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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01399F, Paper
A versatile and efficient modular synthetic platform was developed for assembling multifunctional conjugates and targeted forms of platinum–(benz)acridines, a class of highly cytotoxic DNA-targeted hybrid agents. The synthetic strategy involved...
CanCan Qin, JiaLi Cao, Jun Chen, GaoLe Dai, TongFu Wu, Yanbin Chen, YueFeng Tang, AiDong Li and Yanfeng Chen
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01764A, Paper
Ultrathin TiO2 coating confers a significant improvement in the cycle performance of nickel-rich LiNi0.6Co0.2Mn0.2O2 cathode material.
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01726F, Paper
New 5,5-diethylbarbiturate (barb) complexes of Ni(II), Cu(II) and Zn(II) with 1,10-phenantroline (phen) and 2,2’-dipyridylamine (dpya), namely [Ni(phen-κN,N’)3]Cl(barb)∙7H2O (1), [Cu(barb-κN)(barb-κ2N,O)(phen-κN,N’)]∙H2O (2), [Cu(barb-κN)2(phen-κN,N’)] (2a), [Zn(barb-κN)2(phen-κN,N’)]∙H2O (3), [Ni(barb-κ2N,O)(dpya-κN,N’)2]Cl∙2H2O (4), [Cu(barb-κ2N,O)2(dpya-κN,N’)]∙2H2O (5) and [Zn(barb-κN)2(dpya-κN,N’)]...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01722C, Paper
The synthesis, electrochemistry and photophysical properties of a family of Pt(IV) complexes with cyclometalated 2-(9,9-dimethylfluoren-2-yl)pyridine (flpy) are reported. Homoleptic and heteroleptic tris-cyclometalated complexes with a meridional configuration, mer-[Pt(C^N)2(flpy)]OTf, with C^N...
Huaiyi Huang, Pingyu Zhang, Yu Chen, Kangqiang Qiu, Chengzhi Jin, Liang-Nian Ji and Hui Chao
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01270A, Paper
DNA binding and DNA transcription inhibition is regarded as a promising strategy for cancer chemotherapy. Herein, chloro terpyridyl Ru(II) complexes, [Ru(tpy)(N^N)Cl]+ (Ru1, N^N = 2,2’-bipyridine; Ru2, N^N = 3-(Pyrazin-2-yl)-as-triazino[5,6-f]acenaphthylene; Ru3,...
Guo-Yu Yang, Lei-Lei Li, Rui Pan, Junwei Zhao and Bai-Feng Yang
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01629D, Paper
Six new lanthanide (Ln) germanate cluster organic frameworks (LnGeCOFs) derived from {Ln8Ge12} cage cluster units {[Nd(pza)2(H2O)2)] [Nd8Ge12(μ3-O)24E12(pza)(H2O)12]}•3H2O (1), {[Dy(CH3COO)(CO3)(H2O)]2[Dy8Ge12(μ3-O)24E12(H2O)12]}•12H2O (2), {[TbGeE(HO)2O(pza) (H2O)]2[Tb8Ge12(μ3-O)24E12(H2O)6]}•18H2O (3), {[DyGeE(HO)2O(C3H5NO2)(H2O)]2[Dy8Ge12(μ3-O)24E12(H2O)8]}•8H2O (4), {[Tb(pca)2 (H2O)]3[Tb8Ge12(μ3-O)24E12(H2O)4]}•(OH)3•10H2O (5) and {[Dy(pza)2(H2O)][Dy(pza)2(H2O)2][Dy(pza)3(H2O)][Dy8Ge12(μ3-O)24E12(pza)(HCOO)...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00945J, Paper
Highly flexible bis-phospholane ligands form 16- to 28-membered dinuclear macrocyclic silver(I) complexes selectively without using high-dilution techniques. Comparison with gold(I) complexes gives further evidence that gold(I) is significantly smaller than silver(I).
Phuong V. Dau, Zhicheng Zhang, Phuong D. Dau, John K. Gibson and Linfeng Rao
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01694D, Paper
Three amine-functionalized diamide ligands form tridentate complexes with Nd3+ in aqueous solutions. The stability constants of the complexes follow the order of the ligand basicity that can be tuned by different substitutional groups.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01417H, Paper
Four potassium calix[4]arene crown ether inclusion complexes with different structures have been synthesized and show different activities in the isoselective ROP of lactide (a best Pm value is 0.73).
Dries Parmentier, Tom Vander Hoogerstraete, Dipanjan Banerjee, Yash A. Valia, Sybrand J. Metz, Koen Binnemans and Maaike C. Kroon
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00833J, Paper
The extraction mechanism of cobalt, nickel and zinc with the ionic liquid tetraoctylammonium oleate is reported.
Junhua Jia, Luling Wu, Yu Ding, Chusen Huang, Weiping Zhu, Yufang Xu and Xuhong Qian
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01258B, Communication
A DPA-based fluorescent probe was designed and synthesized for the recognition of mercuric ions and imaging in living cells. The fluorescent probe exhibits excellent selectivity and sensitivity toward Hg2+, and the detection limit was calculated to be 5.49 nM.
Hidetaka Nakai, Kazuhiro Kitagawa, Juncheol Seo, Takahiro Matsumoto and Seiji Ogo
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01303A, Communication
A gadolinium(III) complex that shows crystalline-state phosphorescence is presented; crystals color can be changed by doping of 1-naphthol.
