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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
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Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04118C, Communication
Two novel core-shell Ni-Ln nanosized clusters, Na4(H3O)4[Nd38Ni42.5(ID(A)42(OA(c)4(CH3CH2OH)2(CO3)18(μ3-OH)62(μ3-O)6(H2O)12]Cl6•26H2O (1) and Na[Pr42Ni38(μ3-OH)71(μ3-O)4(ID(A)38(NH2CH2COO)2(OA(c)2(CH3CH2OH)2(CO3)16(H2O)6Cl7]Cl3•37H2O (2) (IDA=iminodiacetat(e), were successfully prepared using Cl- anion and the flexible ligand iminodiacetic acid. Structural analysis indicates that the discrete...
Schirin Hanf, Raul Garcia-Rodriguez, Sascha Feldmann, Andrew David Bond, Evamarie Hey-Hawkins and Dominic S Wright
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04390A, Paper
In the current work a range of multidentate pyridyl-phosphine ligands are synthesised with tuneable electronic and steric character, through the incorporation of a variety of alcohols into (amino)pyridyl-phosphine frameworks. The...
Douglas W. Crandell, Haiyang Zhu, Xiaofan Yang, John Hochmuth and Mu-Hyun Baik
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03894H, Paper
The copper-exchanged aluminosilicate zeolite SSZ-13 is a leading catalyst for the selective catalytic reduction of NO.
Brain Abeykoon, Jean-Marc Grenèche, Erwann Jeanneau, Dmitry Chernyshov, Christelle Goutaudier, Aude Demessence, Thomas Devic and alexandra fateeva
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04208B, Paper
Two new 3D porphyrin-based metal organic frameworks were obtained by solvothermally reacting iron (III) chloride, a free base (5,10,15,20-Tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrin) (H2TTPP) and either pyrazine or DABCO. Both MOFs displayed a 3-D...
Stephan R Mathis (II), Saki T Golafale, John Bacsa, Conrad Wayne Ingram, Alexander Steiner, F. Patrick Doty, Elizabeth Auden and Khalid Hattar
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03755K, Paper
Ultra large pore isostructural metal organic frameworks (MOFs) which exhibit both photoluminescence and scintillation properties, were synthesized from trans - 4, 4’-stilbenedicarboxylic acid (H2L) and trivalent lanthanide (Ln) metal salts...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04512J, Paper
The paper reports the formation of unprecedented iridium(III)-derived topological macrocycles. Discrete molecular Borromean rings 1 and 3 in pure form are synthesized via coordination-driven self-assembly of acceptor [(Cp*Ir)2(OO∩OO)](OTf)2 ( Cp*=...
Ana Arauzo, Elena Bartolomé, A C Benniston, Silvia Melnic, Sergiu Sova, Javier Luzón, Pablo Javier Alonso, Anne-Laure Barra and Juan Bartolomé
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02509A, Paper
In this paper we present the characterization of the complex with formula [Mn2Ca2(hmp)6(H2O)4(CH3CN)2](ClO4)4 (1), where hmp-H = 2-(hydroxymethyl)pyridine. Compound 1 crystallizes in the monoclinic space group C2/c with the cation...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04268F, Paper
Two new dysprosium complexes, [Dy(H5L)(NO3)2(CH3OH)2]∙4CH3OH (1), [Dy2(H5L)2(NO3)4(H2O)2]∙10CH3OH (2) were isolated from the reaction of a novel 1,8-naphthalenediol-based ligand N,N'-((1,8-dihydroxynaphthalene-2,7-diyl)bis(methanylylidene))bis(2-hydroxybenzohydrazide), H6L with dysprosium(III) nitrate upon crystallization at different temperatures. Because of...
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04266J, Communication
A unique dysprosium selenoarsenate(III) contains large oligomeric cluster [As3Se6]3− anions with binuclear dysprosium complexes as counterions, and exhibits a photocurrent response and slow magnetic relaxation behavior.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03488H, Paper
Reported are the syntheses, structures and magnetic properties, also by NMR spectroscopy in solution, of a series of 13 linear trinuclear 3d–4f compounds with a lanthanide(III) surrounded by two NiII ions, NiII2LnIII, where the central LnIII is hexacoordinate.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03814J, Paper
Comparison of the results of EDA-NOCV for the M←C bond in [NHC(R) → MR′] and [{P(Ph)3CHR} ← MCl] complexes reveals that the phosphorus ylides are slightly better σ-donors and weaker π-acceptors than the corresponding NHC(R).
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03872G, Paper
Octaaminospherosilicates have been synthesized using hydrogenation over Pd/C and were reacted in situ with propyl isocyanate to give octafunctional hydrogen bond bearing spherosilicates [CnH2n(NHCONH)C3H7]; (n = 4, 5, 6, 11).
