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Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.177 48 Issues per Year
 
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Guo-Xuan Wen, Min-Le Han, Xue-Qian Wu, Ya-Pan Wu, Wen-Wen Dong, Jun Zhao, Dong-Sheng Li and Lufang Ma
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03057B, Paper
A super-stable multifunctional terbium(III)-organic framework, namely {[Tb(TATAB) (H2O)2]•NMP•H2O}n (Tb-MOF, H3TATAB = 4,4′,4′′-s-triazine-1,3,5-triyltri-m-aminobenzoic acid, NMP = N-methyl-2-pyrrolidone) was synthesized. Tb-MOF exhibits a 2D sql structure with binuclear [Tb2(COO)4(H2O)4]2+ unit as 4-connected...
 
Milan Milutinovic, Jovana Bogojeski, Olivera R. Klisurić, Andreas Scheurer, Sofi K C Elmroth and Zivadin D Bugarcic
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02772E, Paper
A novel rhodium(III) complex [RhIII(H2LtBu)Cl3] (1) (H2LtBu = 2,6-bis(5-tert-butyl-1H-pyrazol-3-yl)pyridine) was synthesized containing a pincer type, tridentate nitrogen−donor chelate system. Single crystal X-ray structure analysis revealed that 1 crystallizes in the...
 
Jordann A. L. Wells, Megan L. Seymour, Markéta Suvova and Polly L. Arnold
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02630C, Paper
Two lower-oxidation state uranium cations can be readily combined and controlled in a robust and derivatisable tetra-aryloxide ligand framework. These di-UIII/IV systems are a new platform at which to use the multi-electron reductive capacity of the two actinide centres.
 
Yang-Tian Yan, Wenyan Zhang, Yunlong Wu, Jiang Li, Zheng-Ping Xi, Yao-Yu Wang and Lei Hou
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02846B, Paper
By an asymmetrical rigid pentacarboxylatic acid ligand, 2,4-di(3′,5′-dicarboxylphenyl)benozoic acid (H5L), four new three-dimensional (3D) metal−organic frameworks (MOFs), namely, {[Cu2(HL)(H2O)2]•2DMF•2H2O}n (1), {[Co2(L)(DMA)]•H2N(Me)2}n (2), {[Co2(L)(H2O)]•H2N(Me)2}n (3), {[Mn2(L)(DMF)(H2O)]•H2N(Me)2}n (4), were solvothermally synthesized. H5L...
 
Marwène Oumezzine, Aurelian Catalin Galca, Iuliana Pasuk, Cristina Florentina Chirila, Aurel Leca, Victor Kuncser, Liviu Cristian Tanase, Andrei Kuncser, Corneliu Ghica and Mohamed Oumezzine
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01914E, Paper
Epitaxial La0.67Ba0.33Ti0.02Mn0.98O3 (denoted as LBTMO hereafter) thin films of approximately 95 nm thickness were deposited by a pulsed laser deposition technique onto SrTiO3 (STO) (001) substrates.
 
Linda E Eijsink, Sebastien C. P. Perdriau, Johannes G. de Vries and Edwin Otten
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02478E, Paper
The pincer complex (PNN)RuH(CO), with a de-aromatized pyridine in the ligand backbone, is shown to react with nitriles in a metal-ligand cooperative manner. This leads to the formation of a...
 
Kevin Barthelmes, Andreas Winter and Ulrich S. Schubert
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02613C, Perspective
A detailed overview about the synthesis, properties and applications of all reported ruthenium-fullerene compounds.
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02646J, Paper
Two series of lanthanide coordination polymers, [Ln(Hdpstc)(H2O)2]n•nH2O (Ln = Sm (1), Eu (2), Gd (3), Tb (4), Dy (5), Ho (6), Er (7), Yb (8), [Ln(Hdpstc)(phen)(H2O)]n•1.5nH2O (Ln = Pr (9),...
 
José J. Baldoví, Yan DUAN, Carlos Bustos, Salvador Cardona-Serra, Pierre Gouzerh, richard villanneau, Geoffrey Gontard, Juan Modesto Clemente Juan, Alejandro Gaita-Ariño, Carlos Giménez-Saiz, Anna Proust and Eugenio Coronado
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02258H, Paper
Polyoxometalate (POM) chemistry has recently offered excellent examples of single ion magnets (SIMs) and molecular spin qubits. Compared with conventional coordination compounds, POMs provide rigid and highly symmetric coordination sites....
 
Helene Strauch, Joern Engelmann, Klaus Scheffler and H A Mayer
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02365G, Paper
A fast and simple route was developed to synthesize a new T8-silsesquioxane based contrast agent for potential application in Magnetic Resonance Imaging. For this purpose the novel C2-thiol-functionalized T8-silsesquioxane (3)...
 
