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Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
 
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Xinyuan Zhang, Jiyong Yao, Xingxing Jiang, Ying Fu, Zheshuai Lin, Guochun Zhang and Yicheng Wu
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02255J, Paper
K3LaTe2O9, a rare quaternary alkali-lanthanide tellurate with face-sharing TeO6 octahedra.
 
Korey Prescott Carter, Cecilia Zulato, Emille Martinazzo Rodrigues, Simon Pope, Fernando Aparecido Sigoli and Christopher L Cahill
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02596F, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
 
A. Starobrat, M. J. Tyszkiewicz, W. Wegner, D. Pancerz, P. A. Orłowski, P. J. Leszczyński, K. J. Fijalkowski, T. Jaroń and W. Grochala
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02005K, Paper
Metathetic reactions using salts of highly-fluorinated weakly coordinating anions permit synthesis of high-purity hydrogen storage materials.
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02661J, Perspective
Ortho-vanillin became very popular in coordination chemistry because of its Schiff bases, which generate a rich variety of complexes, ranging from oligonuclear species to coordination polymers. The hetrobinuclear 3d-3d’ and...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02572A, Paper
The reaction of 3-perylenylmethylen-4’-ethylaniline (1) with [Pt2Me4(μ-SMe2)2] (and subsequent addition of PPh3) or with [Pt2(η3-C4H7)2(μ-Cl)2] produced cyclometallated PtII complexes [Pt(C^N)Me(PPh3)] (2) and, respectively, [Pt2(C^N)2(μ-Cl)2] (3) (HC^N = 3-C20H11CH=NC6H4-p-C2H5), with Pt...
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02350E, Perspective
Advances and recent breakthroughs in catalytic synthesis of carboxylic acids and their derivatives starting from unsaturated hydrocarbons are discussed.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01552A, Paper
The effects of pH value on the phase transition, microstructure evolution and upconversion properties were demonstrated in Yb3+–Er3+ codoped LiYF4/YF3 nanoparticles.
 
Andy Schmied, Axel Straube, Toni Grell, Sascha Jähnigen and Evamarie Hey-Hawkins
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02567B, Paper
Flexible 1,1′-bis(phospholanoalkyl)ferrocenes react selectively with platinum(II), gold(I) and rhodium(I) to give macrocyclic chelate complexes.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02285A, Communication
An inverse linear relationship between the experimentally observed 195Pt NMR signals and the overall sum of coordinated halido X ligands’ ionic radii was discovered in Pt(II) and Pt(IV) complexes.
 
Vinod G. Landge, Manoj K. Sahoo, Siba P. Midya, Garima Jaiswal and Ekambaram Balaraman
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02772A, Communication
The first example of ligand-enabled C(sp3)-alkynylation of 8-methylquinoline is reported. The reaction is catalysed by well-defined Pd(II) complexes. The present C(sp3)-alkynylation has a broad substrate scope as well as functional group tolerance and proceeds under mild conditions.
 
Jie Liang, Jie Su, Yanping Chen, Zhaofei Li, Kuo Li, Hao Zhang, Xiaodong Zou, Fuhui Liao, Yingxia Wang and Jianhua Lin
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00487J, Paper
PKU-13 and PKU-13a, constructed by the same r52 layers by the insertion of mono- and double-layers of SDA molecules respectively, exemplify a structural transformation by the treatment of acetic acid.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01193K, Paper
Synthesis of gold nanoparticle (GNP) decorated-graphene sheets (GO-GNPs) using the template of graphene oxide (GO) by a one-pot solution-based method.
 
Marlene Kaposi, Mirza Cokoja, Christine Hutterer, Simone A. Hauser, Tobias Kaposi, Florian Klappenberger, Alexander Pöthig, Johannes Barth, Wolfgang A. Herrmann and Fritz Elmar Kühn
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01340B, Paper
Amino-functionalised metal-organic frameworks UiO-66 and -67 were post-synthetically modified with salicylaldehyde. A molybdenum complex was immobilised on the resulting materials. They were characterised by 13C-MAS-NMR and PXRD to confirm immobilisation...
 
