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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Asami Mori, Takayoshi Suzuki, Yuichi Nakatani, Yukinari Sunatsuki, Masaaki Kojima and Kiyohiko Nakajima
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02345A, Communication
A reaction of [PdCl2(cod)] (cod = 1,5-cyclooctadiene) and an E/Z mixture of quinoline-2-carbaldehyde (pyridine-2-carbonyl)-hydrazone (HL) gave two kinds of PdII mononuclear complexes, [PdCl(Z-L-κ3N,N’,N”)] (1) and [PdCl2(E-HL’-κ2N,N’)] (2), where L– is...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01991E, Paper
Highly electron-poor SPhos ligands bearing either 2,6-bis(trifluoromethyl)-4-pyridyl (BFPy) or 3,5-(CF3)2C6H3 groups were synthesised. The former ligand highly accelerated the Pd-catalysed direct arylation of 2-propylthiophene, 2-methylthiophene or benzo[b]thiophene with only 1...
Nan Wu, Caroline F. C. Melan, Kristina A. Stevenson, Olivier Fleischel, Huan Guo, Fatemah Habib, Rebecca J. Holmberg, Muralee Murugesu, Nicholas J. Mosey, Hélène Nierengarten and Anne Petitjean
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00233H, Paper
The 2-pyridyl–1,2,3-triazole chelate was found to display unique coordination properties.
Reinhold Tacke, Claudia Kobelt, Johannes A. Baus, Rüdiger Bertermann and Christian Burschka
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01581B, Paper
A novel donor-stabilised silicon(II) complex with an SiN3 skeleton was synthesised and its reactivity profile was characterised (reactions with N2O, S8, Se, Te, Me3SiN3, PhSCH2N3 and [Fe(CO)5]).
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02198G, Perspective
Rare-earth metal complexes of reduced π ligands are reviewed with an emphasis on their electronic structure and bonding interactions. This perspective discusses reduced carbocyclic and acyclic π ligands; in certain...
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01722J, Paper
The vapor diffusion sol–gel method was used to synthesize complex ternary scheelite nanocrystals of arbitrary and well-defined elemental stoichiometry.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02214B, Communication
Trifluoromethylsulfinyl 3 and trifluoromethylthio 5 compounds are independently obtained by using the sulfone-type reagent 1 under Cu catalysis.
Dheivasigamani Thangaraju, Rajan Karthikeyan, Natarajan Prakash, Sridharan Moorthy Babu and Yasuhiro Hayakawa
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01542A, Paper
Cu2ZnSnS4 (CZTS) and CZTS decorated rGO were synthesized and their optical properties were analyzed.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01884F, Paper
The palladacyclopentadienyl complexes with substituted phosphoquinolines react with halogens giving σ-butadienyl or a zwitterionic derivative depending on the ligand structure.
Rik Van Deun, Dorine Ndagsi, Jing Liu, Isabel Van Driessche, Kristof Van Hecke and Anna M. Kaczmarek
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02112J, Paper
Color-tunable Y2WO6 microstructures doped or co-doped with Sm3+, Eu3+, Tb3+, and Dy3+ were synthesized in the presence of glycerol both as a solvent and a structure directing agent for obtaining white light emitting materials.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02336J, Paper
We used halloysite, a nano-sized natural mineral and high surface area montmorillonite as supports for nano-sized Mn oxides to synthesize efficient water-oxidising catalysts.
Ivan Nemec, Raphael Marx, Radovan Herchel, Petr Neugebauer, Joris van Slageren and Zdeněk Trávníček
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02162F, Paper
Magnetic properties of a pentacoordinate Co(II) complex were studied experimentally and theoretically. The compound behaves as a field-induced single-molecule magnet.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01794G, Paper
Single-phase Sr5(PO4)3F:Eu2+,Mn2+ phosphors are prepared, showing white-light emission under near UV excitation. The photoluminescence intensity is enhanced by 85% by using KCl as flux. The relationship between photoluminescence and the crystal and electronic structures is studied.
