Journal cover: Inorganic Chemistry Frontiers

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Eleutheria Papazoi, Antigoni Douvali, Sofia Rapti, Euaggelia Skliri, Gerasimos S. Armatas, Giannis S. Papaefstathiou, Xin Wang, Zhen-Feng Huang, Spyridon Kaziannis, Constantine Kosmidis, Antonios G. Hatzidimitriou, Theodore Lazarides and Manolis J. Manos
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00548A, Research Article
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
A microporous Mg2+ MOF shows single-crystal-to-single-crystal exchange of Mg2+ by Cu2+ ions.
 
John P. Sheckelton, Kemp W. Plumb, Benjamin A. Trump, Collin L. Broholm and Tyrel M. McQueen
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00470A, Research Article
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
A change of van der Waals stacking occurs spontaneously at 90 K in a cluster magnet.
 
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00508J, Research Article
The joint contribution of appropriate intramolecular coupling and local ion symmetry to improve magnetic relaxation in a series of dinuclear Dy2 SMMs.
 
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00446F, Research Article
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
A remarkable enhancement of the LIB electrode activity of graphene-based nanocomposites can be achieved via the incorporation of clay nanosheets.
 
Shengwen Liu, Mingyu Tong, Guoqiang Liu, Xian Zhang, Zhaoming Wang, Guozhong Wang, Weiping Cai, Haimin Zhang and Huijun Zhao
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00403B, Research Article
Co9S8@S,N-doped carbon materials derived from S,N-containing Co-MOFs exhibited superior performance as bifunctional oxygen electrocatalysts and supercapacitor electrode materials.
 
K. Muñoz-Becerra, D. Aravena, E. Ruiz, E. Spodine, N. Soto-Donoso, V. Paredes-García and D. Venegas-Yazigi
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00394J, Research Article
Models for the 1,1 and 1,3-bridging modes of phosphate for copper(II) compounds were developed. Using unrestricted corresponding orbitals (UCO), a graphical identification of the predominant exchange pathway was described.
 
Dong Luo, Pei Shi, Shaohua Fang, Wenbin Guo, Li Yang and Shin-ichi Hirano
Inorg. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QI00571C
Assembled microspherical cathodes have attracted great attention thanks to their high tap density, good rate capability and cycling stability. However, for layered Li-rich transition-metal oxides (LROs), the preparation of uniform...
 
Antigoni Margariti, Sofia Rapti, Athanasios Katsenis, Tomislav Friščić, Yiannis Georgiou, Manolis Manos and Giannis S. Papaefstathiou
Inorg. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QI00542J
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
A new Ca2+ two-dimensional framework, namely [Ca(H4L)(DMA)2]•2DMA (Ca-MOF) was obtained from the initial use of N,N’-bis(2,4-dicarboxyphenyl)-oxalamide (H6L). We discovered that this Ca-MOF is capable of exchanging the Ca2+ ions by...
 
Bin Duan, Yingke Ren, Yafeng Xu, Wenyong Chen, Qing Ye, Yang Huang, Jun Zhu and Songyuan Dai
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00492J, Research Article
Hydrogen halides as additives form a new intermediate to obtain high quality perovskite films.
 
Duo Wang, Jie Chen, Li Ren, Qinglan Li, Dongdong Li and Jihong Yu
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00488A, Research Article
AIEgen-functionalised mesoporous silica nanoparticles can be used for cell imaging and monitoring the drug release process by different emission colours based on the FRET mechanism.
 
Inorg. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QI00570E
The Sandwich-type polyoxometalates K6Na2Ni2[Ni4(H2O)2(SiW9O34)2]•30H2O(Ni4), K6Na2Co2[Co4(H2O)2(SiW9O34)2]•30H2O(Co4) and K10[Ni(H2O)2(γ-SiW10O35)2]•13.25H2O(Ni1) doped TiO2 respectively were applied to the photoanodes of dye-sensitized solar cells (DSSCs) for the first time, enhancing the current intensity and photoelectric...
 
Carl K. Brozek, Andrew Ozarowski, Sebastian A Stoian and Mircea Dinca
Inorg. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QI00584E
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
Temperature-dependent 57Fe Mössbauer spectra were collected on FexZn4–x(1,4-benzenedicarboxylate)3 (Fe-MOF-5). When measured under an Ar atmosphere, the data at higher temperatures reveal thermal population of the lowest-lying electronic excited state, as...
 
Qunxing Zhao, Mingming Zhao, Jiaqing Qiu, Huan Pang, Wen-Yong Lai and Wei Huang
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00595K, Research Article
Mn3[Co(CN)6]2·nH2O nanocrystals are firstly applied in flexible solid-state electrochemical energy storage devices.
 
