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Journal cover: Journal of the Chemical Society, Dalton Transactions

Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
 
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Karlee Bamford, Lauren Longobardi, Lei Liu, Stefan Grimme and Douglas W Stephan
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT01024A, Paper
Redox active, or non-innocent, ligands containing O or N heteroatoms are frequently used in transition metal complexes, imparting unique catalytic properties, but have seen comparatively limited use in the chemistry...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00362E, Paper
Acetamide diethylphosphonate (AcPhos)-functionalized silica has been shown to have a high affinity for U(VI) in pH 2-3 nitric acid. Previous work with AcPhos-functionalized silica has focused on actinide and lanthanide...
 
Akihiro Tsurusaki, Keisuke Yoshida and Soichiro Kyushin
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00395A, Communication
The reactions of trialkyl borates B(OR)3 (R = Me, i-Pr) with dimethylphenylsilyllithium gave lithium alkoxytris(dimethylphenylsilyl)borates 1a,b. X-ray crystallographic analysis showed that 1a,b were obtained as a contact ion pair and...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00806F, Paper
Synthesis of novel heteroleptic organomagnesium(II) amide complexes [IMesMg(Ar){N(SiMe3)2}]; (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene), Ar = 2,6-Me2C6H3 (Xyl) (1) and 2,4,6-Me3C6H2 (Mes) (2) are reported. Both compounds 1 and 2 were confirmed by...
 
Bence Kutus, Norbert Varga, Gábor Peintler, Alexandru Lupan, Amr A Attia, Istvan Palinko and Pal Sipos
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00909G, Paper
The complex formation between Nd(III) and D-gluconate (Gluc–) is of relevance in modelling the chemical equilibria of radioactive waste repositories. In the present work, the formation of NdpGlucqH–r complexes at...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00718C, Paper
The diversity of the self-assembled structures of a Cu complex via hydrogen bonding, including a square planar unit, is reported. The Cu complex forms two self-assembled structures by hydrogen bonding,...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00640C, Communication
Ti-SSZ-70 and Ti-ECNU-6, with identical intralayer sturcture but distinct interlayer connections, were prepared from similar synthetic gels free of alkali metal ions and boric acid. Ti-SSZ-70, composed of vertically mis-aligned...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00477J, Paper
The crystallographic signatures and characterization of two novel mixed metal hybrid open-framework [Na2Mn2(C2O4)(SO3)2(H2O)2], 1 and [NaEu(C2O4)(SO3)(H2O)3], 2 are reported for the first time, synthesized under hydrothermal conditions to generate 3D...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00457E, Paper
Three isostructural halozincates, [HNH][ZnX4]∙H2O (HNH2+ = protonated nicotinohydrazide, X = I (1), Br (2), Cl (3)), have been synthesized and exhibit halogen-dependent photoinduced electron transfer and chromic properties. Due to...
 
Ian R Colinas, Kenneth Kazuya Inglis, Frédéric Blanc and Scott Oliver
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00475C, Paper
We report a detailed study of the host-guest interaction for a cationic metal-organic framework that can reversibly capture perchlorate in record amount. The structural transformation and flexibility of silver 4,4'-bipyridine...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00545H, Paper
We present the variable-pressure luminescence spectra of crystals of isostructural palladium(II) and platinum(II) complexes with bis-N-benzyl-N’-3-methylpyridyldithiocarbamate (bmpDTC) ligands. The d-d luminescence band maxima Emax for these complexes are compared to...
 
Marcus Lau, Thomas Straube, Vikas Aggarwal, Ulrich Hagemann, Bernardo de Oliveira Viestel, Nils Hartmann, Torsten Textor, jochen gutmann and Stephan Barcikowski
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00010C, Paper
Indium tin oxide (ITO) particle coatings are known for high transparence in the visible, good conductive properties and near-infrared absorption. These properties depend on ITO particle’s stoichiometric composition, defects and...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00733G, Paper
Two new dinuclear nickel(II) complexes namely [Ni2(L1)2(OAc)2(H2O)2].CH3CN (1) and [Ni2(L2)2(SCN)2(CH3OH)2].CH3OH (2) have been synthesized from designed Schiff-base ligand 4-Bromo-2-[(2-hydroxy-1,1-dimethyl-ethylimino)-methyl]-phenol (HL1) and its reduced analogue 4-Bromo-2-[(2-hydroxy-1,1-dimethyl-ethylamino)-methyl]-phenol (HL2), respectively. Both 1 and...
 
