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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.177 48 Issues per Year Indexed in Medline
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Sophie De-Botton, Ponit Romm, Guillaume Bensoussan, Maria Hitrik, Sanaa Musa and Dmitri Gelman
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02201D, Paper
The manuscript describes the synthesis and coordination chemistry of a novel diphoshine pincer ligand based on p-hydroquinone-functionalyzed dibenzobarrelene scaffold. The p-hydroquinone fragment of the ligand is oxidatively and coordinatively non-innocent...
Benhua Xu, Xiao-Liang Tang, Ji-An Zhou, Wan-Min Chen, Haile Liu, zhenghua Ju and Wei-Sheng Liu
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02835G, Paper
A functional amide-type pincer ligand was designed and synthesized, which could capture effectively Tb3+ ion to form a phosphorescence complex-based chemosensor Tb-1. The chemosensor could further coordinate with Pb2+ ion...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02635D, Communication
Lanthanide contraction was used for helicity fine-tuning and helix winding control of single-helical tetranuclear complexes LZn3Ln (Ln = La–Lu); heavier lanthanides formed a tighter helix with a higher M/P ratio...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01709F, Paper
Two types of zinc flavonolato complexes ([(6-Ph2TPA)Zn(flavonolato)]ClO4 and Zn(flavonolato)2) of four extended flavonols have been prepared, characterized, and evaluated for visible light-induced CO release reactivity. Zinc coordination of each flavonolato...
Reina Shimokawa, Yumi Kawada, Miki Hayashi, Yasutaka Kataoka and Yasuyuki Ura
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02948E, Communication
A cationic SNS-benzylpalladium complex was reacted with O2 under several conditions, affording oxygenated compounds derived from the benzyl ligand. The addition of n-Bu4NX remarkably accelerated the oxygenation, furnishing benzaldehyde as...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02186G, Paper
The binding-induced luminescence enhancement of an Eu-containing polyoxometalate (POM), EuSiWMo, by the arginin/lysine-rich cationic peptides supplied a platform to detect the capsid proteins of human papillomaviruses (HPVs). However, the strong...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02922A, Paper
Different di and trinuclear rare-earth metal complexes supported by 3-amido appended indolyl ligands were synthesized and their catalytic activities towards isoprene polymerization were investigated. Treatment of [RE(CH2SiMe3)3(thf)2] with 1 equiv....
xuejun Lu, Youlai Jin, xinyi zhang, Guangqing Xu, Dongmei Wang, Jun Lv, Zhixiang Zheng and Yucheng Wu
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02247B, Paper
MoS2/graphitic C3N4 (MoS2/g-C3N4) hybrids were synthesized via a facile bathing and ultrasound method. In this process, a well bonded interface structure was formed between ultrathin MoS2 nanosheets and g-C3N4 through...
Chong Wu, Jiang-Lin Zhao, Xue-Kai Jiang, Chuan-Zeng Wang, Xin-Long Ni, Xi Zeng, Carl Redshaw and Takehiko Yamato
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02274J, Paper
The heavy atom effect and blocking thereof were demonstrated within the same system by the use of a C3-symmetric homooxacalix[3]arene scaffold.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02657E, Communication
A bis(2-pyridyl)tetraarylethylene exhibits selective “turn-on” fluorescence enhancement in the presence of Zn2+ ions.
Zhangang Han, Huixia Zhang, Jinshuang Yan and Xueliang Zhai
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02618D, Communication
A highly Al-doped β-isomer Keggin-type cluster was synthesized and characterized.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01310D, Paper
Azobenzene-derived tris-β-diketonate lanthanide complexes were synthesized and they show good trans-to-cis photoisomerization behavior both in solution and in the solid state.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02061E, Paper
A cyanide containing mimic of the [FeFe]-hydrogenase cofactor has been characterized, highlighting the importance of the bridgehead nitrogen for proton reduction catalysis.
Liang Li, Yulin Yang, Ruiqing Fan, Jian Liu, Yanxia Jiang, Bin Yang and Wenwu Cao
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02584F, Paper
Decatungstate acid (DA) was utilized to modify TiO2 in the photoanode of dye sensitized solar cells.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02431A, Paper
The bifunctionality of Fe-PNP plays a role in stabilizing the ion-pair complex in the dehydrogenation via a hydrogen bonding and a C–H agostic interaction.
