Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 3.806 48 Issues per Year Indexed in MEDLINE
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Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02144D, Paper
The development of theranostic mesoporous hollow silica nanospheres having therapeutic and diagnostic functions has been achieved. The exterior surface of the hollow mesoporous silica nanosphere was selectively acid functionalized and...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02038C, Paper
In the present study, the tin complex immobilized on silica gel as a novel, green, highly efficient and heterogeneous reusable catalyst was synthesized by grafting 2-amino benzamide on to the...
Chandan Giri, Filip Topić, Prasenjit Mal and Kari Rissanen
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02180K, Communication
In presence of triflate as the counter anion, 1,2-diaminobenzene and 2-formylpyridine self-sort with iron(II) to a low-spin [Fe(L1)](OTf)2 complex in which both aminal and imine moieties coexist simultaneously, while under...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02239D, Paper
Racemic trans-1,2-diphosphinocyclohexane (t-chxnP2) has been synthesised and its coordination chemistry to Cu(I), Ag(I), Mn(I) and Fe(II) investigated. Compounds of empirical formula [Cu(t-chxnP2)2]BF4 and [Ag(t-chxnP2)2]BF4 have been prepared as isomeric mixtures...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02151G, Communication
Herein we present a new and promising approach for the high-resolution modeling of vibrational Resonance Raman spectra of metal complexes in solution. The model explicitly includes Duschinsky couplings, solvent effects,...
Yunqing Luo, Shanshan Fan, Nongyi Hao, Shuangling Zhong and Wencong Liu
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01695E, Communication
A facile, low-cost and green ultrasound-assisted method has been developed to ultra-fast synthesize Mn3O4 nanosheets supported on the reduced graphene oxide (RGO). Such hybrid materials exhibited ultrahigh performance as lithium...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01441C, Paper
Composites made of Higher Manganese Silicides (HMS) – based compound MnSi1.75Ge0.02 and multi-walled carbon nanotubes (MWCNTs) have been prepared by an easy and effective method including mechanical milling under mild...
Suman Kumar Tripathy, Umasankar De, Niranjan Dehury, Satyanarayan Pal, Hyung Sik Kim and Srikanta Patra
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01033G, Communication
Heterodinuclear Ir–Ru (2) with polypyridyl based phpy ligand shows autophagy induced cell death, whereas homodinuclear Ru–Ru (1) is inactive.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02026J, Paper
Mono and bis-chelate N-benzoylbenzamidinate aluminium complexes are found to be highly active initiators for polymerization of ε-caprolactone and cyclohexene oxide.
Weibo Hua, Jibin Zhang, Zhuo Zheng, Wenyuan Liu, Xihao Peng, Xiao-Dong Guo, Benhe Zhong, Yan-Jie Wang and Xinlong Wang
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01611D, Paper
An as-prepared Na-doped Ni-rich LiNi0.5Co0.2Mn0.3O2 cathode material, Li0.97Na0.03Ni0.5Co0.2Mn0.3O2, successfully shows both high rate capability and high tap density.
Luca Maidich, Giuseppina Zuri, Sergio Stoccoro, Maria Agostina Cinellu and Antonio Zucca
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02080D, Paper
The reaction of the cyclometalated rollover complex [Pt(bpy-H)(Me)(DMSO)] (bpy-H = cyclometalated 2,2′-bipyridine) with two diphosphines, dppm (1,1-bis(diphenylphosphino)methane) and dppe (1,2-bis(diphenylphosphino)ethane), was investigated.
Alnald Javier, Ding Li, Juan Cruz, Elizabeth Binamira-Soriaga, Perla B. Balbuena and Manuel P. Soriaga
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02137A, Paper
From themed collection The Carbon–Metal Bond and C–H Metalation
The electrode-surface C–H activation and metalation of 2,3-dimethyl-1,4-dihydroxybenzene on Pd was investigated by electrochemistry, electron spectroscopy, and density functional theory. At high concentrations, formation of a (5,6-η)-o-phenylene organopalladium surface compound was indicated.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01809E, Paper
Different LiFe0.5Mn1.5O4 spinels are synthesized and characterized structurally and electrochemically to highlight the improvement of electrochemical behaviour with LiMn1.5Fe0.5O4/Li2MnO3 composite.
