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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00247A, Paper
A variety of iron(III) oxides and oxyhydroxides were synthesised and characterised using three distinct methods of preparation: microemulsion, precipitation and sol-gel. The results clearly showed that the structure, textural properties,...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01175F, Paper
Heteroleptic complexes [Ir(dfppy)2(BrL)]3CH3OH (1) and [Pt(dfppy)(BrL)]CH3OH (2) have been prepared based on the same ligands including bisthienylethene BrLH (Scheme 1) and dfppyH = (2-(2,4-difluorophenyl)-pyridine). Complexes 1 and 2 reveal distinct...
Souvik Pandey, Alex P Andrews and Ajay Venugopal
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01032F, Communication
We report here, the first example of an inorganic organic hybrid material incorporating a helical iodobismuthate [BiI4]∞ templated by 2,6-diisopropylanilinium cations. The realisation of the helical iodobismuthate opens up the...
Richard O. Bonsu, Duane C. Bock, Hankook Kim, Roman Y. Korotkov, Khalil A Abboud, Timothy Anderson and Lisa McElwee-White
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01078D, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
Nathaniel J. Hartmann, Guang Wu and Trevor. W. Hayton
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00885B, Communication
Activation of carbon disulfide (CS2) by “masked” terminal nickel sulfide, [K(18-crown-6)][(LtBu)Ni(S)], gives a trithiocarbonate complex. This result confirms the nucleophilicity of the sulfide ligand and expands the scope of reactivity for late metal sulfides.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01339B, Paper
A series of fluorophosphonium cations incorporating (C6Cl5) substituents, [Ph2PF(C6Cl5)][B(C6F5)4] 8, [PhPF(C6Cl5)2][B(C6F5)4] 9, and [(C6F5)PF(C6Cl5)2][B(C6F5)4] 10, were prepared and tested for air stability and catalytic activity.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00886K, Paper
A facile method was developed to evaluate the relative water stability of MOFs by controlling the volume ratio of DMF and H2O.
M. D. Santana, L. López-Banet, G. Sánchez, J. Pérez, E. Pérez, L. García, J. L. Serrano and A. Espinosa
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04913J, Paper
Cyclometallated Pd(II) complexes with different stackings show emission in solid state in relationship to them.
Lei Xu, Yanping Luo, Lin Sun, Shan Pu, Min Fang, Rong-Xing Yuan and Hong-Bin Du
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00992A, Paper
N-Quaternization of pyridine sites in UiO-67-bpy affords a cationic MOF UiO-67-bpy-Me with faster and improved anionic dye and CO2 adsorption, and extended visible-light absorption properties, which make UiO-67-bpy-Me more efficient in photodegrading organic dyes.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00601A, Paper
Three phosphorescent cyclometalated iridium(III) complexes with mitochondria-specific localization and apoptosis-inducing capability have been explored as the theranostic anticancer agents.
Wilaiwan Chouyyok, Jonathan W. Pittman, Marvin G. Warner, Kara M Nell, Donald Clubb, Gary A Gill and Raymond Addleman
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01318J, Paper
The ability to collect uranium from seawater offers the potential for a nearly limitless fuel supply for nuclear energy. We evaluated the use of functionalized nanostructured sorbents for the collection...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00713A, Paper
ITQ-8 is a new hydrous layer silicate (HLS) with a chemical composition of [(C4H8(C7H13N)2]8 [Si64O128(OH)16] • 48 H2O per unit cell. The synthesis of ITQ-8 was first described in 2002...
