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Journal cover: Journal of the Chemical Society, Dalton Transactions

Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.177 48 Issues per Year
 
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Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03073D, Paper
The azido ligand is widely used in coordination chemistry both as a ligand and as a metal-bound reactant. Its role as a bridge for magnetic exchange coupling has attracted a...
 
Hitomi Ohmagari, Ryo Ohtani, Manabu Nakaya, Masaaki Ohba, Masaaki Nakamura, Leonard F Lindoy, Osamu Sato and Shinya Hayami
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03474H, Communication
Cobalt-iron Prussian blue analogues are magnetic functional compounds that exhibit a charge-transfer-induced spin transition (CTIST), however, a role of guest species such as water in influencing the magnetic behaviour has...
 
Anuson Sansee, Sureemas Meksawangwong, Kittipong Chainok, Katherine J Franz, Miroslav Gal, Lars-Olof Palsson, Wikorn Puniyan, Rakcahrt Traiphol, Robert Pal and Filip Kielar
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02776H, Paper
Herein we report the synthesis and investigation of propertis of two tris-cyclometalated luminescent iridium complexes. These complexes are simple derivatives of fac-[Ir(ppy)3] bearing amino alkyl groups on one of the...
 
M. K. Kadirov, I. R. Knyazeva, I. R. Nizameev, R. A. Safiullin, V. I. Matveeva, K. V. Kholin, V. V. Khrizanforova, T. I. Ismaev, A. R. Burilov, Yu. H. Budnikova and O. G. Sinyashin
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02881K, Communication
The catalytic activity of nickel complexes of calix[4]resorcinols in PEMFC has been studied.
 
Toyotaka Nakae, Masakazu Hirotsu, Shigetoshi Aono and Hiroshi Nakajima
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03399G, Communication
Iron(III) carbonyl complexes are stabilized by an N,C,S-pincer ligand and two axial phosphines, showing CO-releasing properties induced by visible light.
 
Kangqiang Qiu, Yukang Liu, Huaiyi Huang, Chaofeng Liu, Hongyi Zhu, Yu Chen, Liangnian Ji and Hui Chao
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03328H, Communication
An efficient method that controls biscylometalated iridium(III) complexes to target mitochondria or lysosomes was presented.
 
Xiumei Song, Lichao Tan, Xiaojun Sun, Huiyuan Ma, Lin Zhu, Xiaoqing Yi, Qiang Dong and Junyu Gao
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03261C, Paper
A hierarchical structure of NiCo2O4@rGO composite has been fabricated, with its structure and morphology well characterized by XRD, TEM, XPS and BET.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02604D, Paper
A tripalladium(II) cyclophane system containing transannular π⋯π interactions acts as an efficient and quantitative triiodide scavenger through in situ crystallization of triiodide-exchanged species during a photoreaction. The recycling behavior can be ascribed to the rigidity and stability of the molecules.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03153F, Paper
The preparation of metal-free, Zn(II), In(III), and Cu(II)-phthalocyanines containing tetrakis-(3-phenylphenoxy) groups was achieved.
 
María J. Romero, Rocío Carballido, Laura Rodríguez-Silva, Marcelino Maneiro, Guillermo Zaragoza, Ana M. González-Noya and Rosa Pedrido
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03106D, Communication
We report on a meso-helicate exhibiting the inert pair effect for the first time, demonstrating that this effect must be considered for the controlled assembly of Pb(II) supramolecular helicates/mesocates.
 
Ana Mitrović, Jakob Kljun, Izidor Sosič, Stanislav Gobec, Iztok Turel and Janko Kos
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02369J, Paper
The clioquinol–ruthenium complex [Ru(η6-p-cymene)(Cq)Cl] inhibits cathepsin B and reduces tumour cell invasion at non-cytotoxic concentrations, revealing a specific anti-cancer mechanism not related to a general compound-induced cytotoxicity.
 
