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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.097 48 Issues per Year Indexed in Medline
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Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00687B, Paper
The invitation of aliphatic amines en (ethylenediamine), aep (N-(2-aminoethyl)piperazine) and tepa (tetraethylenepentamine), and aromatic species 2,2’-bipy (2,2'-bipyridine) and dpe (1,2-di(4-pyridyl)ethylene) as structure directing agents (SDAs) into inorganic iodoplumbates affords six...
Giampaolo Ricciardi, Angela Rosa, Silva Bortolussi, Daniela Pietrangeli, Antonietta Pepe, Saverio Altieri, Elisa Viola, Maria Pia Donzello, Nicoletta Protti, Cinzia Ferrari, Annamaria Clerici, Laura Consolino and Ian Postuma
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00394F, Paper
The zinc(II) complex of the octa-anionic 2,3,9,10,16,17,23,24-octakis-(7-methyl-7,8-dicarba-nido-undeca-boran-8-yl)hexyl-thio-6,13,20,27-phthalocyanine (nido-[ZnMCHESPc]Cs8, 7) has been obtained in the form of caesium salt through mild deboronation of the neutral precursor, the closo-[ZnMCHESPc] complex, 6, by...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00815H, Paper
The promising green oxynitride phosphor, Ba3-xMgxSi6O12N2:Eu2+ was synthesized by the solid-state reaction method. The effect of Mg2+ doping on the structure and photoluminescence (PL) properties of Ba3Si6O12N2:Eu2+ was investigated systematically....
Gabriele Albertin, Stefano Antoniutti, Jesús Castro and Gianluca Dottorello
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00755K, Paper
The preparation of half-sandwich diazoalkane complexes with an indenyl ligand is described. Reactivity studies with alkenes and alkynes led to cyclisation and/or substitution reactions.
E. Salojärvi, A. Peuronen, R. Sillanpää, P. Damlin, H. Kivelä and A. Lehtonen
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00995B, Paper
Dioxotungsten(VI) complexes react with thionation reagents to form disulphides and furthermore with activated alkyne to generate dithiolene complexes.
Miguel F. Silva Valverde, Eileen Theuergarten, Thomas Bannenberg, Matthias Freytag, Peter G. Jones and Matthias Tamm
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01362C, Paper
The reaction of a sterically demanding NHC affords frustrated carbene-trimethylsilylium ion pairs, which exhibit FLP-type reactivity such as carbon dioxide fixation and metal–halide bond activation.
Macguire R. Bryant, Andrew D. Burrows, Christopher M. Fitchett, Chris S. Hawes, Sally O. Hunter, Luke L. Keenan, David J. Kelly, Paul E. Kruger, Mary F. Mahon and Christopher Richardson
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00011D, Paper
A variety of coordination materials are formed from the heteroditopic ligand 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoate.
Michael Naguib, Raymond R. Unocic, Beth L. Armstrong and Jagjit Nanda
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01247C, Communication
Large-scale delamination of MXenes was achieved by using a simple aqueous organic base treatment followed by agitation in water.
Piermaria Pinter, Andrea Biffis, Cristina Tubaro, Mario Tenne, Maria Kaliner and Thomas Strassner
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01067E, Paper
Palladium(II) complexes with N-heterocyclic dicarbene ligands featuring electron-withdrawing substituents have been prepared and tested as catalysts in alkyne hydroarylations.
Laurence J. Kershaw Cook, Julie Fisher, Lindsay P. Harding and Malcolm A. Halcrow
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00732A, Paper
Iron(II) and zinc(II) complexes of bis[2,6-di(pyrazol-1-yl)pyrid-4-yl]disulfide assemble into tetranuclear metallacycles according to ES-MS, DOSY NMR and conductivity data. The iron complex exhibits a thermal spin-state equilibrium in solution, which the iron centres appear to undergo independently of each other.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00602C, Paper
The first neutral 3D sra-LOF built from a 1D inorganic rod-shaped chain [Ln(CO2)2(HCO2)]n (Ln = Eu, Gd, Dy) was synthesized.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00685F, Paper
The X-ray structural investigation rationalized the variable axial ligand distances. EPR revealed five resonance positions and the simulations gave reasonable zero field splitting parameters.
Misun Lee, Sung Min Shin, Nakcheol Jeong and Praveen K. Thallapally
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01322D, Communication
Chiral metal–organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations.
R. Pazik, Miroslaw Maczka, Malgorzata Malecka, Lukasz Marciniak, Anna Ekner-grzyb, Lucyna Mrówczyńska and Rafael J Wiglusz
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00671F, Paper
SrTiO3 nanoparticles co-doped with a broad concentration range of the Er3+ and Yb3+ ions were fabricated using citric route as a function of annealing temperature at 500-1000oC. Effect of broad...