Sixuan Zhou, Trinath Mishra, Daniel Lyman, Patricia Tucker and Susan E. Latturner
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00539J, Research Article
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
Cerium cobalt borocarbide grown from Ce/Co eutectic flux has a partially disordered structure containing cobalt squares capped with borocarbide chains.
 
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00515B, Research Article
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
Mesoporous assemblies of p-CuS/n-CdS nanocrystal junctions with high surface areas and uniform pores demonstrate a high performance and stability in photocatalytic hydrogen generation from water using visible light.
 
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00520A, Research Article
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
The structural stability of undoped and doped (Sb, Bi, Ca, Zn) Mg2Si0.4Sn0.6 is investigated by high resolution synchrotron PXRD and related to measured physical properties, revealing a stabilizing effect of cation doping.
 
Tristan Barbier, David Berthebaud, Raymond Frésard, Oleg I. Lebedev, Emmanuel Guilmeau, Volker Eyert and Antoine Maignan
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00510A, Research Article
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
An effective strategy to enhance thermoelectric performance consists of scattering phonons by point defects, such as the ones intrinsic to the n-type isocubanite CuFe2S3.
 
Zhong-Min Su, Wei Xie, junsheng qin, Wen-Wen He, Kui-Zhan Shao, dong-ying du, Shun-Li Li and Ya-Qian Lan
Inorg. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QI00528D
A novel anionic luminescent MOF (NENU-524) with lon topology was successfully synthesised. The most interesting structural feature of NENU-524 is the trigonal prism unit {Zn8(btca)6(2-NH2-bdc)3}, which can be regarded as...
 
Inorg. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QI00518G
Ammonia borane (AB) has been regarded as a promising candidate for chemical hydrogen storage but needs an efficient catalyst for hydrolytic hydrogen generation. In this communication, CoP nanoarray in situ...
 
Saskia Speed, Min Feng, Guglielmo Fernandez Farcia, Fabrice Pointillart, Bertrand Lefeuvre, Francois RIOBE, Stephane Golhen, Boris Le Guennic, Federico Totti, Yannick Guyot, Olivier Cador, Olivier Maury and Lahcène Ouahab
Inorg. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QI00546B
The reaction between the 2-{TTF-fused-1H-benzimidazol-2-yl}pyridine alkylated either with the di-(pyrazol-1-yl)-4-pyridyl (L1) or dimethyl-2,2’-bipyridine (L2) moiety and 1 equiv. of Ln(hfac)32H2O (LnIII = DyIII and YbIII) leads to three dinuclear complexes...
 
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00462H, Research Article
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
Anionic layers in CsGaS2 undergo a transition to infinite strands at high temperature and transfer back under pressure.
 
Lidia Rosado Piquer, Erika Jiménez, Yanhua Lan, Wolfgang Wernsdorfer, Guillem Aromi and E. Carolina Sañudo
Inorg. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QI00468G
A heterometallic Ni4Tb field-induced SMM has been grafted onto the surface of superparamagnetic iron oxide nanoparticles. The magnetic coupling within the Ni4Tb and between the Ni4Tb and iron oxide nanoparticle...
 
M. Q. Arguilla, N. D. Cultrara, Z. J. Baum, S. Jiang, R. D. Ross and J. E. Goldberger
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00476H, Research Article
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
We synthesize EuSn2As2, the first exfoliatable layered magnetic Zintl–Klemm phase that features van der Waals bonding between neighboring layers.
 
Inorg. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QI00491A, Research Article
From themed collection In honour of Mercouri G. Kanatzidis for his contributions to Inorganic Chemistry for over 30 years
The synthesis and properties of two families of mixed metal U(IV)/M(II) fluorides via a mild hydrothermal method.
 
Anna Piecha-Bisiorek, Anna Gągor, Dmitry Isakov, Piotr Zielinski, Miroslaw Galazka and Ryszard Jakubas
Inorg. Chem. Front., 2017, Accepted Manuscript
DOI: 10.1039/C6QI00583G
Crystals of diisopropylammonium iodide are synthesized, grown and characterized. Two phases: P21/m (Z=1) and P212121 (Z=2) are found. In contrast with analogous compounds no polar phase occurs, despite a critical-like...
 

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38 citations
Graphene oxide-based nanomaterials are suitable materials for the preconcentration of radionuclides and heavy metal ions from aqueous solutions in environmental pollution cleanup.
DOI: 10.1039/C4QI00221K
Published: 30 Mar 2015
37 citations
Of the two major capacitances contributing to electrochemical storage devices, pseudo-capacitance, which results from the reversible faradaic reactions, can be much higher than the electric double layer capacitance.
DOI: 10.1039/C5QI00187K
Published: 12 Nov 2015
16 citations
ZnCo2O4 nanoparticles were synthesized by thermal annealing of a new mixed-metal MOF and show high capacitance for electrochemical capacitors.
DOI: 10.1039/C4QI00167B
Published: 26 Dec 2014

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