 80th Birthday of Professor Ei-ichi Negishi
Oxidative C–H amination has proved to be an efficient strategy to construct pyrido[2′,1′:2,3]imidazo[4,5-b]indoles and their π-expanded analogs.
 
Arun Kumar Sinha, Bibhas Mondal, Mousumi Kundu, Biswajit Chakraborty and Ujjal Kanti Roy
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00235K, Research Article
Electrochemical synthesis, characterization and reactivity of a wire-shaped nano zinc architecture.
 

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