Journal cover: Journal of the Chemical Society, Dalton Transactions

Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
 
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Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03518F, Paper
In order to understanding of how the polarization of aromatic systems, through the introducing of nitrogen heteroatom, affects the π-π interactions and crystal packing of mercury coordination compounds, in this...
 
Xinhao Shi, Wei Gu, Zhang Cuiling, Longyun Zhao, Weidong Peng and Yuezhong Xian
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03883E, Paper
In this work, we developed a novel, label-free, colorimetric sensor for Pb2+ detection based on the acceleration of gold leaching by graphene oxide (GO) at room temperature. Gold nanoparticles (AuNPs)...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03599B, Paper
The insertion reactions of lithium silylquinolylamide dimers [{8-(2-R-C9H5N)N(Me3Si)}Li•OEt2]2 (R = H, 1a; R = Me, 1b) with dimethylcyanamide afforded dimeric lithium 8-quinolylguanidinates [{8-(2-R-C9H5N)NC(NMe2)N(SiMe3)}Li]2 (R = H, 2a; R = Me,...
 
Saverio Santi, Annalisa Bisello Bisello, Roberta Cardena and Alessandro Donoli
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03581J, Perspective
In this review, the properties of the most significant examples of multi(ferrocenyl) cations containing a number of ferrocenyl units from two to six will be discussed and the results compared...
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03820G, Paper
Mixed cyanide/isocyanide Pt(II) complexes exhibit vapoluminescence. Mechanistic studies of polymorphs and solvates of these complexes indicate large reversible photoluminescence changes accompany inclusion of stoichiometric amounts of water.
 
Keith J. Cordrey, Magda Stanczyk, Charlotte A. L. Dixon, Kevin S. Knight, Jonathan Gardner, Finlay D. Morrison and Philip Lightfoot
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03721A, Paper
Phase behaviour in the layered perovskite LaTaO4 has been analysed, including an unusual tilt-induced axial thermal contraction effect.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03426K, Paper
Here, we demonstrate an uninterrupted galvanic replacement reaction (GRR) for the synthesis of metallic (Ag, Cu and Sn) and bimetallic (Cu–M, M[double bond, length as m-dash]Ag, Au, Pt and Pd) sponges/dendrites by sacrificing the low reduction potential metals (Mg in our case) in acidic medium.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03282A, Paper
A new strategy of utilizing the cage size effect for simultaneously enhancing the β0 and the VIP.
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT04038D, Communication
In this work, the (1-x)(K0.48Na0.52)(Nb0.95-y-zTazSby)O3 -xBi0.5(Na0.82K0.18)0.5ZrO3, {abbreviation: KNNST-BNKZ-x-y-z} lead-free piezoceramics were prepared by conventional solid-state reaction method, and the composition dependence of their phase structures and electrical properties was systematically...
 
Srikanta Patra, Tushar Kant Beuria, Suman Kumar Tripathy, Niranjan Dehury, Anupam Sahoo, Satyanaryan Pal and Ashoka Charry Taviti
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03647F, Paper
Abstract Mononuclear half sandwiched complexes [(p-cym)RuCl(bpmo)](ClO4) {[1](ClO4)} and [(p-cym)RuCl(bpms)](PF6) {[2](PF6)} have been prepared by reacting heteroscorpionate ligands bpmo = 2-methoxyphenyl-bis(3,5-dimethylpyrazol-1-yl)methane and bpms = 2-methylthiophenyl-bis(3,5-dimethylpyrazol-1-yl)methane, respectively, with dimeric precursor complex [(p-cym)RuCl(-Cl)]2...
 
Haihong Yin, Ke Yu, Jingjing Hu, Changqing Song, Bangjun Guo, Zhiliang Wang and Ziqiang Zhu
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00015G, Paper
Three different kinds of V2O5/ZnO heteronanorods were synthesized through a CVD process and oxidized in air at temperatures of 350, 420 and 500 °C. These 1D heteronanorods are formed by...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03897E, Communication
Copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) click chemistry has inherent challenges for copper-labeled radiopharmaceuticals. An azide-modified phosphonate-based cross-bridged macrocyclic chelator was synthesized for click chemistry conjugation with azide-modified Y3-TATE (a somatostatin analogue)...
 
