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Journal cover: Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry

Organic synthesis, supramolecular chemistry, chemical biology and more.
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Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00542C, Paper
A new family of protic NHC Ru complexes ligated with a phosphine-tethered imidazole moiety were prepared, which can act as excellent catalysts for acceptorless dehydrogenation of secondary alcohols and dehydrogenative...
Meirong Jia and Reuben J. Peters
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C7OB00510E, Communication
Isoprenoid precursors readily undergo (poly)cyclization in electrophilic reaction cascades, presumably as internal addition of the carbon–carbon double-bonds from neighboring isoprenyl repeats readily forms relatively stable cyclohexyl tertiary carbocation intermediates.
Chada Raji Reddy, Santosh Kumar Prajapti, Kamalkishor Warudikar, Ravi Ranjan and Billa Bhargava Rao
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C7OB00405B, Review Article
Various ipso-annulation strategies to access diversely substituted spirocyclohexadienones and their applications have been presented.
Nikolai Yu. Kuznetsov, Rabdan M. Tikhov, Ivan A. Godovikov, Michael G. Medvedev, Konstantin A. Lyssenko, Elena I. Burtseva, Elena S. Kirillova and Yuri N. Bubnov
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C7OB00331E, Communication
A series of (R)- and (S)-isomers of new adamantane-substituted heterocycles were synthesized and tested for antiviral activity.
Steve Huvelle, Ahmed Alouane, Thomas le Saux, Ludovic Jullien and Frederic Schmidt
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00121E, Paper
Kinetic analysis of disassembly of self-immolative spacers based on cyclisation processes was performed. Five compounds were synthesized belonging to two different series, and their kinetic constants were determined. Electro-donating substituents...
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00413C, Review Article
Numerous efficient synthetic methods for enantioselective indole functionalization emerged in recent years. This review summarizes major achievements in the transition-metal-catalyzed enantioselective indole functionalization reactions since 2010, which focuses on C-C...
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00293A, Paper
A ZnBr2-mediated oxidative spiro-bromocyclization of N-arylpropiolamide is described here for the synthesis of 3-Bromo-1-azaspiro[4.5]deca-3,6,9-triene-2,8-dione with a high efficiency. One equivalent of water is introduced into the final product. The reaction...
Zhen Zhang, Cheng Li, Shao-Hua Wang, Fu-Min Zhang, Xue Han, Yong-Qiang Tu and Xiao-Ming Zhang
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C7OB00620A, Paper
Herein we present a novel tandem SN2′ nucleophilic substitution/oxidative radical cyclization of aryl substituted allylic alcohols with 1,3-dicarbonyl compounds.
Arbia Talbi, Acha Arfaoui, Talia Bsaibess, Mohamed Lotfi Efrit, Anne Gaucher, Damien Prim and Hedi M'Rabet
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00206H, Paper
The selective installation of α-methylamine residues at the butenolide core is described from α-bromomethylene--butenolide and primary as well as secondary amines in methanol at 0 °C. The preparation of mono-...
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00466D, Review Article
Thiopeptide antibiotics are a class of typical ribosomally synthesized and post-translationally modified peptides (RiPPs) with complex chemical structures that are difficult to construct via chemical synthesis. To date, more than...
Ying Chen, Yong Liu, Yongchao Yao, Shiyong Zhang and Zhongwei Gu
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C7OB00169J, Paper
With special confined water pools, reverse micelles (RMs) have shown potential for a wide range of applications.
Peter Wipf, James Burnett, Chaemin Lim, Brian Daniel Peyser, Lalith P. Samankumara, Marina Kovaliov, Raffaele Colombo, Stacie Bulfer, Matt Laporte, Ann Hermone, Connor McGrath, Michelle Arkin, Rick Gussio and Donna Huryn
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00526A, Paper
The turnstile motion of two neighboring threonines sets up a dynamic side chain interplay that can accommodate both polar and apolar ligands in a small molecule allosteric protein binding site....
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00240H, Paper
A facile, green, metal-free based new one-pot synthetic strategy has been developed for the easy access to a wide array of medicinally promising functionalized pyridines having an ester, nitrile or...
