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Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.177 48 Issues per Year Indexed in Medline
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Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01828A, Paper
A series of lanthanide-based coordination polymers {[Yb1-xErx(4,4’-bpdo)3(H2O)2](CF3SO3)3}∞ were synthesised by solvent diffusion techniques, where 4,4’-bpdo = 4,4’-bipyridine-N,N’-dioxide, and using differing mole fractions of Yb(III) and Er(III) which were systematically varied...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01932C, Paper
A series of bis(phosphine) molybdenum (II) diazenides [(dppe)2Mo(NNCy)(I)], [(dppe)2(CH3CN)Mo(NNCy)][BArF24] and [(dppe)2)(3,5-(CF3)2C6H3CN)Mo(NNCy)][BArF24] (dppe = 1,2-bis(diphenylphosphino)ethane; Cy = cyclohexyl; ArF24 = (3,5-(CF3)2C6H3)4) were synthesized and structurally characterized. Treatment of the diazenido complexes...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01948J, Paper
Interactions between the uranyl oxo atom and group 14 metal cations in macrocyclic Pacman complexes depend on both molecular cleft constraints and the fifth equatorial ligand of the uranyl.
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01917J, Paper
Water dispersible citrate-capped LaF3:Eu(5%) nanocrystals (NCs) have been partially surface-functionalized by 1,10-phenanthroline (phen) via ligand exchange method to produce novel water dispersed citrate/phen-capped LaF3:Eu(5%) NCs in which citrate ligands preserve...
Vera Ilynichna Isaeva, Oleg Leonidovich Eliseev, Ruslan V. Kasantsev, Vladimir V. Chernyshev, Pyotr E. Davydov, B. R. Saifutdinov, A. L. Lapidus and Leonid Kustov
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01394E, Paper
Novel nanohybride materials were prepared by immobilizing Co nanoparticles on microporous framework MIL-53(Al) as a porous host matrix. The synthesized cobalt-containing materials were characterized by XRD, STEM, and oxygen titration....
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02060G, Communication
Backbone functionalization of the pre-coordinated emblematic IMes ligand with COOH moiety was achieved upon treatment of Cp(CO)2Mn(IMes) with n-BuLi followed by CO2 and HCl to afford Cp(CO)2Mn(IMesCOOH). The later reacts...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02013E, Perspective
While β-diketiminate (BDI or ‘nacnac’) ligands have been widely adopted to stabilize a wide range of metal ions in multiple oxidation states and coordination numbers, in several occurrences these ligands do not behave as spectators and participate in reactivity.
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02059C, Perspective
General considerations on the differences and similarities between heterogeneous photocatalysis and thermal catalysis are presented. Some research papers are reviewed where a reaction has been carried out in the presence...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02283A, Communication
An acetal-linked self-quenched zinc(II) phthalocyanine tetramer has been prepared. In an acidic environment in phosphate buffered saline or inside tumour cells, the phthalocyanine units of the tetramer are separated thereby...
Marco Lelli, Norberto Roveri, Cristina Marzano, James D Hoeschele, Alessandra Curci, Nicola Margiotta, Valentina Gandin and Giovanni Natile
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01976E, Paper
Hydroxyapatite (HA) nanocrystals are important inorganic constituents of biological hard tissues in vertebrates and have been proposed as bone substitute or coating material for prostheses in biomedicine. Hydroxyapatite is also...
Jitka Pracharova, Tereza Radosova Muchova, Eva Dvorak Tomastikova, Francesco Paolo Intini, Concetta Pacifico, Giovanni Natile, Jana Kasparkova and Viktor Brabec
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01467D, Paper
The limitations associated with the clinical utility of conventional platinum anticancer drugs have stimulated research leading to design of new metallodrugs with improved pharmacological properties, particularly with increased selectivity for...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01795A, Paper
A solvent-dependent reversible fluorescent-colorimetric bis-iminopyridyl Schiff base receptor (N1E,N4E)-N1,N4-bis(quinolin-4-ylmethylene)benzene-1,4-diamine (L) has been developed for the first time for sensitive and selective determination of Al3+ and Cu2+ in aqueous solution.
Gamage S. P. Garusinghe, S. Max Bessey, Alice E. Bruce and Mitchell R. M. Bruce
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01400C, Communication
The 4-centered, metallacycle structure proposed as an intermediate in gold(I) thiolate, disulfide exchange.
