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Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
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Erwin G Abucayon, Rahul L Khade, Douglas Powell, Michael J Shaw, Yong Zhang and G B Richter-Addo
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03860C, Paper
Hydride attack at a ferric heme-NO to give a Fe–HNO intermediate is a key step in the global N-cycle. We demonstrate differential reactivity when 6- and 5-coordinate ferric heme-NO models...
Thorfinnur Gunnlaugsson, Bjørn la Cour Poulsen, Sandra Estalayo-Adrián, Salvador Blasco, Sandra Bright, John Moffat Kelly and D. Clive Williams
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03792E, Paper
Four new Ru(II) polypyridyl complexes that contain an extended aromatic moiety derived from pyrazino[2,3-h]dipyrido[3,2-a:2’,3’-c]phenazine and either 1,10-phenanthroline (phen) or 1,4,5,8-tetraazaphenanthrene (TAP) have been synthesized, their solid state X-ray crystal structuree...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03502G, Paper
Three new ruthenium(II) complexes of NCN pincer and phenylcyanamide derivative ligands of formula [Ru(L)(Ph2phen)(3,5-(NO2)2pcyd)], 1, [Ru(L)(Me2phen)(3,5-(NO2)2pcyd)], 2, [Ru(L)(Cl2phen)(3,5-(NO2)2pcyd)], 3 (HL: 5-methoxy-1,3-bis (1-methyl-1H-benzo[d]imidazol-2-yl)benzene, 3,5-(NO2)2pcyd: 3,5-(NO2)2pcyd, Ph2phen: 4,7-diphenyl-1,10-phenanthroline, Me2phen: 4,7-dimethyl-1,10-phenanthroline, Cl2phen: 4,7-dichloro-1,10-phenanthroline)...
Peng Tong, Wenjie Xie, Dawei Yang, Baomin Wang, Xiaoxiao Ji, Jianzhe Li and Jingping Qu
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03275C, Paper
Using an assembly method, dinuclear CoCo and CoFe complexes supported by a bdt ligand, [Cp*Co(μ-η2:η2-bdt)(μ-I)CoCp*][PF6] (1[PF6], Cp* = η5-C5Me5, bdt = benzene-1,2-dithiolate), and [Cp*Co(μ-η2:η4-bdt)FeCp'][PF6] (3[PF6], Cp' = η5-C5Me4H) were synthesized...
xiaojuan Wang, Ting He, Lan Yang, Huiqiong Wu, Jiafu Yin, Rujuan Shen, Juan Xiang, Yi Zhang and Chuan-Wan Wei
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03828J, Communication
Two novel multi-responsive metallohydrogels, namely, 2–PF–Ni and 3–PF–Ni, were successfully constructed from phenylalanine derivatives. The 2–PF gelator shows specific responses to Ni2+; particularly, 2–PF–Ni is lavender, which has been rarely...
Nicolas Großmann, Andrea Magri, Martin Laux, Benjamin Stadtmüller, Philip Thielen, Bernhard Schaefer, olaf fuhr, Mario Ruben, Mirko Cinchetti and Martin Aeschlimann
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03183H, Paper
Recently, research has revealed that molecules can be used to steer the local spin properties of ferromagnetic surfaces. One possibility to manipulate ferromagnetic-metal -molecule interfaces in a controlled way is...
Jean-Marie E. P. Cols, Cameron E. Taylor, Kevin J. Gagnon, Simon J. Teat and Ruaraidh D. McIntosh
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03842E, Paper
The synthesis and full characterisation of four discrete tetrametallic titanium complexes is reported.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03271K, Communication
Carbonyl groups (C[double bond, length as m-dash]O) have been newly introduced as sole bridging groups in the field of energetic materials. Moreover, the biomimetic synthesis and energetic organic catalyst were used to synthesize new energetic compounds.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03104H, Paper
The influence of stabilizers on the catalytic performance of small rhodium nanoparticles was studied through a model hydrogenation reaction.
Shan Wang, Changmin Hou, Long Yuan, Mingyang Qu, Bo Zou and Dayong Lu
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02661C, Communication
Monodispersed samples of perovskite structures, DyCrO3 and HoCrO3, were prepared by a mild hydrothermal method. These two samples show a weak antiferromagnetism to paramagnetism transition at ca. 100 K, which is much lower than that of samples prepared by a solid state method.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03721F, Paper
Copper(I) 5-phenylpyrimidine-2-thiolate complexes exhibit intriguing luminescence properties and excellent visible light-directed catalytic activity towards aerobic oxidative hydroxylation of arylboronic acids.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03449G, Paper
Novel CoTiO3/g-C3N4 heterostructures with improved photocatalytic activity were successfully synthesized by a facile in situ growth route with the flux-grown CoTiO3 polyhedral crystals serving as an efficient visible-light sensitizer.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02995G, Paper
Ionic iron(II) complexes, [HL][Fe(PR3)X3], showed high catalytic activities in alkyl Grignard cross-coupling of aryl phosphates, and the corresponding reductive cross-coupling.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03073D, Paper
Peripheral substituents on click-derived tripodal ligands dictate the reactivity of their copper(II) azido complexes.
