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Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
 
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Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01773D, Paper
In biology, aromatic hydroxylation is carried out by a family of heme and nonheme oxygenases, such as cytochrome P450, toluene monooxygenases (TMOs) , methane monooxygenases (MMO). In contrast, a vast...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01982F, Paper
A solvothermal method has been widely used to synthesize different kinds of materials. However, only little is known about how precursor solutions react to form solid precipitates by using this...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01459J, Paper
A new series of Pr1-xCexScO3 (0.0 ≤ x ≤ 1.0) compounds was synthesized by a two-step synthesis route, involving combustion reaction followed by reduction while heating in low partial pressure...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02853A, Paper
The current work revealed the comparative analysis of bare and surface functionalized tungsten trioxide (WO3) nanoparticles that can be successfully utilized as competent photocatalyst for the degradation of organic dye...
 
A Schulz, Alexander Villinger, Jonas Bresien, Kirill Faust, Christian Hering and Julia Rothe
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02757H, Paper
Different reactions of Mes* substituted phosphanes (Mes* = 2,4,6-tri-tert-butylphenyl) led to the formation of the bicyclic tetraphosphane Mes*P4Mes* (5) and its unknown Lewis acid adduct 5·GaCl3. In this context, the...
 
Go Nakamura, Mio Kondo, Meredith Crisalli, Sze Koon Lee, Akane Shibata, Peter C Ford and Shigeyuki Masaoka
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02994E, Paper
Four novel phosphine-substituted ruthenium(II) polypyridine complexes with nitrogen oxides—trans(P,NO2)-[Ru(trpy)(Pqn)(NO2)]PF6 (trans-NO2), cis(P,NO2)-[Ru(trpy)(Pqn)(NO2)]PF6 (cis-NO2), [Ru(trpy)(dppbz)(NO2)]PF6 (PP-NO2), and cis(P,NO)-[Ru(trpy)(Pqn)(NO)](PF6)3 (cis-NO)—were synthesised (trpy = 2,2’:6’,2”-terpyridine, Pqn = 8-(diphenylphosphanyl)quinoline, and dppbz = 1,2-bis(diphenylphosphanyl)benzene). The influence...
 
I. Gryca, Joanna Palion, Barbara Machura, Mateusz Penkala, Rafał Kruszynski, Joan Cano, Francesc Lloret and Miguel Julve
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02522B, Paper
Two new Re(IV) compounds of formula H2tppz[ReCl6] (1) and [Cu(bpzm)2(µ-Cl)ReCl3(µ-ox)Cu(bpzm)2(µ-ox)ReCl3(µ-Cl)]n (2) [tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine and bpzm = bis(pyrazolyl-1-yl)methane] have been prepared and their crystal structures determined by X-ray diffraction on...
 
Dietrich Gudat, Markus Blum, Oliver Puntigam, Sebastian Plebst, Fabian Ehret, Johannes Bender and Martin Nieger
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02854J, Paper
The homolytic P–P bond fission in a series of sterically congested tetraaminodiphosphanes (R2N)2P–P(NR2)2 ({4}2 – {9}2, two of which were newly synthesized and fully characterized) into diaminophosphanyl radicals (R2N)2P• (4...
 
Laurence J. Taylor, Brian A. Surgenor, Piotr Wawrzyniak, Matthew J. Ray, David B. Cordes, Alexandra M. Z. Slawin and Petr Kilian
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02539G, Paper
Borane adducts of peri-substituted bis(phosphines) eliminate hydrogen at room temperature, without the presence of catalysts. These reactions are the first examples of “spontaneous” phosphine–borane dehydrocoupling.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02861B, Communication
Three different indium building blocks, from a positive trimer to a negative monomer, lead to In-MOFs with tunable framework charge.
 
Aleksei O. Tolpygin, Tatyana A. Glukhova, Anton V. Cherkasov, Georgy K. Fukin, Diana V. Aleksanyan, Dongmei Cui and Alexander A. Trifonov
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02570B, Paper
The introduction of a pendant Ph2P(O) group into an amidinate ligand resulted in high 1,4-cis selectivity (96.6%) while maintaining very high activity.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01975C, Paper
The synergistic effect of F127 and carbon on EMD with superior performance for use in alkaline rechargeable batteries is reported.
 
A. Ben Khélifa, M. Salah Belkhiria, G. Huang, S. Freslon, O. Guillou and K. Bernot
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02377G, Paper
An isopolyoxomolybdate-based POM is coordinated to trivalent cerium ions to afford a hybrid complex namely, [Ce(dmso)8][Ce(η2-NO3)2(dmso)4(α-Mo8O26)0.5][Mo6O19].
 
