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Green Chemistry

The home of cutting-edge research on the development of alternative sustainable technologies.
Impact Factor 8.506 24 Issues per Year Indexed in Web of Science
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Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01318J, Paper
Important goals of green chemistry include maximizing the efficiency of reactants and minimizing the production of waste. In this study, a novel approach to improve the atom economy of a...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01339B, Paper
Lignin obtained from two different sources, from the Kraft process (KF-lignin) and from dissolution of wood using ionic liquid (IL-lignin), was dissolved in alkaline solution and crosslinked with different methods,...
Thiago M. Lima, Carolina G. S. Lima, Anuj K. Rathi, Manoj B. Gawande, Jiri Tucek, Ernesto A. Urquieta-González, Radek Zbořil, Márcio W. Paixão and Rajender S. Varma
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01296E, Paper
A magnetic ZSM-5 zeolite with a core–shell type structure was synthesized, fully characterized and had its catalytic activity evaluated on the valorization of bio-derived furfuryl alcohol.
Aron Deneyer, Thijs Ennaert, Guillaume Cavents, Jan Dijkmans, Jens Vanneste, CM Courtin, Michiel Dusselier and Bert F Sels
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01644H, Paper
Processing raw (ligno)cellulosic feedstock into renewable light naphtha alkanes could lead to a gradual replacement of fossil feedstock for the production of chemicals, materials and fuels. The production of drop-in...
Sathish Murali, Selvaraj Silambarasan, Madhan Balaraman and Raghava Rao Jonnalagadda
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01774F, Paper
For the first time, the GSK’s solvent selection guide (SSG) has been explored for leather making with a view of sustainable manufacturing. A novel “Solvent Selection Tool” has been developed...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01565D, Communication
Using CsOH as the only catalyst and utilizing its “cesium effect”, a clean synthesis of a wide range of primary, secondary, and tertiary carboxamides was achieved by aminolysis reactions of...
Jotheeswari Kothandaraman, Alain Goeppert, Miklos Czaun, G A Olah and G K Surya Prakash
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01165A, Paper
Conversion of carbon dioxide (CO2) captured from industrial sources (e.g. flue gas of power plants) or even from ambient air to value-added chemicals/fuels through CO2 capture and utilization (CCU) as...
Svetlana Tsupova, Frank - Rominger, Matthias Rudolph and Stephen Hashmi
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01622G, Paper
This study describes the use of hydroxymethylfurfural (HMF) as a precursor to phenols that are accessible within a few simple catalytic steps. A key step is an efficient transformation of...
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01742H, Paper
An aromatic nucleophilic substitution reaction in ionic liquids is promoted by an electrophile–nucleophile dual activation.
João H. P. M. Santos, Margarida Martins, Armando J. D. Silvestre, João A. P. Coutinho and Sónia P. M. Ventura
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01440B, Paper
The ability of polymeric-based ABS to fractionate phenolic compounds from lignin depolymerisation was assessed.
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01231K, Paper
Production of phenol in high yield and selectivity by directly catalytic hydroxylation of benzene (HOB) is challenging. In this study, a carbon support bimetallic Cu-Ag NPs composite was synthesized (Cu-Ag/C)...
Daoshan Yang, Ben Huang, Wei Wei, Jin Li, Gu Lin, Yaru Liu, Jiehua Ding, Pengfei Sun and Hua Wang
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01403H, Paper
Visible light along with 1 mol% Eosin Y catalyzed the direct oxysulfonylation of alkenes with sulfinic acids via a photoredox process has been developed at room temperature under transition-metal-free conditions....
Li Chen, Jinmo Zhao, Sivaram Pradhan, Bruce E. Brinson, Gustavo E. Scuseria, Z. Conrad Zhang and Michael S. Wong
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01600F, Paper
The nonselective nature of glucose pyrolysis chemistry can be controlled by preventing the sugar ring from opening and fragmenting.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01647B, Paper
Each step of the total synthesis was optimized to decrease the mass intensity related to the reaction, workup and purification.
