Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 3.806 48 Issues per Year Indexed in MEDLINE
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Mirjana D. Đurović, Ralph Puchta, Živadin D. Bugarčić and Rudi van Eldik
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00247D, Paper
The type of reaction that occurs between [AuCl4] and Br, I, NO2, tu, py and DMSO, as well as their kinetic parameters, were determined using UV-vis, rapid-scan, stopped-flow measurements, cyclic voltammetry, 1H NMR and theoretical calculations.
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00764F, Communication
Electrophilic iodination of the 7,9-dicarba-nido-undecaborate anion with molecular iodine in the presence of AlCl3 generated a new carborane anion—8-iodo-7,9-dicarba-nido-undecaborate—in excellent yield. The capping of the new anion with HBCl2 yielded...
Thangaraj Selvam, Alexandra Inayat and Wilhelm Schwieger
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00573B, Perspective
Layered materials, such as layered sodium silicates and layered double hydroxides (LDHs), are well-known for their remarkable adsorption, intercalation and swelling properties. Their tunable interlayers offer an interesting avenue for...
Maria Rangel, Andreia Leite, André M. N. Silva, Tania Moniz, Ana Nunes, Maria J Amorim, Carla Queirós, Luis Cunha-Silva, Paula Gameiro and John Burgess
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00642A, Paper
We report the synthesis and characterization of a set of 3-hydroxy-4-pyridinone copper(II) complexes with variable lipophilicity. EPR spectroscopy was used to characterize the structure of copper(II) complexes in solution, and...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00450G, Communication
The fluxional terminal and semibridging NO-coordinate ligands of DNIC [Fe4(-S)2(-NO)2(NO)6]2–, a precursor of Roussin’s black salt (RBS), are characterized by IR NO), 15N(NO) NMR and single-crystal X-ray diffraction.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00101J, Communication
Two structural isomers of bipolar host materials containing the dimesitylborane moiety were synthesized and the quantum efficiency of their devices depends on the substituent position of the dimesitylborane moiety.
Sohail Ahmed, Muhammad Adil Mansoor, Muhammad Mazhar, Tilo Söhnel, Hamid Khaledi, Wan Jefrey Basirun, Zainudin Arifin, Shahzad Abubakar and Bakhtiar Muhammad
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00719K, Paper
Y2CuO4–5CuO composite thin films having a band gap of 1.82 eV and a photocurrent density of 9.85 μA cm−2 at 0.8 V have been deposited from a solution of precursor 1 by AACVD.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00090K, Paper
Reactions of the mixed-valence cluster [Pt3(μ-PPh2)3Ph(PPh3)2] with various electrophiles have been investigated.
Zacharoula Iatridi, Violetta Georgiadou, Melita Menelaou, Catherine Dendrinou-Samara and Georgios Bokias
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00393D, Paper
Oleylamine-coated CoFe2O4 magnetic nanoparticles were successfully encapsulated into hydrophobically modified water-soluble polymers. The resulting hydrophilic nanohybrids exhibit promising r2-relaxivity properties.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00692E, Paper
A thin film of LDH intercalated with fluorescein exhibits intense photoemission with a uniform lifetime from individual LDH nanocrystals.
Anna S. Degtyarenko, Marcel Handke, Karl W. Krämer, Shi-Xia Liu, Silvio Decurtins, Eduard B. Rusanov, Laurence K. Thompson, Harald Krautscheid and Konstantin V. Domasevitch
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00174E, Paper
Three types of polynuclear Cu(II) clusters rely on the compatibility of short-distance hydroxo-, carboxylato and pyridazine bridges and are applicable for the construction of 3D MOF structures.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00576G, Paper
Systematic development of the geometric and electronic properties of the amino acid based salt receptors leads to a very effective and selective NaNO2 receptor.
Yongbing Lou, Jingjing Wang, Yinhua Tao, Jinxi Chen, Akio Mishima and Masaaki Ohba
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00388H, Paper
The versatile bridging modes of 1,4-naphthalene dicarboxylic acid promote the formation of three new different manganese coordination polymers.
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00905C, Communication
A pair of enantiomorphic frameworks, featuring a rare chiral 3D inorganic connectivity and a {Pb18} wheel has been obtained via spontaneous resolution. They exhibit rapid, highly selective and sensitive sensing...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00621F, Paper
Electron-withdrawing perfluoroalkyl peripheral substituents enhance the photosensitizing properties of metal phthalocyanines while increasing their solubility, thus providing opportunities for advanced characterization of their catalytically-relevant excited states. Optical absorption and electron...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00833B, Paper
A series of cyclopalladated 2-(4-bromophenyl)pyridine (bpp) complexes [Pd(bpp)(NHC)Cl] 1–3, [Pd(bpp)(acac)] 4, cyclometalated iridium(III) complexes [Ir(bpp)2Cl]2 5 and [Ir(bpp)2(acac)] 6 have been synthesized and characterized. Their detailed structures have been determined...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00608A, Paper
Abstract: Porous cobalt oxide (Co3O4) nanorod (50-100 nm) and nanosheet-like (70-100 nm) particles were synthesized by a facile hydrothermal method at 150oC for 2-5h and 12-24h, respectively using aqueous-based precursors...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00973H, Paper
This contribution explores the effect of some solvent properties, such as volatility, polarity, and Lewis basicity on the formation of molecular self-assembled nanostructures in the solid state, obtained either by...
Min Pang, Xuesong Zhai, Jing Feng, Shuyan Song, Ruiping Deng, Zhuo Wang, Xin Ge, Shuang Yao and Hongjie Zhang
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00708E, Paper
Water-soluble hexagonal NaScF4:Yb/Er nanocrystals have been directly synthesized via a facile one-step hydrothermal route. The as-prepared nanocrystals were monodisperse and could form stable colloidal solutions in polar solvents, such as...
Haitang Shi, Xue Chen, Linlin Li, Longfei Tan, Xiangling Ren, Jun Ren and Xianwei Meng
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00825A, Communication
This communication describes a novel environmentally-friendly method to prepare bioactive Urease/ZnFe2O4 nanocomposites through one-pot and one-step process. The synthetic procedure is triggered through a biological mineralization process of decomposition of...
Hongxia Guan, Gui-Xia Liu, Jinxian Wang, Xiang Ting Dong and Wen Sheng Yu
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00158C, Paper
Tb3+ and/or Sm3+ doped NaGdF4 luminescence nanomaterials have been successfully synthesized by SDS-assisted one-step hydrothermal method. The samples were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), transmission...
Jason Laurence Dutton, David John Wilson and Kalon J Iversen
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00946K, Frontier
N-heterocyclic carbenes (NHCs) are generally considered to be extremely robust, ideal spectator ligands. However, in the past two years there have been several reports of the activation of the endocyclic...
A R Kennedy, R E Mulvey, Robert Urquhart and Stuart Duncan Robertson
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00808A, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00610K, Paper
The synthesis, spectroscopic characterisation, and thermal studies of pyridyl adducts of Zn(II) and Cd(II) complexes of N-ethyl-N-phenyl dithiocarbamate, represented as [ZnL2py] and [CdL2py2], are reported. Single-crystal X-ray structural analysis of...
Christopher J. D. Austin, Jan Kahlert, Fatiah Issa, John H. Reed, Jason R. Smith, Joseph A. Ioppolo, Jennifer A. Ong, Joanne F. Jamie, David Hibbs and Louis M. Rendina
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00444B, Paper
The first examples of indoleamine-2,3-dioxygenase-1 (IDO1) inhibitors containing a carborane cage are reported.

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