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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Maria Luísa Ramos, Licinia L. G. Justino, Paulo Eduardo Martins de Castro Nev Abreu, Sofia M Fonseca and H D Burrows
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03473F, Paper
Multinuclear (1H, 13C, 95Mo and 183W) NMR spectroscopy, combined with DFT calculations, provides detailed information on the complexation between the Mo(VI) and W(VI) oxoions and 8-hydroxyquinoline-5-sulfonate (8-HQS) in aqueous solution....
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03138A, Communication
The aqueous reaction dynamics of the manganese(II)-functionalised Wells-Dawson polyoxometalate [Mn4(H2O)2(P2W15O56)2]^16- has been determined as a function of pH using variable temperature 17O NMR, and compared with that of the well-studied...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03065J, Paper
The three deeply blue emitting Cu(I) compounds [Cu(PPh3)tpym]PF6, [Cu(PPh3)tpym]BF4, and [Cu(PPh3)tpym]BPh4 (tpym = tris(2-pyridyl)methane, PPh3 = triphenylphosphine) featuring the tripodally coordinating tpym and the monodentate PPh3 ligand were studied with...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03134F, Paper
A comparative study to investigate the effects of metal substitution on the photocatalytic activity of metal oxide cluster anions is presented. The study shows the change in the photochemical properties...
Debasis Das, Prateeti Chakraborty, Jaydeep Adhikary, Sugata Samanta, Ishani Majumder, Chiara Massera, Daniel Escudero, Sanjib Ghosh, Antonio Bauza and Antonio Frontera
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02768C, Paper
Three dinuclear zinc(II) complexes with “end-off” compartmental ligands, namely 2,6-bis(N-ethylmorpholine-iminomethyl)-4-R-phenol (R=-CH3, Cl, tBu) have been synthesized with the aim of exploring the role of the para substituent present in ligand...
Gyandshwar Kumar Rao, Serge Gorelsky, Ilia Korobkov and Darrin Richeson
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03515E, Paper
A series of monovalent group 11 complexes, [2,6-{Ph2PNMe}2(NC5H3)]CuBr 1, [2,6-{Ph2PNMe}2(NC5H3)]CuOTf 2, [2,6-{Ph2PNMe}2(NC5H3)]AgOTf 3, and [2,6-{Ph2PNMe}2(NC5H3)](AuCl)2 4, supported by a neutral PN3P ligand have been synthesized and characterized by multinuclear NMR...
jianqiang liu, X. F. Li, C. Y. Gu, Júlio C.S. da Silva, Amanda L. Barros, Severino Alves Júnior, B. H. Li, Fei Ren, Stuart R. Batten and Thereza A. Soares
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02171E, Paper
Three novel metal organic frameworks (MOFs) with chemical formulae {(NH2(CH3)2[(Sm3(L1)2(HCOO)2(DMF)2(H2O)]·2DMF·18H2O}n (1), {[(Cu2(L2)(H2O)2]·1.5DMF}n (2) and {[(Zn2(L1)(DMA)]·1.75DMA}n (3) (H4L1 =2,6-di(3’,5’-dicarboxylphenyl)pyridine, H4L2 =2,5-di(3’,5’-dicarboxylphenyl)pyridine) were synthesized and structurally characterized. 1 and 2 show classical...
Franz A. Mautner, Christian Berger, Michael Scherzer, Roland C. Fischer, Lindley Maxwell, Eliseo Ruiz and Ramon Vicente
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03034J, Paper
Three new 1D azido-bridged manganese(II) complexes with general formula [Mn(N3)2(L)2] and different topologies are reported. Their magnetic properties have been studied.
Tania Lozano-Cruz, Paula Ortega, Belen Batanero, Jose Luis Copa-Patiño, Juan Soliveri, Javier de la Mata and Rafael Gomez Ramirez
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02230D, Paper
A series of novel water-soluble ammonium-terminated carbosilane dendrons containing a ferrocene unit at the focal point were synthesized. The synthetic route is based on the initial amination of ferrocenecarboxaldehyde with...
Deirdra A. Evers, Mark W. Bezpalko, Bruce M Foxman and Christine M. Thomas
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03549J, Paper
A chelating diphosphine ligand with a central N-heterocyclic phosphenium cation (NHP+) has been used to explore the coordination chemistry of NHPs with nickel. Treatment of the chlorophosphine precursor [PPP]Cl (1)...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03696H, Communication
Ultrathin CoMn2O4 nanosheets supported on reduced graphene oxide (rGO) are successfully synthesized through a simple co-precipitation method with a post-annealing treatment. With the assistance of citrate, the free-standing CoMn2O4 ultrathin...
