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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Milton N. Jackson, Maisha K. Kamunde-Devonish, Blake A. Hammann, Lindsay A. Wills, Lauren B. Fullmer, Sophia E. Hayes, Paul H.-Y. Cheong, William H. Casey, May Nyman and Darren W. Johnson
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01268F, Perspective
This Perspective highlights several modern characterization techniques used to identify nanoscale inorganic clusters in the context of multiple case studies.
Benedikt Waerder, Simon Steinhauer, Christian G. Reuter, Julia Bader, Beate Neumann, Hans-Georg Stammler, Yury V. Vishnevskiy, Berthold Hoge and Norbert W. Mitzel
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT90132D, Correction
Alan K. Brisdon, Hana Ali Ghaba, Bernd Beutel, Amina Egjandi, Arij Addaraidi and Robin G. Pritchard
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02043C, Paper
From HFC replacements CF3CF2CH2F and Z-CF3CF[double bond, length as m-dash]CFH new E-perfluoropropenyl phosphine ligands are prepared, including the first perfluoroalkenyl bidentate phosphine, (E-CF3CF[double bond, length as m-dash]CF)2PCH2CH2(E-CF[double bond, length as m-dash]CFCF3)2.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02275D, Paper
Addition of HCl to perfluorocarbene complexes of iridium occurs regiospecifically and stereospecifically.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02191J, Paper
Copper(II) and palladium(II) meso-tetraferrocenylporphyrins (CuTFcP and PdTFcP) were employed as catalysts for electrochemical proton reduction in DMF using trifluoroacetic acid (TFA) or triethylamine hydrochloride (TEAHCl) as acids.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01998B, Paper
The electronic interactions between an organometallic center and a non-innocent framework were tuned by chemical substitution.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02018B, Paper
Bulged structures in nucleic acids recognized and stabilized by helical bimetallic species have been identified and have been proposed to be linked to the biological activity of these species.
Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin and Matti Haukka
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03167A, Paper
In this work, several new examples of rare AuIIIAuIII aurophilic contacts are reported.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02147B, Paper
Six new Co(II) coordination polymers have been synthesized and characterized. The N-donor co-ligands and pH value have an effect on the final structures.
Qi Sun, Xiangrui Jia, Xuefei Wang, Huogen Yu and Jiaguo Yu
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01859E, Paper
A facile in situ ion-exchange reaction of WO42− on the Bi(NO3)3 solid surface was developed to prepare porous Bi2WO6 nanosheets.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01961C, Paper
Novel 3D hierarchical Ag3PO4/MoS2 composites were successfully prepared through a facile and reproducible hydrothermal-in situ precipitation method.
Tainan Duan, Ting-Kuang Chang, Yun Chi, Jin-Yun Wang, Zhong-Ning Chen, Wen-Yi Hung, Chang-Hsuan Chen and Gene-Hsiang Lee
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01844G, Paper
Ir(III) complexes with functional 2-(pyrimidin-5-yl)pyridine cyclometalates display blue electroluminescence with CIEx,y coordinates occurring at (0.16, 0.17) at 100 cd m−2.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01595B, Paper
A cobalt-1,4-naphthalenedicarboxylic acid system in a systematic series of ionic liquids with different alkyl chain lengths of imidazolium cations governed the construction of four MOFs with regular changes of secondary building units (SBUs).
Richard Weihrich, Wenjie Yan, Jan Rothballer, Philipp Peter, Stefan Michael Rommel, Sebastian Haumann, Florian Winter, Christian Schwickert and Rainer Poettgen
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02036K, Paper
The half metal (HFM) Sn2Co3S2 shows a fascinating S = 1/2 magnetism. Anisotropic coupling of spins in and between Co Kagomé layers by Sn sites is now studied from substitution...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02358K, Paper
A series of bright, europium (III) complexes has been prepared based on an achiral heptadentate triazacyclononane ligand bearing two strongly absorbing, coordinated aralkynyl pyridyl moieties. The binding of chiral carboxylates,...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01552A, Paper
The pH value plays an important role in controlling the crystallization process and microstructure of the final products in the synthesis of nanocrystals with solvothermal method. This work reported the...