Viola Kolaříková, Ondřej Šimůnek, Markéta Rybáčková, Josef Cvačka, Anna Brezinova and Jaroslav Kvíčala
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02258D, Paper
Using three different approaches, racemic 1-(perfluoroalkyl)ethylamines were synthesized from perfluoroalkyl iodides or perfluoroalkanoic acids, and further transformed to the corresponding N,N'-disubstituted ethane-1,2-diimines and ethane-1,2-diamines as mixtures of diastereoisomers. Their cyclization...
 
Phillip Nejman, Brian Morton-Fernandez, David Moulding, Kasun Arachchige, David Bradford Cordes, Alexandra Slawin, Petr Kilian and J D Woollins
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02542G, Paper
The synthesis of a range of rhodium(III) and iridium(III) half sandwich complexes with aryl dithiolato ligands of varying geometry and flexibility is reported. These include dinuclear [Cp*M(S‒R‒S)]2 complexes 3b and...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02860D, Paper
The highly diastereoselective synthesis of P-stereogenic phosphinic amides via directed ortho lithiation (DoLi) of (SC)-P,P-diphenylphosphinic amides with t-BuLi followed by electrophilic quench reactions is described. Functionalised derivatives containing a wide...
 
Nurşen SARI, ELVAN HASANOĞLU ÖZKAN, NURDAN KURNAZ YETİM and Hayrettin Tümtürk
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03004H, Paper
Ligated Pt(II) and Pt(IV) complexes on nanoparticles have been synthesized for the identification of pesticides according to template method. The morphologies has been investigated using scanning electron microscopy and characterized...
 
Congzhi Wang, John Gibson, Jianhui Lan, Qunyan Wu, Yuliang Zhao, Jun Li, Zhifang Chai and Weiqun Shi
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02811F, Paper
Synthesis of complexes with direct actinide-actinide (An-An) bonding is an experimental ‘holy grail’ in actinide chemistry. In this work, a series of actinide dimetallocenes An2Cp*2 (Cp* = C5(CH3)5, An =...
 
Daniela Olea-Román, Nicolas Bélanger-Desmarais, Marcos Flores-Alamo, Claudia Bazán, Félix Thouin, Christian Reber and Silvia E Castillo-Blum
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02563J, Paper
The synthesis, characterization and solid-state luminescence spectroscopy of mononuclear, heterodinuclear (d-f) and heterotrinuclear (d-f-d) coordination compounds with the compartmental ligand N,N’-bis(3-hydroxyl salicylidene)benzene-1,2-diamine (H2L) are reported. The trivalent lanthanide ions NdIII,...
 
D P Rillema, Stanislav Stoyanov, Arvin John Cruz, Huy Nguyen, Curtis E. Moore, Wei Huang, Khamis Siam, Ali Jehan and Venugopal R. Komreddy
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01891A, Paper
A series of platinum(II) biphenyl 2,2’-bipyridine complexes containing electron-donating and electron-withdrawing moieties on the 4 and 4’ positions of the bipyridine ligand exhibit emission from excited states in the 600...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01847A, Communication
The introduction of 4 wt% of MNH2 (M = Li, Na) and other additives (Li, MgH2, NaCl, and NaBr) into pure Mg by ball milling greatly enhances the first hydrogenation...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02407B, Communication
A class of monoorganoimido-substituted hexamolybdates containing a pyridine group have been firstly synthesized. Furthermore, a reaction protocol of alkylation based on the resulting pyridine-functionalized hexamolybdates has been developed, with which...
 
Amit K Vishwakarma, Kaushal Jha, Jayasimhadri Mula, Sivaiah Bathula, Bhasker Gahtori and D Haranath
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02436F, Paper
Single-phase cool white-light emitting BaNb2O6:Dy3+ phosphors have been synthesized via conventional solid-state reaction method and characterized using X-ray diffraction (XRD), Rietveld structural refinement studies, scanning electron microscopy (SEM) observations and...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02164B, Communication
Dependence of microwaves dielectric properties on the structural characteristics of ZnZr(Nb1-xAx)2O8 (A=Ta, Sb) (0≤x≤0.10) ceramics is investigated. All the compounds are prepared by a conventional solid-state reaction method and analyzed...
 
Hui Zhang, Wei Li, Xuguang Xu, Gang Mu, Xiaoming Xie and Fu Qiang Huang
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02766G, Paper
The Tl doped type II clathrate Cs8Na16-xTlxGe136 was synthesized from the elements. The structure was refined by single crystal and powder diffraction. Cs8Na16-xTlxGe136 crystalized in the space group . The...
 
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