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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.097 48 Issues per Year Indexed in MEDLINE
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Mahpuzah Abai, Martin P. Atkins, Amiruddin Hassan, John D. Holbrey, Yongcheun Kuah, Peter Nockemann, Alexander A. Oliferenko, Natalia V. Plechkova, Syamzari Rafeen, Adam A. Rahman, Rafin Ramli, Shahidah M. Shariff, Kenneth R. Seddon, Geetha Srinivasan and Yiran Zou
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03273J, Paper
Efficient ionic liquid based mercury scrubbing technology from gram to ton scale.
Łukasz Orzeł, Bartłomiej Szmyd, Dorota Rutkowska-Żbik, Leszek Fiedor, Rudi van Eldik and Grażyna Stochel
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03809F, Paper
The reactivity of Cu(II) towards chlorophylls can be tuned by slight changes in the composition of the medium, leading to different reaction pathways and products in organic solvents.
R. S. Anju, Koushik Saha, Bijan Mondal, Thierry Roisnel, Jean-François Halet and Sundargopal Ghosh
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00179J, Paper
Photolysis of arachno-[(Cp*Ru)2(B3H8)(CS2H)] in the presence of [Re2(CO)10] produced [(Cp*Ru)2B3H5(CH2S2){Re(CO)4}2], with a planar 8-membered ring containing heavier transition metals and a main group element.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00146C, Paper
This work provides rare examples of lanthanoid selenidoantimonates based on dinuclear lanthanide complexes.
Luka A. Wright, Eric G. Hope, Gregory A. Solan, Warren B. Cross and Kuldip Singh
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00062A, Paper
The structural properties of a series of ONN-Pd(II) chloride pincer complexes have been shown to influence the conversion to 4-chlorotoluene upon oxidation with di-p-tolyliodonium triflate.
Yahya Al-Khafaji, Xinsen Sun, Timothy J. Prior, Mark R. J. Elsegood and Carl Redshaw
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00272A, Paper
Reaction of the pro-ligands α,α,α′,α′-tetra(3,5-di-tert-butyl-2-hydroxyphenyl-p-(or -m-)xylene-para-(or -meta-)tetraphenol with [MCl5] (M = Nb, Ta) or [Nb(O)Cl3(NCMe)2] afforded complexes capable of the ROP of e-caprolactone at high temperature.
Melissa Wu. M, Arran M. Gill, Lu Yunpeng, Laura Falivene, Li Yongxin, Rakesh Ganguly, Luigi Cavallo and Felipe García
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00079C, Paper
Treatment of a series of aromatic NHCs with trimethylaluminium produced their corresponding NHC·AlMe3 adducts displaying different stabilities. Their stabilities are rationalized using topographic steric maps and NHC % V Bur.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03816A, Paper
New luminescent PhHg(II) dithioester complexes 1–3 have been synthesized and their crystal structures revealed O,S-coordination in 1 and 2 whereas less preferred S,S-coordination is observed in 3. The keto-form of β-oxodithioester ligands is stabilized in these complexes.
Tatiyana V. Serebryanskaya, Alexander S. Novikov, Pavel V. Gushchin, Andrey A. Zolotarev, Vladislav V. Gurzhiy and Vadim Yu. Kukushkin
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03870C, Paper
Intermolecular ligand–ligand coupling as a novel approach to the construction of dimetallic systems.
B. Stadelmann, J. Bender, D. Förster, W. Frey, M. Nieger and D. Gudat
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00008D, Paper
Treatment of an N-heterocyclic chlorophosphine with Collman's reagent or K[HFe(CO)4]/NaH gave a unique anionic phosphenium complex which behaves as an ambident nucleophile.
Rajendra S. Dhayal, Jian-Hong Liao, Hsing-Nan Hou, Ria Ervilita, Ping-Kuei Liao and C. W. Liu
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03810J, Paper
The first Cu(I) compounds supported by dialkyl diselenocarbamates were reported to exhibit tetrahedral, hydride-centered tetracapped tetrahedral and hydride-centered tricapped tetrahedral core structures.