Xiu-ling Zhang, Yong-Zheng Zhang, Da-Shuai Zhang, Bao-yong Zhu and Jian-Rong Jeff Li
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01770J, Paper
By the solvothermal reaction of a triangular ligand, 2,4,6-tris-(4-carboxyphenoxy)-1,3,5- triazine (H3tcpt) with Zn(NO3)2 in N,N'-dimethylacetamide/acetonitrile/H2O (v/v/v = 1:1:1) mixed solvent, a two-fold interpenetrated three-dimensional (3D) porous metal-organic framework, [Zn2(tcpt)OH]∙solvents (1∙solvents),...
Nilusha Priyadarshani, Bojana Ginovska, Tim Bays, John C. Linehan and Wendy Shaw
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01649E, Paper
Inspired by nature’s ability to regulate catalysis using physiological stimuli, azobenzene was incorporated into Rh(bis)diphosphine CO2 hydrogenation catalysts to photoinitiate structural changes to modulate the resulting catalytic activity. The rhodium...
Evamarie Hey-Hawkins, Andy Schmied, Axel Straube, Sascha Jähnigen and Toni Grell
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02567B, Paper
The two highly flexible ligands 1,1’-bis(4-phospholanobutyl)ferrocene (5a) and 1,1’-bis(5-phospholanopentyl)ferrocene (5b) reacted with [PtCl2(cod)] (cod = 1,5-cyclooctadiene), [AuCl(tht)] (tht = tetrahydrothiophene) and [{RhCl(CO)2}2] to give the respective chelate complexes cis-[PtCl2(5a,b-κ2P,P’)] (7a,b),...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01569C, Paper
Herein, synthesis, structural characterization, magnetic properties and guest binding activities of four Fe3+ based double stranded helicates namely; [Fe2(L)2](ClO4)(Cl)∙4(CH3OH)∙2(H2O) (1), [Fe2(L)2](BF4)2∙2(H2O) (2), [Fe2(L)2](NO3)2∙3(CH3OH)∙2(H2O) (3), [Fe2(L)2](Cl)2∙2(CH3OH)∙4(H2O) (4) are reported. Complexes 1-4...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01722J, Paper
A series of compositionally complex scheelite-structured nanocrystals of the formula A1-xxWO4 (A = Ca, Sr, Ba) have been prepared under benign synthesis conditions using the vapor diffusion sol-gel method. Discrete...
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02038G, Paper
Fluorescent (E)-4,4′-dimethyl-2,2′-bis(trimethylsilyl)azobenzene was synthesized.
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02285A, Communication
An inverse linear relation between experimentally observed 195Pt NMR signals and the overall sum of coordinated halido ligands’ ionic radii was discovered in Pt(II) and Pt(IV) complexes. The reduction of...
Abdelkrim El Kadib, Younes Brahmi, Nadia Katir, Juan Antonio Macia Agullo, Ana Primo, Mosto Bousmina, Jean-Pierre Majoral and Hermenegildo Garcia
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02367J, Paper
The sol-gel co-condensation of organo-phosphonate to titanium alkoxide enables access to novel organic-inorganic hybrids based on phosphonate-bridged titanium dioxide. In this contribution, we bring new perspectives to the long established...
Gabriela Espinoza Quintero, Isabelle Paterson-Taylor, Nicholas H. Rees and Jose M. Goicoechea
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02380G, Paper
Reactions of the protonated heptaphosphide dianion, [HP7]2−, with one equivalent of E[N(SiMe3)2]2 (E = Ge, Sn, Pb) give rise to novel derivatized cluster anions [P7EN(SiMe3)2]2− (E = Ge (1), Sn (2) and Pb (3)). 1 readily decomposes in solution at room temperature to afford the dimeric product [(P7Ge)2N(SiMe3)2]3− (4).

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