Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 3.806 48 Issues per Year Indexed in MEDLINE
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Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02084G, Paper
Transparent needle like single crystals of the isostructural compounds [Sb4O7+3δX4][Zn3]1+δ(X = Cl, Br, I), δ≈ 0.2 were obtained from chemical reactions in evacuated and sealed silica tubes. First the average...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02366H, Paper
Reaction of analgin (NaL) with Co(II), Ni(II) and Cu(II) salts in ethanol affords complexes of the type [ML2], which were characterized by elemental analysis, FT IR, UV-Vis., EPR, TG/DTA, magnetic...
Oliver Clemens, Carine Rongeat, Munnangi Anji Reddy, Andreas Giehr, Maximilian Fichtner and Horst Hahn
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02485K, Paper
Here we report on the first electrochemical fluorination exemplarily performed on perovskite type BaFeO2.5. A cell setup of the type BaFeO2.5 II La0.9Ba0.1F2.9 II MFx (with MFx being MgF2 and...
Lesley Cherise Lewis-Alleyne, Bassem Basil, Tobias Böttcher and Gerd-Volker Röschenthaler
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02214A, Communication
NHCMeSiCl4, (NHCMe = 1,3-dimethylimidazolidin-2-ylidene), was used to synthesise novel NHCMe-Pt(II) complexes. An atypical trans-cis isomerisation process has also been achieved for [Pt(NHCMe)2Cl2], while the synthesis of the unique double-complex salt,...
Reiner Anwander, Nicole Dettenrieder, Christoph Schädle and Caecilia Maichle-moessmer
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02155J, Paper
Treatment of boryllithium (THF)2Li[B(NDippCH)2] (Dipp = 2,6-diisopropylphenyl) with various amounts of AlMe3 or GaMe3 leads to the formation of inter group 13 compounds. Equimolar reactions result in ate complexes of...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01953A, Paper
Solvothermal reactions of the semirigid 3,5-bi(4-carboxyphenoxy)benzoic acid (H3BCP) and transitional metal cations with the help of three ancillary bridging imidazole linkers afford six coordination polymers, namely, [Co(HBCP)(1,4-bib)0.5]n (1), {[Mn1.5(BCP)(1,4-bib)0.5(μ2-H2O)(H2O)2]•(1,4-bib)0.5}n (2),...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01451K, Paper
A new family of tetranuclear heterometallic assemblies, [FeIII2Gd2(H2L)4(η2-NO3)2]•2ClO4∙2CH3OH∙2H2O (1), [FeIII2Dy2(H2L)4(η2-NO3)2]•2ClO4∙2CH3OH∙2H2O (2), [FeIII2Tb2(H2L)4(η2-NO3)2]•2ClO4∙2CH3OH∙2H2O (3) have been successfully synthesized employing a multidentate Schiff-base ligand, (E)-2,2'-(2-hydroxy-3-((2-hydroxyphenylimino)methyl)-5-methylbenzylazanediyl)-diethanol (H4L), Fe(ClO4)2.6H2O and LnIII nitrate salts. These...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01620C, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02050B, Paper
Two interesting polyoxometalate-templated host-guest compounds 1 and 2 with the same chemical formulae of [Ag6(tpt)4(SiW12O40)Cl2]•2H2O have been obtained by the hydrothermal reactions of monlacunary Keggin-type K8[α-SiW11O39]•13H2O with CH3COOAg and tpt...
Isabelle M. DIXON, Sheryar Khan, Fabienne Alary, Martial Boggio-Pasqua and Jean-Louis Heully
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01939C, Paper
The abundance and low toxicity of iron with respect to ruthenium would certainly make it inescapable for photophysical applications if one could circumvent its tendency to make high-spin compounds and...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01750A, Paper
The selective oxidation of saturated hydrocarbons to terminal oxygenates under mild catalytic conditions has remained a centuries long challenge to chemical catalysis. In an attempt to address this challenge, two...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01076K, Paper
The hybrid nanocomposites based on N-doped SrTiO3 nanoparticles wrapped g-C3N4 nanosheets were prepared by a facile and reproducible polymeric citrate and thermal exfoliation method. The results clearly indicated that the...
