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Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
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Rubén Gil-García, María Ugalde, Natalia Busto, Hector Lozano, José Maria Leal, Begoña Pérez, Gotzon Madariaga, Maite Insausti, Luis Lezama, Roberto Sanz, Lidia M. Gómez-Sainz, Begona Garcia and Javier García-Tojal
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02907H, Paper
Thiosemicarbazones and their metal derivatives have long been screened as antitumor agents and their interactions with DNA have been analyzed. Here, we describe the synthesis and characterization of compounds containing...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03440C, Communication
A new terpyridine-diphos hybrid ligand [4′-{p-(Ph2P)2NC6H4}-2,2′:6′2′′-terpy] (1) and its RuII, PdII, AuI and ZnII complexes are described. Preliminary studies on absorption and emission properties are also reported.
Farooq Khurum Shehzad, Ningning Qu, Yunshan Zhou, Lijuan Zhang, Huanyao Ji, Zonghai Shi, Jiaqi Li and Sadaf ul Hassan
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03454C, Paper
A notable third-order NLO response of the films is proportional to the discrepancy of LUMO levels between CuTAPc and POMs.
wei yongqin, Rongjian Sa and Wu Kechen
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03655D, Paper
A long π-conjugated organic ligand 2-(2,4-disulfophenyl)imidazo(4,5-f)(1,10)-phenanthroline (H3sfpip) featuring blue-green emission was used to construct Eu(III) MOFs in order to obtain a target white-light-emitting LnMOF without dopant atom in the structure....
Khaled Cheaib, Yoann Roux, Christian Herrero, Alexandre Trehoux, Frederic Avenier and Jean-Pierre Mahy
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03710K, Communication
Dioxygen activation at copper(I) centres is of primary importance for the development of sustainable oxidation catalysis, but regeneration of copper(I) centres after each catalytic cycle remains a major problem for...
Maurizio Remelli, Carlo Ceciliato, Remo Guerrini, Paulina Kolkowska, Karolina Krzywoszynska, Severo Salvadori, Daniela Valensin, Joanna Watly and Henryk Kozlowski
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03598A, Paper
Hemopressin is a neuropeptide, derived from the degradation of the α(1)-chain of hemoglobin, which possesses several pharmacologic properties, such as the ability to block cannabinoid CB1 receptor activity, to cause...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03602C, Paper
Semiconducting hybrid bismuth iodides, templated on piperizinium cations and their methylated derivatives, have pseudo three-dimensional connectivity reminiscent of the perovskite structure.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03464K, Paper
Treatment of the 2,5-bis(2′-pyridyl)pyrrolato (PDP) anion with {Ru(COD)Cl2}n in THF readily yielded [Ru(PDP)(COD)Cl] (1) in almost quantitative yield.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03630A, Communication
Three-dimensional diamond-like framework tellurides AXII4XIII5Te12 with very low thermal conductivities are reported for the first time.
Hailong Yan, Tong Li, Yang Lu, Jinbing Cheng, Tao Peng, Jinyou Xu, Linying Yang, Xiangqiang Hua, Yunxin Liu and Yongsong Luo
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03435G, Paper
In this article, ordered ZnO@ZnS core–shell structures have been produced on a stainless mesh by a two-step approach without using a template.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03748H, Paper
A new C–N linked heterocoupled energetic compound and its energetic salts have been prepared as heat-resistant energetic materials.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03572H, Paper
Treatments of N-aryl-phenanthren-o-iminoquinone (aryl = 2,6-Me2C6H3 (MeL); 2,6-iPr2C6H3 (iPrL)) with iron powder in THF at 75 °C generate complexes [η2L]2Fe[η1LH] (1a, L = MeL; 1b, L = iPrL) in moderate yields.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03049A, Paper
The structures of three luminescent compounds based on CuI are determined by XRPD data. The hybrid organic–inorganic [Cu2I2(3pica)] shows a concomitant triple emission at room temperature.
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03382B, Communication
A series of Eu3+-, Tb3+-, and Tm3+-doped CaWO4 phosphor nanocrystals have been synthesized under benign conditions using the vapor diffusion sol–gel method. The high degree of synthetic flexibility inherent to...
Lijuan Han, Ya-jie Kong, Tingjiang Yan, Lu-Tong Fan, Qi Zhang, Hua-Jun Zhao and Hegen Zheng
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03273G, Paper
A new copper-based coordination compound constructed by 2, 2'-bipyridine and pentafluorobenzoate ligands, Cu2(2, 2'-bipy)2(pfbz)4 (1), (where 2, 2'-bipy = 2, 2'-bipyridine; pfbz = pentafluorobenzoate), has been hydrothermally synthesized and structurally...
