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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Hans-Kristian Norheim, Jan Capar, Rune F. Einrem, Kevin J. Gagnon, Christine M. Beavers, Hugo Vazquez-Lima and Abhik Ghosh
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03947A, Paper
With a noninnocent {FeNO}7-(corrole˙2−) formulation, the first FeNO octabromocorrole derivatives deepen our appreciation of ligand noninnocence.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03459K, Paper
Kinetic data and product analyses support a mechanism in which cob(II)alamin (Cbl(II)˙) is reduced by (H)NO to give cob(I)alamin (Cbl(I)) and ˙NO. Cbl(I) is subsequently oxidized back to Cbl(II)˙ by a second (H)NO molecule, and Cbl(II)˙ reacts rapidly with ˙NO to form nitroxylcobalamin, NOCbl.
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04298D, Frontier
Recent developments have substantially expanded the scope of N-heterocyclic carbenes (NHCs) as ancillary ligands in coordination chemistry and homogeneous catalysis. This review provides a short overview of the emerging field...
Marina Rozova, Vladislav V. Grigoriev, Ivan A. Bobrikov, Dmitry Filimonov, Konstantin V. Zakharov, Olga S. Volkova, Alexander N. Vasiliev, Evgeny Viktorovich Antipov, Alexander A Tsirlin and Artem M. Abakumov
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04296H, Paper
Abstract Highly homogeneous mullite-type solid solutions Bi2Fe4-xCrxO9 (x = 0.5, 1, 1.2) were synthesized using soft chemistry technique followed by solid-state reaction in Ar. The crystal structure of Bi2Fe3CrO9 was...
Jamila G. Vaughan, Damien Carter, Andrew Rohl, Mark Ian Ogden, Brian W. Skelton, Peter V Simpson and David H Brown
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04213E, Paper
Dinuclear silver, di- and tetra-nuclear gold, and mononuclear palladium complexes with chelating C,N,C diethylaminotriazinyl-bridged bis(NHC) pincer ligands were prepared and characterised. The silver and gold complexes exist in a twisted,...
Rabha Kerdjoudj, Miroslav Pniok, Cyrille Alliot, Vojtech Kubicek, Jana Havlíčková, Frank Roesch, Petr Hermann and Sandrine HUCLIER-MARKAI
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04084A, Paper
Complexation ability of DOTA analogs bearing one methylenephosphonic (DO3AP) or methylenephosphinic (DO3APPrA and DO3APABn) acid pendant arm toward scandium were evaluated. Stability constants of their scandium(III) complexes were determined by...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03915K, Paper
The preparation of a novel triphosphenium zwitterion featuring di-, tri-, and tetra-coordinate phosphorus centres derived from a 1,2,4-tris-(diphenylphoshinyl)cyclopentadienyl framework is described. The reactivity of this potentially multidentate donor with protons,...
Kasper Trans Møller, Morten Brix Ley, Pascal Schouwink, Radovan Cerny and Torben R. Jensen
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03590B, Paper
Three new perovskite-type bimetallic alkali metal strontium borohydride compounds, α-MSr(BH4)3 (M = K, Rb, Cs), have been synthesized and investigated by in-situ synchrotron radiation powder X-ray diffraction, thermal analysis combined...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03399C, Paper
Electronic energies and elastic constants of four amino functionalized MIL-47(V) supercells were computed using plane wave density functional theory to determine the influence of the substituent positions on the organic...
M. Paskevicius, B. Richter, M. Polański, S. P. Thompson and T. R. Jensen
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04304B, Paper
The reactions between metal borohydrides and elemental sulfur are investigated in situ during thermal treatment and are found to be highly exothermic (up to 700 J g−1).
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03418C, Paper
Photosensitized H2 generation can be sustained for several hours in aqueous solution using a protein scaffold that nucleates formation of platinum nanoparticles (Pt NPs) and contains “built-in” zinc-porphyrin photosensitizers.
Zoe Livingstone, Alberto Hernán-Gómez, Sharon E. Baillie, David R. Armstrong, Luca M. Carrella, William Clegg, Ross W. Harrington, Alan R. Kennedy, Eva Rentschler and Eva Hevia
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04044B, Paper
Structurally tracking the reaction of a sodium butylmagnesiate supported by a bulky silyl(bisamide) ligand towards quinoxaline, SET reactivity.
