Journal cover: Inorganic Chemistry Frontiers

INORGANIC
CHEMISTRY

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Zelin Sun, Erlin Yue, Mengnan Qu, Irina V. Oleynik, Ivan I. Oleynik, Kanshe Li, Tongling Liang, Wenjuan Zhang and Wen-Hua Sun
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00162A, Research Article
Cycloalkyl-modified 8-arylimino-5,6,7-trihydroquinolylnickel pre-catalysts highly polymerize ethylene into branched polyethylene waxes.
 
Wen-Yang Gao, Sathvik Palakurty, Lukasz Wojtas, Yu-Sheng Chen and Shengqian Ma
Inorg. Chem. Front., 2015, Accepted Manuscript
DOI: 10.1039/C4QI00240G
From themed collection Crystal engineering for molecular materials
Open metal sites are devised to dangle on cobalt trigonal prismatic secondary building units of a porous MOF which is constructed from the rigid octacarboxylate ligand of 1,3,6,8-tetra(3,5-dicarboxylphenyl)pyrene; and the...
 
Sourav Chakraborty, Sourav Bhowmick, Jianqiu Ma, Hongwei Tan and Neeladri Das
Inorg. Chem. Front., 2015, Accepted Manuscript
DOI: 10.1039/C4QI00211C
Design, synthesis and characterization of two new triptycene containing ditopic Pt(II) organometallic complexes are being reported. These complexes comprise of two peripheral bis(trans-trialkylphosphine)platinum units either directly σ-bonded to the central...
 
Hua Lin, Jin-NI Shen, Yong-Fang Shi, Long-Hua Li and Ling Chen
Inorg. Chem. Front., 2015, Accepted Manuscript
DOI: 10.1039/C4QI00202D
New quaternary selenides, Cs[RE9Mn4Se18] (RE = Ho–Lu), have been synthesized by high temperature solid state reactions of elements with reactive CsCl flux. These compounds adopt the BaV13O18-structure type in the...
 
Flavia Artizzu, Francesco Quochi, Angela Serpe, Elisa Sessini and Paola Deplano
Inorg. Chem. Front., 2015, Accepted Manuscript
DOI: 10.1039/C4QI00188E, Chemistry Frontiers
An overview of the different strategies proposed for the preparation of heterolanthanide assemblies suitable to work as (multi-) functional materials, with spotlights on the structure/property relationship, is provided. Three classes...
 
Inorg. Chem. Front., 2015, Accepted Manuscript
DOI: 10.1039/C4QI00125G
A series of inorganic acids were introduced into the self-assembly with the bent 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (4-bpo), yielding seven anion-assisted supramolecular salts, i.e. [(4-H2bpo2+) • (NO3−)2] • 2H2O (1), (4-H2bpo2+) • (HPO42−)...
 
Inorg. Chem. Front., 2015, Accepted Manuscript
DOI: 10.1039/C4QI00175C
From themed collection Crystal engineering for molecular materials
Luminescent two dimensional coordination polymers {[Cd(SDB)(H2O)].3H2O}n 1, {[Zn3(µ-OH)2(SDB)2].(PPZ)}n 2, (where SDB = 4,4′-sulfonyldibenzoate ; PPZ = Piperazine) have been synthesized by solvothermal methods. Crystal structure of 1 revealed that carboxylate...
 
Inorg. Chem. Front., 2015, Accepted Manuscript
DOI: 10.1039/C4QI00129J
From themed collection Crystal engineering for molecular materials
Five new coordination polymers, {Cu(Hiso)2•2H2O}n (1), {Mn(Hiso)(H2O)3}n (2), {Mn(Hiso)(H2O)2}n (3), {[Cu(Hiso)(4,4′-bipy)(H2O)]•2H2O}n (4) and {[Ni(Hiso)(4,4′-bipy)(H2O)}]•0.5(4,4′-bipy)}n (5) (H3iso = 2,4-dihydroxy pyrimidine-5-carboxylic acid or isorotic acid; 4,4′-bipy = 4,4-bipyridyl), have been synthesized using...
 
Dongdi Zhang, Chao Zhang, Pengtao Ma, Bassem S. Bassil, Rami Al-Oweini, Ulrich Kortz, Jingping Wang and Jingyang Niu
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00169A, Research Article
Herein we present two structurally novel nanoscale clusters [{Nb6(O2)4P2W12O57}2]20− (1) and [{P2W12Nb7O63(H2O)2}4{Nb4O4(OH)6}]30− (2) formed by controlling the reaction parameters.
 
