Journal cover: Journal of the Chemical Society, Dalton Transactions

Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
 
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Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04196E, Paper
In recent years, a series of fluoride carbonate crystals as second harmonic generation (SHG) materials have been considerably developed, however the lead in these materials are potential threat to the...
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04409C, Paper
An internal base bound to one of the diiron undergoes dissociation under a CO atmosphere and the freed base group as a proton relay enhances the catalysis of proton reduction.
 
Ralf Mede, Juliane Traber, Moritz Klein, Helmar Görls, Guido Gessner, Patrick Hoffmann, Michael Schmitt, Jürgen Popp, Stefan H. Heinemann, Ute Neugebauer and Matthias Westerhausen
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03551E, Paper
The 2,2-bis(3,5-dimethyl-1-pyrazolyl)ethanol heteroscorpionate ligand stabilizes a water-soluble and quite non-toxic photoCORM.
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04419K, Communication
We report herein the synthesis and structure of a 45-atom trigonal-prismatic Au-Ag bimetallic nanocluster, formulated as Au9Ag36(SPhCl2)27(PPh3)6, based on single-crystal X-ray crystallograpic determination. The structure can be described as a...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04702E, Perspective
Self-assembled metallosupramolecular architectures have become an increasingly popular area of inorganic chemistry. These systems show a range interesting biological, electronic and photophysical properties. Additionally, they display extensive host-guest chemistry that...
 
Sergiu Sova, Maria Cazacu, Ghénadie Novitchi, Giorgio Zoppellaro, Cyrille Train and Vladimir Arion
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00141J, Paper
A new iron(III)-centred ferric wheel Fe{Fe}6 of formula [Fe7(H2L)6(NCS)6](ClO4)3∙10H2O, where H4L = N,N´-bis(3-carboxylsalicylidene)-1,3-bis(3-aminopropyl)tetramethyldisil-oxane, was synthesised and fully characterised. There are competing antiferromagnetic exchange interactions along the rim (J1 = ‒1.00...
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04500F, Paper
Tremella-like nickel oxalate@nickel oxide (NiC2O4@NiO) core/shell hierarchical nanostructures have been successfully synthesized on nickel foam through a facile hydrothermal method followed by an electrochemical activation process.
 
Shiqing Wang, Xiaoping Yang, Jinjie Qian, Qipeng Li, Zhongning Chen, Lijie Zhang, Shaoming Huang, Chengri Wang and Richard A. Jones
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03830A, Communication
Two classes of magnetic Ni–Ln clusters with 7-metal cone-like and 13-metal sandwich architectures were constructed using a flexible long-chain Schiff base ligand.
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04458A, Paper
The new pyrrole ring π-bond bridged binuclear Mo complex catalyzes the regioselective hydroamination of phenylacetylene with a series of secondary amines at room temperature giving the products in very high yields.
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04695A, Paper
A new 1D CuII coordination polymer possesses antiferromagnetic exchange interactions, which was confirmed by the low-temperature heat capacity.
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04753J, Paper
By HR MALDI-FT-ICR and 1H NMR experiments we provide evidence that HS coordination occurs at the zinc centre. The zinc hydrosulfido adduct remained stable for a whole week, as assessed via NMR.
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04124H, Paper
A one-third lanthanum deficiency was created in Ba2LaMO6 compounds to form Ba2(La0.727Ba0.182M0.091)MO6 compounds (M5+ = Nb, Sb, and Bi) and the subsequent distortion of the octahedra was probed by various techniques.
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04522G, Paper
The M06-2X, B3PW91 and B3LYP computational results show that, from the kinetic viewpoint, only bulkier substituents have a significant stabilizing effect on the triply bonded RGa[triple bond, length as m-dash]SbR compounds.
 
Jiuqing Wen, Jun Xie, Rongchen Shen, Xin Li, XingYi Luo, Hongdan Zhang, Aiping Zhang and Guican Bi
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04575H, Paper
Ni12P5 modified g-C3N4 photocatalysts exhibit significantly enhanced photocatalytic H2-evolution activities under visible light irradiation.
 
