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Journal cover: Organic Chemistry Frontiers

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Xin Xiao, Zhong-Zheng Gao, Jing Zhang, Nana Sun, Ying Huang, Zhu Tao and Jianzhuang Jiang
Org. Chem. Front., 2016, Accepted Manuscript
DOI: 10.1039/C6QO00310A, Research Article
A novel supramolecular polymer Q[14]-TBPyP was successfully constructed from the host twisted cucurbit[14] (Q[14]) molecule and a four-arm 5,10,15,20-tetrakis(N-butyl-4-pyridinium)porphyrin tetrabromide (TBPyP) guest molecule depending on the host-guest interactions and characterized...
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00284F, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
An iterative asymmetric hydration of dienoates approach to Leucasndrolide A was explored.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00199H, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
Polypropionates are synthesized using a combination of a copper-catalyzed asymmetric allylic alkylation, ruthenium-catalyzed cross-metathesis and iridium-catalyzed asymmetric allylic etherification.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00253F, Research Article
MeOTf-catalyzed arylalkyne–aldehyde metathesis and Nazarov cyclization represent a sustainable and atom-economical approach for the construction of indanones with high stereoselectivity.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00277C, Research Article
Selective palladium diacetate-catalyzed α- and β-arylations of the furan rings of (ortho-bromophenyl)furan-2-yl-methanones 1 under two different conditions are reported.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00270F, Research Article
A palladium-catalyzed highly efficient and atom-economical intramolecular cross dehydrogenative coupling (CDC) reaction to access fused polyheterocycles containing a coumarin nucleus has been developed.
 
Org. Chem. Front., 2016, Accepted Manuscript
DOI: 10.1039/C6QO00187D, Research Article
This paper describes an easy access to carboxylic acids via Pd-catalyzed hydrocarboxylation of olefins with HCOOLi and Ac2O under mild conditions without using external CO gas.
 
Shuangshuang Duan, Dan Long, Changgui Zhao, Gaoyuan Zhao, Ziyun Yuan, Xingang Xie, Jianguo Fang and Xue Gong She
Org. Chem. Front., 2016, Accepted Manuscript
DOI: 10.1039/C6QO00222F, Research Article
An efficient approach for the synthesis of 9/6/6 tricyclic structure of Lycopodium alkaloid palhinine A has been accomplished. The developed synthetic route features oxidative dearomatization and tandem hydroxyl oxidation/intramolecular Diels-Alder...
 
Caiyou Chen, Xiu-Qin Dong and Xumu Zhang
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00233A, Review Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
This review covers the recent studies featuring the development of catalysts for alkene hydroaminomethylation.
 
José Miguel Alonso, María Teresa Quirós and María Paz Muñoz
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00207B, Review Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
This review covers chirality transfer in metal-catalysed intermolecular addition reactions involving allenes, including axial-to-central chirality transfer, asymmetric catalysis and racemization.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00203J, Research Article
Pd mediated one pot sequential Sonogashira coupling followed by annulation using o-alkynyl aldehyde is reported.
 
Huanhuan Liu, Tianran Zhai, Shiteng Ding, Yalei Hou, Xiangyu Zhang, Lei Feng and Chen Ma
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00231E, Research Article
New method for synthesis of 2-hetarylquinazolin-4(3H)-ones from 2-aminobenzamides and (2-azaaryl)methanes under transition-metal free conditions, featuring a wide substrate scope with a broad range of functional group tolerance under mild conditions.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00248J, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
Careful consideration of the chemical mechanism for an oxidative condensation reaction led to improved current flow for the electrolysis.
 
Susan M. Stevenson, Eric T. Newcomb and Eric M. Ferreira
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00224B, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
Platinum- and iridium-catalyzed cycloisomerizations of 1,6 enynes that proceed via a C–C bond migration into a carbenoid intermediate are described.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00204H, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
A series of tetraphenylethene derivatives with through-space conjugation and aggregation-enhanced emission properties are synthesized and studied.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00208K, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
The diastereo- and enantioselective synthesis of cyclohexanone-fused spirospyrazolones through an asymmetric Michael/Michael/aldol cascade reaction catalyzed by squaramide and diphenylprolinol silyl ether, followed by a sequential oxidation was developed.
 
Io Sato, Hirotsugu Suzuki, Yasuhiro Yamashita and Shū Kobayashi
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00242K, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
Catalytic asymmetric 1,4-addition reactions of simple esters have been developed. The desired reactions proceeded smoothly with high enantioselectivities.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00227G, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
A new type of phosphoramidite-thioether ligand has been developed for Pd-catalysed asymmetric C-3 allylic alkylation of indoles with excellent yields and enantioselectivities.
 
Hideki Abe, Takuma Hikichi, Kosuke Emori, Toyoharu Kobayashi and Hisanaka Ito
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00213G, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
The asymmetric total synthesis of the optically pure catunaregin was accomplished in 7 steps from a known methyl ester using an asymmetric syn-selective aldol reaction and the successive ketalization of a furan diol derivative under acidic conditions.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00210B, Review Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
With the advent of directed evolution of stereoselective enzymes almost 20 years ago and the rapid development of this exciting area of research, the traditional limitations of biocatalysts in organic chemistry have been eliminated.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00178E, Research Article
From themed collection HOT articles in Organic Chemistry Frontiers in 2016
Pd-catalyzed difluoroallylation of unactivated C(sp2)–H bonds with readily available Rf-Br reagents is described.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00153J, Review Article
Recent advances in photoinduced trifluoromethylation and difluoroalkylation under photocatalysis are summarized. Most of the photoredox reactions proceed efficiently under mild conditions with simple operation. Various fluorinated reagents are developed and applied in different transformations.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00139D, Chemistry Frontiers
Photoredox catalysis is a versatile strategy for difunctionalization of carbon–carbon multiple bonds.
 
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00130K, Research Article
From themed collection Celebrating the 75th Birthday of Professor Barry Trost
Complementary diastereoselectivity for C–H and C–C bond formation, in para disposition, leading to one indenonaphthacene derivative: proton versus potassium assistance.
 

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94 citations
In this review, a summary of transition metal-catalyzed C–H activation by utilizing the functionalities as directing groups is presented.
DOI: 10.1039/C5QO00004A
Published: 03 Jun 2015
89 citations
This review focuses specially on the use of monodentate nitrogen-based directing group for C–H functionalization published during the past 2 years (2012–2013).
DOI: 10.1039/C4QO00068D
Published: 14 May 2014
44 citations
This review is focused on the recent advances in the transition metal-catalyzed direct remote C–H-functionalization of alkyl groups via C(sp3)–H bond activation. In general, carboxamide/ester-chelated β-functionalization reactions are summarized.
DOI: 10.1039/C4QO00207E
Published: 01 Dec 2014

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