Journal cover: Journal of the Chemical Society, Dalton Transactions

Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
 
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Letizia Sambri, Andrea Baschieri, Sara Muzzioli, Elia Matteucci, Stefano Stagni and Massimiliano Massi
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01910E, Communication
The design of a relatively simple bifunctional ligand led to the obtainment of three new Ir(III)2-Eu(III) heterometallic complexes. Variation of the degree of fluorination in the cyclometalating ligands coordinated to...
 
Wei Liu, Ying Ji, Xijian Bao, Ying Wang, Benxian Li, Xiaofeng Wang, Xudong Zhao, Xiaoyang Liu and Shouhua Feng
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01707B, Paper
Two new europium silicates, Na15Eu3Si12O36 (denoted as 1) and K2EuSi4O10F (denoted as 2), were successively synthesized under high-temperature and high-pressure conditions, and structurally characterized by single-crystal and powder X-ray diffraction...
 
Daria Mikhailova, Phillip Reichel, Alexander A Tsirlin, Artem M. Abakumov, Anatoliy Senyshyn, Kailash M. Mogare, Marcus Schmidt, Chang-Yang Kuo, Chih-Wen Pao, Tun-Wen Pi, Jyh-Fu Lee, Zhiwei Hu and Hao Tjeng
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01893A, Paper
We have realized a reversible structure transformation from one-dimensional 1D K4CdCl6-type Sr3CoMO6 with the Co2+/M4+ cation ordering into two-dimensional 2D double layered Ruddlesden-Popper structure Sr3CoMO7-δ with a random distribution of...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00908H, Paper
Two new coordination polymers, [Ni(H2O)(Hpdcd)(H2O)2].DMF (1) and [Co(H2O)(Hpdcd)(H2O)2].DMF (2) (H3pdcd = 1-(4-carboxypheny)-2,5-dimethyl, 1H-pyrrole-3,4-dicarboxylic acid), which were designed based on a tertiary amine ligand, were synthesized and characterized using multiple spectroscopic...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01476F, Paper
Abstract A simple and convenient approach denoted as gel-deposition-precipitation (G-D-P) for the preparation of core-shell-like silica@nickel species nanoparticles was studied systematically. Core-shell-like silica@nickel species nanoparticle consisted of a Si-rich core...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01686F, Paper
The CoMn2O4 hierarchical microspheres assembled by nanosheets through thermal decomposition of precursor at different temperatures were first used as catalysts in the reduction of p-nitrophenol to p-aminophenol. The sample prepared...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02101K, Paper
We report a novel synthesis approach employing bamboo leaves as sources of both C/N dopant and reductant to the formation of C/N co-doped TiO2 modified by Ag and g-C3N4 (Ag/CN-TiO2@g-C3N4)....
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01999G, Paper
The xFe2O3/yBiOCl composites (xFe/yBi, x/y = 0/100, 5/100, 10/100, 20/100, 30/100, 40/100 molar ratios) are, for the first time, prepared through an in situ hydrolysis method under hydrothermal conditions. The...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01575D, Paper
A vanadtungstate cluster-based organic–inorganic hybrid material [NiL4VIVWVI10WV2O40(VIVO)2] (1, L = 1,4-bis(imidazol-1-ylmethyl)benzene) was synthesized and characterized by elemental analysis, IR spectra, thermal gravimetric analysis, and single crystal X-ray direction analysis. Structural...
 
Yuancheng Li, TaeBum Lee, Kushan Weerasiri, Tanyu Wang, Emily Elizabeth Buss, Michael L. McKee and Anne E. V. Gorden
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01562B, Paper
The Cu(II) complex 1, Cu(II)-6-N-3,5-di-tert-butylsalicylidene-6,7-quinoxalinol-diamine, has been developed to address problems with current methods of catalytic oxidation using tert-butyl hydroperoxide (TBHP). Complex 1 demonstrated an increased capability to utilize TBHP...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01741B, Paper
ABSTRACT Chiral oxazoline based bi and hexadentate ligands built on cyclophosphazene cores have been synthesized and characterized. (NPPh2)2[NP(m-OC6H4C(O)OCH3)2] (1) was prepared by the reaction of gem-(NPPh2)2(NPCl2) with methyl-3-hydroxy benzoate in...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02045F, Communication
A 3D rare tetranuclear {In4(μ2-OH)3} building block based MOF {[In4/3(μ2-OH)(2,6-pydc)(1,4-bda)0.5(H2O)]•2H2O}n (2) is obtained through crystal transformation from a dimeric complex In3(2,6-pydc)3(1,4-bda)1.5(H2O)6 (1). With an 2D + 3D → 3D compact...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02100B, Paper
Four cationic iridium(III) complexes of the form [Ir(C^N)2(N^N)]+ bearing either a 2,5-dipyridylpyrazine (2,5-dpp) or a 2,2’:5’,2’’-terpyridine (2,5-tpy) ancillary ligand and either 2-phenylpyridine (ppy) or a 2-(2,4-difluorophenyl)-5-methylpyridine (dFMeppy) cyclometalating ligands were...
 