Ganesan Anandhababu, Syed Comail Abbas, Jiangquan Lv, Kui Ding, Qin Liu, Dickson D. Babu, Yiyin Huang, Jiafang Xie, Maoxiang Wu and Yaobing Wang
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04705J, Paper
Synthesis of highly ORR active Porous 2D PFe–Pc electrocatalyst via simple solid-state chemical reaction without pyrolysis is reported.
 
P. Goodrich, H. Q. Nimal Gunaratne, L. Hall, Y. Wang, L. Jin, M. J. Muldoon, A. P. C. Ribeiro, A. J. L. Pombeiro, V. I. Pârvulescu, P. Davey and C. Hardacre
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04572C, Paper
A bis-oxazoline ligand has been complexed using Cu(II) and Zn(II) trifluoromethanesulfonate and a range of chiral ionic liquid (CIL) additives based on natural products were used as a co-catalyst for a Diels–Alder reaction.
 
Jiang Wang, Lin-Xi Shi, Jin-Yun Wang, Jin-Xiang Chen, Shenghua Liu and Zhong-Ning Chen
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04421B, Paper
4,5-Bis(2-methyl-5-phenylthiophen-3-yl)-1,3-dithiol-2-one (L1o) was elaborately designed to afford dithienyl-dithiolene as a new photochromic ligand. We descibe herein the preparation and characterization of unprecedented photochromic dithienyl-dithiolene complexes with cis-orientation of dithienylethene (DTE)...
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT90010D, Correction
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04675D, Paper
Four Cd(II)-based compounds (1-4) were synthesized from solvothermal reactions involving in situ aldimine condensation of o-diamino-functionalized precursor 3,6-di(4H-imidazol-4-yl)benzene-1,2-diamine (L), Cd(NO3)2•4H2O and aldehyde. Two modes of cycloaddition ([4+1] cycloaddition and [4+2]...
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04638J, Paper
The homogeneous catalytic dehydrogenation of formic acid in aqueous solution provides an efficient in situ method for hydrogen production, under mild conditions, and at an adjustable rate.
 
Javier Fernández Sanjulián, Madhu Chennabasappa, Susana García-Martín, Gwilherm Nénert, Alain Wattiaux, Etienne Gaudin and Olivier Toulemonde
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03927H, Paper
An oxygen-vacancy ordering related to the “314” model known for the Sr3Y1Co4O10.5 oxide is proposed for Sr4FeCo3O10.52 material despite there is neither A-site ordering nor A-site mismatch.
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04701G, Paper
A new 3-D open-framework Li-rich vanadoborate Li10[V12B18O60H6]•28H2O (1) has been successfully synthesized under hydrothermal conditions. The framework of this compound is constructed from the connection of [V12B18O60H6]10− clusters linked through...
 
Gen Liu, Yan Xu, yide han, Junbiao Wu, Junli Xu, Hao Meng and Xia Zhang
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04582K, Paper
A hierarchical zeolitic imidazolate framework-8 (micro/meso-ZIF-8) was fabricated by using cetyltrimethylammonium bromide as structure-controlling agent and L-histidine as co-templates. Compared to the conventional microporous ZIF-8 (micro-ZIF-8), the hierarchical porous structure...
 
S Melnikova, Maxim Molokeev, Natalia Mikhailovna Laptash, Evgeniy Il'ich Pogoreltsev, Sergey V Misyul and Igor Nikolaevich Flerov
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04874A, Paper
Single crystals of silicon double salt (NH4)3SiF7 = (NH4)2SiF6•NH4F = (NH4)3[SiF6]F were grown and studied by the methods of polarization optics, X-ray diffraction and calorimetry. A sequence of symmetry transformations...
 
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04472G, Paper
Well-defined CdS nanograin-sensitized one-dimensional (1D) Zr:α-Fe2O3 nanostructured arrays with enhanced photoelectrochemical performance are synthesized directly on F-doped SnO2 (FTO) using the hydrothermal method. Owing predominantly to the appropriate photogenerated electron–hole...
 
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