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Journal cover: Journal of the Chemical Society, Dalton Transactions

Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.177 48 Issues per Year
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Tomasz Korzeniak, Dawid Pinkowicz, Wojciech Nitek, Tomasz Dańko, Robert Pełka and Barbara Sieklucka
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01957A, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
Sophia G Robinson, Phillip T Burns, Amanda M Miceli, Kyle A Grice, Caitlin E Karver and Lihua Jin
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01675H, Paper
The binding of drugs to metalloenzymes is an intricate process that involves several interactions, including binding of the drug to the enzyme active site metal, as well as multiple interactions...
Michihiro Nishikawa, Taichi Sano, Masaya Washimi, Koichiro Takao and Taro Tsubomura
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01239F, Paper
The synthesis, characterization, and emission properties of 2-coordinate dicopper(I) complexes bearing two trimethylene-bridged bis-NHC ligands, [Cu2(L3(Me)2](PF6)2 (1), [Cu2(L3Et)2](PF6)2 (2), [Cu2(L3Bu)2](PF6)2 (3), [Cu2(L3MeOPh)2](PF6)2 (4) and [Cu2(L3Mes)2](PF6)2 (5), where L3R denotes trimethylene-bridged...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02075E, Paper
A new long-tethered boron-containing (P-B-P)-pincer ligand 8 has been synthesized. Complexation of 8 with [Ir(coe)2Cl]2 (coe = cyclooctene) resulted in (P-B-P)(hydrido)chloroiridium complex (P-B-P)Ir(H)Cl 9. Subsequent reaction with nBuLi led to...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01672C, Paper
Versiliaite and apuanite are two minerals containing Fe2+ and Fe3+ in a low-dimensional structure exhibiting chains of edge-linked FeO6 octahedra. The chemistry of these minerals has not been fully examined...
René Pretorius, Manuel R. Fructos, Helge Müller-Bunz, Robert Arthur Gossage, Pedro J. Perez and Martin Albrecht
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02181F, Paper
A series of novel 1,2,3-triazolylidene gold(I) chloride complexes have been synthesised and fully characterised. Silver-free methodologies for chloride ion abstraction of these complexes were evaluated for their potential as Au-based...
Fabrice Pointillart, Xunshan Liu, Mikael Kepenekian, Boris Le Guennic, Stephane Golhen, Vincent DORCET, Thierry Roisnel, Olivier Cador, Zhonglu You, Jürg Hauser, Silvio Decurtins, Lahcene Ouahab and Shi-Xia Liu
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00920D, Communication
A mononuclear Fe(II) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows a Near-Infrared (NIR) sensitization...
Robin B. Bedford, Peter B. Brenner, David Elorriaga, Jeremy N. Harvey and Joshua Nunn
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01823H, Paper
The performance of Fe-amine pre-catalysts in a representative Kumada reaction is inversely proportional to the lability of the chelate ligand.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01688J, Paper
[LGa-M(C6F5)3] (M = B 1, Al 2, Ga 3) reacts with benzaldehyde in different ways including the formation of the zwitterionic species [LGa(C6F5){CH(Ph)(OAl(C6F5)2)}] (5).
Douglas P. Solowey, Takashi Kurogi, Brian C. Manor, Patrick J. Carroll and Daniel J. Mindiola
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01534D, Paper
The synthesis and characterization of a terminal titanium oxo complex generated by alkylidene benzophenone cross-metathesis is reported.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01406B, Paper
Sonogashira and Suzuki–Miyaura coupling were catalyzed with Pd(II) complexes (0.001–2 mol%), and transfer hydrogenation (in water–glycerol) was catalyzed with Ru(II) complexes (≤0.4 mol%).
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01696K, Communication
This study presents a convenient modification of the well-known MOF, MIL-101, with ethylenediamine (ED) on its open-metal sites to substantially improve the HCHO adsorption properties.
Cesar Ray, Jorge Bañuelos, Teresa Arbeloa, Beatriz Lora Maroto, Florencio Moreno Jiménez, Antonia R Agarrabeitia, Maria Jose Ortiz, IÑIGO LOPEZ ARBELOA and Santiago De la Moya
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01849A, Paper
A series of uncommon bis(BODIPYs), involving a flexible bridge linking BODIPY α-positions and key functionalities to efficiently endure electronic push-pull effect, has been synthesized, as well as photophysically and structurally...