Sebastian Schmitz, Jan van Leusen, Natalya V. Izarova, Yanhua Lan, Wolfgang Wernsdorfer, Paul Kögerler and Kirill Yu. Monakhov
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03392J, Communication
Cooperative hydrogen bonds are key to the formation of nanosized {[{LnIII}{H2O⊂CrIII3LnIII6}]2(H2O)}-type single-molecule magnets, templated by a central water triad.
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03358J, Paper
Seven Eu-(H)BDC compounds, [RMI][Eu2(BDC)3Cl] (R = ethyl (1), propyl (2), butyl (3), H2BDC = 1,4-benzendicarboxylic acid), [EMI]2[Eu2(BDC)3(H2BDC)Cl2] (4), [Eu(BDC)(HCOO)] (5), [Eu(BDC)Cl(H2O)] (6) and [Eu3(BDC)4Cl(H2O)6] (7), were synthesized under ionothermal conditions....
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03270B, Paper
Two Cu(I) cyanide coordination polymers (CPs), namely, [Cu2(L1)(CN)2]n (1) and [Cu2(L2)(CN)2]n (2) (L1 = 4,4′-bis(2-methylbenzimidazol-1-ylmethyl)biphenyl, L2 = 4,4′-bis(5,6-dimethylbenzimidazol-1-ylmethyl)biphenyl) were synthesized and structurally characterized by single crystal X-ray diffraction, IR spectroscopy,...
 
Lixin Zang, Huimin Zhao, Jianyu Hua, Feng Qin, Yangdong Zheng, Zhiguo Zhang and Wenwu Cao
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03197H, Paper
The mechanism for the 40-fold enhancement in Gd-HMME RTP intensity by adding imidazole and Gd3+ is revealed.
 
Jing Xiang, Chang Shen, Shun-Cheung Cheng, Fei Yu, Wing-Kin Chu, Hua Feng, Shek-Man Yiu, Chi-Chiu Ko and Chi-Fai Leung
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02986H, Communication
Luminescent porous coordination polymers, cage-containing chains [Pb5(L1)6(N3)2(OH)2]n (1) and 1-D double helical chains [Pb(L2)(N3)]n (2) with 1-D channels were prepared by solvothermal reactions.
 
Rosa Padilla, Verónica Salazar-Pereda, Daniel Mendoza-Espinosa, José M. Vásquez-Pérez, Noemí Andrade-López, Joaquín Tamariz, José G. Alvarado-Rodríguez and Julián Cruz-Borbolla
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02866G, Paper
Coupling of the exocyclic diene-[Ir] complexes 2 with several aromatic aldehydes leads to the bicyclic derivatives 4 and a novel series of bicyclic Fischer-type carbenes 5.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03050E, Paper
Gold nanoparticles supported by imidazolium-based porous organic polymers exhibit higher catalytic activity, selectivity and recyclability than those supported by a non-ionic analogue.
 
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02564A, Communication
The chirality transfer between inorganic polyoxometalate clusters is realized by the suitable mediation of counterions through multi-interactions in aqueous solution.
 
Rebecca C. Gregory, Glyn R. Hemsworth, Johan P. Turkenburg, Samuel J. Hart, Paul H. Walton and Gideon J. Davies
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02793H, Paper
The enzymatic deconstruction of recalcitrant polysaccharide biomass is central to the conversion of these substrates for societal benefit, such as in biofuels.
 
Suman Rana, Neena G. Shetake, Kanhu Charan Barick, BN Pandey, Hemant Salunke and Puthusserickal Hassan
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03323G, Paper
Interfacial engineering of magnetic nanoparticles (MNPs) with specific functional groups or targeting ligands is important for their in-vivo applications. We report here the preparation and characterization of bifunctional magnetic nanoparticles...
 
Davide Espa, Luca Pilia, Luciano Marchiò, Flavia Artizzu, GABRIELE DI CARLO, Daniele Marinotto, Angela Serpe, Francesca Tessore and Paola Deplano
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02911F, Paper
A film of [Pd(R2pipdt)(dmit)] (1), where R2pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmetacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02406H, Paper
Theoretical calculations on a series of molecular models based on amino derivatives of linear and cycled acenes acting as organic linkers between two copper(II) ions have shown a wire-like magnetic...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02168A, Communication
Hydrothermal reactions of Cu(II)/Zn(II)/Cd(II) with 5, 5'-bistetrazole (H2BT) lead to three new energetic coordination polymers: [CuBT(H2O)]n (1) , [ZnBT(H2O)2]n (2) , and [CdBT(H2O)2]n (3). These crystal structures were determined by...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03243E, Paper
The behavior of a series of Manganese (Mn) carbonyl compounds with 2,2′:6′,2′′-terpyridine (tpy) in κ2-N,N′ and κ3-N,N′,N′′ coordination modes under electrochemically reducing conditions is reported. In the presence of carbon...
 
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