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Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
 
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Wilaiwan Chouyyok, Jonathan W. Pittman, Marvin G. Warner, Kara M Nell, Donald Clubb, Gary A Gill and Raymond Addleman
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01318J, Paper
The ability to collect uranium from seawater offers the potential for a nearly limitless fuel supply for nuclear energy. We evaluated the use of functionalized nanostructured sorbents for the collection...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00713A, Paper
ITQ-8 is a new hydrous layer silicate (HLS) with a chemical composition of [(C4H8(C7H13N)2]8 [Si64O128(OH)16] • 48 H2O per unit cell. The synthesis of ITQ-8 was first described in 2002...
 
Caterina F Ramogida, Eszter Boros, Brian O. Patrick, Stefan Zeisler, Joel Kumlin, Paul Schaffer, Michael J Adam and Chris Orvig
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00932H, Paper
The chiral acyclic “pa” ligand (pa = picolinic acid) H2CHXdedpa (N4O2) and two NI-containing dedpa analogues (H2CHXdedpa-N,N’-propyl-2-NI, H2dedpa-N,N’-propyl-2-NI, NI = nitroimidazole) were studied as chelators for copper radiopharmaceuticals (CHX =...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00800C, Paper
A novel water-soluble colorimetric and fluorescent palladium probe with an excellent selectivity and sensitivity has been designed. Notably, based on palladium triggered terminal allyl ethers cleavage reaction, the probe could...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01157H, Perspective
Supramolecular chemistry of bis-imidazole ligand namely 1,4-bis(imidazol-1yl-methyl)benzene, popularly known as bix was explored by various researchers to synthesize functional coordination polymers (CPs). The flexibility of the bix ligand, its unpredictable...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00993J, Paper
This paper describes a simple and fast aqueous-phase route to the synthesis of Ag/AgCl hybrid nanostructures. These hybrid nanostructures were synthesized by reduction of AgCl nanoparticles with controlled shapes prepared...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00442C, Paper
A series of four indole-derivative β-diketone mononuclear dysprosium complexes, namely, Dy(EIFD)3(bpy)·CH2Cl2 (1), Dy(EIFD)3(phen)·CH2Cl2 (2), Dy(EIFD)3(dpq)·CH2Cl2 (3), and Dy(EIFD)3(dppz) (4) (EIFD = 1-(1-ethyl-1H-indol-3-yl)-4,4,4-trifluorobutane-1,3-dione, bpy = 2, 2'-bipyridine, phen = 1, 10-phenanthroline,...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00777E, Paper
A series of TbIII triple-decker heteroleptic crownphthalocyaninate complexes consisting of a homodinuclear compound [(15C5)4Pc]Tb[(15C5)4Pc]Tb(Pc) (1) and two novel heterodinuclear compounds [(15C5)4Pc]Tb[(15C5)4Pc]Y(Pc), (2), and [(15C5)4Pc]Y[(15C5)4Pc]Tb(Pc) (3), have been synthesized. All compounds...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04953A, Paper
Three new Ni(II)-clusters based on a Y-shaped ligand (biphenyl-3,4′,5-tricarboxylate, H3BPT), [Ni5(HBPT)4(OH)2(H2O)12]n (1), [Ni4(BPT)2(OH)2(H2O)6]n∙4nH2O (2), and [Ni7(BPT)2(1,4-bib)2(OH)6(HCO2)2]n∙3nH2O(3) (1,4-bib = 1,4-bi(1H-imidazol-1-yl)benzene), have been synthesized under the solvothermal condition. They were studied by...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00979D, Paper
A distorted octahedral CoII complex was reported with homoscorpionate ligands. This complex is a field-induced single-molecule magnet with two slow relaxation processes under low dc field (< 800 Oe) and...
 
Leighton J. Alcock, Germán Cavigliasso, Anthony C. Willis, Robert Stranger and Stephen F. Ralph
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01176D, Communication
The rare trigonal prismatic geometry is readily adopted in complexes of a large cavity hexaamine cage ligand.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00859C, Paper
We prepared through CO2 air fixation novel Ni8Ln6 complexes showing a remarkable μ5-carbonate bridged octanuclear planar {Ni4Ln4} core and unusual MCE behaviour.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00265J, Communication
3-Aminopyridine-2-carboxylic acid can serve as an AIE-active turn on fluorescence chemosensor for Zn2+. The AIE behaviors are attributed to the cooperative effect of J-aggregation and hydrogen bonds. And selecting proper ratio of the solvents can prove the sensitivity.
 
