Journal cover: Journal of the Chemical Society, Dalton Transactions

Journal of the Chemical Society, Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
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Han Li, Wei Shi, Zheng Niu, Jingmin Zhou, Gang Xiong, Lei-Lei Li and Peng Cheng
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02871F, Communication
Two remarkable pentanuclear 3d-4f clusters Ln3Fe2 were synthesized and structurally characterized. Magnetic studies indicate that Gd3Fe2 possesses the significant magnetic entropy change (-ΔSm) of 31.7 J kg-1 K-1 and slow...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03320E, Paper
The metastable tetragonal Cu2Se phase as nanoflakes has been synthesized for the first time by treating CuCl2 taken in a mixture (1:1) of 1-octadecene and oleylamine with H2N−(CH2)3−SePh dissolved in...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03124E, Paper
Interpenetration is an intrinsic behaviour for the porous coordination networks. To prevent the interpenetration, a common strategy is the imposition of geometric or steric restrictions by incorporating bulky moieties into...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02993C, Paper
Two novel organic-inorganic hybrids, Na[PMoV8MoVI4O38(OH)2Zn4][pyim]2∙1.5H2O [ε(pyim)2] (pyim = 2-(2-Pydidyl)-imidazole) and [PMoV8MoVI4O37(OH)3Zn4]2[pyim]6∙4H2O [ε2(pyim)6], based on ε-Zn Keggin units {ε-PMoV8MoVI4O40-x(OH)xZn4} have been successfully synthesized under hydrothermal conditions by controlling pH values. Structural...
Xuebin Yu, Yingbin Tan, Lijun Zhang and Xiaowei Chen
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01592D, Paper
This paper reports a complete AB regeneration process, in which Bu3SnH was utilized as a reductant for reductive dechlorination of BCl3, and Et2PhN was selected as “helper ligands” to generate...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02603A, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02703E, Paper
Hydrogen bonding of water molecules to Mn4O4 inner cubane of S = 19/2 Mn12 SMM gives rise to geometric and magnetic asymmetries. Two Mn ions hydrogen bonded to water molecules depart from their Mn4+(S = 3/2) states and acquire an incipient Mn3+(S = 4/2) character. The magnetic moment vectors of the cubane Mn ions are inequivalent.
Paul A. Scattergood, Milan Delor, Igor V. Sazanovich, Oleg V. Bouganov, Sergei A. Tikhomirov, Alexander S. Stasheuski, Anthony W. Parker, Gregory M. Greetham, Michael Towrie, E. Stephen Davies, Anthony J. H. M. Meijer and Julia A. Weinstein
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01682C, Paper
Charge-transfer excited state branches over 3 pathways on the timescale up to 14 ps.
Qilu Yao, Ming Huang, Zhang-Hui Lu, Yuwen Yang, Yuxin Zhang, Xiang Chen and Zhen Yang
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02873B, Paper
Diverse mesoporous CuO nanostructures have been prepared by a facile and scaleable wet-chemical method and reduced to mesoporous Cu nanostructures by using the reductant of ammonia borane (AB). These mesoporous...
Benjamin James Pages, Dale L Ang, Elisé Patricia Wright and Janice Rae Aldrich-Wright
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02700K, Perspective
Increasing numbers of DNA structures are being revealed using biophysical, spectroscopic and genomic methods. The diversity of transition metal complexes is also growing, as the unique contributions that transition metals...
Tien-Wen Tseng, Tzuoo-Tsair Luo, Chang-Hsiu Tsai, Chun-Chi Chen, Gene-Hsiang Lee, Chih-Chieh Wang and Lu Kuang-Lieh
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02169J, Communication
The 2D protuberant-grid-type Zn(II)-organic framework consists of unusual racemic interdigitated bilayers and is comprised of a 3D intersecting channel system. The framework is thermally stable and the channels contain multiple...
Susan Berners-Price, Joseph J Moniodis, Donald S Thomas, Murray S Davies and Nicholas Patrick Farrell
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02942A, Paper
2D [1H, 15N] HSQC NMR spectroscopy has been used to monitor the reaction of fully 15N-labelled [{trans-PtCl(NH3)2}2(μ-trans-Pt(NH3)2{NH2(CH2)6NH2}2)]4+ (BBR3464 (15N-1)) with the 14-mer duplex (5'-{d(ATACATG(7)G(8)TACATA)}-3' . 5'-{d(TATG(18)TACCATG(25)TAT)}-3' or I) at pH...
