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Green Chemistry

The home of cutting-edge research on the development of alternative sustainable technologies.
Impact Factor 8.02 24 Issues per Year Indexed in Web of Science
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Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00511J, Paper
Novel rare earth metal-zinc heterotrinuclear complexes have been synthesized, which showed high efficiency and selectivity in initiating the copolymerization of CO2 and cyclohexene oxide under mild conditions. Significant cooperation between...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00507A, Paper
In the present study, a carbon dot/hemoglobin (CD/Hb) complex is used as a bio-receptor in an optical cholesterol biosensor. This optical sensor detects cholesterol through fluorescence enhancement of CD, which...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00924G, Paper
Visible light promoted straightforward highly regioselective synthesis of 1,3-oxathiolane-2-thiones (cyclic dithiocarbonates) starting directly from styrenes, CS2 and air (O2) is reported. The protocol utilizes eosin Y as an organophotoredox catalyst...
Sicong Tian, Jianguo Jiang, Feng Yan, Kaimin Li, Xuejing Chen and Vasilije Manovic
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC00400H, Paper
A highly efficient CO2 capture process integrating calcium looping and waste recycling into iron and steel production is proposed, which can also valorize the waste steel slag via a simultaneous iron and CaO recycling.
Michael J. Liszka, Aram Kang, N. V. S. N. Murthy Konda, Kim Tran, John M. Gladden, Seema Singh, Jay D. Keasling, Corinne D. Scown, Taek Soon Lee, Blake A. Simmons and Kenneth L. Sale
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC00657D, Paper
We describe a novel class of ionic liquids based on di-carboxylic acids that have high pretreatment efficiency and are compatible with both commercial enzyme mixtures and microbial fermentation host organisms.
Qing Xu, Huamei Xie, Er-Lei Zhang, Xiantao Ma, Jianhui Chen, Xiao-Chun Yu and Huan Li
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC00938G, Communication
A selective Hofmann N-alkylation reaction of amines/amides catalytic in alkyl halides is achieved by using alcohols as the alkylating reagents, affording mono- or di-alkylated amines/amides in high selectivities.
Nongthombam Geetmani Singh, Makroni Lily, SHOUGAIJAM PREMILA DEVI, Noimur Rahman, Aziz Ahmed, Asit Kumar Chandra and Rishanlang Nongkhlaw
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00724D, Paper
A novel class of organo-nanocatalyst was fabricated by encapsulating magnetic Fe2O3@SiO2 nanoparticles with thiamine hydrochloride. Its catalytic applications in the synthesis of oxygen and nitrogen containing spiro heterocycles via. ultrasonication...
Alex Wang, Nitash P Balsara and Alexis T Bell
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00581K, Paper
Furfural derived by the dehydration of xylose can serve as a platform molecule for the sustainable production of fuels. While xylose dehydration can be acid-catalyzed, this process is plagued by...
Margarida Martins, Flávia Vieira, Isabel Correia, Rute Ferreira, Helena Abreu, Joao A.P. Coutinho and Sónia P.M. Ventura
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01059H, Paper
Bioactive compounds extracted from natural renewable sources have attracted an increasing interest from both industry and academia. Several biocompounds are present in red macroalgae, among which R-phycoerythrin (R-PE), a phycobiliprotein...
Francois Jerome, Gregory Chatel and Karine De Oliveira Vigier
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00814C, Tutorial Review
In this review, we discuss on the recent progress made in the field of non-thermal technologies for the selective depolymerization of cellulose to processable glucans. The synergy of these technologies...
Siew Ping Teong, Dingyi Yu, Yin Ngai Sum and Yugen Zhang
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00872K, Communication
A mild and easy-to-handle protocol to produce propargylamines with terminal alkyne through catalytic cross-coupling of tertiary amines and calcium carbide has been developed. The reaction preceeds via sp3 C-H bond...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00779A, Communication
we disclose a reaction cascade involving cyclopropylimine rearrangement and Povarov reaction for the synthesis of hexahydropyrroloquinolines from anilines and cyclopropyl aldehyde. This method provides facile and convenient access to pharmacologically...