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01394E, Communication
A green method for epoxidation of imines using environmentally benign oxidant system, H2O2/dimethyl carbonate, was developed. N-Alkyloxaziridines were prepared in high yields from N-alkylamines and (hetero)aromatic aldehydes in one-pot fashion....
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01581F, Paper
In this report synthesis of isoquinolinones, isocoumarins, N-methyl isoquinolinones and olefination of Weinreb amides by C-H bond activation using Ru(II)/PEG-400 as green and recyclable media is documented. This developed methodology...
Nan An, John-Hanson Machado, Yuechuan Tang, Jakub Kostal and Adelina Voutchkova-Kostal
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC00945J, Paper
From themed collection Molecular Design for Reduced Toxicity
A predictive method is reported for estimating skin permeation of organic chemicals exclusively from NMR spectroscopic data and molecular weight, which does not require knowledge of chemical structure.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01782G, Communication
The Cu-catalyzed hydroarylation, hydroalkenylation, and hydroallylation of (trifluoromethyl)alkynes with organoboron reagents produced diverse (trifluoromethyl)alkenes.
Karthick Murugappan, Calvin Mukarakate, Sridhar Budhi, Manish Shetty, Mark R. Nimlos and Yuriy Román-Leshkov
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01189F, Paper
Supported MoO3 catalysts are effective catalytic fast pyrolysis catalysts that can generate ca. 30 C% hydrocarbons, including aromatics, olefins, and paraffins from pine.
Lu Lin, Yanbing Cheng, Yunqiao Pu, Su Sun, Xiao Li, Mingjie Jin, Elizabeth A. Pierson, Dennis C. Gross, Bruce E. Dale, Susie Y. Dai, Arthur J. Ragauskas and Joshua S. Yuan
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01131D, Paper
Lignin is the second most abundant biopolymer on the earth, yet its utilization for fungible products is complicated by its recalcitrant nature and remains a major challenge for sustainable lignocellulosic biorefineries.
Michael R. Chapman, Maria H. T. Kwan, Georgina E. King, Benjamin A. Kyffin, A. John Blacker, Charlotte E. Willans and Bao N. Nguyen
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01601D, Communication
A route to access the privileged imidazo[1,2-a]pyridine scaffold in one step, 1–10 minutes using only aqueous NaOH, is reported.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01089J, Paper
Sulfated zirconia in pure and highly dispersed form is a tunable and effective solid acid catalyst for the batch and continuous liquid phase esterification of carboxylic acids.
Green Chem., 2016, Advance Article
DOI: 10.1039/C5GC03080C, Communication
This is the first report on metallic species transfer from aqueous hydrochloric and oxalic acid media into hydrophobic deep eutectic and low-transition-temperature mixtures composed of quaternary ammonium salts or menthol and carboxylic acids.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01097K, Paper
To prepare cyclohexanol and alkyl cyclohexanols from non-fossil-based biomass, a selective catalytic process over a Ru/ZrO2–La(OH)3 bifunctional catalyst was developed for the partial hydrodeoxygenation of lignin-derived phenols into cyclohexanols with yields over 86.9%.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC01326K, Paper
An ionic Pd(II) complex stabilized by a water soluble pyridinium modified β-cyclodextrin was prepared and characterized by NMR, mass spectrometry, FT-IR spectroscopy, UV-visible spectroscopy and DLS (dynamic light scattering).

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61 citations
The synthesis of cyclic carbonates from epoxides and carbon dioxide using sustainable metal-based catalysts is critically reviewed.
DOI: 10.1039/C4GC01719F
Published: 19 Nov 2014
66 citations
The conversion of carbon dioxide (CO2), an abundant renewable carbon reagent, into chemicals of academic and industrial interest is of imminent importance to create a higher degree of sustainability in chemical processing and production.
DOI: 10.1039/C4GC01959H
Published: 11 Dec 2014
14 citations
The recent developments of lignin were reviewed in terms of different approaches to synthesize lignin-based copolymers, the resulting features and the potential applications of such copolymers.
DOI: 10.1039/C5GC02616D
Published: 08 Jan 2016

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