Peng-Fei Liu, Kai Tao, Guo-Chang Li, Meng-Ke Wu, Shuai-Ru Zhu, Fei-Yan Yi, Wen-Na Zhao and Lei Han
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02083F, Communication
A hexagonal nanosheet LDH@ZIF-8 composite was fabricated by in situ growth of ZIF-8 on Zn–Al LDH and exhibited a CO2 adsorption capacity of 1.0 mmol g−1 at room temperature and 1 bar.
Takuya Hasegawa, Sun Woog Kim, Shinnosuke Kamei, Tadashi Ishigaki, Kazuyoshi Uematsu, Koutoku Ohmi, Kenji Toda and Mineo Sato
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01715K, Paper
Crystal structure of a Ba2TiP2O9 phosphor has been revealed by Rietveld refinement, it has monoclinic structure which consists of PO4 tetrahedra and TiO5 pyramidal polyhedra connected to form a chain structure along the c-axis.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02094A, Perspective
This Perspective illustrates the state-of-the-art of stereoselective carbene transfer reactions catalysed by chiral metal porphyrin complexes. A particular attention is focused on the active role of the porphyrin ligand to drive the carbene insertion into the target organic skeleton.
Farid M Sroor, Cristian G. Hrib, Phil Liebing , Liane Hilfert, Sabine Busse and Frank T Edelmann
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01974A, Paper
The lithium-cyclopropylethynylamidinates Li[c-C3H5-C≡C-C(NR)2] (1a: R = iPr, 1b: R = cyclohexyl (Cy)) have been used as precursors for the preparation of five new series of half-sandwich complexes. These complexes contain...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02359B, Communication
A highly thermal stable MOF, comprised of Mg2+ and H2EBTC2- with a formula of [Mg(H2EBTC)(DMF)2], emits dual band luminescence centered at 376 and 555 nm. The former is assigned to fluorescence...
Na Li, Hao Wang, Dao-Liang Song, Chao Li, Ruo-Ning Li, Shimin Hou, Yongfeng Wang and Richard Berndt
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01963C, Communication
Single Co adatoms adsorbed on a double-layer NaCl film supported by Cu(111) were negatively charged after applying a positive voltage pulse to the sample in a scanning tunnelling microscope. Density...
Xiu-Jun Zheng, Nicola Bell, Charlotte Stevens, Yu-Xi Zhong, Georg Schreckenbach, Polly Louise Arnold, Jason Love and Qing-Jiang Pan
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01625A, Paper
The computationally- and experimentally-determined molecular structures of a bis-uranyl(VI) complex of an expanded Schiff-base polypyrrolic macrocycle [(UO2)2(L)] are in close agreement only if the pyridine in the fifth equatorial donor...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01930G, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
Zheng Xu, Guoqiang Li, Yuan-Yuan Ren, Hua Huang, Xiaoping Wen, Qiang Xu, Xiaotian Fan, Zhao Huang, Junhai Huang and Lin Xu
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01398H, Paper
A simple fluorescent probe NHQ based on quinoline was successfully prepared via one-step synthesis. The probe NHQ exhibited “turn-on” fluorescence and excellent selectivity toward Cd2+ in different buffer solutions such...
Cuijuan Zhang, Tomoya Tsuboi, Hiroaki Namba, Yasuaki Einaga and Takashi Yamamoto
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01723A, Paper
Magnetic properties of the layered double hydroxides (LDH) containing transition metal ions are still developing, compared with the layered metal hydroxides salt that exhibits structure-dependent magnetism. In this article, we...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01573E, Communication
The substitution effect on a series of POM-type ionic liquids, has been investigated. The physicochemical properties of the ILs are highly related to their structures. When protons are substituted for ammonium, high conductivity and better thermostability are observed.
Amr A. A. Attia, Alexandru Lupan and R. Bruce King
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01982J, Paper
The lowest energy structures of the tetracarbalanes C4Aln−4Men (n = 11, 12, 13, 14) are deltahedra having the carbon atoms at degree 4 vertices. The lowest energy structures for the smaller tetracarbalanes C4Aln−4Men (n = 6, 7, 8) have pentagonal or hexagonal open faces with all four carbon atoms at degree 3 vertices.

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DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015

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