Branson A Maynard, Jessica C. Brooks, Emily Elizabeth Hardy, Christopher J Easley and Anne E. V. Gorden
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00106D, Communication
Metal templation by condensation of 2,3-diaminophenazine with 3,5-di-tert-butyl-2-hydroxybenzaldehyde around metal centers [M= Cu(II), and UO2(VI)] affords a new class of M[di-tert-butyl salphenazine] metal complexes. Reported here is the synthesis, single...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03801K, Paper
The structure, bonding and reactivity of 2-adamantylidene and its heavier group-14 analogues, 2X (X10H14, X = C – Sn), have been studied at the M06/def2-TZVPP//BP86/def2-TZVPP level of theory. 2-adamantylidene and...
 
Jaewoo Kwak, Nguyen Van Nghia, Junseong Lee, Hyoseok Kim, Myung Hwan Park and Min Hyung Lee
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00042D, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00144G, Communication
High regioselectivity was achieved in the Cu(I)-catalyzed borylation of internal propargylic alkynes with a silyl substituent to afford mutifunctionalized alkenylboron compounds. While both the silyl and propargylic substituents are known...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03267E, Paper
A systematic theoretical study is reported on the mechanisms for reductive elimination from arylPd(II) trifluoromethyl complexes, an important elementary reaction for Pd-catalyzed trifluoromethylation reactions. Various mechanisms leading to the formation...
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03698K, Communication
A new thermally stable copper phosphonate with pores of 9.4 Å diameter and a high water uptake at p/p0 = 0.2 is described.
 
Kamran T Mahmudov, M. Fátima C. Guedes da Silva, Manas Sutradhar, Maximilian N. Kopylovich, Fatali E. Huseynov, Nazim T. Shamilov, Anna A. Voronina, Tatyana M. Buslaeva and Armando J. L. Pombeiro
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03788J, Paper
The complexes [KLa(HL1)2{(CH3)2NCHO}2(H2O)3] (1) and [Sm(H2O)9](E-H2L2)3•2H2O (2) were synthesized by reaction of lanthanum(III) and samarium(III) nitrates with potassium 3-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl)-2-hydroxy-5-nitrobenzenesulfonate (KH2L1) and potassium (E,Z)-5-chloro-3-(2-(1,3-dioxo-1-phenylbutan-2-ylidene)hydrazinyl)-2-hydroxybenzenesulfonate (KH2L2), respectively. Both complexes were fully characterized...
 
Angel M. Arevalo-Lopez and J. Paul Attfield
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03780D, Paper
Magnetic moments show a surprising degree of spin canting in the antiferromagnetic structure of the brownmillerite Ca2Cr2O5, obtained from the high pressure perovskite CaCrO3 through hard-soft chemistry.
 
Xiaoming Lv, Yihua Zhu, Hongliang Jiang, Xiaoling Yang, Yanyan Liu, Yunhe Su, Jianfei Huang, Yifan Yao and Chunzhong Li
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03803G, Paper
The NiCo2O4 nanocage with a hollow cavity, large roughness and high porosity exhibits an excellent and stable activity for the oxygen evolution reaction (OER) catalysis.
 
Antonio J. Dos santos-García, Elena Solana-Madruga, Clemens Ritter, David Ávila-Brande, Oscar Fabelo and Regino Sáez-Puche
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03849E, Paper
Mn2CrSbO6-perovskite was synthesized at high pressure in order to stabilize the small Mn2+ cations on the A-perovskite site. Mn2CrSbO6-ilmenite polymorph can be prepared, starting from the perovskite, by a “hard-soft” phase transformation increasing the temperature at room pressure.
 
Gurpreet Kaur, Matthew I. J. Polson and Richard M. Hartshorn
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03089C, Paper
Box structures containing four ligands and four metal ions (two of each of two kinds) and labile ligands that point into the box cavity have been prepared – as well as decanickel wheels.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03691C, Paper
The critical effects of small organic ligands such as urea on the assembly of 1D strontium vanadium oxide chains using the principles of molecular self-assembly are discussed.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03557G, Paper
Synthesis of alloy AuCu nanoparticles with the L10 structure in an ionic liquid using sputter deposition.
 
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