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Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
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Yuzhong Wang, Hunter P. Hickox, Pingrong Wei and Gregory H. Robinson
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00066A, Communication
C4-Ferrocenylsilyl-bridged and -substituted N-heterocyclic carbenes and their germanium chloride complexes have been prepared and characterized.
D. Cirri, S. Pillozzi, C. Gabbiani, J. Tricomi, G. Bartoli, M. Stefanini, E. Michelucci, A. Arcangeli, L. Messori and T. Marzo
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03867K, Paper
PtI2(DACH) has been prepared and tested. PtI2(DACH) shows different chemical and biological features than oxaliplatin, manifesting cellular effects nearly comparable to those of parent drug in three cellular lines of CRC.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00287D, Paper
Leaf-like CuO–Cu2O nanosheets have been prepared on copper foam by a one-step simple anodization method, which can be used as an advanced binder-free supercapacitor electrode.
Ouafa Khalfaoui, Adel Beghidja, Jérôme Long, Ahlem Boussadia, Chahrazed Beghidja, Yannick Guari and Joulia Larionova
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00326A, Paper
Discret and extended architectures based on an association of lanthanide ions with two derivatives of cinnamic acid (2-methoxycinnamic and 3-methoxycinnamic acids) have been synthesized and characterized by IR spectroscopy, elemental...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04299F, Paper
A discrete tetranuclear thiourea-based metal-organic marocycle (MOM) with large size was constructed by the well-designed organic ligand and metal ions nickel(II) via self-assembly. Incorporating thiourea groups as hydrogen-bond donors into...
Felix Böcher, Sean Culver, Jan Peilstoecker, Kai Weldert and Wolfgang Zeier
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00381A, Paper
AgBiSe2 has recently shown to exhibit promising thermoelectric properties due to a low intrinsic thermal conductivity, stemming from a large degree of lattice anharmonicity. While samples synthesized via solid-state routes...
LaRico J. Treadwell, Timothy J Boyle, W. Adam Phelan, Marie V Parkes and David P. Young
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04083G, Paper
A series of nickel(II) aryloxide ([Ni(OAr)2(py)x]) precursors was synthesized from an amide-alcohol exchange using [Ni(NR2)2] in the presence of pyridine (py). The H-OAr selected were the mono- and di-ortho-substituted 2-alkyl...
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00090A, Paper
Sequential formation of β-Ca3(PO4)2r-TiO2 composites from the solution precursors that yields good mechanical strength.
Nathalie Bridonneau, Luca Rigamonti, Giordano Poneti, Dawid Pinkowicz, Alessandra Forni and Andrea Cornia
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00248C, Paper
Molecular structures and magnetic properties of the homoleptic iron(II) compounds [Fe(bpp-COOMe)2](ClO4)2 (1) and [Fe(bpp-triolH3)2](ClO4)2 (2) have been investigated to ascertain their spin crossover (SCO) behaviour. In these hexacoordinated complexes, the...
Ismael Marcos, Olaya Domarco, Carlos Peinador, Alberto Fernández, Jesús José Fernández Sánchez, Digna Vazquez-Garcia and Marcos D. García
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04476J, Paper
We report herein the self-assembly of a series of new square and rectangular-shaped dinuclear M2L2 metallacycles (M = Pd(II)/Pt(II)), receptors self-assembled in water from four different N-monoalkyl-4,4’-bipyridinium derivatives as ligands...
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00005G, Paper
Two new MOFs have been constructed by the Dimroth rearrangement of the in situ generated organic ligand 5-((2H-tetrazol-5-yl)amino)isophthalic acid (H3L).
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04866H, Paper
Keggin-type polyoxometalates (H3PMo12O40, H3PW12O40 and H4SiW12O40) were supported chemically on silicacoated perovskite-type LaMnO3 nanoparticles for the removal of organic pollutants in water.
Ahmet Nedim Ay, Hande Akar, Adnana Zaulet, Clara Viňas, Francesc Teixidor and Birgul Zumreoglu-Karan
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00100B, Paper
Carborane-intercalated layered double hydroxide nanohybrids (CB-LDH) and a magnesium ferrite (MF) supported-CB-LDH core–shell nanocomposite (CB-LDH@MF) are reported.