Sanjit Konar, Upendarrao Golla, Amit Adhikary, Amit Kumar Mondal and Raghuvir Singh Tomar
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01496H, Paper
Four complexes of formulae [CuII2(H2L1)(HL1)](ClO4)3∙4 H2O (1), [CuII2L2 (CH3OH)2] (ClO4)2∙2 CH3OH (2), [CoII2(H2L1)2](ClO4)4∙H2O (3), and [CoIII2(L2)2](Cl)2 (4) were synthesized via self-assembly of succinohydrazone derived ligands (H2L1 = N’,N’4-bis(2-pyridyl)succinohydrazide and H2L2=N’,N’4-bis(2-hydroxybenzylidene)succinohydrazide)...
Francisco Martínez-Olid, Román Andrés, Ernesto de Jesús, Juan C. Flores, Mª Pilar Gómez-Sal, Karine Heuzé and Luc Vellutini
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01330A, Communication
Pre-synthesized mono- and bis(NHC) palladium complexes have been grafted onto magnetic core/shell γ-Fe2O3/silica particles and tested as catalysts in model the Suzuki–Miyaura coupling reactions. The bis(NHC) immobilized complex was found...
Jolie Lam, Benjamin Guenther, Jeff Farrell, Patrick Eisenberger, Brian Bestvater, Paul David Newman, Rebecca Melen, Cathleen Crudden and Douglas W Stephan
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02202B, Paper
The carbene derived from (1R,3S)-camphoric acid was used to prepare the borane adduct with Piers’ borane 7. Subsequent hydride abstraction gave the borenium cation 8. Adducts with 9-BBN and the...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01425A, Paper
Reactions of the N-heterocyclic carbene derivatives of selenium(II) dihalides, LSeX2 (X = Cl, Br; L = 1,3-dibutylbenzimidazol-2-ylidene, C15H22N2) (4b, 4b'), L'SeX2 (X = Cl, Br; L' = 1,3-dinpropylbenzimidazol-2-ylidene, C13H18N2) (4c,...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01585A, Paper
Activation of sulfur containing heteroallenes by nickel(II) alkyl complexes supported by the bulky hydrotris(3-phenyl-5-methylpyrazolyl)borate (TpPh,Me) ligand is described.
Kai Schwedtmann, Robin Schoemaker, Felix Hennersdorf, Antonio Bauzá, Antonio Frontera, Robert Weiss and Jan J. Weigand
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01871H, Paper
Cationic NHCs featuring a phosphonium moiety in the 5-position are prepared from the reaction of imidazolium salts with a tert. phosphane. They are used as ligands for the preparation of transition metal complexes, dehydrogenation reactions of prim. and sec. phosphanes and the preparation of a N-heterocyclic olefin (NHO).
Paul A. Shaw, Jessica M. Phillips, Guy J. Clarkson and Jonathan P. Rourke
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02088G, Paper
The oxidation of three different complexes of the doubly cycloplatinated 2,6-di(4-fluorophenyl)pyridine ligand (namely DMSO, PPh3 and PPr3 derivatives, 1a, 1b and 1c, respectively) with the electrophilic oxidant iodobenzenedichloride was studied.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01989G, Perspective
This perspective article tackles the open question why cyclometalated polypyridine ruthenium(II) complexes typically only emit very weakly at room temperature and delivers answers beyond the standard schemes involving 3MC and tunneling decay channels.
Gernot Heitmann, Christian Schütt, Jens Gröbner, Lukas Huber and Rainer Herges
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01727D, Paper
Molecular spin switching with light under aqueous conditions has been performed with azoimidazole functionalized Ni-porphyrins. The change in contrast in MRI images is clearly visible.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02100J, Paper
The synthesis and co-ordination chemistry of a new N-heterocyclic carbene (“IPaul”) with spatially-defined steric impact is reported.
Wen Zhou, Michael B. Watson, Shuai Zheng, Nigam P. Rath and Liviu M. Mirica
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02185A, Paper
Ligand effect studies on (RN3C)NiIIIL2 complexes reveal aerobically-induced aromatic cyanation with tBuNC at room temperature for the (NpN3C)Ni system.
Ji Zhang, Lei Sun, Xiao-Yu Geng, Bin-Bin Zhang, Guo-Liang Yuan and Shan-Tao Zhang
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01880G, Communication
The thermal depolarization of Bi0.5Na0.5TiO3-BaTiO3 is deferred by introducing ZnO to construct composite, the detailed crystal structures of unpoled and poled composites were comparatively investigated.
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