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00438A, Paper
The reaction of the dialdehyde N,N-di(α-formylpyrrolyl-α-methyl)-N-methylamine 1 with two equiv of 2,6–diisopropylanilline yielded two Schiff bases: bis(iminopyrrolylmethyl)amine (H2L) and its hydrolyzed monoimino compound (H2L') after column separation. The dimeric lithium...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00622H, Paper
Ultrathin nanosheet-assembled cobalt molybdate (CoMoO4) owing to the mesoporous morphology was synthesized by urea-assisted solution combustion route at a temperature of 400 ᵒC. The as-prepared CoMoO4 was modified using chitosan...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00257E, Paper
Visible light responsive 2:1 Ni/Ti layered double hydroxide (LDH) was synthesized by a single step hydrothermal route using commercially available Ni(NO3)2.6H2O, TiCl4 and urea. The material exhibited significant absorption in...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00258C, Paper
The investigation of a pentagonal bipyramidal Co(II) complex with large positive anisotropy (D ≈ +30 cm-1) revealed field induced Single-Molecule Magnet behaviour with Ueff ≈ 50 K at 1.0 kOe....
Ajai kumar Singh, Gyandshwar Kumar Rao, Arun Kumar, Fariha Saleem, Mahabir Pratap Singh, Satyendra Kumar, Bharat Kumar and Goutam Mukherjee
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03471F, Paper
The ligands PhSCH2CH2EAr (L1−L3; E = S, Se or Te) and their Pd-complexes [PdLCl2]; (1−3] have been synthesized and authenticated with their 1H, 13C{1H}, 77Se{1H} and 125Te{1H} NMR spectra. Single...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03838J, Paper
A new copper-grafted mesoporous poly-melamine-formaldehyde (Cu-mPMF) has been synthesized from melamine and paraformaldehyde in DMSO medium, followed by grafting of Cu(II) at its surface. Cu-mPMF has been characterized by elemental...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00534E, Paper
Novel macrocyclic complexes, tetramers of a five-membered ring consisting of an organic isocyanate dimer and palladium, were prepared from bis(phosphine)palladium–styrene and benzyl isocyanate. Isocyanate cyclotrimerization with tetrameric or single palladacycles...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00546A, Paper
Two sandwich-type Cu3Cl- or Cu2{Te2Ru4(CO)10}-bridging di-TeRu5 clusters, [{TeRu5(CO)14}2Cu3Cl]2─ (1) and [{TeRu5(CO)14}2Cu2{Te2Ru4(CO)10}]4─ (2), were obtained from the reaction of [TeRu5(CO)14]2─ with 1 equiv of [Cu(MeCN)4][BF4] in CH2Cl2 or THF at 0...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00431D, Communication
Three manganese phosphate-oxalates have been synthesized under solvent-free conditions. These inorganic-organic hybrid solids are based on a pcu-type topology with nanobelt-like, sql-, and cds-type manganese oxalate skeletons, respectively. The amine...
Phonpimon Wongmahasirikun, Paweenuch Prom-on, Preeyanuch Sangtrirutnugul, Palangpon Kongsaeree and Khamphee Phomphrai
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00139K, Paper
A new class of salicylaldiminato tin(II) catalysts having different alkoxy side chains has been developed. The ligands were modified to have different length and flexibility as –(CH2)2– (2a), –(CH2)3– (2b),...
Fu-Ping Huang, Cheng Yang, Hai-Ye Li, Peng-Fei Yao, Xiao-Huan Qin, Shi-Ping Yan and Mohamedally Kurmoo
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT04006F, Paper
Two doubly interpenetrated coordination polymers [Co2(BDC)2(bpt)2].nSolvent based on dimeric secondary building units and crystallizing with distinct solvent molecules (1-H2O and 2-MeOH for nSolvent = 2H2O and MeOH.H2O, respectively), were obtained...
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03785E, Communication
A panchromatic hybrid crystal of anionic iodoplumbate nanowires and J-aggregated protonated naphthalene diimides has been formed through charge-assisted anion–π and lone pair–π interactions.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00247H, Paper
The cleave and capture capacity of various bimetallic amido–alkyl mixtures is illustrated through reaction with the deprotonation sensitive N,N-dimethylphenylethylamine.
Timo Bartsch, Oliver Niehaus, Dirk Johrendt, Yasuhiro Kobayashi, Makoto Seto, Paula M. Abdala, Manfred Bartsch, Helmut Zacharias, Rolf-Dieter Hoffmann, Birgit Gerke, Ute Ch. Rodewald and Rainer Pöttgen
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00193E, Paper
The title compounds were synthesised and characterised.

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