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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04049C, Perspective
Metal-organic frameworks (MOFs) are a class of porous solid, which have a variety of potential applocations. Unfortunately, MOFs often lack hydrolytic stability, which hinders their use as viable materials for...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03537F, Paper
The coordination behaviour of hexakis(3-pyridyloxy) cyclophosphazene (L) towards divalent metal ions is described. The reaction of L with hydrated metal nitrates afforded [{N3P3(O-C5H4N-3)6}2{Zn(H2O)3(NO3)}2{Zn(H2O)2(NO3)2}]n[NO3]2n ·4nH2O·nCH3OH (1), [{N3P3(O-C5H4N-3)6}2{ Zn(H2O)3(NO3)}2{Cu(NO3)2}]n[NO3]2n· 4nH2O·nCH3CN (2), [{N3P3(O-C5H4N-3)6}2{(NO3)Cd-(μ-(NO3)-Cd(NO3)2(μ-(NO3)...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03918E, Paper
An Al–Cl functionalized germane with an activated Ge–Cl bond showed a tBu/Cl exchange via a transient germyl cation.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT04152J, Communication
A new, strongly luminescent iridium(III) bibenzimidazole anion sensor system based on an H-bond driven light switch is presented.
Guoqiang Feng, Xingxing Jiang, Wenjuan Wei, Pifu Gong, Lei Kang, Zhihua Li, Yanchun Li, Xiaodong Li, Xiang Wu, Zheshuai Lin, Wei Li and Peixiang Lu
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03505H, Paper
The hydrostatic behaviour of a cubic dense inorganic–organic framework [DABCOH22+][K(ClO4)3] has been systematically studied via high-pressure synchrotron X-ray powder diffraction. Further first principles calculations of full elastic tensors give full mapping of the Young's moduli, shear moduli and Poisson's ratios of this material.
Antonio J. Calahorro, Itziar Oyarzabal, Belén Fernández, José M. Seco, Tian Tian, David Fairen-Jimenez, Enrique Colacio and Antonio Rodríguez-Diéguez
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03946K, Paper
We report lanthanide-based MOFs with interesting magnetic behaviours. To the best of our knowledge, Nd3+ and Yb3+ materials are the first examples of 3D- and 2D-MOFs, respectively, that show slow relaxation of magnetization.
Abhijit Ghosh, Sabyasachi Ta, Milan Ghosh, Subhajit Karmakar, Avishek Banik, Tushar Kanti Dangar, Subhra Kanti Mukhopadhyay and Debasis Das
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03431K, Paper
Structurally characterized naphthalene-based ratiometric probe detects zinc acetate (ZA) by colorimetric and fluorescence tools. In vitro tracking of ZA in endophytic bacteria in rice root tissue and human breast cancer cells (MCF7) is possible.
Jagriti Gupta, Jeotikanta Mohapatra, PARAG BHARGAVA and Dhirendra Bahadur
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04135J, Paper
Polyacrylic acid functionalized Fe3O4 nanoparticles (PAA-MNPs) of average size of 10 nm are prepared by a simple soft chemical approach. These PAA-MNPs are conjugated with folic acid through peptide bonding...
Veronica Paradiso, Valerio Bertolasi, Chiara Costabile and Fabia Grisi
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03758A, Paper
New second generation ruthenium catalysts bearing unsymmetrical NHCs show different catalytic efficiencies depending on the size of the N-alkyl group (methyl or cyclohexyl) and on the backbone configuration.
Rachael A. Kelsey, David A. Miller, Sean R. Parkin, Kun Liu, Joe E. Remias, Yue Yang, Felice C. Lightstone, Kunlei Liu, Cameron A. Lippert and Susan A. Odom
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT02943K, Paper
Carbonic anhydrase converts CO2 to HCO3 in physiological conditions, but in the highly basic amine-containing solutions used industrially for carbon capture, the enzyme does not function. Instead small molecule mimics can catalyze CO2 hydration.
Xiao-Lin Zhao, Dan Tian, Qiang Gao, Hong Wei Sun, Jian Xu and Xian-He Bu
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03283K, Paper
A new luminescent lanthanide metal-organic framework was synthesized under hydrothermal condition by introducing the tetracarboxylic acid ligand (H4bptc) as a chromophore to sentisize the luminescence of Tb3+ ion. Interestingly, despite...
ying-juan hao, fa-tang li, Jun Zhao, Rui-hong Liu, Xiao-jing Wang, Yu-pei Li and Ying Liu
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04175A, Paper
Porous sphere-like tricobalt tetraoxide (Co3O4)-cobalt chloride hydrate (CoCl2×6H2O, CCH) heterojunctions are obtained by a one-step facile solution combustion route. The heterostructure is confirmed by XRD, HRTEM, and XPS measurements. Their...