Rabia Naeem, Muhammad Ali Ehsan, Rosiyah Yahya, Manzar Sohail, Hamid Khaledi and Muhammad Mazhar
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02656G, Paper
Pristine Mn2O3 and Ag–Mn2O3 nanocomposite thin films deposited by AACVD on FTO showed photocurrent densities of 1.8 and 3 mA cm−2 respectively.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02317G, Paper
We combined experimental and theoretical studies of βII-Li3VO4, KCd4(VO4)3 and Ca3(VO4)2 crystals, which turns out that the metal cation types and coordination around VO4 groups, the distorted and parallel oriented VO4 tetrahedron, could produce the large SHG coefficient.
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02236G, Communication
An efficient oxygen-phosphoryl bond-forming reaction via iron-catalyzed cross dehydrogenative coupling has been developed. This transformation proceeds efficiently under the oxidant- and halide-free reaction conditions with H2 liberation, and represents a...
Huai-Jun Lin, Hai-Wen Li, Biswajit Paik, Jianhui Wang and Etsuo Akiba
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02845D, Paper
Three-component Mg(NH2)2-LiNH2-4LiH composite reversibly stores hydrogen exceeding 5 wt% at temperature as low as 150 oC. In this work, a number of additives such as CeF4, CeO2, TiCl3, TiH2, NaH,...
Subhabrata Banerjee, Sho Kataoka, Toshikazu Takahashi, Yoshihiro Kamimura, Kunio Suzuki, Kazuhiko Sato and Akira Endo
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02868C, Communication
In this report, we synthesized ordered coordination polymers using polyhedral oligomeric silsesquioxanes (POSS) as a building block. A POSS with eight carboxylic terminals was coordinated with copper ions at various...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03086F, Paper
Three new coordination polymers have been synthesized based on three linear pyridine ligands with different side chains and one flexible V-shaped dicarboxylate co-ligand: {[Co(L1)(sdb)]}n (1), [Co(L2)(sdb)∙1.5H2O]n (2), {[Co(L3)(sdb)]∙2DMF}n (3) (L1...
Mariete Barbosa Moreira, Camila Fontes Neves Silva, Rafaela Pesci, Victor Deflon and Sofia Nikolaou
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02511K, Paper
We synthesized and characterized a series of oxo-centered carbonyl-triruthenium complexes with general formula [Ru3O(CH3COO)6(L)2(CO)], where L = 2,6-dimethylpyrazine (dmpz) (1), isonicotinamide (adpy) (2), 4-acetylpyridine (acpy) (3), 3-methylpyridine (3-pic) (4), 4-methylpyridine...
Wenhua Zhang, Chen Zhihao, Majd Al-Naji, Penghu Guo, Stefan Cwik, Olesia Kozachuk, Yuemin Wang, M Muhler, Nicole Wilde, Roger Gläser and Roland A. Fischer
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02893D, Communication
Simultaneous incorporation of palladium within Pd-Pd and/or Pd-Cu paddlewheels as framework-nodes and Pd nanoparticles (NPs) dispersion into MOF have been achieved for the first time via one-pot synthesis. The framework...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03094G, Paper
We report the synthesis, single-crystal structure characterization and detail magnetic study of a homometallic hexanuclear CuII cluster Cu6(3-OH)2(ppk)6(H2O)2(NO3)4 (1) and a 3D compound [{MnCu2(dpkO2H)2(dpkO2)N3}.(NO3).H2O]n (2) (ppk = phenyl-2-pyridylketoxime; dpk =...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02930B, Paper
Tetraalkyl-diglycolamide (TRDGA) ligands have potential utilization for the separation of actinide and lanthanide ions in nuclear industry as chelates in aqueous solution if water-soluble or as extractants in organic solvents...

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97 citations
Porphyrin sensitizers have exhibited power conversion efficiencies that are comparable to or even higher than those of well-established highly efficient DSSCs based on ruthenium complexes.
DOI: 10.1039/C4DT02756F
Published: 10 Nov 2014
43 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015
53 citations
The recent developments in lanthanide SMMs highlighted in this frontier article indicate the directions to which further synthetic efforts should be focused.
DOI: 10.1039/C4DT03329A
Published: 21 Jan 2015

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