Subrat Kumar Barik, Dipak Kumar Roy and Sundargopal Ghosh
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03027C, Paper
We report the synthesis, isolation and structural characterization of several moderately air stable nido-metallaboranes that represent boron rich open cage systems. The reaction of [Cp*CoCl]2, (Cp* = η5-C5Me5), with [BH3•thf]...
Fei Peng Zhuang, tao liu, Xianhui Xie, Cheng He and Chunying Duan
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02056A, Communication
It is a challenge to synthesize porous tubular coordination polymer with magnetic properties. Utilizing [FeII(bipy)(CN)4]2− (bipy = 2,2-bipyridine) as the building block to react with Mn2+, we successfully synthesized a...
Masaru Mochizuki, Tatsunari Inoue, Katsunori Yamanishi, Shiori Koike, Mitsuru Kondo, Liang Zhang and Hiromi Aoki
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02900C, Communication
Highly efficient perchlorate removal from water by a water-insoluble M2L4 type molecule is described.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02841D, Communication
A three-dimensional (3D), luminescent, 5-fold interpenetrating metal–organic framework (MOF), [Zn2(fdc)2(bpee)2(H2O)·2H2O] (1) exhibiting highly selective sensing of nitrobenzene (NB) via a fluorescence quenching mechanism has been demonstrated.
Verity S. Stafford, Kogularamanan Suntharalingam, Arun Shivalingam, Andrew J. P. White, David J. Mann and Ramon Vilar
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02910K, Paper
A series of metal complexes with substituted terpyridines show high affinity towards quadruplex DNA, particularly bimetallic (trpy)Pt/M(cyclen) complexes.
Fatih Pekdemir, Sertan Kurnalı, Abdurrahman Şengül, Ahmet Altındal, Ali Rıza Özkaya, Bekir Salih and Özer Bekaroğlu
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01761G, Paper
The ZnPc-perylenediimide hybrid displayed a well-defined electrochromic behaviour and the best photovoltaic conversion efficiency observed with a Pc-based organic solar cell.
Éva G. Bajnóczi, Eszter Czeglédi, Ernő Kuzmann, Zoltán Homonnay, Szabolcs Bálint, György Dombi, Péter Forgo, Ottó Berkesi, István Pálinkó, Gábor Peintler, Pál Sipos and Ingmar Persson
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02706J, Paper
In hyper-alkaline aqueous solutions, the three-legged stool-like [Sn(OH)3] is the only hydroxido complex with a very short (2.078 Å) Sn–O distance.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02294G, Paper
Accurate electronic structure calculations of the lowest excited states have been performed on twenty snapshots of a molecular dynamics simulation of [Fe(bpy)3]2+ dissolved in water.
Kuaibing Wang, Xiaobo Shi, Aiming Lu, Xiaoyan Ma, Zhiyang Zhang, Yanan Lu and Hongju Wang
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02456G, Paper
High N-doped C/Mn3O4 composites are charged and discharged faster and have higher capacitance than C/Mn3O4 nanostructures with low N-amounts with 96% retained capacitance after 500 cycles at a constant current.
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02468K, Paper
Nanolayered Mn oxides have been prepared by a very simple, cheap and high-yield method using soap, KOH, MnCl2 and H2O2. Scanning electron microscopy, transmission electron microscopy, dynamic light scattering, thermogravimetric...
Biprajit Sarkar, Stephan Hohloch, Fenja Leena Duecker, Selina Kaiser, Aljosa Bolje, Janez Kosmrlj and Ramananda Maity
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02879A, Paper
Cp*-Ir(III) complexes with additional chelating ligands are known active pre-catalysts for the oxygenation of C-H bonds. We present here eight examples of such complexes where the denticity of the chelating...
Davood Zare, Yan Suffren, Laure Guénée, Svetlana V. Eliseeva, Homayoun Nozary, Lilit Aboshyan-Sorgho, Stéphane Petoud, Andreas Hauser and Claude Piguet
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02336F, Paper
An unprecedented molecular [ErN9] chromophore emits simultaneous dual green (542 nm) and near-infrared (1540 nm) light upon indirect excitation.
Alexey Nazarov, Samuel M. Meier, Olivier Zava, Yulia Novosova, Elena Rudolfovna Milaeva, Christian Hartinger and Paul Dyson
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02764G, Paper
Chemotherapeutics for the treatment of tumorigenic conditions that feature novel modes of action are highly sought after to overcome the limitations of current chemotherapies. Herein, we report the conjugation of...
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