Nidhu Banik, Valerie Vallet, Florent Réal, Réda Mohamed Belmecheri, Bernd Schimmelpfennig, Joerg Rothe, Remi Marsac, Patric Lindqvist-Reis, Clemens Walther, Melissa Anne Denecke and Christian M. Marquardt
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03560K, Communication
A century after its discovery, the structure of the Pa4+ ion in acidic aqueous solution has been investigated for the first time experimentally and by quantum chemistry. The combined results...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03699B, Perspective
Based on the bottom-up chemistry techniques, the size, shape, and composition controlled synthesis of nanoparticles can now be achieved uniformly, which are of great importance to the nanoscience community as...
Derek M Peloquin, Domelia R Dewitt, Shreya S Patel, Jon W Merkert, Bernadette Donovan-Merkert and Thomas Andrew Schmedake
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03548A, Communication
Tris(bipyridyl)silicon(IV) was electrochemically reduced in acetonitrile to obtain the UV-vis spectra of its reduced species. Three stable, reversible reduced states (3+, 2+, and 1+) were observed with distinct isosbestic points...
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02972D, Communication
Site-specific substitution of Nb for W in an α-Keggin polyoxometalate leads to the formation of [Ag42(CO3){C[triple bond, length as m-dash]CC(CH3)3}27(α-A-SiW9Nb3O40)2], where corner-shared triads of NbO6 octahedra bind to the Ag42 cluster moiety.
Ines E. Collings, Joshua A Hill, Andrew B Cairns, Richard I Cooper, Amber L Thompson, Julia E Parker, Chiu Tang and Andrew Goodwin
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03263F, Paper
The compositional dependence of thermal expansion behaviour in 19 different perovskite-like metal–organic frameworks (MOFs) of composition [AI][MII(HCOO)3] (A = alkylammonium cation; M = octahedrally-coordinated divalent metal) is studied using variable-temperature...
Giovanni Massasso, Maria Rodriguez-Castillo, Jérôme Long, Julien Haines, Sabine Devautour-Vinot, Guillaume Maurin, Agnès Grandjean, Barbara Onida, Bruno Donnadieu, Joulia Larionova, christian guerin and Yannick Guari
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02907D, Paper
A series of thermally stable Hofmann-type clathrate structures with the general formula M(pz)[M’(CN)4], where M and M’ are bivalent metal ions MII = NiII, CoII, MII’ = NiII, PdII, PtII,...
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03249K, Paper
Spin-crossover, governed by conformational changes of nitrile molecule, triggers corrugation of polymeric skeleton and formation of superstructure in [Fe(hbtz)2(allyl cyanide)2](ClO4)2.
Gavin A. Craig, Christopher H. Woodall, Scott C. McKellar, Michael R. Probert, Konstantin V. Kamenev, Stephen A. Moggach, Euan K. Brechin, Simon Parsons and Mark Murrie
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03320A, Communication
The crystal structure and magnetic properties of the compound Na5[Mn(L-tart)2]·12H2O (1, L-tart = L-tartrate) have been investigated over the pressure range 0.34–3.49 GPa. 1 retains its magnetic anisotropy even under pressure.
Maxim A. Zakharov, Gennady V. Fetisov, Alexei A. Veligzhanin, Michael A. Bykov, Ksenia A. Paseshnichenko, Sergei F. Dunaev and Leonid A. Aslanov
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02941D, Paper
Ionic liquids (IL) and low-transition-temperature mixtures (LTTM) based on amine alcohol were prepared and solitonic proton charge transfer proposed to occur in LTTM.
Ruichan Lv, Chongna Zhong, Arif Gulzar, Shili Gai, Fei He, Rui Gu, Shenghuan Zhang, Guixin Yang and Piaoping Yang
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03604F, Paper
MgSiO3:Eu-DOX-DPP-RGD hollow microspheres employed for simultaneous imaging and anti-cancer therapy have been designed by sequentially loading DOX, DPP, and a targeted peptide of RGD on MgSiO3:Eu hollow spheres.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02886H, Paper
The intramolecular C–H oxidative addition in the IrI2P,P′-SiNP) moiety is triggered by trimethyl phosphite and yields the IrIIIH(κ3C,P,P′-{SiNP-H}) scaffold.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02585K, Paper
Luminescent bimetallic Ru(II)-terpyridine complexes based on the pyrenyl-bis-phenylimidazole spacer as highly efficient sensors for cyanide in aqueous, organic and solid media are reported.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03405A, Communication
A 2D layered viologen-based zinc complex exhibits the rare discolored function of reversible photochromism and thermochromism. Interestingly, its fluorescence can be switched by visible light irradiation and heating in air.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02552D, Paper
This study on Cu-doped Li[NiCoMn]1/3O2 provides support for reusing Cu as a beneficial dopant in the production of metal-doped Li[NiCoMn]1/3O2 from spent LIBs.

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