Yuanzhan Li, Keqing Zhao, chun Feng, Mark Robert James Elsegood, Timothy J. Prior, Xinsen Sun and Carl Redshaw
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01936A, Paper
By varying the reaction conditions, the reaction of [W(eg)3] (eg = 1,2-ethanediolato) with p-tert-butylcalix[n]areneHn (n = 6 or 8) in refluxing toluene affords, following work-up, a number of products which...
 
Margaret Yankey, Collins Obuah, Ilia Guzei, Emmanuel Yaw Osei-Twum, Giovanni Hearne and James Darkwa
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01886A, Paper
The reaction of 2-{[2-(1H-imidazol-4-yl)-ethylimino]-methly}-phenol (L1), 2,4-di-tert-butyl-6-{[2-(1H-imidazol-4-yl)-ethylimino]-methyl}-phenol (L2) or 4-tert-butyl-2-{[2-(1H-imidazol-4-yl)-ethylimino]-methly}-phenol (L3) with iron(II) precursors produced either iron(II) or iron(III) complexes, depending on the nature of the anions in the iron(II) precursor...
 
Mary Pryce, Conor Long, Jenifer Manton, Suzanne McMahon, Gregory M Greetham, ian Clarke, Wybren Jan Buma, Sander Woutersen, Saeed Amirjalayer, Emma Harvey and Anthony Coleman
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01544D, Paper
The photochemistry and photophysics of three model “half-sandwich” complexes (6-benzophenone)Cr(CO)3, (6-styrene)Cr(CO)3, and (6-allylbenzene)Cr(CO)3 were investigated using pico-second time-resolved infrared spectroscopy and time-dependent density functional theory methods. The (6-benzophenone)Cr(CO)3 complex was...
 
yangjuan ou, Dongguang Yin, Xianzhang Cao, chenchen wang, kailin song, bin liu, lu zhang, yanlin han and minghong wu
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00509K, Paper
A series of NaLuF4-based hexagonal phase upconversion nanocrystals (UCNs) were synthesized by a facile solvothermal method and the properties of the UCNs were investigated. The results show that the as-prepared...
 
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01243G, Communication
Upon addition of hexafluorophosphate salts, the nonemissive aqueous solution of a chloroplatinum(II) complex showed a remarkable luminescence enhancement.
 
Morten B. Ley, Mark Paskevicius, Pascal Schouwink, Bo Richter, Drew A. Sheppard, Craig E. Buckley and Torben R. Jensen
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01125B, Paper
Extraction of rare earth metal borohydrides with dimethyl sulfide produces M(BH4)3S(CH3)2 (M = Y or Gd) compounds, which eliminates halide salts.
 
Michael G. Pfeffer, Christian Pehlken, Robert Staehle, Dieter Sorsche, Carsten Streb and Sven Rau
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00761A, Paper
Supramolecular activation of an intramolecular ruthenium palladium hydrogen evolving photocatalyst using polyaromatic compounds.
 
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01522C, Paper
Isomeric (twisted and zigzag) double-chain {[Mn(H2O)4]2Ru2(CO3)4Br2}nn complexes show two-step magnetic ordering (5.0 K and 2.6 K) and metamagnetic behavior (1.2 kOe).
 
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01438C, Paper
A Pd–Ni alloy nanoparticle doped mesoporous SiO2 film shows good catalytic activity for C–C coupling with recyclability because the Ni in Pd–Ni inhibits Pd-oxidation.
 
Fu wen Fu, Michael L Huang, Meiling Du, Cunyan Hu, Liufang Wang, Cong Li, Yangyang Han, Xin Gan, Yong Chen and Weihua Mu
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01735H, Paper
Intensely luminescent 1,8-naphthyridine-BF2 complexes 19 containing terminal bidentate N^N^O and/or N^C^O groups are synthesized and structurally characterized by X-ray diffraction, electrospray ionization mass spectrometry, 1H and 19F NMR spectroscopy and...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01821D, Paper
The article deals with the newly designed mononuclear and asymmetric dinuclear osmium(II) complexes OsII(bpy)2(HL2–) (1) and [(bpy)2OsII(μ-HL2)OsII(bpy)2](Cl)2 ([2](Cl)2) / [(bpy)2OsII(μ-HL2)OsII(bpy)2](ClO4)2 ([2](ClO4)2), respectively, (H3L=5-(1H-benzo[d]imidazol-2-yl)-1H-imidazole-4-carboxylic acid and bpy=2,2/-bipyridine). The identity of 1...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01863J, Paper
A series of allyl modified nickelalactone derivatives of the general formula [(L)nNi{CH2C(CH3)C(CH3)CH2COO}] was synthesized via ligand exchange reactions in order to investigate the influence of the neutral ligand L on...
 
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