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Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
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Marko Damjanović, Prinson P. Samuel, Herbert W. Roesky and Markus Enders
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00408G, Paper
A paramagnetic, easy-plane anisotropic FeI complex, bearing cyclic-alkyl(amino) carbene (cAAC) ligands, is studied by means of NMR and DFT.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00675F, Paper
Crystal structures and electronic spectra of the adducts of polycyano anions with cationic solvatochromic Cu(II) complexes were investigated.
Nobuhiko Dojun, Yukari Sekine, Koichiro Ishimori and Takeshi Uchida
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00121E, Communication
The heme-degradation reaction by HutZ from Vibrio cholerae is inhibited by the iron chelators.
Norbert Szimhardt, Marc F. Bölter, Maximilian Born, Thomas M. Klapötke and Jörg Stierstorfer
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00536A, Paper
The moment of detonation during a hot plate test of highly energetic sodium 1,1′-dinitramino-5,5′-bitetrazolate, the representative of the synthesized alkaline and transition metal salts which are very sensitive toward friction, impact heat and partly also susceptible to laser irradiation.
C. R. Ehgartner, S. Grandl, A. Feinle and N. Hüsing
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00558J, Paper
Flexible inorganic–organic silica aerogels based on methyltrimethoxysilane (MTMS, CH3Si(OCH3)3) can overcome the drawbacks of conventional silica aerogels by introducing high mechanical strength, elastic recovery and hydrophobicity to monolithic materials.
Karlee Bamford, Lauren Longobardi, Lei Liu, Stefan Grimme and Douglas W Stephan
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT01024A, Paper
Redox active, or non-innocent, ligands containing O or N heteroatoms are frequently used in transition metal complexes, imparting unique catalytic properties, but have seen comparatively limited use in the chemistry...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00362E, Paper
Acetamide diethylphosphonate (AcPhos)-functionalized silica has been shown to have a high affinity for U(VI) in pH 2-3 nitric acid. Previous work with AcPhos-functionalized silica has focused on actinide and lanthanide...
Akihiro Tsurusaki, Keisuke Yoshida and Soichiro Kyushin
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00395A, Communication
The reactions of trialkyl borates B(OR)3 (R = Me, i-Pr) with dimethylphenylsilyllithium gave lithium alkoxytris(dimethylphenylsilyl)borates 1a,b. X-ray crystallographic analysis showed that 1a,b were obtained as a contact ion pair and...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00806F, Paper
Synthesis of novel heteroleptic organomagnesium(II) amide complexes [IMesMg(Ar){N(SiMe3)2}]; (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene), Ar = 2,6-Me2C6H3 (Xyl) (1) and 2,4,6-Me3C6H2 (Mes) (2) are reported. Both compounds 1 and 2 were confirmed by...
Bence Kutus, Norbert Varga, Gábor Peintler, Alexandru Lupan, Amr A Attia, Istvan Palinko and Pal Sipos
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00909G, Paper
The complex formation between Nd(III) and D-gluconate (Gluc–) is of relevance in modelling the chemical equilibria of radioactive waste repositories. In the present work, the formation of NdpGlucqH–r complexes at...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00718C, Paper
The diversity of the self-assembled structures of a Cu complex via hydrogen bonding, including a square planar unit, is reported. The Cu complex forms two self-assembled structures by hydrogen bonding,...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00640C, Communication
Ti-SSZ-70 and Ti-ECNU-6, with identical intralayer sturcture but distinct interlayer connections, were prepared from similar synthetic gels free of alkali metal ions and boric acid. Ti-SSZ-70, composed of vertically mis-aligned...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00477J, Paper
The crystallographic signatures and characterization of two novel mixed metal hybrid open-framework [Na2Mn2(C2O4)(SO3)2(H2O)2], 1 and [NaEu(C2O4)(SO3)(H2O)3], 2 are reported for the first time, synthesized under hydrothermal conditions to generate 3D...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00457E, Paper
Three isostructural halozincates, [HNH][ZnX4]∙H2O (HNH2+ = protonated nicotinohydrazide, X = I (1), Br (2), Cl (3)), have been synthesized and exhibit halogen-dependent photoinduced electron transfer and chromic properties. Due to...