Marcus Fischer, Johannes Schwegler, Carolin Paula, Peter Steffen Schulz and Martin Hartmann
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03930H, Communication
An organic imidazolium salt of terephthalic acid has been utilized as linker precursor for the synthesis of an aluminum-based metal organic framework (MOF) with MIL 53(ht) structure. This material shows...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03520E, Paper
Two tetranuclear NiII complexes, namely [Ni4(L)4(CH3OH)3(H2O)]•CH3OH (1), (Pr3NH)2[Ni4(L)4(CH3COO)2] (2, Pr3N = tripropylamine), were synthesized from a tridentate Schiff base ligand H2L (2-[(E)-(2-hydroxybenzylidene)amino]phenol) and Ni(CH3COO)2•4H2O, using different solvents and their ratios...
Angelos Canaj, Milosz Siczek, Marta Otreba, Tadeusz Lis, Giulia Lorusso, Marco Evangelisti and Constantinos J Milios
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02932A, Paper
The solvothermal reaction between Ln(NO3)3·6H2O (Ln: Gd, Tb and Dy), 2-hydroxy-1-naphthaldehyde , 2-OH-naphth, and ethylenediamine, en, in MeOH in the presence of base, NEt3, led to the formation of the...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03558B, Paper
Three novel 2D coordination polymers [Tb2(µ4-L)2(µ-HL)(µ-HCOO)(DEF)]n (Tb-L), [Eu(µ4-L)(L)(H2O)2]n (Eu-L), and [Nd(µ4-L)(L)(H2O)2]n (Nd-L) were assembled from the corresponding lanthanide(III) nitrates and 5-methoxy-(4-benzaldehyde)-1,3-benzenedicarboxylic acid (H2L) as a main multifunctional building block bearing...
Richard O'Donoghue, Daniel Peeters, Detlef Rogalla, Hans-Werner Becker, Julian Rechmann, Sebastian Henke, Manuela Winter and Anjana Devi
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03571J, Paper
Molecular engineering of seven closely related zinc ketoiminates, namely, [Zn(dapki)2], [Zn(daeki)2], [Zn(epki)2], [Zn(eeki)2], [Zn(mpki)2], [Zn(meki)2], [Zn(npki)2], lead to optimisation of the precursor thermal properties in terms of volatilisation rate, onset...
Susanta Hazra, Ricardo Meyrelles, Adilia Januário Charmier, Patrícia Rijo, M. Fátima C. Guedes da Silva and Armando J. L. Pombeiro
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03118H, Paper
The 1D supramolecular chain of the NH3+–C2H4–NH3+·[SnCl6]2− adduct, supported by N–H⋯Cl bonds, is entrapped by mononuclear CuII or NiII complexes via strong N–H⋯O interactions in the 1D chain of heterobimetallic Cu2Sn or Ni2Sn cocrystals (1–4).
Michael Hill, Thomas Wildsmith, Andrew Lee Johnson, Kieran C. Molloy, Andrew Kingsley, John P Lowe and James D Parish
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02508K, Paper
The stannous alkoxides [Sn(OR)2] [R = i-Pr, t-Bu, C(Et)Me2, CHPh2, CPh3] have been synthesised by reaction of Sn(NR'2)2 with two equivalents of HOR [R' = Me, R = i-Pr; R'...
Verónica Jornet-Mollá, Yan Duan, Carlos Giménez-Saiz, João C. Waerenborgh and Francisco M. Romero
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02934E, Paper
Flexible and rigid dicarboxylate anions influence the ground spin state of iron(II) spin crossover complexes via hydrogen bonding.
Stefan Suckert, Michał Rams, Michael Böhme, Luzia Silvana Germann, Robert E. Dinnebier, Winfried Plass, Julia Werner and Christian Nather
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03752F, Paper
Reaction of cobalt(II) and nickel(II) thiocyanate with ethylisonicotinate leads to the formation of [M(NCS)2(ethylisonicotinate)2]n with M = Co (2-Co) and M = Ni (2-Ni), which can also be obtained by...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02693A, Paper
A metal–organic frameworks (MOFs) MIL-125(Ti)-NH2 and its derivative MIL-125(Ti)-AM and MIL-125(Ti)-AM-Eu are synthesized. The structure and morphology of the obtained-samples are characterized by some characterization methods such as XRD, SEM,...

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123 citations
Porphyrin sensitizers have exhibited power conversion efficiencies that are comparable to or even higher than those of well-established highly efficient DSSCs based on ruthenium complexes.
DOI: 10.1039/C4DT02756F
Published: 10 Nov 2014
11 citations
The emerging new solid-state LED phosphors and the methodologies for their development have been reviewed in this perspective.
DOI: 10.1039/C6DT01230B
Published: 30 May 2016
56 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015

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