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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.097 48 Issues per Year Indexed in Medline
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Samantha M. McNeill, Dan Preston, James E. M. Lewis, Anja Robert, Katrin Knerr-Rupp, Danyon O. Graham, James R. Wright, Gregory I. Giles and James D. Crowley
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01259G, Paper
A quadruply-stranded dipalladium(II) helicate exhibits low micromolar IC50 values against a range of different cancer cell lines. Preliminary mechanistic studies indicate that the helicate induces cell death by disrupting the cell membrane.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01343G, Communication
Bond ionicity, lattice energy, and coefficient of thermal expansion were calculated using a semiempirical method.
Xiaotian Qi, Yingzi Li, Guanghui Zhang, Yang Li, Aiwen Lei, Chao Liu and Yu Lan
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01366F, Paper
A combined experimental and DFT study was conducted to reveal the difference between dinuclear and mononuclear zinc mediated nucleophilic addition.
Sergio Pedrosa, Fernando Vidal, Lucia Myongwon Lee, Ignacio Vargas-Baca, Pilar Gómez-Sal and Marta E. G. Mosquera
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01320H, Paper
Controlled generation of novel bridging or terminal imido-pyridine complexes is achieved, including the unusual species [Li(THF)][Ti(η5-C5Me5)(NR)(NHR)2]. Computational studies corroborate its charge-separated nature.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01190F, Paper
GO/CPNB was fabricated successfully, which displays excellent photocatalytic activity in visible light. Furthermore, the influence of GO on photocatalytic activity is discussed.
Dongguang Yin, Xianzhang Cao, Lu Zhang, Jingxiu Tang, Wenfeng Huang, Yanlin Han and Minghong Wu
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01059D, Paper
Upconversion nanocrystals have a lot of advantages over other fluorescent materials.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00420A, Paper
The significant influence of the synthetic approach and halogen substituent on Zn(II) coordination assemblies with 5-halonicotinic acids has been demonstrated.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01681A, Communication
Quantum dot sensitized photoactive CORMs show a 2 to 6-fold increase of the photodecomposition rate upon irradiation with visible light.
Zsolt Baranyai, Dominik Reich, Adrienn Vágner, Martina Weineisen, Imre Tóth, Hans-Jürgen Wester and Johannes Notni
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00576K, Paper
The kinetic inertness profile of Cu(II) complexes of TRAP-conjugates enables simple Cu(II) removal after click functionalisation and confirms their suitability for Cu-64-PET.
Juliane Schott, Jerome Kretzschmar, Satoru Tsushima, Björn Drobot, Margret Acker, Astrid Barkleit, Steffen Taut, Vinzenz Brendler and Thorsten Stumpf
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00213C, Paper
A combination of different spectroscopy techniques, DFT calculations and advanced data analysis explained the Eu(III)–organoborate complexation.
Ming-Hsun Ho, Molly O'Hagan, Michel Dupuis, Daniel L. DuBois, R. Morris Bullock, Wendy J. Shaw and Simone Raugei
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00782H, Paper
Water is found to accelerate proton delivery and removal in electrocatalysts for H2 production, resulting in a marked increase in the catalytic rates. The significant reduction in protonation/deprotonation barriers observed in the presence of water has important implications for design catalysts with improved performance.
W Levason, Gillian Reid, Jennifer Burt and William Grantham
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01448D, Paper
Rare examples of phosphine complexes of lead(II) are reported. The reaction of Pb(NO3)2 with Me2P(CH2)2PMe2, o-C6H4(PMe2)2 or Et2P(CH2)2PEt2 (LL) in H2O/MeCN gave white [Pb(LL)(NO3)2], irrespective of the ratio of reagents...
youyi xia, xiang deng, Shuxin Yan, chang Gao, cong Ma and ling Jin
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01659B, Paper
Nanoporous gold (NPG) is attractive due to highly catalytic activity. From an applied and economical point of view, fabricating thin NPG film is recognized to be an ideal approach. Herein,...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01850A, Paper
TiO2/SnOx-Au ternary heterostructures were successfully fabricated via a simple in situ reduction of AuCl4- on TiO2 surface pre-modified with Sn2+. The samples were characterized by XRD, TEM, XPS, N2 physical...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01333J, Paper
We first report an efficient soft-templating strategy for the synthesis of mesoporous ZnAl2O4 by using supramolecular assembly of lauric acid (surfactant) as a template under alkaline pH conditions. 50:50 (V/V)...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01012H, Paper
Chitosan coated magnetic nanoparticles were synthesized and used as support for the immobilization of cobalt(II) acetylacetonate complex [Co(acac)2] and quaternary triphenylphosphonium iodide [P+Ph3Br-] targeting -NH2 and -OH moieties located on...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01102G, Paper
Oxamidato-bridged Re(I)-based hexanuclear trigonal prisms with ester functionality have been synthesised via a multicomponent self-assembly process under solvothermal conditions. Self-assembly of Re2(CO)10, oxamide ligands (H2L1 = N,N'-dibutyloxamide, H2L2 = N,N'-dioctyloxamide,...
Nadia Marino, Donatella Armentano, Giovanni De Munno, Francesc Lloret, Joan Cano and Miguel Julve
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00553A, Paper
The honeycomb mixed-ligand complex {[Co2(bpm)(ox)2]n·5nH2O} was prepared and magneto-structurally characterized. The values of the antiferromagnetic interactions through bpm (Jbpm = −5.0 cm−1) and ox (Jox = −11.1 cm−1) ligands obtained by fit were suported by DFT type calculations.
José M. López-de-Luzuriaga, Elena Manso, Miguel Monge, M. Elena Olmos, María Rodríguez-Castillo and Diego Sampedro
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00584A, Paper
Coordination of 4-(dimethylamino)pyridine to perhalophenyl gold(I) fragments leads to the formation of novel fluorescent complexes, in which the photophysical properties of the ligand are greatly influenced by the polarity induced by the organometallic fragment.
J. Paul Attfield, Phil Lightfoot and Russell E. Morris
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT90083B, Editorial
Welcome to this themed issue of Dalton Transactions focusing on perovskites.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00743G, Paper
We describe the structural and variable temperature magnetic susceptibility properties of an unusual homoleptic bimetallic iron(III) thiocyanate tetraanion.
Fanny Bonnet, Hellen E. Dyer, Yassine El Kinani, Carin Dietz, Pascal Roussel, Marc Bria, Marc Visseaux, Philippe Zinck and Philip Mountford
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00252D, Paper
New bis(phenolate)amine-supported neodymium borohydride complexes and their previously reported samarium analogues were tested as catalysts for the polymerisation of styrene and isoprene.
Jorge L. Cholula-Díaz, Gerald Wagner, Dirk Friedrich, Oliver Oeckler and Harald Krautscheid
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00419E, Paper
HRTEM images and SAED patterns reveal the orthorhombic domain structure of CuInS2 nanoparticles.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00816F, Communication
The potentially N4O4-octadentate ligand unprecedentedly coordinates to the Tb3+ ion in a N4O3-heptadentate fashion and provides a highly luminescent and highly oxygen-sensitive terbium(III) complex.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01206F, Paper
Controlled in situ nucleophilic addition reaction results in two Cu(II) mixed-ligand coordination polymers, and the one-step nucleophilic addition for in situ reaction is proposed.

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