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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.177 48 Issues per Year Indexed in Medline
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Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02670B, Paper
A novel intercluster compound, [{(Au{P(p-ClPh)3})2(μ-OH)}2]3[α-PMo12O40]2·3EtOH (1-PMo12), was obtained as orange-yellow plate crystals in 12.0% yield from a 6:1 molar ratio reaction of the monomeric phosphanegold(I) carboxylato complex [Au(RS-pyrrld){P(p-ClPh)3}] (RS-Hpyrrld =...
Aliona Dobrova, Sonja Platzer, Felix Bacher, Miljan N.M. Milunovic, Anatolie Dobrov, Gabriella Spengler, Eva Anna Enyedy, Ghénadie Novitchi and Vladimir Arion
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02784A, Paper
Two water-soluble thiosemicarbazone-proline (H2L1) and thiosemicarbazone-homoproline hybrids (H2L2) were synthesised. By reaction of H2L1 with NiCl2∙6H2O, PdCl2 and CuCl2∙2H2O, in ethanol the series of square-planar complexes [Ni(H2L1)Cl]Cl∙1.3H2O (1∙1.3H2O), [Pd(H2L1)Cl]Cl∙H2O (2∙H2O)...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02718K, Paper
Chelating bis-N-heterocyclic carbene (bis-NHC) complexes of iron(II) containing pyridyl ligands have been prepared by the reaction of [FeCl2L] [L = bipy (1), phen (2)] with [LiN(SiMe3)2] and a bis(imidazolium) salt....
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02393B, Communication
An edge-directed strategy was adopted to construct highly ordered polyhedral structures using flexible functions. Half-sandwich M6(L1)4 octahedral and M8(L2)4 cubic cages have been assembled using flexible Schiff-base ligands upon coordination...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02531E, Paper
Charge recombination occurring at the TiO2/QDs/electrolyte interface is a crucial factor that limits the power conversion efficiency (η) of quantum dot-sensitized solar cells (QDSSCs). This paper presents a new approach...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02195F, Paper
Two new coordination polymers were synthesized solvothermally using 4,4’-dimethoxy-3,3’-biphenyldicarboxylic acid (H2dmbpdc), and di- and trivalent metal salts (Cu(NO3)2∙2.5H2O and La(NO3)3∙6H2O). Their structures were determined by single-crystal X-ray diffraction analysis, and...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02763F, Paper
We applied a test set of ligand dissociation enthalpies derived entirely from a unified experimental approach to evaluate the efficacy of various methods for modeling organometallic chemistry. This differs from...
Jingjing Jiao, Li Dou, Huimin Liu, Fengli Chen, Dongjie Bai, YunLong Feng, Shunshun Xiong, De-Li Chen and Yabing He
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02150F, Paper
There has been considerable interest in adsorptive separation of C2H2/CH4 and CO2/CH4 gas mixtures due to its industrial significance and scientific challenge. In this work, we designed and synthesized a...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02068B, Paper
Reaction of the non dried monobenzylated [tBuC5(OBn)(OH)4] ligand with excess of Bi[N(SiMe3)2]3, yields a mixture of the dimeric complex 1 [Bi{tBuC5(OBn)(OH)}]2 in 12% yield and complex 2 [Bi10O8{tBuC5(OBn)(OH)}4] in 48%....
Lei Yu, Guilong Wang, Gengping Wan, Guizhen Wang, Shiwei Lin, Xinyue Li, Kan Wang, Zhiming Bai and Yang Xiang
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01927G, Paper
In this work, we report an atomic layer deposition (ALD) method to fabricate NiO/CNT hybrid structures in order to improve electronic conductivity, enhance cycling stability and increase rate capability of...
Rubel Chakravarty, Sudipta Chakraborty, Rakesh R Shukla, Jitendra Bahadur, Ramu Ram, S Mazumder, Haladhar Deb Sarma, A. K. Tyagi and Ashutosh Dash
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01921H, Paper
The present article reports the synthesis and characterization of mesoporous tin oxide (MTO) nanoparticles following a solid-state mechanochemical route. The synthesized material was used as an advanced sorbent material for...
Sasikarn Hanprasit, Nuttanee Tungkijanansin, Arisa Prompawilai, Supattra Eangpayung and Vuthichai Ervithayasuporn
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02585D, Communication
The nucleophilicity of both ortho- and meta-nitrophenolate anions is strong enough to give substituted products, but their basicity also facilitates cage-rearrangement reactions in polyhedral oligomeric silsesquioxanes (POSS). Anions having stronger...
