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Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
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Takeshi Kobayashi, Frédéric A Perras, Anna Murphy, Yao Yao, Jaclyn Catalano, Silvia Centeno, Cecil Dybowski, Nicholas Zumbulyadis and Marek Pruski
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00182G, Paper
Dynamic nuclear polarization (DNP) is used to enhance the (ultra)wideline 207Pb solid-state NMR spectra of lead compounds of relevance in the preservation of cultural heritage objects. The DNP SSNMR experiments...
Seong-Hun Park, Myung-Hwa Jung, Yong-Jung Lee and Young-Duk Huh
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00071E, Paper
We present a confined condensation technique for the fabrication of layered copper hydroxide frameworks from lamellar copper-organic assemblies with long alkyl chains through the selective introduction of hydroxo bridging ligands....
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00298J, Paper
Three dinuclear lanthanide complexes, [Ln2(thd)4Pc]·2C6H6 (Hthd = 2,2,6,6-tetramethylheptanedione, Ln = Sm (1), Tb (2), Dy (3)), have been synthesized based on phthalocyanine (Pc). They can be reversibly transformed into [Ln2(thd)4Pc]...
Elnaz Hobbollahi, Manuela List, Benjamin Hupp, Fabian Mohr, Raphael J. F. Berger, Andreas Steffen and Uwe Monkowius
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00180K, Communication
The metallophilic interactions in the cluster [Au2CuCl2(P∩N)2]PF6 give rise to very efficient cold-white light emission.
Gabriella Tamasi, Antonello Merlino, Federica Scaletti, Petra Heffeter, Anton A. Legin, Michael A. Jakupec, Walter Berger, Luigi Messori, Bernhard K. Keppler and Renzo Cini
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04295C, Paper
fac-[RuII(CO)3Cl2(MBI)] and -[RuII(CO)3Cl2(DMBI)] are CO-releasing materials able to link histidines of proteins, and the latter showed antitumor effects in murine colon cancer.
Patrick Eisenberger and Cathleen Crudden
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04232E, Perspective
The synthesis, stability and catalytic reactivity of borocations are described in the context of their reaction in frustrated Lewis pair-type processes. The reactivity of these unique Lewis acids can be...
Jedrzej Kobylarczyk, Dawid Pinkowicz, Monika Srebro, James Hooper and Robert Podgajny
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00293A, Paper
Hexacyanidometalates (M = FeIII, CoIII) and multisite anion receptor HAT(CN)6 (1,4,5,8,9,11-hexaazatriphenylenehexacarbonitrile) recognize each other in acetonitrile solution and self-assemble into the novel molecular networks (PPh4)3[M(CN)6][HAT(CN)6] (M = Fe, 1; Co,...
Maxim A. Faraonov, Dmitri V. Konarev, Alexey M. Fatalov, Salavat S. Khasanov, Sergey Troyanov and Rimma N. Lyubovskaya
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04896J, Paper
Crystalline anionic salts of titanyl macrocycles with acceptor substituents or extended π-system have been obtained for the first time: (PPN+)2{O=TiIV(PcCl84–)}2– (1), (PPN+){O=TiIV(Nc3•–)}•–·2C6H4Cl2 (2) and (PPN+)2{O=TiIV(AceTPrzPz4–)}2– ·1.2C6H4Cl2·0.8C6H5CN (3) where PPN+ is...
shuai liu, Nan Peng, Yu Bai, Huiyan XU, Dayan Ma, Fei Ma and Kewei Xu
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00085E, Paper
One-dimensional tellurides are the good candidates for thermoelectric applications, but the fabrication of telluride nanotubes is still challenging. To this end, solvothermal approach is proposed to synthesize Bi2Te3, PbTe, CuxTe...
Katarzyna Czerwińska, Marlena Golec, Magdalena Skonieczna, Joanna Palion, Dorota Zygadło, Agata Szłapa, Stanislaw Krompiec, Barbara Machura and Agnieszka Szurko
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04584G, Paper
Two gold(III) complexes incorporating 2,2′:6′,2′′-terpyridine derivatives have been synthesised and characterized as well as the possibility of tuning the cytotoxic activity by structural modifications of terpy ligand has been examined....
Yunjun Shen, Yani Pan, Kang Zhang, Xuewei Liang, Jiyong Liu, Bernhard Spingler and Simon Duttwyler
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00269F, Paper
The regioselective derivatization of the monocarba-closo-dodecaborate anion via catalytic B–H bond activation is reported.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00327G, Paper
The first structurally characterised chelated, saturated bis(NHC) complexes are reported along with facile ligand fragmentations during their synthesis.
