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Journal cover: Journal of the Chemical Society, Dalton Transactions

Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
 
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Brant Walkley, Rackel San Nicolas, Marc-Antoine Sani, John D Gehman, Jannie S J van Deventer and John L Provis
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04878H, Paper
This study demonstrates production of stoichiometrically controlled alkali-aluminosilicate gels (‘geopolymers’) via alkali-activation of high-purity synthetic amorphous aluminosilicate powders. This method provides for the first time a process by which the...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00333H, Communication
A new Cd-doped titanium-oxo cluster (TOC) stabilized by tert-butylacetic acid ligands has been prepared through easily handled solvothermal reaction; photocatalytic studies indicate that it displays good H2 evolution ability (3.15...
 
Adrien T. Normand, Constantin G. Daniliuc, Gerald Kehr, Pierre Le Gendre and Gerhard Erker
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00416D, Communication
Cooperation between zirconium and phosphorus enables the direct synthesis of a new PNN ligand via a spectrosopically characterized σH adduct.
 
Evamarie Hey-Hawkins, Alexandr Vinogradov, Haldor Zaake-Hertling, Angela Aleksovska, Sina Gruschinski, Sara Schmorl, Berthold Kersting, Eva M Zolnhofer, Joerg Sutter, Karsten Meyer, Peter Lönnecke and Valentin Milichko
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00390G, Paper
A highly stable metal–organic framework, [{Fe3(ACTBA)2}X·6DEF]n (1; X = monoanion), based on trinuclear iron(III) secondary building units connected by tetracarboxyles with an anthracene core, 2,6,9,10-tetrakis(p-carboxylatophenyl)anthracene (ACTBA), is reported. Depending on...
 
Aliza G. Furneaux, Nicholas A. Piro, Raúl Hernández Sánchez, Kathryn M. Gramigna, Natalie Fey, Michael J. Robinson, W. Scott Kassel and Chip Nataro
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04721H, Paper
[Re(CO)3(dippf)Br]+: the first structurally characterized complex of a coordinated bis(phosphino)ferrocenium ligand.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04435A, Paper
Facile synthetic access to four novel, neutral, heteroleptic copper(I)-complexes, incorporating 4H-imidazolates as well as the phosphane ligands XantPhos and DPEPhos is reported.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00034G, Paper
The synthesis, reactivity and catalytic transfer hydrogenation activity of three metal–ligand cooperative ruthenium(II) complexes (3–5) with a 2-hydroxypyridylmethylene fragment are reported.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00137H, Paper
Four inner C-benzyl and C-xylyl-substituted cobalt(II) complexes of a 2-N-substituted N-confused porphyrin were synthesized and the D-parameter is related to the structural parameters of the cobalt(II) complexes.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04594K, Paper
A [Pb2I6] twin chain hybrid crystal shows novel switchable ion conductivity arising from the structural phase transition and color-tunable photoluminescence attributed to the broadband semiconductor emission of twin chain.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04563K, Paper
The picket-fence porphyrin system is used a model for a sterically-constrained, protected binding environment to study H2S and HS ligation.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04759E, Paper
With the help of rationally selected N-donor ligands, different dimensional architectures 1–5 have been synthesized and they display dual-emission properties.
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00198J, Paper
A family of cyclometallated Au(III) and Pt(II) complexes containing a CNC-pincer ligand (CNC = 2,6-diphenylpyridine) supported by pyrene-based mono- or bis-NHC ligands, have been synthesized and characterized, together with the...
 
Roberto Puentes, Julia Torres, Carlos Kremer, Joan Cano, Francesc Lloret, Davide Capucci and Alessia Bacchi
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT05060J, Paper
Two novel families of coordination polymers, [Ln(bzlida)(Hbzlida)]∙H2O (Ln = La, Nd) and [Ln2(bzlida)3]∙3H2O (Ln = Nd, Sm, Eu, Gd) were prepared by hydrothermal reaction of Ln2O3 with benzyliminodiacetic acid (H2bzlida)....
 