Nils Tenhumberg, Hendrik Büttner, Benjamin Schäffner, Daniela Kruse, Michael Blumenstein and Thomas Werner
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC00671J, Paper
Taking Control! The binary catalyst system composed of MoO3 and an organic phoshponium salt [Bu4P]X proved very efficient to produce oleochemical cyclic carbonates from renewables.
Jing Hou, Ming-Lei Yuan, Jian-Hua Xie and Qi-Lin Zhou
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC00549G, Communication
A protocol for nickel-catalyzed hydrocarboxylation of alkynes with formic acid was developed.
Green Chem., 2016, Advance Article
DOI: 10.1039/C5GC02729B, Paper
An efficient, low cost, and stable bi-functional electrocatalyst for ORR and OER consisting of N, Fe, and S multi-doped nanoporous carbon was produced by a facile one-step pyrolysis of sewage sludge under NH3 conditions.
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00798H, Paper
The cleavage of inter- and intramolecular linkages is a crucial but complicated issue for isolation and depolymerization of lignin in lignocellulosic biomass to produce biofuel. Herein, Na2CO3-H2O-tetrahydronfuran system was adopted...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00771F, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
Hugo E. Gottlieb, Grazyna Graczyk-Millbrandt, Graham G. A. Inglis, Abraham Nudelman, David Perez, Yanqiu Qian, Leanna E. Shuster, Helen F. Sneddon and Richard J. Upton
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC00446F, Paper
Updated guide to NMR chemical shifts of solvents as trace impurities, combining new greener solvent data with previously reported information.
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC00605A, Critical Review
Itaconic acid has attracted considerable attention as a bio-based building block in radical polymerizations. However, only a few studies have been dedicated to polyesters derived from this interesting α,β-unsaturated dicarbonic acid. This review aims to highlight the most important work in this field and show the unique properties of these renewable unsaturated polyesters.
Bart Van den Bogaert, Lio Van Meerbeeck, Koen Binnemans and Tom Van Gerven
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00541A, Paper
The influence of irradiance on the photochemical reduction of europium(III) to europium(II) is studied. It is known that europium removal from various rare-earth mixtures is feasible by means of photochemical...
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC01028H, Paper
An epoxidized lignin derivative was prepared directly inserting epichlorohydrin on the phenolic functionalities. The epoxidized lignin was then converted to cyclic carbonates through the coupling reaction of CO2 with the...
Jit Kumar Bhatt, Dibyendu Mondal, Ranjitsinh V Devkar and Kamalesh Prasad
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00853D, Paper
Herewith we have utilized the ability of a choline based deep eutectic solvent (DES) to dissolve DNA and disperse graphene for the synthesis of a Fe3O4 functionalized DNA-N-doped graphene hybrid...
Wenbin Jin, Qiwei Yang, Binbin Huang, Zongbi Bao, Baogen Su, Qilong Ren, Yiwen Yang and Huabin Xing
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00584E, Paper
Water is an ideal green solvent for the solubilization and separation of valued-added bioactive compounds in various chemical and biological processes, partly because water has a minimal impact on the...
James Sherwood, Helen L Parker, Kristof Moonen, Thomas James Farmer and Andrew J Hunt
Green Chem., 2016, Accepted Manuscript
DOI: 10.1039/C6GC00932H, Paper
Dipolar aprotic solvents such as N-methypyrrolidinone (NMP) are under increasing pressure from environmental regulation. NMP is a known reproductive toxin and has been placed on the EU "Substances of Very...
Mengmeng Zhao, Shigenori Kuga, Min Wu and Yong Huang
Green Chem., 2016, Advance Article
DOI: 10.1039/C6GC00660D, Paper
Dry milling of cellulose in a PTFE pot causes friction-transfer of PTFE, leading to nanocoating of cellulose by PTFE.

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