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02240H, Paper
The kinetics of phosphine substitution in CpRu(PAr3)2Cl by PMePh2 under pseudo-first order conditions in CDCl3 have been measured for PAr3 = PPh3, 1a, PPh2(p-tol), 1b, P(p-tol)3, 1c, P(p-CH3OC6H4)3, 1d, and...
Michael Holthausen, Ian Mallov and Douglas W Stephan
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02406K, Paper
The phosphinimines R3PNSiMe3 (R = t-Bu: 1a, R = Cy: 1b, R = Et: 1c, R = Ph: 1d) are reacted with a series of chloro and fluoroboranes (9Cl-9-BBN, (C6F5)2BCl,...
Yui Morishima, David James Young and Kiyoshi Fujisawa
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01978D, Paper
Five halogen substituted pyrazolates, 4-chloro-3,5-diisopropylpyrazole (4-Cl-3,5-iPr2pzH), 4-bromo-3,5-diisopropylpyrazole (4-Br-3,5-iPr2pzH), 4-iodo-3,5-diisopropylpyrazole (4-I-3,5-iPr2pzH), 4-chloro-3,5-diphenylpyrazole (4-Cl-3,5-Ph2pzH), and 4-bromo-3,5-diphenylpyrazole (4-Br-3,5-Ph2pzH) were conveniently prepared by halogenation of the appropriate pyrazoles with N-halosuccinimides (NXS) (X = Cl,...
Paul David Newman, Peter G Edwards, Mary F Mahon, Wenjian Zhang and Elisenda Reixach
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02203C, Paper
Nine-membered 1,4,7-triphosphamacrocycles with unsaturated benzo-backbones have been prepared using the [(CO)3Mn]+ unit as a template. Two synthetic methods have been employed for the macrocyclisation both of which involve the attack...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02264E, Communication
The hydrothermal stability of aluminium hydroxide isophthalate MOF CAU-10-H was proven, under humid multi-cycling conditions. Detailed in-situ thermogravimetric measurements and in-situ powder X-ray diffraction analysis during water ad-/desorption were used....
Tony D. Keene, Michael J. Murphy, Jason R. Price, Natasha F. Sciortino, Peter D. Southon and Cameron J. Kepert
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02205J, Paper
The properties of atmospheric CO2 fixation, metamagnetism, reversible guest adsorption and zero thermal expansion have been combined in a single robust MOF, [Cu3(bpac)3(CO3)2](ClO4)2·H2O (1·H2O).
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01751J, Paper
Visible light induces photoreductive elimination of bromine, chlorine, and for the first time, fluorine from the tellurium center of 2,5-diphenyltellurophene.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01376J, Perspective
This Perspective reviews our recent efforts towards the low-temperature synthesis of complex perovskite oxide ABO3 (A = Sr, Ba; B = Ti, Zr) nanocrystals using the vapor diffusion sol–gel method and the determination of their room-temperature crystal structure.
Jesús J. Pérez-Torrente, Marta Angoy, Daniel Gómez-Bautista, Adrián Palacios, M. Victoria Jiménez, F. Javier Modrego, Ricardo Castarlenas, Fernando J. Lahoz and Luis A. Oro
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02105C, Paper
Hindered rotation about the metal–cyclooctene bond in bis-cyclooctene zwitterionic complexes results in an unusual equilibrium between two rotational isomers.
Stefan Heimann, Dieter Bläser, Christoph Wölper, Rebekka Haack, Georg Jansen and Stephan Schulz
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01940G, Paper
The bonding situation in triethylchalcogenostiboranes Et3Sb[double bond, length as m-dash]E (E = S 1, Se 2) in the solid state was investigated by single crystal X-ray diffraction and by computational results. 1 and 2 show polarized Sb–E single bonds rather than π-interactions.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02014F, Communication
Here we report a versatile magnetic susceptibility equation for tetranuclear octahedral high-spin cobalt(II) complexes and a magnetic analysis for a tetranuclear defect cubane cobalt(II) complex based on this equation.
Steinar Birgisson, Kirsten Marie Ørnsbjerg Jensen, Troels Lindahl Christiansen, Jon Fold von Bülow and Bo Brummerstedt Iversen
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01307G, Paper
The reaction details for hydrothermal synthesis of LiMn2O4 nanocrystallites is revealed through in situ X-ray powder diffraction studies.

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