Anastas Sidiropoulos, Brooke Osborne, Alexandr N. Simonov, Deepak Dange, Alan M. Bond, Andreas Stasch and Cameron Jones
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02074J, Paper
Adducts of an expanded ring N-heterocyclic carbene (6-Dip) with ECl3 (E = P, As or Sb) have been prepared, and the reduction of one, [(6-Dip)PCl3], is shown to give an unusual tetraphosphorus dicationic complex.
Trevor J. Ferris, Putthiporn Charoenphun, Levente K. Meszaros, Gregory E. D. Mullen, Philip J. Blower and Michael J. Went
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01928H, Paper
Preparation of Zr(IV) complexes containing monobasic bidentate ligands under radiopharmaceutical conditions has been evaluated. 89Zr(oxinate)4 is the most promising candidate for cell tracking.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02065K, Paper
The one-electron reduction product, ˙CCl3, irreversibly inactivates P450 via covalently binding to the meso-carbon, whereas the two successive one-electron reductions product, :CCl2, reversibly inhibits P450 by coordinating to iron.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02079K, Paper
Coordination complexes of amide-based ligands with appended heterocyclic rings create a hydrogen bonding cavity that effectively binds the substrate(s). Such cavity-based complexes function as reusable and heterogeneous catalysts for various organic transformations.
Xiaoming Lv, Yihua Zhu, Hongliang Jiang, Hua Zhong, Xiaoling Yang and Chunzhong Li
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02245A, Paper
The gold@titanium dioxide octahedral nanocages (Au@TiO2) with a well-defined double-shelled structure with Au as the internal shell and TiO2 as the external shell exhibit excellent and stable activity for the catalytic reduction of 4-nitrophenol.
Cyrille Galven, Denis Mounier, Thierry Pagnier, Emmanuelle Suard, Françoise Le Berre and Marie-Pierre Crosnier-Lopez
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01723D, Paper
LiHSrTa2O7 undergoes a reversible structural transition from an orthorhombic to a tetragonal symmetry around 200 °C. This transition, from acentric to centric space group, is revealed especially by the vanishing of the SHG signal.
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02144D, Paper
The development of theranostic mesoporous hollow silica nanospheres having therapeutic and diagnostic functions has been achieved. The exterior surface of the hollow mesoporous silica nanosphere was selectively acid functionalized and...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02038C, Paper
In the present study, the tin complex immobilized on silica gel as a novel, green, highly efficient and heterogeneous reusable catalyst was synthesized by grafting 2-amino benzamide on to the...
Chandan Giri, Filip Topić, Prasenjit Mal and Kari Rissanen
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02180K, Communication
In presence of triflate as the counter anion, 1,2-diaminobenzene and 2-formylpyridine self-sort with iron(II) to a low-spin [Fe(L1)](OTf)2 complex in which both aminal and imine moieties coexist simultaneously, while under...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02239D, Paper
Racemic trans-1,2-diphosphinocyclohexane (t-chxnP2) has been synthesised and its coordination chemistry to Cu(I), Ag(I), Mn(I) and Fe(II) investigated. Compounds of empirical formula [Cu(t-chxnP2)2]BF4 and [Ag(t-chxnP2)2]BF4 have been prepared as isomeric mixtures...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02151G, Communication
Herein we present a new and promising approach for the high-resolution modeling of vibrational Resonance Raman spectra of metal complexes in solution. The model explicitly includes Duschinsky couplings, solvent effects,...
Yunqing Luo, Shanshan Fan, Nongyi Hao, Shuangling Zhong and Wencong Liu
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01695E, Communication
A facile, low-cost and green ultrasound-assisted method has been developed to ultra-fast synthesize Mn3O4 nanosheets supported on the reduced graphene oxide (RGO). Such hybrid materials exhibited ultrahigh performance as lithium...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01441C, Paper
Composites made of Higher Manganese Silicides (HMS) – based compound MnSi1.75Ge0.02 and multi-walled carbon nanotubes (MWCNTs) have been prepared by an easy and effective method including mechanical milling under mild...

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