Dietmar Stalke, Arne Visscher, Sebastian Bachmann, Christoph Schnegelsberg, Thorsten teuteberg and Ricardo A. Mata
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00557H, Paper
Fluorescence spectroscopic investigations of the new acridine derivative bis(N,N-dimethyl-aminemethylene)acridine (3) show remarkable selectivity and sensitivity towards Zn2+ and Cd2+ ions in methanol and for the latter even in water. Through...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00275G, Paper
A series of P-NHC-type hybrid ligands containing both PR2 and N-heterocyclic carbene (NHC) donors on meta-bis-substituted phenylene backbones, LCy, LtBu and LPh (R = Cy, tBu, Ph, respectively), was accessed...
 
Sheng Zhang, Hongshan Ke, Quan Shi, Jiangwei Zhang, Qi Yang, Qing Wei, Gang Xie, Wenyuan Wang, Desuo Yang and sanping chen
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00219F, Paper
Three mononuclear dysprosium(III) complexes derived from three β-diketonate ligands, 4,4,4-Trifluoro-1-(4-methylphenyl)-1,3-butanedione (tfmb), 4,4,4-Trifluoro-1-(4-fluorophenyl)-1,3-butanedione (tffb) and 4,4,4-Trifluoro-1-(2-naphthyl)-1,3-butanedione (tfnb) as well as auxiliary ligands, 5-Nitro-1,10-phenanthroline (5-NO2-Phen), DMF and 2,2`-bipyridine (bpy) have been synthesized...
 
Ramesh Maragani, Prabhat Gautam, Shaikh M. Mobin and Rajneesh Misra
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04988A, Paper
The single crystal X-ray structures of ferrocenyl-bisthiazoles 3 and 5 show skew-eclipsed conformations.
 
Mitsukimi Tsunoda, Martin Fleischmann, J. Stuart Jones, Nattamai Bhuvanesh, Manfred Scheer and François P. Gabbaï
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT01887K, Paper
From themed collection Fluorine
Organomercurials (C6F5)2Hg and [o-C6F4Hg]3 interact with Ni(II)-salen to form adducts held by arene-perfluoroarene and hydrogen bonding interactions, as well as interactions between Hg, the salen ligand, and Ni.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00318D, Paper
The reactions of N,N′-bis(di-tert-butylphosphanyl)-imidazole-2-ylidene (PCNHCP) with [Rh(μ-Cl)(COD)]2, [Rh(μ-Cl)(CO)2]2, [Fe4Cl8(THF)6], elemental Se and [(C6F5)BO]3, have been investigated to evaluate the stereoelectronic properties of this hybrid ligand.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04706D, Perspective
A key part of the development of metal based Positron Emission Tomography probes is the chelation of the radiometal.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00062B, Paper
Redox mediated synthesis of Bi2O3/MnO2 nanoflowers for efficient electrochemical sensing of hydrogen peroxide down to 0.05 μM.
 
Astrid Barkleit, Anne Heller, Atsushi Ikeda-Ohno and Gert Bernhard
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04790K, Paper
Batch sorption experiments, potentiometric and spectroscopic titration investigations revealed a fast and strong interaction of Eu(III) and Cm(III) with the digestive enzyme α-amylase.
 
Xuefei Zhao, Lionel Perrin, David J. Procter and Laurent Maron
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00241B, Communication
The first detailed theoretical study on the synthetically important electron transfer reductant SmI2–H2O has been conducted in the context of the activation of important alkyliodide, ketone, lactone and ester substrates, processes of importance in cross-coupling.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04801J, Paper
Photophysical and nuclear magnetic resonance dispersion properties of magnetofluorescent amphiphilic DyIII–DOTAbisamide chelates dispersed in DPPC micelles are presented for application as bimodal contrast agents in optical and high field magnetic resonance imaging.
 
Pawel M. Kozlowski, Brady D. Garabato, Piotr Lodowski and Maria Jaworska
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04286K, Perspective
This Perspective Article highlights recent theoretical developments, and summarizes the current understanding of the photolytic properties of cobalamins from a computational point of view.
 
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