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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00798H, Paper
We report the structure and magnetic properties of two new iridium-based honeycomb Delafossite compounds, Cu3NaIr2O6 and Cu3LiIr2O6, formed by a topotactic cation exchange reaction. The starting materials Na2IrO3 and Li2IrO3,...
Philip Bulsink, Ahlam Alghamdi, Prajesh Joshi, Ilia Korobkov, Tom Woo and Darrin Richeson
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00661B, Paper
The organometallic and coordination chemistry of rhenium (I) has been largely restricted to bidentate α-diimine ligation and facial tricarbonyl coordination geometries. The thermal transformation of bidentate bis(imino)pyridine and bidentate terpyridine...
Sui-Jun Liu, Chen Cao, Chen-Chao Xie, Teng-Fei Zheng, Xiao-Lan Tong, Jin-Sheng Liao, Jing-Lin Chen, He-Rui Wen, Ze Chang and Xian-He Bu
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01349J, Paper
Two GdIII coordination polymers with the formula [Gd(cit)(H2O)]∞ (1) and [Gd(nta)(H2O)2]∞ (2) (H4cit = citric acid, H3nta = nitrilotriacetic acid) have been successfully prepared under hydrothermal conditions. Complex 1 exhibits...
Marcel Kühling, Robert McDonald, Phil Liebing , Liane Hilfert, Michael J Ferguson, Josef Takats and Frank T Edelmann
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01439A, Communication
Well-defined lanthanide polysulfide complexes containing S42- and S52- ligands, the samarium(III) pentasulfide complex Sm(TpiPr2)(κ1-3,5-iPr2Hpz)(S5) and the tetrasulfide-bridged binuclear ytterbium(III) complex (µ-S4)[Yb(TpiPr2)(κ1-3,5-iPr2Hpz)(κ2-3,5-iPr2pz)]2 (TpiPr2 = hydro-tris(3,5-diisopropylpyrazolyl)borate), have been synthesized and structurally characterized...
Hou-Ji Cao, Qianyi Zhao, Qian-Fan Zhang, Jiaxuan Li, Ewan J. M. Hamilton, Jie Zhang, Lai-Sheng Wang and Xuenian Chen
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01272H, Paper
Agostic interactions are often used to activate inert C‒H bonds, and thus facilitate new reactions. We report the first example of designed catalysts based on the agostic interaction. Novel copper(I)...
Rui Li, Fangxia Xie, Jianxin Liu, Yawen Wang, Yunfang Wang, Xiaochao Zhang and Caimei Fan
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00997B, Paper
In this study, a novel visible-light-sensitive Bi4O5Br2 photocatalyst was successfully synthesized via the structure reorganization of BiOBr at room temperature using NH3•H2O as structure-controlling agent. The resulting Bi4O5Br2 photocatalyst presented...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01093H, Paper
Herein we reported that KMnO4 with iron nanoparticles coated with gold layers was a promising catalyst for water oxidation. The compound was characterized by scanning electron microscopy, energy-dispersive spectroscopy, transmission...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01221C, Paper
Photochemical hydrogen evolution studies aimed at evaluating new molecular catalysts have usually exploited Ru(bpy)32+ (where bpy = 2,2’-bipyridine) as the photosensitizer of reference, thanks to its suitable optical and redox...
Manuel Wilke, Ana Guilherme Buzanich, Uwe Reinholz, Klaus Rademann and Franziska Emmerling
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00787B, Paper
We describe a fast and effective synthesis for molecular metal phosphonates, which are of interest based on their catalytic and magnetic properties. The isomorphic compounds [M(II)(HO3PPh)2(H2O3PPh)2(H2O)2] (M = Mn (1),...
Markus Braumueller, Martin Schulz, Magdalena Staniszewska, Dieter Sorsche, Markus Wunderlin, J Popp, Julien Guthmuller, Benjamin Dietzek and Sven Rau
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01047D, Paper
With Re(L1)-Re(L3) a series of rhenium(I) tricarbonyl chloride complexes with bpy-R2 derivatives L1-L3 (bpy = 2,2’-bipyridine, R represents the substitution at 4- and 4’-position) and their corresponding trishomoleptic Ru(L1)3-Ru(L3)3 as...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00776G, Paper
The reactivity of thorium–phosphido and thorium–arsenido bonds was probed using tert-butyl isocyanide, tBuNC.
Laia Cuesta-Aluja, Javier Castilla and Anna M Masdeu-Bultó
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01069E, Paper
A higly stable and easy to synthesize aluminium complex bearing a flexible N2O2-donor salabza ligand (N,N’-bis(salicylene)-2-aminobenzylamine) in combination with tetrabutylammonim bromide forms an active binary catalytic systems for the cycloaddition...