Ersin Celik, Michael Maczka, Nils Bergen, Thorsten Brinkhoff, Stefan Schulz and Jeroen S. Dickschat
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C7OB00357A, Communication
The uptake and conversion of the algal sulfoquinovose catabolite 2,3-dihydroxypropane-1-sulfonate by marine bacteria was studied in isotopic labelling experiments.
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C7OB00371D, Communication
Pd(t-Bu3P)2 has been successfully identified as an efficient catalyst for the hydroaminocarbonylation of aromatic alkenes to branched amides under relatively mild reaction conditions.
Pedro Merino, Tomás Tejero, Ignacio Delso and Rosa Matute
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C7OB00429J, Review Article
The reactivity of nitrones in cycloadditions and related reactions is revisited by introducing a topological perspective.
Thilini D. Kondasinghe, Hasina Y. Saraha, Samantha B. Odeesho and Jennifer L. Stockdill
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C7OB00536A, Communication
We present a mild, convenient method for direct conversion of Allocam protected peptides to disulfide-containing protected peptides on solid support.
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C6OB02761J, Review Article
The Diels–Alder reaction that involves a nitrogen atom in the diene or dienophile is termed the aza-Diels–Alder reaction.
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00372B, Communication
An useful enantioselective Friedel-Crafts reaction of 3,5-dimethoxylphenol with nitroolefins catalyzed by a bifunctional quinine derived thiourea catalyst 9 was developed. The Michael addition products could be obtained in good to...
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00332C, Review Article
Hydrogen sulfide (H2S) is an important endogenous signaling molecule with multiple biological functions. Development of colorimetric and fluorescent probes for visualization of H2S is useful for studying H2S biology. This...
Katharina Pallitsch, Alexander Roller and Friedrich Hammerschmidt
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00546F, Paper
Three functionalised propylphosphonic acids were synthesised to study C-P bond cleavage in R. huakuii PMY 1. (R)-1-Hydroxy-2-oxopropylphosphonic acid [(R)-5] was prepared by chiral resolution of (±)-dimethyl 1-hydroxy-2-methylallyllphosphonate [(±)-12], followed by...
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00248C, Communication
A new disconnection toward tri- and tetrasubstituted furans has been conceptualized and demonstrated. A mild, base mediated reaction of allenoate pronucleophile with α-haloketones/dicarbonyl compounds results in a Csp2-alkylation/enolization/O-vinylation sequence to...
Dipendu Das, Hina P.A. Khan, Rahul Shivahare, Suman Gupta, Jayanta Sarkar, Imran Siddiqi, RAVI SANKAR AMPAPATHI and Tushar Kanti Chakraborty
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C6OB02610A, Paper
Leishmaniasis, caused by the protozoan parasites of the genus Leishmania, is one of the most neglected diseases endemic in many continents posing enormous global health threats and therefore, the discovery...
Govindaraju T, Chilakapati Madhu, Chandrashekhar Voshavar and K Rajasekhar
Org. Biomol. Chem., 2017, Accepted Manuscript
DOI: 10.1039/C7OB00167C, Communication
Unnatural CDP-amino acid (kd) is used in the design and synthesis of novel cell penetrating peptidomimetic (Kkd-5). The balanced cationic nature and structural rigidity of Kkd-5 resulted in serum stability,...
Org. Biomol. Chem., 2017, Advance Article
DOI: 10.1039/C7OB00118E, Paper
A simple direct C–H arylation of two difficult coupling partners, selenochromones and electron-rich aryl bromide, has been developed, affording diverse polymethoxyselenoflavones with great efficiency and high selectivity.
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28 citations
A unified strategy for the palladium-catalyzed Suzuki–Miyaura cross-coupling of amides with boronic acids for the synthesis of ketones by N–C bond activation is reported.
DOI: 10.1039/C6OB00084C
Published: 11 Feb 2016
57 citations
This review article covers the main types of gold(i) complexes used as precatalysts under homogeneous conditions in organic synthesis and discusses the different ways of catalyst activation as well as ligand, silver, and anion effects.
DOI: 10.1039/C5OB00736D
Published: 19 May 2015
58 citations
The recent advances in the copper-catalysed azide–alkyne cycloaddition (CuAAC) reactions are reviewed.
DOI: 10.1039/C5OB01457C
Published: 31 Jul 2015

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