Richard F. D'Vries, German E. Gomez, José H. Hodak, Galo J. A. A. Soler-Illia and Javier Ellena
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04033G, Paper
Characterization and optical properties of a 1D coordination polymer and 2D and 3D Metal–Organic Frameworks obtained from lanthanide metals, 3-hydroxinaftalene-2,7-disulfonic acid.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03799A, Paper
Why are boron containing systems so effective at CO coupling? Full quantum chemical calculations with density functional theory (DFT) provide interesting insights into why recently reported CO coupling by diboryne systems is such a facile process.
Tuhin Samanta, Shyam Sarkar, Venkata. N. K. B. Adusumalli, Athma E. Praveen and Venkataramanan Mahalingam
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT02974K, Communication
We report the enhancement of both visible and near infrared (NIR) emissions from Nd3+ ions via Ce3+ sensitization in colloidal nanocrystals for the first time.
Fangyuan Gai, Tianlei Zhou, Guang Chu, Ye Li, Yunling Liu, Qisheng Huo and Farid Akhtar
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03052H, Paper
This work demonstrates the design and synthesis of large pore mesoporous silica nanoparticles by using mixed anionic surfactants as soft templates to introduce amino group for Fe3+ fluorescent detection.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04218F, Communication
The ligating ability of MesPyBN to form Y-MesPyBN was proven, and the low-lying triplet state was maintained after complex formation.
Christophe Werlé, Dylan M. Anstine, Lydia Karmazin, Corinne Bailly, Louis Ricard and Jean-Pierre Djukic
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03648H, Paper
Three novel hemichelates of Pd(II) resulting from the reaction of indene and hydrophenanthrene-based organometallic anions with three μ-chloro-bridged palladacycles are reported.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03779D, Paper
2-(1-aryliminoethyl)-9-arylimino-5,6,7,8-tetrahydrocycloheptapyridylcobalt chlorides polymerized ethylene in high activities, producing useful waxes.
Andreas O. Schüren, Verena K. Gramm, Maximilian Dürr, Ana Foi, Ivana Ivanović-Burmazović, Fabio Doctorovich, Uwe Ruschewitz and Axel Klein
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT02769A, Paper
Iron sulphur halide clusters [Fe4S4X4]2− and [Fe4S4X2Y2]2− were synthesised and characterised using HR-MS and UV-vis-NIR in solution and using IR and synchrotron XRPD in the solid.
Damiano Cattaneo, Stewart J. Warrender, Morven J. Duncan, Richard Castledine, Nigel Parkinson, Ian Haley and Russell E. Morris
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03955J, Paper
CPO-27 MOFs suitable for nitric oxide delivery applications are synthesised at 20 L and 100 L scale under environmentally benign conditions.
Izabela Gryca, Barbara Machura, Jan Grzegorz Małecki, Joachim Kusz, Lidia S. Shul'pina, Nikolay S. Ikonnikov and Georgiy B. Shul'pin
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03598H, Paper
The reactions of mer-[Re(p-NTol)X3(PPh3)2] with phenolate-based ligands gave 16 new rhenium(V) complexes. Only a few of them exhibited high catalytic activity.
Đani Škalamera, Ernest Sanders, Robert Vianello, Aleksandra Maršavelski, Andrej Pevec, Iztok Turel and Srećko I. Kirin
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03387J, Paper
The stoichiometry and stereochemistry of bis(2-picolyl)amine (bpa) or bis(2-quinaldyl)amine (bqa) metal complexes were studied by spectroscopy, crystallography and DFT calculations.
Mohammed Enamullah, Mohammad Abdul Quddus, Mohammad Rezabul Hasan, Gennaro Pescitelli, Roberto Berardozzi, Gamall Makhloufi, Vera Vasylyeva and Christoph Janiak
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03940A, Paper
Ni-Schiff base complexes combine ligand chirality, chirality at metal, and helical ligand folding in a concerted way.
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04049C, Perspective
Metal-organic frameworks (MOFs) are a class of porous solid, which have a variety of potential applocations. Unfortunately, MOFs often lack hydrolytic stability, which hinders their use as viable materials for...

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