Vadapalli Chandrasekhar, Joydeb Goura, Jamie Brambley, Paul Goddard, Craig Topping, R Suriya Narayanan and Arun Kumar Bar
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT03871E, Paper
Sequential reaction of a multi-site compartmental ligand,2-methoxy-6-[{2-(2-hydroxyethylamino)ethylimino}methyl] phenol (LH3) with lanthanide(III) salts followed by the addition of Co(OAc)2·4H2O, in a 1:1:2 ratio, in the presence of tetramethylammonium hydroxide as the...
Nathalie Bridonneau, Lise-Marie Chamoreau, Geoffrey Gontard, Hans-Jürgen von Bardeleben, Jean-Louis Cantin and Valerie Marvaud
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00743K, Paper
A high-nuclearity metal-cyanide cluster [Mo6Cu14] has been prepared and its photomagnetic properties investigated. The photoswitchable magnetic phenomenon observed is thermally reversible (T ≈ 230 K). In the field of photomagnetism,...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00706F, Paper
The defect chemistry of Cr-doped SrTiO3 is modified through a simple chemical reduction route to increase the Cr3+ dopants in the lattice.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01360K, Communication
Two 3d–4f heterometallic MOFs have been synthesized based on a tetracarboxylic ligand, and show good selective fluorescence sensing capabilities for nitrite and benzaldehyde.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00138F, Communication
The first polyoxometalates modified by a porphyrin-resembling planar Schiff base with excellent third-order NLO and catalytic properties have been successfully developed.
Pau Clavero, Arnald Grabulosa, Mercè Rocamora, Guillermo Muller and Mercè Font-Bardia
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00995F, Paper
Optically pure P-stereogenic monophosphorus ligands containing a heterocyclic substituent have been prepared. They have been coordinated to Ru-η6-arene moieties in which the ligands act as mono- or bidentate. The complexes catalyse asymmetric transfer hydrogenation reactions with up to 70% ee.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00347H, Paper
A recycling method for polyacrylamidoxime polymers.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04781A, Paper
Three structurally related RuII-p-cymene complexes of imidazole based Schiff bases show steric hindrance influences, hypoxia reactivity, cell cycle arrest and resistance to glutathione. The complexes show anti-metastatic and anti-angiogenic effects.
Peng Wang, Xiaomin Hao, Jianhua Cheng, Jianbin Chao and Xia Chen
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00001K, Paper
Treatment of tautomers of β-quinolyl ketone-enaminones 1a-6a with AlMe3 afforded the quinolyl β-ketiminato dialkylaluminium complexes LAlMe2 1b-6b (L = [(2-C9H6N)-CH=C(R)-O-] (R = CH3 (1b), tBu (2b), Ph (3b), o-Tolyl (4b),...
Jing-Yuan Xu, Wen-Jing Lian, Xin-Tian Wang, Cheng-Zhi Xie, He Tian, Xue-Qing Song, He-Ting Pan and Xin Qiao
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00461J, Paper
Four novel mononuclear Schiff base copper(II) complexes, [Cu(L)(OAc)]•H2O (1), [Cu(HL)(C2O4)(EtOH)]•EtOH (2), [Cu(L)(Bza)] (3) and [Cu(L)(Sal)] (4) (HL = 1-(((2-((2-hydroxypropyl)amino)ethyl)imino)methyl)naphthalene-2-ol), Bza = benzoic acid, Sal = salicylic acid) have been synthesized...
Kang-Long Wong, Yat-Ming So, guocang wang, Herman H-Y. Sung, Ian D Williams and Wa-Hung Leung
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00678G, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
Nathaniel Hartmann, Guang Wu and Trevor W. Hayton
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00885B, Communication
The “masked” terminal nickel sulfide complexes [K(L)][(LtBu)NiII(S)] (LtBu = {(2,6-iPr2C6H3)NC(tBu)}2CH, L = 18-crown-6, 2,2,2-cryptand) activate CS2 to give trithiocarbonate products [(LtBu)NiII(S,S:κ2-CS3)]- or [(S,S:κ2-CS3)NiII{S,S:κ2-CS2(LtBu)}]-, further confirming the nucleophilicity of the sulfide...
Kayleigh Marshall, Qianlong Wang, Hannah Sullivan and Mark T Weller
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00582A, Paper
Eleven first row transition metal fluoride sulfates synthesised in hydrofluorothermal conditions have been structurally characterised by single crystal X-ray diffraction and exhibit a wide variety of structural motifs. The polyionic...

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