Chengzhen Wei, Cheng Cheng, De Chen Kong, Wei Min Du, Jianbo Zhao, Yeqin Feng and Qingling Duan
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00355B, Paper
In this work, we have successfully developed a simple self-template route for preparation of hollow ellipsoids Ni-Mn sulfides. This route involves the synthesis of solid state Ni-Mn ellipsoids via a...
 
Aleksei Yu. Nikulin, Elena A. Zvereva, Vladimir B. Nalbandyan, Igor Shukaev, Alexander I. Kurbakov, Maria D. Kuchugura, Grigoriy V. Raganyan, Yuri Popov, Vladislav D. Ivanchenko and Alexander N. Vasiliev
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04859E, Paper
MSb2O6 compounds (M = Mg, Co, Ni, Cu, Zn) are known in the tetragonal trirutile forms, slightly distorted monoclinically with M=Cu due to the Jahn-Teller effect. In this work, using...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04262G, Paper
The new water soluble complex [RuCp(H2O-κO)(PTA)2]+ (1) (PTA = 1,3,5-triaza-7-phosphaadamantane) has been synthesized and fully characterized by NMR and IR. The crystal structure of 1(CF3SO3)·3.5H2O was characterized by single crystal...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00627F, Paper
Four titanium-oxo-clusters with cyclohex-3-ene-1-carboxylate (Cec) ligands, Ti6(2O)2(3O)2(Cec)4(OiPr)12 (PTC-91; HOiPr = isopropanol), Ti6(3O)6(Cec)6(OiPr)6 (PTC-92 and PTC-93) and H2[Ti18(2O)11(3O)14(Cec)20(OiPr)4] (PTC-94), have been solvothermally synthesized under different conditions, respectively. These clusters with the...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00629B, Paper
Photocatalytic hydrogen (H2) production from water by using solar energy and photocatalyst is a green and sustainable route to tackle the energy issues. Herein, carbon/g-C3N4 nanocomposites were successfully synthesized via...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00056A, Paper
A unique redox active flexible solid-state asymmetric supercapacitor with ultra-high capacitive and energy density was fabricated using a composite comprising MgCo2O4 nanoneedles and micro and mesoporous silicon carbide flakes (SiCF)...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00848A, Paper
Increasing electrical conductivity in oxides, which are inherently insulators, can be potential route in developing oxides based thermoelectric power generators with higher energy conversion efficiency. In the present work environmental...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00819H, Paper
Novel layer-like Ni(OH)2 co-catalysts decorated ZnIn2S4 microsphere photocatalysts were synthesized for the first time via a facile in-situ deposition method to boost the photocatalytic H2 production performance. The physical and...
 
Klara Melanova, Ludvík Beneš, Jan Svoboda, Vitezslav Zima, Milan Vlček and Miroslava Trchova
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00492C, Paper
Eight new barium methylphosphonates were prepared and described. In dependence on pH, either barium hydrogen methylphosphonate or barium methylphosphonates can be formed. In the case of barium methylphosphonates, BaCH3PO3·3H2O crystallizes...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00615B, Paper
Four structurally intriguing members of a new family of lanthanide (Ln)-containing organophosphonate-functionalized polyoxotungstates with the general formula K2[Ln(H2O)4(AsW9O33)(W2O3)(O3PCOHCH3PO3)Ln(H2O)7]2∙15H2O [Ln = Ce (1Ce), Nd (2Nd), Sm (3Sm) and Eu (4Eu)] were...
 
Cheng-Hua Deng, Tao Li, Jing-Huo Chen, Jian-Gong Ma and Peng Cheng
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00808B, Communication
Pinene is a family of bicyclic monoterpene found in nature, which appears in conifers, limes and numerous other plants, and exhibits important applications in the production of perfumery, turpentine, antiseptic,...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00789B, Paper
Different aluminum complexes were synthesized by the reaction of aluminum alkyls with a hexadentate salen-type Schiff base. Reaction of N,N’-bis(3,5-di-tert-butylsalicylidene)-2,2’-(ethylenedioxy)dianiline (LH2) with one equiv of AlMe3 in toluene at 100...
 
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