Caterina F Ramogida, Eszter Boros, Brian O. Patrick, Stefan Zeisler, Joel Kumlin, Paul Schaffer, Michael J Adam and Chris Orvig
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00932H, Paper
The chiral acyclic “pa” ligand (pa = picolinic acid) H2CHXdedpa (N4O2) and two NI-containing dedpa analogues (H2CHXdedpa-N,N’-propyl-2-NI, H2dedpa-N,N’-propyl-2-NI, NI = nitroimidazole) were studied as chelators for copper radiopharmaceuticals (CHX =...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00800C, Paper
A novel water-soluble colorimetric and fluorescent palladium probe with an excellent selectivity and sensitivity has been designed. Notably, based on palladium triggered terminal allyl ethers cleavage reaction, the probe could...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01157H, Perspective
Supramolecular chemistry of bis-imidazole ligand namely 1,4-bis(imidazol-1yl-methyl)benzene, popularly known as bix was explored by various researchers to synthesize functional coordination polymers (CPs). The flexibility of the bix ligand, its unpredictable...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00993J, Paper
This paper describes a simple and fast aqueous-phase route to the synthesis of Ag/AgCl hybrid nanostructures. These hybrid nanostructures were synthesized by reduction of AgCl nanoparticles with controlled shapes prepared...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00442C, Paper
A series of four indole-derivative β-diketone mononuclear dysprosium complexes, namely, Dy(EIFD)3(bpy)·CH2Cl2 (1), Dy(EIFD)3(phen)·CH2Cl2 (2), Dy(EIFD)3(dpq)·CH2Cl2 (3), and Dy(EIFD)3(dppz) (4) (EIFD = 1-(1-ethyl-1H-indol-3-yl)-4,4,4-trifluorobutane-1,3-dione, bpy = 2, 2'-bipyridine, phen = 1, 10-phenanthroline,...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00777E, Paper
A series of TbIII triple-decker heteroleptic crownphthalocyaninate complexes consisting of a homodinuclear compound [(15C5)4Pc]Tb[(15C5)4Pc]Tb(Pc) (1) and two novel heterodinuclear compounds [(15C5)4Pc]Tb[(15C5)4Pc]Y(Pc), (2), and [(15C5)4Pc]Y[(15C5)4Pc]Tb(Pc) (3), have been synthesized. All compounds...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04953A, Paper
Three new Ni(II)-clusters based on a Y-shaped ligand (biphenyl-3,4′,5-tricarboxylate, H3BPT), [Ni5(HBPT)4(OH)2(H2O)12]n (1), [Ni4(BPT)2(OH)2(H2O)6]n∙4nH2O (2), and [Ni7(BPT)2(1,4-bib)2(OH)6(HCO2)2]n∙3nH2O(3) (1,4-bib = 1,4-bi(1H-imidazol-1-yl)benzene), have been synthesized under the solvothermal condition. They were studied by...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00979D, Paper
A distorted octahedral CoII complex was reported with homoscorpionate ligands. This complex is a field-induced single-molecule magnet with two slow relaxation processes under low dc field (< 800 Oe) and...
Leighton J. Alcock, Germán Cavigliasso, Anthony C. Willis, Robert Stranger and Stephen F. Ralph
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01176D, Communication
The rare trigonal prismatic geometry is readily adopted in complexes of a large cavity hexaamine cage ligand.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00859C, Paper
We prepared through CO2 air fixation novel Ni8Ln6 complexes showing a remarkable μ5-carbonate bridged octanuclear planar {Ni4Ln4} core and unusual MCE behaviour.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00265J, Communication
3-Aminopyridine-2-carboxylic acid can serve as an AIE-active turn on fluorescence chemosensor for Zn2+. The AIE behaviors are attributed to the cooperative effect of J-aggregation and hydrogen bonds. And selecting proper ratio of the solvents can prove the sensitivity.
Andrea Schmidt, Manuela Hollering, Markus Drees, Angela Casini and Fritz E. Kühn
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00654J, Paper
Self-assembled Pd(II) coordination cages exhibit promising anticancer activities, while the emission properties studied by fluorescence spectroscopy and DFT calculations are limited.
Domenica Musumeci, Chiara Platella, Claudia Riccardi, Antonello Merlino, Tiziano Marzo, Lara Massai, Luigi Messori and Daniela Montesarchio
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00294C, Paper
The reactivity of cis-PtI2(NH3)2 with selected DNA model systems, in single, double strand or G-quadruplex form, has been studied by circular dichroism, UV-visible spectroscopy and electrospray mass spectrometry using cisplatin as a control.

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