Journal cover: Journal of the Chemical Society, Dalton Transactions

Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
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Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02410A, Paper
Platinum complexes with σ-bonded thioxanthonyl (Tx) ligands exhibit, on irradiation into the Tx π→π* band, dual Tx-based fluorescence and phosphorescence emission with phosphorescence quantum yields of up to 19% in fluid solution at room temperature.
Alessio Terenzi, Antonino Lauria, Anna Maria Almerico and Giampaolo Barone
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02881C, Perspective
Zinc(II) complexes are effective and selective nucleic acid-binders and strongly fluorescent molecules in the low energy range, from the visible to the near infrared. These two properties have been often...
Biprajit Sarkar, Ramananda Maity and Margarethe van der Meer
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03239J, Communication
Synthesis of a ligand platform to generate di- and tri-mesoionic carbenes is reported together with their multinuclear Pd(II) complexes. A complete structural characterization and preliminary electrochemical data are presented.
Jamie McKinven, Gary S. Nichol and Polly L. Arnold
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02995J, Paper
Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th–η6-arene interactions in a thorium bis(arene) sandwich motif.
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02988G, Paper
A simple and versatile method for preparation of new crystalline vanadium oxide hydrate semi-microspheres is developed via a simple hydrothermal route, which are tested as a novel high-energy anode material...
Jean-Rene HAMON, Matias Rioja, Paul Hamon, Thierry Roisnel, Sourisak Sinbandhit, Mauricio Fuentealba, Karina Letelier, Jean Yves Saillard and Andres Vega
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02736A, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
Zong-Wan MAO, Xiao-Hui Zheng, Qian Cao, Yi-Liang Ding, Yi-Fang Zhong, Ge Mu, Peter Qin and Liang-Nian Ji
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02760D, Communication
Two porphyrin-bridged tetranuclear platinum(II) complexes are found to effectively stabilize various kinds of G-quadruplexes. Their clover-like shape endows them with the capability of targeting G-quadruplexes rather than double-stranded structure. Their...
Mathias Glatz, Bernhard Bichler, Matthias Mastalir, Berthold Stöger, Matthias Weil, Kurt Mereiter, Ernst Pittenauer, Guenter Allmaier, Luis F. Veiros and Karl Kirchner
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02866J, Paper
Treatment of anhydrous FeX2 (X = Cl, Br) with 2 equivs of the sterically little demanding N,N'-bisphosphino-2,6-diaminopyridine based PNP ligands PNP-Ph, PNP-BIPOL, PNP-Me, PNP-Et, PNP-nPr and PNP-nBu in THF afforded...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02808B, Paper
A novel interpenetrating metal–organic framework, namely [Zn3L2(oba)3(H2O)2]•4H2O (1), has been synthesized under hydrothermal conditions. Its structure was determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR,...
M. Dommaschk, C. Schütt, S. Venkataramani, U. Jana, C. Näther, F. D. Sönnichsen and R. Herges
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT03048F, Paper
A record player type molecule changes spin state reversibly upon irradiation with green and blue light in solution at room temperature without measureable fatigue.
Alan D. Moghaddam, Jonathan D. White, Rachael M. Cunningham, Andrea N. Loes, Michael M. Haley and Victoria J. DeRose
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02649G, Communication
cis-[Pt(2-azido-1,3-propanediamine)Cl2] is a reagent for high-yield post-treatment fluorescent labelling of Pt(II) biomolecular targets using click chemistry and exhibits a bias in conformational isomers in the context of duplex DNA.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02502D, Communication
A thermo-responsive green-light-emitting supramolecular gel (G-gel) can convert to a blue luminescent gel (B-gel) due to the coordination effect between L and Cd2+.
C. Cesari, S. Conti, S. Zacchini, V. Zanotti, M. C. Cassani and R. Mazzoni
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02747G, Communication
A sterically driven synthetic route from non-bulky silver NHC to novel Ru(NHC) complexes and from bulky Ag(NHC) to unprecedented heterobimetallic Ru–Ag(NHC) complexes is presented.