Matthieu Teci, Eric Brenner, Dominique Matt, Christophe Gourlaouen and Loïc Toupet
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00980D, Paper
Two N-heterocyclic carbene precursors having their nitrogen atoms substituted by the expanded 9-ethyl-9-fluorenyl group, namely imidazolinium chloride 6 and imidazolium chloride 7, have been synthesized in high yields from fluorenone (1).
Jiawei Li, George N. Khairallah, Vincent Steinmetz, Philippe Maitre and Richard A. J. O'Hair
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00942A, Paper
A combination of gas-phase ion trap multistage mass spectrometry (MSn) experiments and density functional theory (DFT) calculations have been used to examine the mechanisms of the sequential decomposition reactions of copper cyanoacetate anions, [(NCCH2CO2)2Cu].
Manfred Scheer, Claudia Heindl, Eugenia V. Presypkina, Aleksandr Viktorovich Virovets and Vladislav Komarov
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01230A, Paper
The potential of K[P3C2R2] (R = tBu, Mes) as building blocks in Metallo-Supramolecular chemistry was investigated and self-assembly processes with Cu(I) halides result in the formation of a large variety...
Miluykov Vasili, Ilya Alexandrovich Bezkishko, Kochetkova Liliya, Olga Kataeva, Tatiana Gerasimova, Sergey Katsyuba, Oleg Geroldovich Sinyashin, Peter Lönnecke, Eva Hey-Hawkins, Anupama Parameswaran, Yulia Krupskaya, Vladislav Kataev and Bernd Buechner
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00624D, Paper
The set of complexes bis-(µ:η1,η1-3,4,5-triaryl-1,2-diphosphacyclopentadienyl)-bis-(tetracarbonyl manganese(I)) (aryl = C6H5 (2a), p-FC6H4 (2b), p-ClC6H4 (2c)) undergo an irreversible rearrangement to mononuclear 3,4,5-triaryl-1,2-diphosphacymantrene (3a-c). According to quantum-chemical calculations binuclear complexes 2 can...
Spyros P Perlepes, Nikolaos C Anastasiadis, Dimitris A Kalofolias, Aggelos Philippidis, Sofia Tzani, Catherine Raptopoulou, Vassilis Psycharis, Constantinos J Milios and Albert Escuer
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01218J, Paper
The use of N-salicylidene-o-aminophenol (H2saph) in 4f-metal chemistry has led to the isolation of seven new isostructural lanthanide(III) [LnIII] complexes. More specifically the Ln(NO3)3∙xH2O/H2saph/Et3N (1:1:1) reaction mixtures in DMF/MeCN gave...
Rik Van Deun, Anna Marta Kaczmarek, Kristof Van Hecke, Isabel Van Driessche and Dorine Ndagsi
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00764J, Paper
In this paper, various microstructures of Ce2(WO4)3 and Ce10W22O81 were prepared by applying a hydrothermal synthesis, in a ligand-free environment, and in the presence of dioctyl sodium sulfosuccinate (DSS) surfactant,...
Jun Jiang, Chunde Wang, Jianwen Liang, Jian Zuo and Qing Yang
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01435B, Paper
Nanorod-FeP@C composites are synthesized via a one-pot solution reaction of ferrocene (Fe(C5H5)2) with excess triphenylphosphine (PPh3) in the sealed vacuum tubes at 390 °C, in which PPh3 is used as...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01134E, Paper
The electron donor−acceptor complexes, which undergo intramolecular charge transfer under external stimulus, are an emerging class of materials showing important application in nonlinear optic. Synthesizing ferrocene/fullerene complexes through face−to−face fusion...
Jun Chen, Qing Zhang, Zhi-Fa Liu, Shuai-Hua Wang, Yu Xiao, Rong Li, Jian-Gang Xu, Ya-Ping Zhao, Fakun Zheng and Guo-Cong Guo
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00929D, Paper
Two new lead(II) coordination polymers, [Pb(NO3)(tzib)]n (1) and [Pb(tzib)2]n (2), were successfully synthesized from the reaction of rigid ligand 1-tetrazole-4-imidazole-benzene (Htzib) and lead(II) nitrate in different solvents. The obtained polymers...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00690B, Communication
The conversion reaction of metal-organic frameworks (MOFs) was adopted as a synthetic method to produce an advanced CO2 absorbent. A Li- and Si-containing MOF is a good precursor for lithium...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00852B, Paper
The synthesis of novel, symmetrical, tetrasubstituted metallophthalocyanines (cobalt, zinc, and manganese) bearing four 2-(4-methyl-1,3-thiazol-5-yl)ethoxy units was reported. The new compounds have been characterized using UV-Vis, IR, 1H NMR, 13C NMR,...

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