Dmitri V. Konarev, Salavat S. Khasanov, Manabu Ishikawa, Akihiro Otsuka, Hideki Yamochi, Gunzi Saito and Rimma N. Lyubovskaya
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00336F, Paper
Complexes of metal-free phthalocyanine (H2Pc) and decamethylmetallocenium cations were obtained and studied.
Alexandros A. Kitos, Constantina Papatriantafyllopoulou, Anastasios J. Tasiopoulos, Spyros P. Perlepes, Albert Escuer and Vassilios Nastopoulos
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04830G, Paper
A series of polynuclear FeIII clusters with unique or rare topologies and interesting magnetic properties have been obtained from the reactions of iron(II)/(III) sources and hydroxyphenone ligands.
Włodzimierz Buchowicz, Łukasz Banach, Radosław Kamiński and Piotr Buchalski
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04811K, Communication
A remarkable helical complex with a chelating Cp-NHC ligand has been synthesised via olefin metathesis in the Ni(II) coordination sphere.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00150A, Paper
Using an improved, chromatography-free dipyrrin synthesis, a new family of actinide dipyrrinate complexes has been synthesized.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00342K, Communication
Two intermetalloid Matryoshka cluster anions [Sb@Pd12@Sb20]3−,4− were isolated as [K(2,2,2-cryptand)]+ and [K(18-crown-6)]+ salt, respectively, revealing a feasible route toward controlled isolation of intermetalloid clusters and their potential in electron reservoir materials.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04759A, Paper
Novel core–shell nanostructured hollow carbon nanospheres@nickel cobalt double hydroxides (HCNs@NiCo-LDH) were fabricated by a facile hydrothermal method, exhibiting a high specific capacitance (2558 F g−1 at 1 A g−1) and outstanding rate capability.
Jingchao Zhang, Baiqing Yuan, Shufang Cui, Nana Zhang, Jingjing Wei, Xiao Wang, Daojun Zhang, Renchun Zhang and Qisheng Huo
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00435D, Paper
Porous Co3V2O8 nanoroses and NiCo2V2O8 nanoplates served as effective electrocatalysts in the oxygen evolution reaction and as electrodes of supercapacitors.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04731A, Paper
Strontium hydroxyapatite (Sr10(PO4)6(OH)2) nanopowders doped with Eu3+ ions were synthesized via a microwave-stimulated hydrothermal method and were heat-treated in the temperature range of 450–650 °C for 3 h.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04817J, Paper
The coordination non-innocence of antimony toward Cl in ClNi(o-(Ph2P)C6H4)3SbCl results from both structural and electronic effects.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04612F, Paper
When silylene transfer reactions are irreversible, the steric hinderance of the alkene and ligands on the metal catalyst does not influence stereoselectivity, but when the reaction is reversible (above), silyene transfer reactions can be diastereoselective.
Matthieu Koepf, Jesse J Bergkamp, Anne-Lucie Teillout, Manuel J. Llansola Portoles, Gerdenis Kodis, Ana L Moore, Devens Gust and Tom A Moore
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C6DT04647A, Paper
The association of different metals in stable, well-defined molecular assemblies remains a great challenge of supramolecular chemistry. In such constructs, the emergence of synergism, or cooperative effects between the different...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00173H, Paper
The thermo-labile triazenide Na[tBu3SiNNNSiMe3] was prepared by the reaction of Me3SiN3 with Na(thf)2[SitBu3] in pentane at -78°C. Treatment of Na[tBu3SiNNNSiMe3] with an excess of carbon dioxide in pentane at -78°C...

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38 citations
The emerging new solid-state LED phosphors and the methodologies for their development have been reviewed in this perspective.
DOI: 10.1039/C6DT01230B
Published: 30 May 2016
64 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015
41 citations
The versatile role of PVP in nanoparticle synthesis is discussed in this Perspective article.
DOI: 10.1039/C5DT02964C
Published: 22 Sep 2015

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