Huiying Tan, Meizhu Rong, Yayun Zhou, Zhiyu Yang, Zhengliang Wang, Qiuhan Zhang, Qin Wang and Qiang Zhou
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01693F, Paper
A single-phased K3ZrF7:Mn4+ has been successfully synthesized, in which Mn4+ playing as the luminescent center to absorb blue light and emit red light. Obvious warm white light can be observed from the WLED based on this red phosphor.
Wei Liu, Ying Ji, Ying Wang, Qiushi Sun, Xudong Zhao, Xiaoyang Liu and Xiaopeng Jia
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01174H, Paper
A new europium silicate, NaEuSi3O7(OH)2 (denoted as 1), was synthesized under high-temperature and high-pressure conditions, and structurally characterized by single-crystal and powder X-ray diffraction (XRD) analyses.
J. V. Suárez-Meneses, A. Oukhrib, M. Gouygou, M. Urrutigoïty, J.-C. Daran, A. Cordero-Vargas, M. C. Ortega-Alfaro and J. G. López-Cortés
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01022A, Paper
Catalytic applications on direct intramolecular arylation was developed using a new family of palladium complexes that includes [N,P] ligands based on the pyrrole ring with α-phosphine and phosphole units.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00449K, Paper
The hybrid MoSe2/rGO nanosheets were synthesized via a facile hydrothermal process. The hybrid nanosheets electrode showed enhanced specific capacitance value than that of the pristine MoSe2. The MoSe2/rGO nanosheets exhibited increasing capacitance retention of up to 180% for the long-term stability test of 10,000 cycles at high current density.
Ni Zhen, Kui Wu, Ying Wang, Qiang Li, Wenhui Gao, Dianwei Hou, Zhihua Yang, huaidong Jiang, yongjun Dong and ShiLie Pan
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01537A, Paper
Two noncentrosymmetric metal chalcogenides, BaCdSnS4 and Ba3CdSn2S8, were synthesized using a high-temperature solid-state reaction in evacuated silica tube. Although two compounds have the same building units in their structures, namely...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01064D, Paper
New cationic enamine--diimine cobalt complex [LCoBr.THF][BArF] (I) and its neutral analogue [LCoBr2] (II) where L = [(2,4,6-Me3-C6H2)NHCMe=C{CMe=(N-2,4,6-Me3(C6H2)}2] and BArF- = [{3,5-(CF3)2C6H3}4B]−, were synthesised and then characterized by single-crystal X-ray diffraction,...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01654E, Paper
C≡CFc, [3](ClO4)) were synthesized by the reactions of [(tppz)(PPh3)2RuCl](ClO4) (tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine)) with ferrocence-acetylide ligands and characterized by ESI-MS, and 1H and 31P NMR spectroscopies. The structure of [1](PF6) was...
Clémence Cheignon, Fabrice Collin, Peter Faller and Christelle Hureau
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01979J, Communication
Evaluation of the pro versus antioxidant activity of ascorbate regarding Cu(Aβ) induced Reactive Oxygen Species production in the context of Alzheimer's disease shows that a protective activity can only be...
Kyounghoon Lee, Haochuan Wei, Anastasia V. Blake, Courtney M. Donahue, Jason M. Keith and Scott R. Daly
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00200E, Paper
Ligand K-edge XAS and DFT studies of ligand variations in Rh(I) pincer complexes and correlations to small molecule reactivity.
Chad S. Smithson, Daniel J. MacDonald, T. Matt Letvenuk, Christian E. Carello, Michael Jennings, Alan J. Lough, James Britten, Andreas Decken and Kathryn E. Preuss
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01249C, Paper
A redox active ligand with three isolatable oxidations states is created by combining a thiazyl ring and an o-naphthoquinone.
Biswanath Das, Bao-Lin Lee, Erik A Karlsson, Torbjörn Åkermark, Andrey Shatskiy, Serhiy Demeshko, Rong-Zhen Liao, Tanja M Laine, Matti Haukka, Erica Zeglio, Ahmed Abdel‐Magied, Per Siegbahn, Franc Meyer, Markus Kärkäs, Eric Johnston, Ebbe Nordlander and Björn Åkermark
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01554A, Communication
The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the dinucleating ligand 2,2'‐(2‐hydroxy‐5‐methyl‐1,3‐phenylene)bis(1H‐benzo[d]imidazole‐4‐carboxylic acid) is described. The two iron complexes were...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01597B, Paper
Liquid-assisted grinding (LAG) reactions have been successfully applied to achieve a series of complexes and coordination polymers based on divalent 3d-transition metal chlorides (TM chlorides) and the aromatic ligand 1H-benzotriazole...
Javier Iglesias-Sigüenza, Cristina Izquierdo, Elena Diez-Martin, Rosario Fernández and Jose M. Lassaletta
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01700B, Frontier
The benzoannulation of the most common families of aromatic NHCs, imizadol-2-ylidenes and 1,2,4-triazol-3-ylidenes, results in heterobicyclic imidazo[1,5-a]pyridine-3-ylidenes (ImPy´s) and [1,2,4]triazolo[4,3-a]pyridin-3-ylidenes (TriPy's), characterized by a bridged N atom. These are versatile...

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