Dalton Transactions
The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor
3.838
48 Issues per Year
Indexed in MEDLINE
Lihua Tian, Tongmei Ma, Xiao-Na Li and Sheng-Gui He
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT50882J, Paper
DOI: 10.1039/C3DT50882J, Paper
Aluminum oxide cluster anions are produced by laser ablation and reacted with n-butane in a fast flow reactor. A reflectron time-of-flight mass spectrometer is used to detect the cluster distribution...
Kuo-Hui Wu, Hiroaki Maeda, Tetsuya Kambe, Ken Hoshiko, Eunice Jia Han Phua, Ryota Sakamoto and Hiroshi Nishihara
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT51186C, Communication
DOI: 10.1039/C3DT51186C, Communication
A bis(terpyridine)iron network polymer was fabricated by electropolymerisation on a glassy carbon electrode. The modified electrode allowed high-speed charging and discharging with a minor capacity decay (only 5% after 3000...
Si Shen, Shufang Xue, Shuang-Yan Lin, Lang Zhao and Jinkui Tang
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT51235E, Communication
DOI: 10.1039/C3DT51235E, Communication
A new Dy3 triangle bridged by deprotonated alkoxyl group of a Schiff-base ligand together with a μ3-OH group has been prepared, in which intramolecular ferromagnetic interactions and single molecule magnet...
Mohammad Mahdi Najafpour, Atefeh Nemati Moghaddam and Yousef Sakha
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT50972A, Paper
DOI: 10.1039/C3DT50972A, Paper
Here, we propose a mathematical model that gives a good fit to the experimental data for water oxidation by Mn oxide-coated montmorillonite with different Mn contents. Our data shows that...
Yu Gao, Qinghong Fang, Qian Zhao and Zhenhe Xu
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT50917F, Paper
DOI: 10.1039/C3DT50917F, Paper
Rare-earth-doped gadolinium oxide (Gd2O3) hollow spheres were successfully fabricated on a large scale by using PS spheres as sacrificed templates and urea as a precipitating agent, which involved the deposition...
Leigh Fon Jones, Stergios Piligkos, Euan Kenneth Brechin, Sean Tomas Meally and Stephanie M. Taylor
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT51131F, Paper
DOI: 10.1039/C3DT51131F, Paper
The synthesis, structural and magnetic characterisation of a family of homo- and heterometallic complexes constructed with the Schiff base ligands 2-iminomethyl-6-methoxy-phenol (L1H) and 2-imino-6-methoxy-phenol (L2H), are discussed. Members include the...
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT90070C, Editorial
DOI: 10.1039/C3DT90070C, Editorial
Welcome to this themed issue of Dalton Transactions in the area of metal-catalysed or -initiated polymerisation and oligomerisation.
Bo Liu, Dong-Sheng Li, Lei Hou, Guo-Ping Yang, Yao-Yu Wang and Qi-Zhen Shi
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT50997D, Communication
DOI: 10.1039/C3DT50997D, Communication
This communication reports an unprecedented acylamide-functionalized 2D → 3D microporous metal–organic polycatenation framework exhibiting highly selective CO2 capture.
Xuan Wang, Xiu-Bing Li, Ren-He Yan, Yan-Qin Wang and En-Qing Gao
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT50510C, Paper
DOI: 10.1039/C3DT50510C, Paper
Imidazolium-based mono- and dicarboxylate zwitterions with azide leads to achiral or chiral Mn(II) coordination polymers with mixed azide and carboxylate bridges, which show different networks and magnetic behaviors.
Lei Wang, Zhongping Yao, Fangzhou Jia, Bin Chen and Zhaohua Jiang
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT50379H, Paper
DOI: 10.1039/C3DT50379H, Paper
The sulfide solid solution has become a promising and important visible-light-responsive photocatalyst for hydrogen production nowadays.
Jing Tong, Di Wu, Ying Li, Ying Wang and Zhijian Wu
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT50224D, Paper
DOI: 10.1039/C3DT50224D, Paper
Low ionization potentials have been observed for polynuclear superalkalies constituted with alkali and monocyclic (pseudo)oxocarbons.
Cristina Tubaro, Marco Baron, Michele Costante, Marino Basato, Andrea Biffis, Armando Gennaro, Abdirisak Ahmed Isse, Claudia Graiff and Gianluca Accorsi
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT51260F, Paper
DOI: 10.1039/C3DT51260F, Paper
Four novel dinuclear N-heterocyclic dicarbene gold(I) complexes with a propylene linker between the carbene moieties have been synthesized and their luminescence and electrochemical properties, together with their reactivity towards bromine...
Arvind K Gupta, Sanjog Sunil Nagarkar and Boomishankar Ramamoorthy
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT51123E, Paper
DOI: 10.1039/C3DT51123E, Paper
Two polymorphic 2D-coordination polymers of composition [ZnL(HCO2)]∞ were synthesized from an in-situ generated ligand [PO2(NH4Py)2]− (L¯). The ligand L¯ was generated by a facile metal-assisted P−N bond hydrolysis reaction from...