Yu-Teng Zhang, Shuang-Bao Li, Xinlong Wang, Yaru Gong, Kui-Zhan Shao and Zhong-Min Su
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02764D, Communication
Two isostructural vanadium-based metal-organic polyhedra (denoted as VMOP-16 and VMOP-17) were synthesized by the solvothermal method, which are built from unprecedented {V7} isopolyoxometalate clusters and dicarboxylate ligands. To our knowledge,...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03154D, Paper
A series of substituted 1,2-diarylhydrazines (ArNHNHAr), Ar = 3,5-(CH3)-C6H3; -Ph; 4-Cl-C6H4; 3,5-Cl-C6H3; 3,5-(CF3)-C6H3, were reacted with Ce(III)[N(SiMe3)2]3 and lithiated bases to explore the use of Ce(III) as a reductant and...
 
Pedro T Gomes, Devarajan Suresh, Bruno Ferreira, Patrícia S. Lopes, Clara S. B. Gomes, Krishnamoorthy paramasivam, Ana Charas, Diogo Vila-Vicosa, Jorge Morgado, Maria Jose Calhorda and Antonio Macanita
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02771G, Paper
The condensation reactions of 2-formylindole (1) or 2-formylphenanthro[9,10-c]pyrrole (2) with various aromatic amines afforded the corresponding phenyl or phenanthrene ring fused mono-/bis-iminopyrrole ligand precursors 38, which, upon reaction with BPh3...
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02855A, Paper
Nickelacarborane derivatives of 1,1′-bis(o-carborane) allow comment on the factors important in the isomerisation of metallacarboranes.
 
Qun-Yan Wu, Fu-Wan Zhai, Yang Liu, Li-Yong Yuan, Zhi-Fang Chai and Wei-Qun Shi
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03009B, Paper
A phosphorylated pentapeptide (WpTPpTW, P1) motif was designed as a model to mimic possible U(VI) coordination sites of genuine phosphorylated proteins.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02823C, Paper
Lithium halide assisted high yield synthesis of few layers of 2H phase semiconducting WS2 in organic solvents is reported.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01228K, Paper
A polydentate tripodal ligand forms a series of tricopper(II) complexes, that feature unique pyrazolate-bridged linear core. The Cu3H−3L2 complex is an efficient catecholase mimic with a surprisingly low pH optimum at pH = 5.6.
 
Renso Visbal, Vanesa Fernández-Moreira, Isabel Marzo, Antonio Laguna and M. Concepción Gimeno
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02878K, Paper
Gold and silver NHC complexes have been developed as theranostic agents. The unexpected biodistribution opens the door to new biological targets for gold and silver complexes.
 
Sophie De-Botton, Ponit Romm, Guillaume Bensoussan, Maria Hitrik, Sanaa Musa and Dmitri Gelman
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02201D, Paper
The manuscript describes the synthesis and coordination chemistry of a novel diphoshine pincer ligand based on p-hydroquinone-functionalyzed dibenzobarrelene scaffold. The p-hydroquinone fragment of the ligand is oxidatively and coordinatively non-innocent...
 
Benhua Xu, Xiao-Liang Tang, Ji-An Zhou, Wan-Min Chen, Haile Liu, zhenghua Ju and Wei-Sheng Liu
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02835G, Paper
A functional amide-type pincer ligand was designed and synthesized, which could capture effectively Tb3+ ion to form a phosphorescence complex-based chemosensor Tb-1. The chemosensor could further coordinate with Pb2+ ion...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02635D, Communication
Lanthanide contraction was used for helicity fine-tuning and helix winding control of single-helical tetranuclear complexes LZn3Ln (Ln = La–Lu); heavier lanthanides formed a tighter helix with a higher M/P ratio...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01709F, Paper
Two types of zinc flavonolato complexes ([(6-Ph2TPA)Zn(flavonolato)]ClO4 and Zn(flavonolato)2) of four extended flavonols have been prepared, characterized, and evaluated for visible light-induced CO release reactivity. Zinc coordination of each flavonolato...
 
Reina Shimokawa, Yumi Kawada, Miki Hayashi, Yasutaka Kataoka and Yasuyuki Ura
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02948E, Communication
A cationic SNS-benzylpalladium complex was reacted with O2 under several conditions, affording oxygenated compounds derived from the benzyl ligand. The addition of n-Bu4NX remarkably accelerated the oxygenation, furnishing benzaldehyde as...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02186G, Paper
The binding-induced luminescence enhancement of an Eu-containing polyoxometalate (POM), EuSiWMo, by the arginin/lysine-rich cationic peptides supplied a platform to detect the capsid proteins of human papillomaviruses (HPVs). However, the strong...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02922A, Paper
Different di and trinuclear rare-earth metal complexes supported by 3-amido appended indolyl ligands were synthesized and their catalytic activities towards isoprene polymerization were investigated. Treatment of [RE(CH2SiMe3)3(thf)2] with 1 equiv....
 
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