Yuki Ide, Nami Murai, Hiroki Ishimae, Masaaki Suzuki, Shigeki Mori, Masashi Takahashi, Mikio Nakamura, Katsumi Yoshino and Takahisa Ikeue
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03859J, Paper
Some iron(III) porphyrin complexes with substituted pyridine N-oxides have exhibited spin-crossover from high-spin to low-spin states with decreasing temperature.
Hua-Yan Si, Chen-Jing Mao, Ya-Meng Xie, Xiu-Guo Sun, Jin-Jin Zhao, Na Zhou, Jian-Qiang Wang, Wen-Jie Feng and Yan-Ting Li
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03683J, Paper
P–N depleted bulk BiOBr/α-Fe2O3 heterojunction (DBH) nanostructures with the growth of (001) BiOBr facets were prepared via a simple hydrothermal method. Such DBH nanostructures show superior hydrogen evolution efficiency.
Dongdong Xu, Fangfang Zhang, Yanzhou Sun, Zhihua Yang, Binghua Lei, Lili Liu and Shilie Pan
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04243K, Paper
A new rare-earth borate, LiRb2LaB2O6, has been synthesized, which possesses a novel MOF-5-like structure and a relatively short UV cut-off edge, compared to other rare-earth borates.
Christopher Benndorf, Sebastian Stein, Lukas Heletta, Marcel Kersting, Hellmut Eckert and Rainer Pöttgen
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04097G, Paper
Yttrium–transition metal–magnesium (indium) Heusler phases were synthesized from the elements in sealed niobium ampoules in a high-frequency furnace or by arc-melting, respectively.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04000D, Communication
By using an Asia flow synthesis system (chip reactor), a new coordination polymer [Co2L4(H2O)2]·CH3CN·H2O (HL = (E)-2-[2-(4-chlorophenyl)vinyl]-8-hydroxyquinoline) has been achieved with 95% yield, demonstrating the uniqueness of flow-type reactions.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04222H, Perspective
The donor strengths of various mono- and bidentate ligands can be easily compared on a unified 13C NMR spectroscopic scale.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04094B, Paper
This paper describes the transition metal chemistry of three bis(X-diphenylphosphino-azol-1-yl)-based bisphosphines: bis(2-Ph2P-imidazol-1-yl)methane (1), bis(5-Ph2P-pyrazol-1-yl)methane (2) and bis(5-Ph2P-1,2,4-triazol-1-yl)methane (3). These show versatility in their coordination behaviour.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03983A, Paper
The pyridyl-N in Pt and Pd complexes of CgP(2-py) can be protonated or can coordinate to form a P,N-chelate; these features are linked with the carbonylation catalysis results.
Niantao Yao, Ru-Fen Zhang, Shaoliang Zhang, Qianli Li and Chunlin Ma
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04061F, Paper
A novel macrocyclic zirconocene (IV) aromatic selenite [(CpZr)8L16]•2(Cp4Zr2(μ-O)Cl2) (complex 1) (Cp = cyclopentadienyl anion; L = 4-fluorobenzeneseleninic acid) was prepared by the reaction of bis(cyclopentadienyl)zirconium dichloride with 4-fluorobenzeneseleninic acid and...
Janusz Lewinski, Iwona Justyniak, Daniel Prochowicz, Adam Tulewicz, Wojciech Bury and Piotr Goś
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03958H, Paper
The octet–compliant group 13 organometallics with highly polarized bonds in the metal coordination sphere exhibit a significant tendency to maximize their coordination number through the formation of adducts with a...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03684H, Paper
A novel ZIF-Ni composite film has been successfully prepared by a facile method involving the in-situ deposition of ZIF-8 on a nickel porous film which is fabricated by selectively etching...
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04182E, Communication
The fluorescence emission-enhanced organogelator with multiple stimuli-responsiveness was successfully prepared form a hexagonal metallacycle via hierarchical self-assembly.
Andrea Leoncini, Seraj A. Ansari, Prasanta Kumar Mohapatra, Arijit Sengupta, Jurriaan Huskens and W Verboom
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03648A, Paper
Three diglycolamide-functionalized (poly(propylene imine) diaminobutane dendrimers, viz. zero generation (LI), first generation (LII), and second generation (LIII), were synthesized and evaluated for their complexation ability towards trivalent actinides and lanthanides....

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23 citations
The emerging new solid-state LED phosphors and the methodologies for their development have been reviewed in this perspective.
DOI: 10.1039/C6DT01230B
Published: 30 May 2016
135 citations
Porphyrin sensitizers have exhibited power conversion efficiencies that are comparable to or even higher than those of well-established highly efficient DSSCs based on ruthenium complexes.
DOI: 10.1039/C4DT02756F
Published: 10 Nov 2014
59 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015

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