Journal cover: Organic Chemistry Frontiers

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Zhang-Jie Shi, Xi-Sha Zhang, Yun-Fei Zhang and Kang Chen
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00172A, Research Article
Oxidant-controlled selective mono-/di- alkenylation of aryl C-H bonds via Pd-catalysis were reported with broad substrate scope. As a unique directing group, thioether can be transformed to sulfoxide by simple oxidation...
 
Zhenbo Mo, Zhenwu Ouyang, Lei Wang, Kathlyn L. Fillman, Michael L. Neidig and Liang Deng
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00175C, Research Article
Monodentate aminocarbene ligands, both NHC and cAAC, are capable of stabilizing low-coordinate iron(I) compounds.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00189C, Highlight
New members in the family of organophosphorus compounds: convenient synthesis and reactivity of the 2-phosphaethynolate anion are highlighted.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00201F, Research Article
A dearomatization strategy of anilines involving an imino exchange as the key step was developed to prepare N-acyl-diarylamines and phenothiazines.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00203B, Research Article
Functionalized imidazoliniums were synthesized efficiently from the three-component domino reaction of N-formylmethyl-substituted tertiary amides and enamides with amines and isocyanides.
 
Xuesong Wang, Guolin Cheng, Jinhai Shen, Xifa Yang, Ming-e Wei, Yadong Feng and Xiuling Cui
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00174E, Research Article
A novel and environmentally benign protocol for diaryl-1,2-diketones was developed.
 
Amandine Xolin, Arnaud Stévenin, Mathieu Pucheault, Stéphanie Norsikian, François-Didier Boyer and Jean-Marie Beau
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00183D, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
Efficient glycosylation reactions of peracetylated β-D-N-acetyl glycosamines are described using catalytic iron(III) triflate under microwave conditions or in a continuous flow process.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00182F, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
Near-infrared absorbing heterocyclic quinoid molecules have been developed as donor materials for organic photovoltaic devices.
 
Xiaoxi Zhou, Chunhong Zhang, Yu-Mei Lin, Xumin He, Yan Zhang, Jianbo Wang and Haiping Xia
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00152D, Research Article
Reactions of the ruthenium vinyl carbene complex [Ru{CHC(PPh3)CH(2-Py)}Cl2PPh3]BF4 (1) with five propargyl alcohols HC≡CC(OH)R1R2, (R1 = R2 = Ph; R1 = Ph, R2 = CH3; R1 = H, R2 =...
 
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00198B, Research Article
Flow regime was implemented as a non-chemical alternative of the reaction control and detrimental acid byproduct sequestration in transition metal catalyzed cross-coupling reactions. The concept was illustrated on the Sonogashira...
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00191E, Research Article
This work reports on selective generation and synthetic applications of functionalized Grignard reagents (1-iodo-4-MgCl-1,3-dienes and 1-iodovinyl phenylmagnesium chlorides).
 
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00202D, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
A metal-free reductive procedure for decyanation of malononitriles and cyanoacetates, using photoactivated organic electron donors, is described. Decyanation of cyanoacetates is more difficult than for malononitriles and it requires higher...
 
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00209A, Review Article
1-Amino-isoquinoline-N-oxides are generated under mild conditions through a silver(I) and copper(I) co-catalyzed reaction of 2-alkynylbenzaldoxime with secondary amines. The reaction proceeds smoothly at room temperature under air, leading to the...
 
Guillaume Prestat, Anne-Doriane Manick, Guillaume Duret, Diem Ngan Tran and Farouk Berhal
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00179F, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
Palladium-catalyzed amino and oxyacetoxylation have been developed to furnish 1,4-benzodiazepinones and 1,4-benzoxazepinones through diheterofunctionalization of alkenes. This study demonstrates the ability of this new methodology to allow 7-exo ring-closure.
 
Org. Chem. Front., 2014, Accepted Manuscript
DOI: 10.1039/C4QO00180J, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
A small library of fine-tunable monodentate phosphoramidite (MPN) ligands was found useful in selecting a highly efficient chiral ligand for the enantioselective Pd-catalyzed tandem allylic alkylation reaction. The reaction gave...
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00178H, Research Article
The kinetic resolution of 4-substituted-3,4-dihydrocoumarins was realized via a Pd-catalyzed allylic substitution reaction, affording optically active mono- and trans-3,4-disubstituted dihydrocoumarin derivatives in high yields with high ee values.
 
François Godin, Martin Duplessis, Cindy Buonomano, Thao Trinh, Karine Houde, Daniel Chapdelaine, Jacques Rodrigue, André Boutros and Yvan Guindon
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00142G, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
A sequence of Mukaiyama aldol and radical hydrogen transfer reactions was applied to α-alkoxy and α-aminoaldehydes for the synthesis of propionate motifs and subunits thereof.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00134F, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
A facile approach for the synthesis of benzo[3.1.0]bicycloalkanes via alkylation/cyclopropanation cascade reactions of benzyl bromide with triphenylphosphonium bromide.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00213J, Research Article
Aryl triazenes were coupled with heteroarenes via C–H functionalization to produce heterobiaryls in moderate to good yields at ambient temperature.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00187G, Highlight
From themed collection In Celebration of Max Malacria’s 65th Birthday
Cycloaddition reactions are powerful tools in synthetic chemistry.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00181H, Highlight
In this highlight, recent advances in the rational bottom-up chemical synthesis of three-dimensional (3-D) conjugated carbon nanostructures are presented.
 
Buddha B. Khatri, Svitlana Kulyk and Scott McN. Sieburth
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00190G, Research Article
From themed collection In Celebration of Max Malacria’s 65th Birthday
Polycyclic aromatics undergo [4 + 4] photocycloaddition to give tricyclic polyene products.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00165F, Research Article
The I2-mediated oxidative dimerization of tetrahydropyrroloindoles allows the convenient and efficient synthesis of target molecules.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00188E, Research Article
The achiral counteranions of chiral cationic Ru-diamine complexes regulated both the enantioselectivity and regioselectivity in the asymmetric hydrogenation of 3-substituted-2H-1,4-benzoxazines.
 
Org. Chem. Front., 2014, Advance Article
DOI: 10.1039/C4QO00132J, Research Article
A new triphosphorus ligand, Tribi, for regioselective linear hydroformylation of terminal and internal olefins with excellent catalytic activity and regioselectivity.
 

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