Wenhai Cao, Xiaoquan Zhu, Pengfei Liu, Shaodong Su, Shengmin Hu, Yuehong Wen, Xintao Wu and Tianlu Sheng
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04420D, Communication
The new benzoquinone-bridged Co2 complexes with different magnetic anisotropy induced by acetonitrile and water molecules are reported.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00308K, Paper
We present a convenient synthesis of the first silylated bistetrazole and its application to access bistetrazolatoborates, structurally characterized by a ten-membered B2N4C4 heterocyclic system. Investigated pyrazinediolatoborates are LiBOB analogues with potential as lithium ion battery additives.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00174F, Communication
Herein, we describe the synthesis and characterization of two newly self-assembled supramolecular coordination complexes (SCCs) by using the cis-{Pt(PEt3)2}2+ center and two different kinds of pyridyl-derivatized ligands.
Vasily A. Ilichev, Anton V. Rozhkov, Roman V. Rumyantcev, Georgy K. Fukin, Ivan D. Grishin, Artem V. Dmitriev, Dmitry A. Lypenko, Eugeny I. Maltsev, Artem N. Yablonskiy, Boris A. Andreev and Mikhail N. Bochkarev
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04519G, Paper
Efficient energy transfer in Yb and room temperature phosphorescence in Gd complexes with readily oxidizable thiophenolate ligands were observed.
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04872B, Paper
A new three–layer perovskite oxide with the Ruddlesden–Popper (R–P) phase, K2CaNaNb3O10, and its protonated form were synthesised and their photocatalytic performance was compared to that of KCa2Nb3O10 or the protonated...
Ainara Telleria, Piet W.N.M. van Leeuwen and Zoraida Freixa
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00542C, Paper
Eight new ruthenium(II) half-sandwich complexes containing azobenzene-appended pyridine (1), bipyridine (2–5) and phosphine (6, 7) ligands have been synthesized and fully characterized. UV-vis spectroscopic studies showed that the trans-to-cis photoisomerization...
Michael Getz, Per-Anders Hansen, Mohammed A. K. Ahmed, Helmer Fjellvåg and Ola Nilsen
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00253J, Paper
Thin films of YbVO4 displaying UV to NIR down conversion have been deposited by atomic layer deposition and crystallized through a flux aided process.
Alexandra Pop, Clément Bellini, Razvan Suteu, Vincent Dorcet, Thierry Roisnel, Jean-Francois Carpentier, Silvestru D Anca and Yann Sarazin
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00279C, Paper
Heteroleptic zinc and cadmium complexes of the type [{Me2N^E^OR2}M-Nu]n (M = Zn, Cd; E = S, Se; R = CH3, CF3; Nu = N(SiMe3)2, I, Cl; n = 1-2) were...
Carol Hua, Jing-Yuan Ge, Floriana Tuna, David Collison, Jing-Lin Zuo and Deanna M. D'Alessandro
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04719J, Paper
Two new Mn2+-based metal–organic frameworks containing the tris(p-tetrazolylphenyl)amine (H3TTPA) ligand exhibit multiple redox-accessible states which have been interrogated using in situ solid state spectroelectrochemical methods.
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04796C, Paper
The development of hybrid organic-inorganic perovskite solar cells is one of the most rapidly growing fields in the photovoltaic community and is on the best way to challenge polycrystalline silicon...
Israel Carreira-Barral, Marta Mato-Iglesias, Andres M. de Blas Varela, Carlos Platas-Iglesias, Peter A Tasker and David Esteban-Gómez
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00093F, Paper
The ditopic receptor L3 [1-(2-((7-(4-(tert-butyl)benzyl)-1,4,7,10-tetraazacyclododecan-1-yl)methyl)phenyl)-3-(3-nitrophenyl)urea] containing a macrocyclic cyclen unit for Cu(II)-coordination and an urea moiety for anion binding was designed for recognition of metal salts. The X ray structure...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00079K, Perspective
The ruthenium(II) complexes with polypyridyl ligands have been extensively studied as promising functional molecules due to unique photochemical and photophysical properties as well as redox properties. In a context, we...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00005G, Paper
Based on the same in-situ formed ligand, two new MOFs, namely, {[Zn2(HL)2]·0.5DMF·H2O}n (1) and {[Cd2(HL)2]·1.5H2O}n (2) (H3L = 5-[(2H-tetrazol-5-yl)amino]isophthalic acid), have been solvothermally synthesized and structurally characterized by elemental analysis,...

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37 citations
The emerging new solid-state LED phosphors and the methodologies for their development have been reviewed in this perspective.
DOI: 10.1039/C6DT01230B
Published: 30 May 2016
78 citations
The recent developments in lanthanide SMMs highlighted in this frontier article indicate the directions to which further synthetic efforts should be focused.
DOI: 10.1039/C4DT03329A
Published: 21 Jan 2015
64 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015

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