Wolf Schorn, David Grosse-Hagenbrock, Benjamin Oelkers and Jörg Sundermeyer
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT03906A, Paper
The preparation, molecular structures and physical properties of novel heavy group 13 metal formazanido complexes are described. The trimethyl derivatives MMe3 (M = Al, Ga, In) react with 1,3,5-triphenylformazan (Htpf)...
Yao-Chang Chen, Nik Reeves-McLaren, Chaou C. Tan, Paul A. Bingham, Susan D. Forder and Anthony R. West
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT02998H, Paper
Four new phases of general formula, Li11RE18M4O39−δ: REM = NdAl, NdCo, SmCo, SmFe, have been synthesised and characterised.
David-R. Dauer, Melchior Flügge, Regine Herbst-Irmer and Dietmar Stalke
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03911H, Paper
A series of functionalised bis-(benzothiazol-2-yl)-amine ligands and the related dimethylaluminium amides were synthesised and characterised. The solid state structural comparison reveals various coordination motifs, specific folding parameters and hydrogen bonding patterns in detail and guide the way to future Janus head ligand design.
Wei Lü, Mengmeng Jiao, Baiqi Shao, Lingfei Zhao, Yang Feng and Hongpeng You
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03465E, Communication
We introduce non-rare-earth ion Mn4+ to transfer energy to Yb3+, which can exhibit strong near-infrared luminescence.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03535J, Communication
A novel heterometallic organic–inorganic hybrid MOF material, Co5In(BTC)4[B2O4(OH)]2, has been synthesized under ionothermal conditions. Its structure is characterized as a 3D open framework constructed by the Co2.5In0.5[B2O4(OH)] cluster and the 1,3,5-benzenetricarboxylate ligand.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03778F, Perspective
This perspective article provides an overview of the advancements in the field of non-precious metal PCsp2P and PCsp3P pincer complexes.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03532E, Paper
Thermodynamics of the U(VI) complexation with benzoic acid was studied by spectrophotometry at varied temperatures (298–353 K). A new μ3-OH bridged U(VI)/benzoate complex crystal was synthesized, and its structure was determined by single-crystal X-ray diffractometry.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04303D, Communication
The oxidation of phenols (X-CH6H4OH) and hydroquinone (H2Q) by HFeO4 proceeds via a hydrogen atom transfer (HAT) mechanism. The Marcus cross relation can be used to predict the rate constant of HAT from H2Q to HFeO4.
Maria Serratrice, Laura Maiore, Antonio Zucca, Sergio Stoccoro, Ida Landini, Enrico Mini, Lara Massai, Giarita Ferraro, Antonello Merlino, Luigi Messori and Maria Agostina Cinellu
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT02714D, Paper
The high antiproliferative effects of a new organoplatinum(II) complex are further enhanced upon coordination of a gold(I) phosphane moiety.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT03780H, Paper
In this paper, hierarchical MnCo2O4@MnO2 core–shell nanowire arrays (MnCo2O4@MnO2 NWAs) with mesoporous and large surface area are synthesized on 3D nickel foam via a facile, two-step hydrothermal approach without any adscititious surfactant and binder.
Yan Qiao, Bin Chen, Yangyang Yang, Xin Wang, yufang xu and Honglin Li
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04214C, Communication
Computational studies in combination with experimental research were used to design a new rapid, selective and sensitive “turn-on” fluorescent sensor (H3) for L-histidine, which can be first quenched by Ni2+...
Ruediger Beckhaus, Okko N Frey, Timo Stalling, Florian Schlüter, Wolfgang Saak, Marc Schmidtmann and Detlev Haase
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04137F, Paper
Deprotonation of 8bH-tetrabenzo[a,c,g,i]fluorene (8bH-Tbf), an extremely large benzannulated cyclopentadienyl derivative, by [NR3R’][OH] (R = nBu, Et; R’ = nBu, Et, Bn) leads to a series of Tbf ammonium salts of...
Jing Zhang, Chaofang Sun, Mingxing Zhang, Frantisek Hartl, Jun Yin, Guang-Ao Yu, li rao and Shenghua Liu
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT04083C, Paper
A series of ruthenium(II) complexes [{RuCl(CO)(PMe3)3(-CH=CH-)}nX], 1a-1c (1a: n = 3, X = 3,3''-dimethyl-2,2':3',2''-terthiophene; 1b: n = 2, X = 2,2'-bithiophene; 1c: n = 2, X = 2,3-bis(3-methylthiophen-2-yl)benzothiophene) and [{Cp*(dppe)2Ru(-C≡C-)}3X],...

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