Christina Wegeberg, Christian Grundahl Frankær and Christine J. McKenzie
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02937J, Paper
Iodine L3-edge XANES spectra using reference compounds with formal iodine oxidation states spanning −1 to +7 show that iodine in an Fe(III) coordinated iodosylbenzene (PhIO) is reduced compared to parent hypervalent PhIO which has been structurally characterized.
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03817D, Paper
Five examples of selectively fluorinated unsymmetrical diiminoacenaphthylenes, 1-[2,6-{(4-FC6H4)2CH}2-4-FC6H4N]-2-(ArN) C2C10H6 (Ar = 2,6-Me2C6H3 L1, 2,6-Et2C6H3 L2, 2,6-iPr2C6H3 L3, 2,4,6-Me3C6H2 L4, 2,6-Et2-4-MeC6H2 L5), have been synthesized and used to prepare their corresponding...
James LaFortune, Tim Johnstone, Manuel Perez, Daniel Winkelhaus, Vitali Podgorny and Douglas W Stephan
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03544B, Paper
A family of electrophilic phenoxy-substituted phosphonium salts [(C6H(5-x)FxO)P(C6F5)3][B(C6F5)4] (x = 0-2, 5) have been synthesized and their air stability was evaluated. Computations of the fluoride ion affinity and global electrophilicity...
G. W. Peterson, M. McEntee, C. R. Harris, A. D. Klevitch, A. W. Fountain, J. R. Soliz, A. Balboa and A. J. Hauser
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03504C, Communication
Electrical impedance spectroscopy, in conjunction with the metal–organic framework (MOF) UiO-66-NH2, is used to detect trace levels of the explosive simulant 2,6-dinitrotoluene.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03678C, Communication
The unprecedented highly porous and stable rare earth cluster based metal–porphyrinic frameworks can be used as efficient catalysts for N–H carbene insertion.
Qi Wu, Hongming Liu, Lei Kang, Zheshuai Lin, Xianggao Meng, Xingguo Chen and Jingui Qin
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02608G, Paper
The synthesis, crystal structure and properties of Rb2SeOCl4·H2O, the first polar material among the A–Se–O–X systems (A = alkali metal or alkali-earth metal), is presented. It shows a powder SHG response of 8 times that of KDP.
Janusz Lewinski, Małgorzata Wolska, Adam Świerkosz, Iwona Justyniak, Agnieszka Grala and Kamil Sokolowski
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03324E, Communication
Equimolar reactions between ZntBu2 and diphenyl phosphate (dpphe-H) or dimethyl phosphate (dmphe-H) result in the formation of [tBuZn(O2P(OR’)2)]-type compounds which crystalize as tetranuclear aggregates, [tBuZn(dpphe)]4 (14) or [tBuZn(dmphe)]4 (24), with...
Yong Yan, Jun Chen, Ning-Ning Zhang, Ming-Sheng Wang, Cai Sun, Xiu-Shuang Xing, Rong Li, Jian-Gang Xu, Fa-Kun Zheng and Guo-Cong Guo
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03794A, Communication
In this work, we reported a new mechanoresponsive luminescent Cd(II) coordination polymer which exhibits sensitivity to mechanical stimulation. The luminescence color changed gradually from weak yellowish-green to bright cyan response...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03602C, Paper
The synthesis, structures and semiconducting properties of three isostructural, piperazinium-cation based iodobismuthates, [NH2(CH2)4NH2][BiI4]2.4H2O, [CH3NH(CH2)4NH2][BiI4]2.3H2O and [CH3NH(CH2)4HNCH3][BiI4]2.2H2O, are reported. The materials have pseudo-three dimensional structures consisting of infinite chains formed from...
Rong-Jia Wei, Ryohei Nakahara, Jamie M. Cameron, Graham N. Newton, Takuya Shiga, Hajime Sagayama, Reiji Kumai, Youichi Murakami and Hiroki Oshio
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT03416K, Communication
A cyanide-bridged trigonal bipyramidal [Co3Fe2] cluster shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition behaviour.
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03409H, Perspective
The coordination chemistry of neutral thio-, seleno- and telluroether ligands towards the hard s-block, f-block and higher oxidation state early d-block metals has developed significantly over the 15 or so...

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120 citations
Porphyrin sensitizers have exhibited power conversion efficiencies that are comparable to or even higher than those of well-established highly efficient DSSCs based on ruthenium complexes.
DOI: 10.1039/C4DT02756F
Published: 10 Nov 2014
11 citations
The emerging new solid-state LED phosphors and the methodologies for their development have been reviewed in this perspective.
DOI: 10.1039/C6DT01230B
Published: 30 May 2016
56 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015

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