Florence Isnard, Marina Lamberti, Luana Lettieri, Ilaria D'auria, Konstantin Press, Rubina Troiano and Mina Mazzeo
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02592G, Paper
Three dinuclear aluminum alkyl complexes of general formula LAl2Me4, where L are salen ligands with alkyl backbone of different length between the nitrogen atoms (1,3-propylene (1), 1,5-pentylene (2) and 1,12-dodecaylene...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01928E, Communication
Polyfluorooxometalates with a nitro ligands, Q9[NaH2CuII(NO2)W17F6O55], are oxygen donors for epoxidation of alkenes and catalytic with O2 as terminal oxidant.
Ramalingam Thirumoorthi, Tristram Chivers, Susanna Häggman, Akseli Mansikkamäki, Ian S. Morgan, Heikki M. Tuononen, Manu Lahtinen and Jari Konu
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02565J, Paper
Structural isomerism: formation of a labile tridentate sulfur-ligand led to the isolation of the first examples of Oh and SP Ni(II) isomers of the same ligand in [Ni{S(H)C(PPh2S)2}2] and their fluxional behaviour is examined.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02320G, Paper
Two new monosubstituted polyoxometalates, with pyridine as a conjugated solvent molecule bound to polyanions, are developed, which give strong third-order NLO responses.
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01860B, Perspective
Compared to other hybrid metal organic materials such as metal-organic frameworks, hydrogen bonded materials self-assembled by metals and organic molecules using second sphere interactions have been poorly investigated. Consequently, their...
Nick A. Giffin, Arthur D. Hendsbee and Jason D. Masuda
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02790C, Communication
The persistent phosphinyl radical, (H2C)2(NDipp)2P˙, formed from the diphosphane [(H2C)2(NDipp)2P]2, was reacted with three heteroallenes.
Dieter Sorsche, Markus Schaub, Frank Heinemann, Johannes Habermehl, Susanne Kuhri, Dirk M. Guldi, Julien Guthmuller and Sven Rau
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01643J, Paper
The synthesis and characterization of a mixed metal ruthenium(II)/gold(III) complex bridged by tetrapyridophenazine (tpphz) are described. It is isostructural and isoelectronic to the well-known photocatalysts with palladium(II) or platinum(II). Concentration...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01704E, Communication
A new cobalt(II) complex reacts with N2O under mild conditions and it catalytically performs the oxidation of aldehydes.
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02349E, Paper
A growing number of halogenated organic compounds have been identified as hazardous pollutants. Although numerous advanced oxidative processes have been developed to degrade organohalide compounds, reductive and nucleophilic molecular approaches...
Mauro Carraro, Martino Gardan, Andrea Sartorel, Chiara Maccato and Marcella Bonchio
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01951J, Communication
Fluorophilic polyoxotungstates perform the selective epoxidations of internal and terminal double bonds by hydrogen peroxide (H2O2) activation in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), under mild temperature conditions. A hybrid synergy of supramolecular interactions,...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02460B, Paper
A Cp*Rh-based nonanucleartriangular macrocycle complex [(Cp*Rh)9L3(NO3)4.5(MeOH)](OTf)4.5(1), two Cp*Ir-based trinuclear complex [(Cp*Ir)3L(MeCN)4](OTf)3(2) and a linear heptanuclear heterometallic complex [(Cp*Ir)6ZnL2(MeCN)8 (MeOH)2](OTf)8 (3) (Cp*=5-pentamethylcyclopentadienyl) have been synthesized from 2-(4-(pyridin-4-yl)phenyl)-1H-imidazole-4,5-dicarboxylic acid proligands. These complexes...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02588A, Paper
The impact of the structural attributes of chiral PC- and PCP-palladium catalysts were investigated in the asymmetric hydrophosphination of various heterocycle-functionalized enone substrates. Due to the architecture of the catalysts,...
Mingxuan Sun, Yalin Fang, Yuanyuan Kong, Shanfu Sun, Zhishui Yu and Ahmad Umar
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02071B, Paper
In situ growth of g-C3N4 on the surface of TiO2 nanotube arrays (g-C3N4/TiO2) was achieved via the vapor-pyrolysis of melamine and a better photo-electrochemical performance was demonstrated.

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95 citations
Porphyrin sensitizers have exhibited power conversion efficiencies that are comparable to or even higher than those of well-established highly efficient DSSCs based on ruthenium complexes.
DOI: 10.1039/C4DT02756F
Published: 10 Nov 2014
38 citations
Ultrasonic power was investigated as a dispersion and mixing tool to accelerate the adsorption of SO, MB, Pb2+ ions and Cr3+ ions onto the novel Fe3O4-NPs-AC composite.
DOI: 10.1039/C5DT01504A
Published: 13 Jul 2015
42 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015

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