Xiaoliang Dong, Litao Liu, Yuhan Zhou, Jun Liu, Yixin Zhang, Yanhui Chen and Jingping Qu
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01445J, Paper
Carboxylate-bridged iron–thiolate clusters were formed from alcohols/aldehydes in air or sodium carboxylates at room temperature.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02028J, Paper
The ZVI-S-PCAT modified silica composite is a successful catalytic framework for synthesizing 5-membered heterocylic rings and a future sensor material.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01095K, Paper
Quantum chemical studies predict the binding of Cesium salts to multitopic ion-pair receptor is through cooperative mechanism.
Agathe Filatre-Furcate, Pascale Auban-Senzier, Marc Fourmigue, Thierry Roisnel, Vincent DORCET and Dominique Lorcy
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02534F, Paper
In the presence of MeI or EtI, N-tert-butyl-1,3-thiazoline-2-thione derivatives undergo a transformation to 2-alkylthio-thiazoledithiolate pro-ligands with elimination of the tert-butyl substituent. The corresponding AuIII dithiolene complexes [Au(RS-tzdt)2]– (R = Me,...
Liqing He, Hai-Wen Li, Nikolay Tumanov, Yaroslav Filinchuk and Etsuo Akiba
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02343B, Paper
Metal dodecaborate M2/nB12H12 is one of the dehydrogenation intermediates of metal borohydride M(BH4)n with a high hydrogen density of approximately 10 mass%, the latter is a potential hydrogen storage material....
Evamarie Hey-Hawkins, Tobias Möller, Peter Wonneberger, Menyhart B. Sarosi and Peter Coburger
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02564H, Paper
The principle of stereotopic face differentiation was successfully applied to 2H-phospholes which undergo a very efficient and highly stereoselective Diels–Alder reaction giving phosphorus-chiral 1-phospha-norbornenes with up to 87% yield. The...
Xingwen Zhang, Zhengyang Zhou, Hongping Wu, ShiLie Pan, Chen Lei, Lu Liu and Zhihua Yang
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00915D, Paper
Owing to the effect of atomic vibrations, high-temperature phase usually features a relatively smaller density when compared with low-temperature phase. In this work, a new SrCdB2O5 phase has been discovered....
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02364E, Paper
Air-sensitive and air-stable primary phosphines (RPH2) were compared for their ability to undergo photoinitiated phosphane-ene chemistry with 1-hexene. Despite their increased air-stability, the primary phosphines displayed equal to or greater...
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01415H, Paper
Complexes of the type P(CH2NArR)3Mo[triple bond, length as m-dash]N act as ditopic ligands that allow for the facile assembly of polymetallic complexes.
Oksana V. Nesterova, Eduard N. Chygorin, Vladimir N. Kokozay, Irina V. Omelchenko, Oleg V. Shishkin, Roman Boča and Armando J. L. Pombeiro
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02076J, Paper
An Fe/Mn Schiff base complex with an unprecedented metal core type for a heterometallic compound, has been prepared by the one-pot direct synthesis method and magnetostructurally characterized.
Tameryn Stringer, Dale Taylor, Hajira Guzgay, Ajit Shokar, Aaron Au, Peter J. Smith, Denver T. Hendricks, Kirkwood M. Land, Timothy J. Egan and Gregory S. Smith
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02378E, Paper
Salicylaldimine ligands and their corresponding Rh(I) complexes were prepared and evaluated as antiparasitic agents.
Anatoliy Marchenko, Georgyi Koidan, Anastasiya Hurieva, Yurii Vlasenko, Aleksandr Kostyuk and Andrea Biffis
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02250A, Paper
Complexes of palladium(II) with newly disclosed, N-phosphanyl acyclic diaminocarbene ligands are synthesized for the first time and structurally characterized. The ligands coordinate palladium(II) in a chelating fashion, yielding remarkably stable...

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