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Green Chemistry

The home of cutting-edge research on the development of alternative sustainable technologies.
Impact Factor 8.506 24 Issues per Year Indexed in Web of Science
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Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC02012G, Paper
This work reports a cost-effective and sustainable protocol for the carbonylative Suzuki–Miyaura cross-coupling reaction catalyzed by palladium nanoparticles (Pd NPs) supported on fibrous nanosilica (KCC-1) with very high turnover number.
Ali Hussain Motagamwala, Wangyun Won, Christos T. Maravelias and James A. Dumesic
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC02297A, Communication
We demonstrate the design of a solvent system for efficient production and enhanced separation of carbohydrates from lignocellulosic biomass.
Fang Chen, Ning Li, Shanshan Li, Guangyi Li, Aiqin Wang, Yu Cong, Xiaodong Wang and Tao Zhang
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01497F, Communication
Jet fuel range cycloalkanes were synthesized in high carbon yield (∼76%) with diacetone alcohol which can be obtained from lignocellulose.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01206J, Paper
MOF-based heteropolyacid materials [Cu–BTC][HPM] can act as a catalyst for the conversion of 5-hydroxymethylfurfural into 5-ethoxymethylfurfural and ethyl levulinate in ethanol.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01290F, Paper
Magnetically recyclable 3D hierarchical hollow nanostructured Au25 nanocluster catalysts, assembled by an Au25Capt18 precursor method, exhibit an extraordinary catalytic performance for the aerobic oxidation of alcohol by molecular oxygen upon strong Au25NCs–LDH–magnetic core synergy.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01728B, Paper
A supramolecular ensemble of triazole-appended perylene bisimide (PBI) derivative 4 and in situ generated copper nanoparticles (CuNPs) serves as a light-harvesting antenna in photocatalytic C(sp2)–H alkynylation and amination reactions of arenes under mild and eco-friendly conditions.
Jennifer N Markham, Ling Tao, Ryan Davis, Nina Voulis, Largus T Angenent, Justin L Ungerer and Jianping Yu
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01083K, Paper
Ethylene is the petrochemical produced at largest volume worldwide. It serves as a building block for a wide variety of plastics, textiles, and chemicals, and can be converted into liquid...
Sander Clerick, Els De Canck, Kevin Hendrickx, Veronique Van Speybroeck and Pascal Van Der Voort
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01494A, Paper
A 100% monoallyl ring-type Periodic Mesoporous Organosilica (PMO) is prepared as a novel, versatile and exceptionally stable catalytic support with a high internal surface area and 5.0 nm pores. Thiol-ene...
Davinia Salvachua, Rui Katahira, Nicholas S Cleveland, Payal Khanna, Michael George Resch, Brenna A Black, Samuel O Purvine, Erika M Zink, Alicia Prieto, Maria Jesus Martinez, Angel Tomas Martinez Ferrer, Blake Simmons, John Gladden and Gregg T. Beckham
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01531J, Paper
In Nature, powerful oxidative enzymes secreted by white rot fungi and some bacteria catalyze lignin depolymerization and some microbes are able to catabolize the resulting aromatic compounds as carbon and...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC02225A, Paper
Development of lignocellulosic biorefinery requires improved environmental and cost-effective processes coupled to tailoring lignocellulosic constitutions with the desired biofuels and chemicals. Here, we first report a novel strategy of lignocellulose...
Phantisa Limleamthong, Maria Gonzalez-Miquel , Stavros Papadokonstantakis, Athanasios Papadopoulos, Panos Seferlis and GONZALO GUILLEN GOSALBEZ
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01696K, Paper
With the growing trend of incorporating sustainability principles in the chemical industry, there is a clear need to develop decision-making tools to quantify and optimise the sustainability level of chemical...
Pedro Lozano, Celia Gomez, Susana Nieto, Gregorio Sánchez, Eduardo Garcia-Verdugo and Santiago V. Luis
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01969B, Paper
The biocatalytic synthesis of monoacylglycerides (MAGs) was carried out by the direct esterification of fatty acids (i.e. capric, lauric, myristic, palmitic and oleic acids, respectively) with glycerol in different ionic...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01820C, Communication