Ian R Colinas, Kenneth Kazuya Inglis, Frédéric Blanc and Scott Oliver
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00475C, Paper
We report a detailed study of the host-guest interaction for a cationic metal-organic framework that can reversibly capture perchlorate in record amount. The structural transformation and flexibility of silver 4,4'-bipyridine...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00545H, Paper
We present the variable-pressure luminescence spectra of crystals of isostructural palladium(II) and platinum(II) complexes with bis-N-benzyl-N’-3-methylpyridyldithiocarbamate (bmpDTC) ligands. The d-d luminescence band maxima Emax for these complexes are compared to...
Marcus Lau, Thomas Straube, Vikas Aggarwal, Ulrich Hagemann, Bernardo de Oliveira Viestel, Nils Hartmann, Torsten Textor, jochen gutmann and Stephan Barcikowski
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00010C, Paper
Indium tin oxide (ITO) particle coatings are known for high transparence in the visible, good conductive properties and near-infrared absorption. These properties depend on ITO particle’s stoichiometric composition, defects and...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00733G, Paper
Two new dinuclear nickel(II) complexes namely [Ni2(L1)2(OAc)2(H2O)2].CH3CN (1) and [Ni2(L2)2(SCN)2(CH3OH)2].CH3OH (2) have been synthesized from designed Schiff-base ligand 4-Bromo-2-[(2-hydroxy-1,1-dimethyl-ethylimino)-methyl]-phenol (HL1) and its reduced analogue 4-Bromo-2-[(2-hydroxy-1,1-dimethyl-ethylamino)-methyl]-phenol (HL2), respectively. Both 1 and...
Chengzhen Wei, Cheng Cheng, De Chen Kong, Wei Min Du, Jianbo Zhao, Yeqin Feng and Qingling Duan
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00355B, Paper
In this work, we have successfully developed a simple self-template route for preparation of hollow ellipsoids Ni-Mn sulfides. This route involves the synthesis of solid state Ni-Mn ellipsoids via a...
Aleksei Yu. Nikulin, Elena A. Zvereva, Vladimir B. Nalbandyan, Igor Shukaev, Alexander I. Kurbakov, Maria D. Kuchugura, Grigoriy V. Raganyan, Yuri Popov, Vladislav D. Ivanchenko and Alexander N. Vasiliev
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04859E, Paper
MSb2O6 compounds (M = Mg, Co, Ni, Cu, Zn) are known in the tetragonal trirutile forms, slightly distorted monoclinically with M=Cu due to the Jahn-Teller effect. In this work, using...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04262G, Paper
The new water soluble complex [RuCp(H2O-κO)(PTA)2]+ (1) (PTA = 1,3,5-triaza-7-phosphaadamantane) has been synthesized and fully characterized by NMR and IR. The crystal structure of 1(CF3SO3)·3.5H2O was characterized by single crystal...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00627F, Paper
Four titanium-oxo-clusters with cyclohex-3-ene-1-carboxylate (Cec) ligands, Ti6(2O)2(3O)2(Cec)4(OiPr)12 (PTC-91; HOiPr = isopropanol), Ti6(3O)6(Cec)6(OiPr)6 (PTC-92 and PTC-93) and H2[Ti18(2O)11(3O)14(Cec)20(OiPr)4] (PTC-94), have been solvothermally synthesized under different conditions, respectively. These clusters with the...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00629B, Paper
Photocatalytic hydrogen (H2) production from water by using solar energy and photocatalyst is a green and sustainable route to tackle the energy issues. Herein, carbon/g-C3N4 nanocomposites were successfully synthesized via...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00056A, Paper
A unique redox active flexible solid-state asymmetric supercapacitor with ultra-high capacitive and energy density was fabricated using a composite comprising MgCo2O4 nanoneedles and micro and mesoporous silicon carbide flakes (SiCF)...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00848A, Paper
Increasing electrical conductivity in oxides, which are inherently insulators, can be potential route in developing oxides based thermoelectric power generators with higher energy conversion efficiency. In the present work environmental...

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45 citations
The emerging new solid-state LED phosphors and the methodologies for their development have been reviewed in this perspective.
DOI: 10.1039/C6DT01230B
Published: 30 May 2016
72 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015
49 citations
The versatile role of PVP in nanoparticle synthesis is discussed in this Perspective article.
DOI: 10.1039/C5DT02964C
Published: 22 Sep 2015

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