OSVALDO DE LAZARO CASAGRANDE, Jean-Francois Carpentier, Evgueni Kirillov, Thierry Roisnel and Adriana Pinheiro
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02025E, Paper
Chromium(III) complexes [CrCl2(L)(THF)] based on monoanionic tridentate ligands [2a, L = {2-(C4H3N-2’-CH=N)C2H4NHPh}; 2b, L = {5-tert-butyl-2-(C4H2N-2′-CH=N)C2H3NHPh}; 2c, L = {2-(C4H3N-2’-CH=N)C2H4OPh}] have been prepared. Complexes 2a,b were converted into the monomeric...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02356D, Paper
Two organoboron based fluorophores Pyrazabole 3 and BODIPY 4 has been designed and synthesized by the Pd-catalyzed Sonogashira cross-coupling reaction and successfully employed for fluoride and cyanide ions sensing. The...
 
Edmundo Guzmán-Percástegui, Mireille Vonlanthen, Beatriz Quiroz-García, Marcos Flores-Alamo, Ernesto Rivera and Ivan Castillo
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02058A, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01569C, Paper
A series of Fe3+ based double-stranded helicates unveil a significant magnetocaloric effect as well as binding activities with Rhodamine B dye and CT-DNA.
 
Younes Brahmi, Nadia Katir, Juan Antonio Macia Agullo, Ana Primo, Mosto Bousmina, Jean Pierre Majoral, Hermenegildo Garcia and Abdelkrim El Kadib
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02367J, Paper
Tuning P-doping: phosphorus dendrimers enabled access, at 60 °C, to ultra-stable organophosphonate-bridged-anatase mesocrystals with a promising water-splitting photo-activity.
 
Qin-Qin Hu, Yi-Zhou Zhu, Shao-Chun Zhang, Yu-Zhang Tong and Jian-Yu Zheng
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01184A, Paper
Three meso-2′-linked porphyrin–BODIPY hybrids (BDP–ZnP, 2BDP–ZnP, and 4BDP–ZnP) were synthesized, and fast and highly efficient energy transfer was achieved.
 
Olena O. Litsis, Vladimir A. Ovchynnikov, Vasyl P. Scherbatskii, Sergiy G. Nedilko, Tatiana Yu. Sliva, Viktoriya V. Dyakonenko, Oleg V. Shishkin, Valentine I. Davydov, Paula Gawryszewska and Vladimir M. Amirkhanov
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02557E, Paper
La–Eu substitution affects the LnPip3Phen properties.
 
Tao Luo, Rui Zhang, Xiao Shen, Wei Zhang, Chuanfa Ni and Jinbo Hu
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02088C, Paper
An efficient 1,2-fluorine migration reaction was realized under Brønsted acid catalysis in the absence of an external fluorinating source. The high fluorine atom economy and very mild conditions make this reaction a promising protocol for the construction of the C–F bond.
 
O. A. Bulavchenko, Z. S. Vinokurov, T. N. Afonasenko, P. G. Tsyrul'nikov, S. V. Tsybulya, A. A. Saraev and V. V. Kaichev
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01440A, Paper
The reduction of the solid solutions MnxZr1−xO2−δ proceeds via two stages. During the first stage, the Mn cations incorporated into the solid solutions MnxZr1−xO2−δ undergo partial reduction. At the second stage, Mn cations segregate on the surface.
 
Suresh Kannan Balasingam, Jae Sung Lee and Yongseok Jun
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01985K, Paper
Few-layered MoSe2 nanosheets are synthesized via a facile hydrothermal method. A symmetric two-electrode device consisting of MoSe2 nanosheets showed enhanced performance and good capacitance retention over 10 000 cycles.
 
Abed Hasheminasab, Lei Wang, Mahesh B. Dawadi, Jacob Bass, Richard S. Herrick, Jeffrey Rack and Christopher Ziegler
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02480C, Communication
Re(CO)3 conjugates 1 and 2 that incorporate azobenzenes can be readily generated via one-pot reactions using Schiff base reaction forming conditions. Excitation of the MLCT bands in 1 and 2...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02371H, Paper
We describe herein the synthesis, characterization and photophysical properties of a series of europium complexes based on three aminophenyl based polyfluorinated β-diketonates, namely, 1-(4-aminophenyl)-4,4,5,5,5-pentafluoro-3-hydroxypent-2-en-1-one, 1-(4-(dimethylamino)phenyl)-4,4,5,5,5-pentafluoro-3-hydroxypent-2-en-1-one and 1-(4-(diphenylamino)phenyl)-4,4,5,5,5-pentafluoro-3-hydroxypent-2-en-1-one and an ancillary...
 
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