Susanne Woehlert, Lars Peters and Christian Nather
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT51085A, Paper
DOI: 10.1039/C3DT51085A, Paper
Reaction of Fe(NCS)2 and Co(NCS)2 with 2-methylpyrazine in different molar ratio and solvents at room temperature leads to the formation of five new coordination compounds of composition M(NCS)2(2-methylpyrazine)2(H2O)2 (M =...
Tebello Nyokong, Racheal Ogbodu and Edith Antunes
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT50335F, Paper
DOI: 10.1039/C3DT50335F, Paper
A conjugate between zinc monoamino phthalocyanine (ZnMAPc) and pyrene (Py) represented as ZnMAPc-Py (complex 3) was synthesized and characterized by various spectroscopic techniques and by elemental analysis. This work also...
Christian Molina, Reinhard Kissner and Willem H. Koppenol
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT50945A, Paper
DOI: 10.1039/C3DT50945A, Paper
The decay of ONOOH near neutral pH has been examined as a function of isomerization to H+ and NO3−, and decomposition to NO2− and O2via O2NOO−.
Yan-Li Gai, Fei-Long Jiang, Lian Chen, Yang Bu, Ming-Yan Wu, Kang Zhou, Jie Pan and Mao-Chun Hong
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT50532D, Paper
DOI: 10.1039/C3DT50532D, Paper
Five entanglement structures of zinc coordination polymers have been synthesized and characterized.
Catharine Esterhuysen and G Frenking
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT32872D, Paper
DOI: 10.1039/C3DT32872D, Paper
DFT calculations using BP86 in conjunction with the SVP and TZVPP basis sets as well as ab initio calculations at SCS-MP2 have been carried out for six dicoordinated carbon molecules...
Christopher S. Hinde, Sivan Van Aswegen, Gillian Collins, Justin D. Holmes, T. S. Andy Hor and Robert Raja
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT50606A, Communication
DOI: 10.1039/C3DT50606A, Communication
A novel method for generating nanoparticles from microporous phosphate frameworks affords active catalysts for sustainable aerobic oxidations.
Self-assembly of a molecular crown as a structural analogue of calix[4]arene to modify Keggin anions
Aixiang Tian, Xiaoling Lin, Jun Ying, Juwen Zhang, Hongyan Lin, Guocheng Liu, Dan Zhao, Na Li and Xiuli Wang
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT50800E, Communication
DOI: 10.1039/C3DT50800E, Communication
Four AgI ions are linked by four 5-phenyl-1H-tetrazole to form a molecular crown [Ag4(ptz)4] as an analogue of calix[4]arene, which are further supported by Keggin anions to build a 2D layer.
S. V. Otari, R. M. Patil, S. R. Waghmare, S. J. Ghosh and S. H. Pawar
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT51093J, Paper
DOI: 10.1039/C3DT51093J, Paper
Schematic of the synthesis of Ag–Alg biohydrogel using microorganisms and its applications.
Joseph Jankolovits, Annabel D. Cutland Van-Noord, Jeff W. Kampf and Vincent L. Pecoraro
Dalton Trans., 2013, Advance Article
DOI: 10.1039/C3DT50535A, Communication
DOI: 10.1039/C3DT50535A, Communication
A systematic crystallography study reveals that CH–O interactions from the proximal phenyl side chains control the selective encapsulation of unsaturated dicarboxylates in Ln(III)[15-metallacrown-5]3+ compartments.
Barry A Blight, Soo-Byung Ko, Jiasheng Lu, Larissa F Smith and Suning Wang
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT51276B, Communication
DOI: 10.1039/C3DT51276B, Communication
An acetylacetonato derivative ligand, dibenzoylmethane (dbm), has been functionalized with a dimesitylboryl group. Phosphorescent N^C-chelate Pt(II) compounds with the new molecule as an ancillary ligand have been achieved and used...
Dao Zhang, Sen Zhou, Zhiming Li, Quanrui Wang and Linhong Weng
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT50957E, Paper
DOI: 10.1039/C3DT50957E, Paper
Two novel amine-containing N-heterocyclic carbene ligand precursors [H(1a-b)]Br have been prepared in good yields and fully characterized; Direct syntheses of cis- and trans-dihalido-bis(NHC) nickel complexes [Ni(NHC)2X2] (X = Cl, Br)...
Hongming Wang
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT50337B, Paper
DOI: 10.1039/C3DT50337B, Paper
The reaction mechanism of CO2 hydrogenation catalyzed by [FeH(PP3)]BF4 (PP3=P(CH2CH2PPh2)3) have been investigated by DFT calculations. The reduction of carbon dioxide is divided into three stages: the activation of CO2,...
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