Yong Wang, Xiao Ma, Shengmin Hu, Yuehong Wen, Zhenzhen Xue, Xiaoquan Zhu, Xudong Zhang, Tianlu Sheng and Xintao Wu
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02272F, Paper
Four 1D cyanide-bridged complexes [cis-MII(L)2(CN)2FeIII(salen)](PF6) (3–6) have been synthesized, of which 3 and 4 are Class II mixed-valence complexes.
Jian-Jun Liu, Yao Wang, Yu-Jian Hong, Mei-Jin Lin, Chang-Cang Huang and Wen-Xin Dai
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02641A, Communication
A polyoxometalate-sensitized photochromic naphthalene diimide coordination network has been assembled under the cooperative effect of anion–π and coordination interactions.
Chandan Giri, Filip Topić, Prasenjit Mal and Kari Rissanen
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02754J, Communication
In a one-pot reaction 1,4-diaminobenzene and 2-formylpyridine, as the reacting subcomponents, self-assemble to a small supramolecular M4L6 pseudo-tetrahedron with unexpected S4 symmetry in the presence of Fe(II) ions.
R. Karthikeyan, M. Navaneethan, J. Archana, D. Thangaraju, M. Arivanandhan and Y. Hayakawa
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02059F, Paper
Hierarchical structures of nickel sulfide have been grown by the hydrothermal method.
David Elorriaga, Fernando Carrillo-Hermosilla, Antonio Antiñolo, Isabel López-Solera, Rafael Fernández-Galán and Elena Villaseñor
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01975J, Paper
Mixed amido-/imido niobium complexes supported by guanidinato ligands were synthesized and their behaviour on some insertion reactions was studied.
Sónia Barroso, Ana M. Coelho, Santiago Gómez-Ruiz, Maria José Calhorda, Željko Žižak, Goran N. Kaluđerović and Ana M. Martins
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00975D, Paper
The reactivity, cytotoxic studies and hydrolytic behaviour of diamine bis(phenolate) titanium complexes are reported.
Ying Cui, Lei Shi, Yanyi Yang, Wansheng You, Lancui Zhang, Zaiming Zhu, Meiying Liu and Licheng Sun
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01538J, Paper
A Ag(I) complex formulated as [H3AgI(H2O)PW11O39]3− is formed in aqueous solution. It can be oxidized by S2O82−, dominantly generating a dark green Ag(II) complex [H3AgII(H2O)PW11O39]2− and a small amount of Ag(III) complex [H3AgIIIOPW11O39]3−, simultaneously evolving O2.
Fabio Piccinelli, Marco Bettinelli, Andrea Melchior, Cristian Grazioli and Marilena Tolazzi
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02326A, Paper
A new family of imine and amine-based racemic ligands containing furan or pyridine as aromatic donating ring [N, N’-bis(2-pyridylmethylidene)- 1,2-(R,R+S,S)-cyclohexanediamine, L1; N, N’-bis(2-furanylmethylidene)- 1,2-(R,R+S,S)-cyclohexanediamine, L2; N, N’-bis(2-pyridylmethyl)- 1,2-(R,R+S,S)-cyclohexanediamine, L3 and...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02233E, Paper
Abstract: Nanocrystalline Li2MSiO4 (M=Fe, Mn) particles embedded between in-situ formed rGO sheets are obtained by adopting customised solvothermal synthesis. An appreciable room temperature specific capacity of 149 mAh g-1 with...
Katie R. Meihaus and Jeffrey R. Long
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02391A, Perspective
Actinide single-molecule magnetism has experienced steady growth over the last five years since the first discovery of slow magnetic relaxation in the mononuclear complex U(Ph2BPz2)3. Given their large spin-orbit coupling...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02877E, Communication
A new pyridyl terminated cyanuric acid platform based tripodal urea receptor is synthesized for coordination driven self-assembly studies in presence of ZnSO4/MgSO4 in aqueous methanol (1:1). Importantly, encapsulation of hydrated...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02647K, Communication
The oxidation of four benzylic alcohols employing hydrogen peroxide and TBHP as oxidants, catalyzed by an iron(III) complex bearing a 14,28-[1,3-diiminoisoindolinato]phthalocyaninato (diiPc) ligand has been studied and found to proceed...
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