Carbon quantum dots (CQDs), a rising star family in photoluminescent (PL) nanomaterials, have been identified to have core-shell structure with the nanocrystalline core of sp2-hybidized carbon clusters and the functional...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC02335E, Critical Review
As the largest contributor to renewable energy, biomass (especially lignocellulosic biomass) has significant potential to address atmospheric emission and energy shortage issues. The bio-fuels derived from lignocellulosic biomass are popularly...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01880G, Communication
Directing functionalization of readily available hydrocarbons under mild conditions fulfills the requirements of green and sustainable chemistry. In this work, a mild and green catalytic oxidative Csp3-H activation of methyl...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01884J, Paper
A composite oxide CuO-ZnO catalyst was prepared and tested in degradation of various polyureas using urea as the carbonyl source for the first time in this field. Under the optimized...
Hui He, Linzhou Zhuang, Shuixia Chen, Hucheng Liu and Qihan Li
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01416J, Paper
A CO2-imprinted adsorbent was synthesized by crosslinking the CO2 pre-adsorbed amino-terminated hyperbranched polymer, which was prepared through the Michael addition reaction between amines and methyl acrylate (MA) at 0 °C, followed by self-condensation of the addition reaction products at 100 °C and 140 °C.
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01995A, Paper
In this study, a novel asymmetric synthesis of all-carbon quaternary stereogenic centres is developed by the connection of three prochiral or achiral components--conjugated enones, organometallic compounds and vinyl esters--at the...
Dibyendu Mondal, Mukesh Sharma, Maria V Quental, Ana P. M. Tavares, Kamalesh Prasad and Mara G Freire
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01482H, Paper
In the past decade, remarkable advances on the production and use of antibodies as therapeutic drugs and in research/diagnostic purposes have lead to their recognition as value-added proteins. These biopharmaceuticals...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01858K, Paper
Ruthenium nanoparticles (2.5 nm) uniformly dispersed on a three-dimensional (3D) interconnected hierarchical porous N-doped carbon (Ru/NHPC) has been successfully developed, serving as a highly active and stable catalyst for the...
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01826B, Paper
Dimethyl carbonate (DMC) chemistry has been extended to include acid-catalysed reactions of different aliphatic alcohols and phenols.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01971D, Paper
In the context of arenes generated from bioresources, a hydrothermally stable catalyst Ru/HZSM-5 is reported for the quantitative conversion of lignin-derived phenol, anisole, guaiacols, and syringols into bioaromatic hydrocarbons in a one-pot aqueous-phase process in moderate conditions (240 °C, 2 bar H2), with a high carbon balance of 98.6%.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01712F, Paper
Fructose presents a highly attractive substrate for future biorefineries for production of biofuels as well as bulk and fine chemicals.
James L. Galman, Iustina Slabu, Nicholas J. Weise, Cesar Iglesias, Fabio Parmeggiani, Richard C. Lloyd and Nicholas J. Turner
Green Chem., 2017, Advance Article
DOI: 10.1039/C6GC02102F, Communication
Bifunctional transaminases enable a strategy for the production of chiral amines using small excesses of diamine donors.
Roland Lee, Jesse R. Vanderveen, Pascale Champagne and Philip G. Jessop
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01697A, Communication
CO2 can act as a catalyst for the production of bio-jet fuel precursors through aldol condensation.

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27 citations
A methodology, based on a combination of SH&E criteria, enables a simplified greenness evaluation of any solvent, in the context of fine or pharmaceutical chemistry.
DOI: 10.1039/C5GC01008J
Published: 13 Aug 2015
68 citations
The conversion of carbon dioxide (CO2), an abundant renewable carbon reagent, into chemicals of academic and industrial interest is of imminent importance to create a higher degree of sustainability in chemical processing and production.
DOI: 10.1039/C4GC01959H
Published: 11 Dec 2014
62 citations
The synthesis of cyclic carbonates from epoxides and carbon dioxide using sustainable metal-based catalysts is critically reviewed.
DOI: 10.1039/C4GC01719F
Published: 19 Nov 2014

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