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Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00013D, Paper
The reaction of ctc-OsII(pap)2Cl2 (pap=2-phenylazopyridine, ctc= cis-trans-cis with respect to chlorides and pyridine/azo nitrogens of pap, respectively) and ambidentate 2,2/-bipyridine-3,3/-diol (H2L) leads to the simultaneous formation of isomeric [OsII(pap)2(HL)]+ (2+/3+),...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04805B, Paper
A functional Cu(I) boron imidazolate framework (BIF) with ladder-chain structure can not only transfer to another single-chain structure by incorporating 4,4’-bipyridine, but also act as a reducing agent to load...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04306A, Paper
The reaction of Ni(NO3)2·6H2O with di-2-pyridyl ketone, (py)2CO, and the R-phenylcyanamides 4Cl-3CF3-PhHNCN and 4F-3CF3-PhHNCN in CH3OH or CH3CH2OH allows the isolation of the tetranuclear compounds [(Ni4(μ-py2COOCH3)2 (μ3-py2COOH)2(μ-1,1-4Cl-3CF3-PhNCN)2(4Cl-3CF3-PhNCN)2]·CH3OH (1), [(Ni4(μ-py2COOCH2CH3)2(μ3-py2COOH)2(μ1,1-4Cl-3CF3-PhNCN)2(4Cl-3CF3-PhNCN)2]· 2EtOH...
Fainan Failamani, Zahida Malik, Leonid Salamakha, Friedrich Kneidinger, Andriy Grytsiv, Herwig Michor, Ernst Bauer, Gerald Giester and Peter Rogl
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04705F, Paper
Phase relations and crystal structures have been evaluated within the sections LaNi2Si2-LaZn2Si2 and CeNi2Si2-CeZn2Si2 at 800°C using electron microprobe analysis and X-ray powder and single crystal structure analyses. Although the...
Juan Xu, fei teng, Yunxuan Zhao, Yandong Kan, Liming Yang, Yang Yang, Wenqin Yao and Yogfa, Zhu
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04797H, Paper
It is still big challenge to facilely tune the energy bands of semiconductor. Herein, we have mainly investigated energy bands and photochemical properties of Bi6S2O15 and Bi2O(OH)2SO4, which have the...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04970A, Paper
The compound BaZn2Si2O7 shows a highly positive coefficient of thermal expansion. At a temperature of 280 °C, it transforms to a high temperature phase, which exhibits a coefficient of thermal...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00287K, Paper
In the present work, a novel biopolymer approach has been made to electrodeposit manganese dioxide from a manganese sulphate in sulphuric acid bath containing chitosan in the absence and presence...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT05020K, Perspective
Currently, transition-metal substituted polyoxotungstates (TMSPTs) have developed as a fast growing and challengeable subfamily of polyoxoxmetalates (POMs). Before 2005, the number of TM cores in TMSPTs is mostly lower than...
Xiao-Feng Tan, Jian Zhou, Lianshe Fu, Hong-Ping Xiao, Hua-Hong Zou and Qiuling Tang
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00205F, Paper
A series of lanthanide fumarates [Sm2(fum)3(H2fum)(H2O)2] (1, H2fum = fumaric acid), [Ln2(fum)3(H2O)4]•3H2O {Ln = Tb (2a), Dy (2b)} and [Ln2(fum)3(H2O)4] {Ln = Y (3a), Ho (3b), Er (3c), Tm (3d)}...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04740D, Paper
A series of transition metal complexes with the ligands 3-pyrazoledicarboxylic acid (H2L1) and ethyl 1-(2-ethoxy-2-oxoethyl)-1H-pyrazole-3-carboxylate (epzc) have been synthesized. The epzc generated 1-(carboxymethyl)-1H-pyrazole-3-carboxylic acid (H2L2) by the reaction of hydrothermal...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00164E, Paper
Phosphorylation reactions of an iron(II) dichloroclathrochelate FeBd2(Cl2Gm)(BF)2 (where Bd2– and Cl2Gm2– are α-benzildioxime and dichloroglyoxime dianions, respectively) with diphenylphosphine oxide and diethyl thiophosphite were performed under phase–transfer conditions. In the...
Rasika Dias, Naveen V Kulkarni, Animesh Das, Shawn Ridlen, Erin Maxfield, Venkata Adiraju and Muhammed Yousufuddin
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00257A, Paper
Ethyl zinc complexes [N{(C3F7)C(Dipp)N}2]ZnEt, [N{(C3F7)C(Cy)N}2]ZnEt, [N{(CF3)C(2,4,6-Br3C6H2)N}2]ZnEt and [N{(C3F7)C(2,6-Cl2C6H3)N}2]ZnEt have been synthesized from the corresponding 1,3,5-triazapentadiene and diethyl zinc. X-ray data show that [N{(C3F7)C(Dipp)N}2]ZnEt has a distorted trigonal planar geometry at...
Meiyan Cui, Zhangzhen He, Nannan Wang, Ying-Ying Tang, Wenbin Guo, Su-Yun Zhang, Ling Wang and Hongping Xiang
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04745E, Paper
A new vanadate compound NaKV4O9•2H2O is successfully synthesized by a conventional hydrothermal method. This compound crystallizes in the monoclinic system with space group C2/c, showing a typical 2D layered structure...
