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Journal cover: Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry

Rapid publication of high quality organic chemistry research
Impact Factor 3.559 48 Issues per Year Indexed in Medline
 
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Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB01186A, Perspective
The principles and prospects of a molecular dyad strategy for photocontrolling biological singlet oxygen are highlighted.
 
Subhabrata Sen, Chandramohan Bathula, Sayantan Tripathy, Ramprasad Srinivasan, Kunal Kumar Jha, Arnab Ganguly, Gopal Chakraboarti, Shailja Singh and Parthapratim Munshi
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB01257D, Paper
The synthesis of a new library of 5-arylidenethiazolidinone compounds using an efficient three component reaction with thiazolidine-2, 4-dione, piperidine and appropriate aldehydes is reported. This reaction is excellently high yielding,...
 
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB01140C, Paper
An efficient direct nucleophilic substitution of benzhydryl alcohols with electron-deficient benzenethiols using cationic Pd(II) catalysts as Lewis acids in water is reported.
 
Xiao-Fei Wang, Shu-Sheng Yu, Chao Wang, Dong Xue and Jianliang Xiao
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB00736H, Paper
A novel and efficient protocol for the synthesis of amides is reported via a BODIPY catalyzed oxidative amidation of aromatic aldehydes under visible light, with broad substrate scope and mild reaction conditions. Mechanistic studies reveal that dioxygen could be activated through both an ET and SET pathway to form the active peroxide intermediates.
 
Marek K. Węcławski, Irena Deperasińska, Arkadiusz Leniak, Marzena Banasiewicz, Bolesław Kozankiewicz and Daniel T. Gryko
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB00981F, Paper
An electron-rich derivative of anthracene reacts with hexamethylenetetramine under acidic conditions to give a rare heterocyclic scaffold possessing a pyridine moiety.
 
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB00778C, Review Article
From themed collection Selective Chemistry with Peptides and Proteins
The incorporation of aldehyde handles into proteins, and subsequent chemical reactions thereof, is rapidly proving to be an effective way of generating homogeneous, covalently linked protein constructs that can display...
 
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB01246A, Communication
Enantioselective introduction of the functionalized monofluorinated methylenes into the allylic fragment under Ir catalysis has been realized, which gave the fluorinated branched allylproducts in good to high yield with excellent...
 
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB90099B, Correction
 
Peng Wu, Michael Åxman Petersen, A. Emil Cohrt, Rico Petersen, Rémy Morgentin, Hugues Lemoine, Carine Roche, Anthony Willaume, Mads H. Clausen and Thomas E. Nielsen
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB01148A, Communication
From themed collection Contemporary Synthetic Chemistry in Drug Discovery
A facile metal-catalyzed diversification step for the synthesis of novel bi- and tricyclic scaffolds from enyne substrates is reported in this study for molecular library production.
 
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB01344A, Paper
Benzofused spiro[3.3]heptane derivatives undergo skeletal reorganisations involving two consecutive carbon–carbon bond cleavages in the presence of rhodium(I) catalysts to afford substituted naphthalenes.
 
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB01208F, Paper
Tertiary amines were employed as amino sources via the selective oxidative cleavage of the C–N bond to construct the S–N bond. Sulphonamides were synthesized using this strategy in moderate to good yields.
 
Annabelle Biscans, Sonia Rouanet, Jean-Jacques Vasseur, Christelle Dupouy and Françoise Debart
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB01272H, Paper
This work describes a novel post-synthetic method on a solid support to introduce various disulfide bond-containing groups at 2′-OH of oligoribonucleotides.
 
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB01158F, Paper
An iodine-promoted synthetic protocol for the construction of functionalized arylazopyrazoles was developed starting from β-ketoesters or 2-arylpyrazol-3-ones and arylhydrazines in the presence of silver catalysts.
 
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB01145D, Paper
A regioselective direct arylation of arenes and olefins at the ortho position is reported. The key to the high selectivity is appropriate choice of diaryliodonium salts as the arylating reagent...
 
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB00869K, Paper
Grignard reagents (RMgBr: R = Et, p-tolyl) selectively attacked the -position of bridgehead double bond of tosylazafulleroid through interaction of Mg with S=O group. The following [5,6]ring closure and C-N...
 
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB01229A, Review Article
The α,α-dicyanoolefins have emerged as versatile reactants, which find use as vinylogous nucleophiles, Michael acceptors and dienophiles in a variety of organic reactions. In the last few years, the reactivity...
 
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB01120A, Paper
A comprehensive mismatch discrimination study of lipidated DNA and LNA-probes (LiNAs) in hybridization-controlled liposome assembly is presented and evaluated for different DNA and RNA targets.
 
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB01226D, Communication
Highly selective metal-catalyzed cycloisomerizations of a 1,5-enyne allow the construction of either lindenane or myliol-type sesquiterpenoids.
 
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB01090C, Paper
An unprecedented syn-selective Meyer–Schuster rearrangement for Z-β-aryl-α,β-unsaturated esters from readily available 1-aryl-3-phenoxy propargyl alcohols is achieved.
 
Sebastian Barata-Vallejo, Sergio Bonesi and Al Postigo
Org. Biomol. Chem., 2016, Advance Article
DOI: 10.1039/C6OB00763E, Review Article
From themed collection Contemporary Synthetic Chemistry in Drug Discovery
The introduction of CF3S groups into compounds with known biological activity can alter their properties significantly, as a result of the increased lipophilicity and electronegativity of the trifluoromethylthio group.
 
MATTHEW JOHN STIRLING, Joseph M. Mwansa, GEMMA SWEENEY, John Blacker and Michael I Page
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB00884D, Paper
The dimeric iodo-iridium complex [IrCp*I2]2 (Cp*=pentamethylcyclopentadiene) is an efficient catalyst for the racemisation of secondary and tertiary amines at ambient and higher temperatures with a low catalyst loading. The racemisation...
 
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB01301E, Communication
A general and efficient methodology for preparing primary sulfonamide has been developed. In the presence of iodine as the catalyst and TBHP (70% in water) as the oxidant, a wide...
 
Jing Yang, Qiu-Yan Han, Cheng-Long Zhao, Tao Dong, Zhi-Yuan Hou, Hua-Li Qin and Cheng-Pan Zhang
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB01384H, Paper
The highly electrophilic aryl(2,2,2-trifluoroethyl)iodonium triflates are first used as trifluoroethyl and aryl transfer reagents in Pd-catalyzed functionalization of arylboronic acids. The electron-rich arylboronic acids reacting with aryl(2,2,2-trifluoroethyl)iodonium triflates (2a-b) in...
 
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB01092J, Paper
Glycoprotein MUC1 is an attractive target for anti-tumor vaccine development. However, the weak immunogenicity of MUC1 remains a significant problem. To solve this problem, several STn derivatives with N-acetyl modifications...
 
Org. Biomol. Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6OB01198E, Paper
A copper-catalyzed transfer aldol type reaction of β-hydroxy ketones or nitrile with aldehydes is reported, which enables chemo- and stereoselective access to (E)-α, β-unsaturated ketones and (E)-acrylonitriles. A key step...
 
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84 citations
DOI: 10.1039/C4OB00276H
Published: 10 Apr 2014
53 citations
DOI: 10.1039/C4OB02117G
Published: 13 Nov 2014
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DOI: 10.1039/C5OB00736D
Published: 19 May 2015

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