Larissa Valerie Meyer, Joachim Vogt, Helmut Schäfer, Martin Steinhart, Rolf Böttcher, Andreas Pöppl, Marit Mai, Claus Feldmann and Klaus Müller-Buschbaum
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00184B, Research Article
From themed collection Crystal engineering for molecular materials
Highly luminescent MOF coatings were grown on nanostructured alumina membranes via melt, electride and CVD approaches.
 
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00158C, Research Article
Substitution of one O atom by S and Se atoms in POMs enhances the redox and acidic properties.
 
Siru Chen, Ming Xue, Yanqiang Li, Ying Pan, Liangkui Zhu, Daliang Zhang, Qianrong Fang and Shilun Qiu
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00167B, Research Article
ZnCo2O4 nanoparticles were synthesized by thermal annealing of a new mixed-metal MOF and show high capacitance for electrochemical capacitors.
 
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00192C, Research Article
The fluorine atoms in BiB2O4F withdraw the non-bonding electrons of Bi3+ and thus strongly increase the SHG efficiency.
 
Shotaro Terashima, Graham N. Newton, Takuya Shiga and Hiroki Oshio
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00172A, Research Article
Using a pyridine–pyrazolate ligand H2L (5,5′-pyridyl-3,3′-bi-1H-pyrazole) with two types of bidentate sites allowed the isolation of two trinuclear complexes, [Cu3(L)2](BF4)2 (1) and [Ni3(L)2(MeOH)4](BF4)2 (2). Both complexes have linear trinuclear structures composed of two L2− ligands and three metal ions in a planar arrangement.
 
Zhiyi Lu, Xiaochao Wu, Xiaodong Lei, Yaping Li and Xiaoming Sun
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00143E, Research Article
Due to the unique structural advantages, hierarchical Co3O4@NiO nanoarrays can be regarded as advanced electrodes for Ni–Zn batteries.
 
Matteo Atzori, Angela Serpe, Paola Deplano, John A. Schlueter and Maria Laura Mercuri
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00179F, Chemistry Frontiers
From themed collection Crystal engineering for molecular materials
This Chemistry Frontier highlights how supramolecular non-covalent interactions can be employed as effective tools in tailoring the magnetic properties of crystalline functional molecular materials.
 
Xianghua Zeng, Xiaojing Yao, Junyong Zhang, Qi Zhang, Wenqian Wu, Aihua Chai, Jinlan Wang, Qingdao Zeng and Jingli Xie
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00227J, Research Article
A series of Zn–S clusters have been synthesised and a very rare 1D helical structure was illustrated by first-principles calculations.
 
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00191E, Review Article
From themed collection Crystal engineering for molecular materials
This review summarizes the construction of nanostructured solid-state metal alkoxides and their conversion into functional inorganic nanomaterials.
 
Wen-Dan Cheng, Chen-Sheng Lin, Zhong-Zhen Luo and Hao Zhang
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00156G, Review Article
From themed collection Crystal engineering for molecular materials
The designs of NCS compounds based on the normal development of NCS chromophores are presented and NLO properties are investigated.
 
Amitabha Datta, Kuheli Das, Chiara Massera, Jack K. Clegg, Michael C. Pfrunder, Eugenio Garribba, Jui-Hsien Huang, Chittaranjan Sinha, Tapas Kumar Maji, Takashiro Akitsu and Shingo Orita
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00201F, Research Article
A robust 2-D coordination polymer that maintains its single-crystallinity upon desolvation is reported.
 
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00183D, Research Article
From themed collection Crystal engineering for molecular materials
Supramolecular assembly of uranyl species via halogen–oxo and halogen–halogen interactions is explored in the solid state.
 
Xiao-Lin Qi, Jia-Wen Ye, Rui-Biao Lin, Pei-Qin Liao, Si-Yang Liu, Chun-Ting He, Jie-Peng Zhang and Xiao-Ming Chen
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00190G, Research Article
From themed collection Crystal engineering for molecular materials
Two genuine supramolecular isomers with a unique type of structural difference and completely different porous properties have been synthesized and characterized.
 
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00145A, Research Article
Mesoporous nickel hydroxide–nickel nanohybrids are successfully obtained via oxidation of Ni nanowire foams indirectly from coordination microfibers, and are successfully applied as high-performance supercapacitor electrodes.
 
Deepika Tyagi, Rohit K. Rai, Ambikesh D. Dwivedi, Shaikh M. Mobin and Sanjay K. Singh
Inorg. Chem. Front., 2015, Advance Article
DOI: 10.1039/C4QI00115J, Research Article
A simple and highly efficient catalytic system based on a phosphine-free ruthenium arene complex for aqueous-phase one-pot direct synthesis of primary amides from aldehydes and hydroxylamine hydrochloride, with a high tolerance for other reactive functional groups, is described.
 

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