Mauro Ravera, Elisabetta Gabano, Ilaria Zanellato, Federico Fregonese, Giorgio Pelosi, James A Platts and Domenico Osella
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04905A, Paper
We report studies of a novel series of Pt(IV) complexes exhibiting an asymmetric combination of acetylamido and carboxylato ligands in the axial positions. We demonstrate efficient synthesis of a series...
Zhen Ma, Bian Zhang, M. Fátima C. Guedes da Silva, Joana Silva, Ana Soraia Mendo, Pedro V Baptista, Alexandra Fernandes and Armando J. L. Pombeiro
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT02744F, Paper
Reactions between 4’-phenyl-terpyridine (L) and several Cu(II) salts (p-toluenesulfonate, benzoate and o-, m- or p-hydroxybenzoate) led to the formation of [Cu(p-SO3C6H4CH3)L(H2O)2](p-SO3C6H4CH3) (1), [Cu(OCOPh)2L] (2), [Cu(o-OCOC6H4OH)2L] (3), [Cu(m-OCOC6H4OH)2L]•MeOH (4•MeOH) and [Cu(p-OCOC6H4OH)2L]•2H2O...
Ana Christina L. Opina, Madeleine Strickland, Yong-Sok Lee, Nico Tjandra, R. Andrew Byrd, Rolf E. Swenson and Olga Vasalatiy
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03210E, Paper
RP-HPLC and NMR studies showed that early lanthanides of SSSS-SSSS-M4DOTMA unprecedentedly favor the SAP conformation, while late lanthanides adopt TSAP.
Y. Maximilian Klein, Markus Willgert, Alessandro Prescimone, Edwin C. Constable and Catherine E. Housecroft
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00166A, Paper
Phosphonic acid-functionalized bpy ligands with 2-thienyl spacers are effective anchors in [Cu(Lanchor)(Lancillary)]+ dyes; DSC performance depends on the position of substitution of the PO(OH)2 group.
Stéphanie Lesturgez, Graziella Goglio, François Weill, Olivier N'Guyen, Olivier Toulemonde, Etienne Durand, Julien Hernandez and Alain Demourgues
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT02761F, Paper
Al3+ substitution for Mn4+/Mn3+ into the Ca0.66Mn2O4 1D tunnel network leads to the stabilization of an orthorhombic unit cell (SG: Pnma) with two different Mn sites attributed mainly to Mn4+ and Mn3+ respectively.
Bradley S. Stadelman, Martin M. Kimani, Craig A. Bayse, Colin D. McMillen and Julia L. Brumaghim
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03384E, Paper
Characterization of Fe(II)–thone and –selone complexes revealed that these ligands oxidize before Fe(II), suggesting an iron-binding mechanism for similar antioxidants.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04983K, Communication
Reactions of [Cp*(OC)3M]Li (Cp* = C5Me5, M = Mo, W) towards t-Bu2P–PCl2 lead to the formation of phosphanylphosphinidene dimers [Cp*(OC)3M(η2-t-Bu2P–P)]2 in fairly good yields.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00031B, Paper
A new family of hexanuclear titanium(IV)-oxo-carboxylate cluster containing a {Ti6O9} core exhibiting remarkable potential as a visible-light homogeneous photocatalyst.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT02678D, Paper
The rational design and synthesis of triarylborane-A2H2 (1) and triarylborane-Zn-A2H2 porphyrins (2) have been reported. Compounds 1 and 2 showed multiple emission bands upon excitation at the triarylborane dominated absorption region (350 nm). The detailed optical and computational studies showed that the multiple emission features of 1 and 2 are because of a partial energy transfer from the donor (triarylborane) to the acceptor (porphyrin).
Aliza G. Furneaux, nicholas piro, Raul Hernandez Sanchez, Kathryn M Gramigna, Natalie Fey, Michael J Robinson, William S. Kassel and Chip Nataro
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04721H, Paper
While the redox active backbone of bis(phosphino)ferrocene ligands is often cited as an important feature of these ligands in catalytic studies, the structural parameters of oxidized bis(phosphino)ferrocene ligands have not...
Hongwei Hou, Yue Tong, Xiao Han, Chao Huang, Chao Zhi Shao, Li’an Guo, Yazhen Wang and Jie Ding
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00067C, Communication
Several new isostructural lanthanide metal–organic frameworks {[Ln3(L)4(OH)(H2O)2]·DMAC}n (Ln = Tb (1), Gd (2), Eu (3), Gd0.81Tb0.10Eu0.09 (4) and Gd0.75Tb0.18Eu0.07 (5)) were designed and prepared. Excitingly, samples 1, 3, 4 and...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT01983D, Paper
Ultra-thin nanosheets (2-6 nm) of the (Y1-xEux)2(OH)5NO3•nH2O layered rare-earth hydroxide (LRH), directly crystallized without exfoliation, were employed for the first time as a sacrificial precursor to synthesize (Y1-xEux)PO4 orthophosphate red...

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