Andrea Schmidt, Manuela Hollering, Markus Drees, Angela Casini and Fritz E. Kühn
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00654J, Paper
Self-assembled Pd(II) coordination cages exhibit promising anticancer activities, while the emission properties studied by fluorescence spectroscopy and DFT calculations are limited.
 
Domenica Musumeci, Chiara Platella, Claudia Riccardi, Antonello Merlino, Tiziano Marzo, Lara Massai, Luigi Messori and Daniela Montesarchio
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00294C, Paper
The reactivity of cis-PtI2(NH3)2 with selected DNA model systems, in single, double strand or G-quadruplex form, has been studied by circular dichroism, UV-visible spectroscopy and electrospray mass spectrometry using cisplatin as a control.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00906A, Paper
In this study, a lead-free ceramic system comprising (0.94 − x)Bi0.5Na0.5TiO3–0.06BaTiO3xBi(Zn0.5Ti0.5)O3 (BNT–BT–BZT) was designed and prepared by a conventional solid-state reaction method.
 
Juan Manuel Sonego, Patricio R. Santagapita, Mercedes Perullini and Matías Jobbágy
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00321D, Paper
Alginate hydrogels are suitable for the encapsulation of biomolecules and microorganisms for the building of bioactive materials.
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00798H, Paper
We report the structure and magnetic properties of two new iridium-based honeycomb Delafossite compounds, Cu3NaIr2O6 and Cu3LiIr2O6, formed by a topotactic cation exchange reaction. The starting materials Na2IrO3 and Li2IrO3,...
 
Philip Bulsink, Ahlam Alghamdi, Prajesh Joshi, Ilia Korobkov, Tom Woo and Darrin Richeson
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00661B, Paper
The organometallic and coordination chemistry of rhenium (I) has been largely restricted to bidentate α-diimine ligation and facial tricarbonyl coordination geometries. The thermal transformation of bidentate bis(imino)pyridine and bidentate terpyridine...
 
Sui-Jun Liu, Chen Cao, Chen-Chao Xie, Teng-Fei Zheng, Xiao-Lan Tong, Jin-Sheng Liao, Jing-Lin Chen, He-Rui Wen, Ze Chang and Xian-He Bu
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01349J, Paper
Two GdIII coordination polymers with the formula [Gd(cit)(H2O)]∞ (1) and [Gd(nta)(H2O)2]∞ (2) (H4cit = citric acid, H3nta = nitrilotriacetic acid) have been successfully prepared under hydrothermal conditions. Complex 1 exhibits...
 
Marcel Kühling, Robert McDonald, Phil Liebing , Liane Hilfert, Michael J Ferguson, Josef Takats and Frank T Edelmann
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01439A, Communication
Well-defined lanthanide polysulfide complexes containing S42- and S52- ligands, the samarium(III) pentasulfide complex Sm(TpiPr2)(κ1-3,5-iPr2Hpz)(S5) and the tetrasulfide-bridged binuclear ytterbium(III) complex (µ-S4)[Yb(TpiPr2)(κ1-3,5-iPr2Hpz)(κ2-3,5-iPr2pz)]2 (TpiPr2 = hydro-tris(3,5-diisopropylpyrazolyl)borate), have been synthesized and structurally characterized...
 
Hou-Ji Cao, Qianyi Zhao, Qian-Fan Zhang, Jiaxuan Li, Ewan J. M. Hamilton, Jie Zhang, Lai-Sheng Wang and Xuenian Chen
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01272H, Paper
Agostic interactions are often used to activate inert C‒H bonds, and thus facilitate new reactions. We report the first example of designed catalysts based on the agostic interaction. Novel copper(I)...
 
Rui Li, Fangxia Xie, Jianxin Liu, Yawen Wang, Yunfang Wang, Xiaochao Zhang and Caimei Fan
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00997B, Paper
In this study, a novel visible-light-sensitive Bi4O5Br2 photocatalyst was successfully synthesized via the structure reorganization of BiOBr at room temperature using NH3•H2O as structure-controlling agent. The resulting Bi4O5Br2 photocatalyst presented...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01093H, Paper
Herein we reported that KMnO4 with iron nanoparticles coated with gold layers was a promising catalyst for water oxidation. The compound was characterized by scanning electron microscopy, energy-dispersive spectroscopy, transmission...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01221C, Paper
Photochemical hydrogen evolution studies aimed at evaluating new molecular catalysts have usually exploited Ru(bpy)32+ (where bpy = 2,2’-bipyridine) as the photosensitizer of reference, thanks to its suitable optical and redox...
 
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