Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 3.806 48 Issues per Year Indexed in MEDLINE
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Rita Mazzoni, Thomas Pasini, Gavino Solinas, Valerio Zanotti, Stefania Albonetti, Fabrizio Cavani, Angelo Vaccari, Andrea Mazzanti and Silvia Ranieri
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00304G, Paper
The bio-based substrate and target product 2,5-bishydroxymethylfuran (BHMF) demonstrated to influence the reaction kinetics in the homogeneous reduction of 5-hydroxymethylfurfural (HMF) catalyzed by the Ru-based Shvo’s catalyst. A combined experimental...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00762J, Communication
It exists a rare all-thiol-stabilized [Ag28(StBu)23]5+ ({Ag28S23} for short) nanocluster with a “crab-like” shape in compound [Ag28(StBu)23](CF3COO)5•8CH3OH (1), which has been synthesized by the self-assembly of AgStBu with CF3COOH, Et3N...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00798K, Paper
Two dimensional (2D) square-like bismuth oxyiodine (BiOI) nanosheets with thickness of about 10 nm and exposed {001} facets are obtained by a facile hydrothermal route without any surfactant and special...
Joseph Becica, Andrew B Jackson, William G. Dougherty, William S. Kassel and Nathan M West
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00734D, Paper
The chiral bis-tropolonate tungsten(II) tricarbonyl compound, (trop)2W(CO)3 (1), has been synthesized and structurally characterized. This seven-coordinate compound readily loses two carbonyl ligands to preferentially bind a series of π-bonding substrates...
Margit Kriechbaum, Daniela Otte, Manuela List and Uwe Monkowius
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00695J, Paper
CsBr3 was investigated as a new and convenient oxidant for NHC-Au(I) complexes (NHC = imidazo[1,5-a]pyridin-3-ylidene) for the preparation of the respective Au(III) complexes. The Au(I) complexes were synthesized by the...
Sebastien Gauthier, Bertrand Caro, Françoise ROBIN-LE GUEN, Nattamai Bhuvanesh, John A. Gladysz, Nicolas LePoul, Laurianne Wojcik, Aurélien Planchat, Yann Pellegrin, errol blart, Denis Jacquemin and Fabrice ODOBEL
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00301B, Paper
In this joint experimental-theoretical work, we present the synthesis and optical and electrochemical characterization of five new bis-acetylide platinum complex dyes end capped with diphenylpyralidene moieties, as well as their...
Jérémy Chaignon, Salah-Eddine Stiriba, Francesc Lloret, Consuelo Yuste, guillaume pilet, Laurent Bonneviot, Belen Albela and Isabel Castro
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C3DT53636J, Paper
Clickable ligands like N,N’-bis((pyridin-2-yl)methyl)prop-2-yn-1-amine (L1) and N-((1-methyl-1H-imidazol-2-yl)methyl)-N-(pyridin-2-ylmethyl)prop-2-yn-1-amine (L2) have been used to synthesise a series of manganese(II) complexes for grafting on appropriate solid supports. These ligands mimic the 2-His-1-carboxylate facial...
Chandan Mukherjee, Veronika Hoeke, Anja Stammler, Hartmut Bögge, Juergen Schnack and Thorsten Glaser
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00670D, Paper
The chiral triplesalen ligand H6chandRR has been used to synthesize the chiral heptanuclear complexes [{(chandRR)MnIII3}2{FeII(CN)6}](ClO4)2 (RR[MnIII6FeII](ClO4)2) and [{(chandRR)FeIII3}2{FeII(CN)6}](ClO4)2 (RR[FeIII6FeII](ClO4)2), which have been characterized by single-crystal X-ray diffraction, mass spectrometry, elemental...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00110A, Communication
A dual-responsive Green-light-emitting supramolecular metal hydrogel (G-gel) was prepared by reaction of a simple hydrazide-functionalized benzimidazole ligand (L) with Tb(NO3)3. The green luminescence of gelator L is enhanced in G-gel...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00866A, Paper
To explore the principle of chiral induction for inorganic clusters, chiral organic cations with two stereocenters R- and S-BPEA are used to encapsulate a series of POMs bearing different structures...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00671B, Paper
Many transition-metal complexes easily change their spin state S in response to external perturbations (spin crossover). Determining such states and their dynamics can play a central role in the understanding...
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C3DT53474J, Paper
Magnetic mesoporous titanium dioxide–graphene oxide (Fe3O4@mTiO2@GO) with a large surface area and a good magnetic responsiveness was synthesized by immobilizing a mesoporous titanium dioxide (mTiO2) shell on the surface of magnetic Fe3O4 nanoparticles prior to binding with graphene oxide (GO).
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C3DT53505C, Paper
Based on quinoline-2,3-dicarboxylic acid (H2L), two 1D metal(II) complexes were synthesized, which exhibit electrocatalytic activities for the degradation of methyl orange (MO), which is probably associated with their electrocatalytic activities for the H2 evolution reaction from water.
Andrey Y. Khalimon, Nicolas A. McLeod, Stanislav K. Ignatov, Andrey I. Okhapkin, Lyudmila G. Kuzmina, Judith A. K. Howard and Georgii I. Nikonov
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00154K, Paper
Coupling of (tBuN)2Mo(PMe3)(L) (L = PMe2, C2H4) with PhSiH3 results in a product of triple silane addition, (tBuN){μ-tBuN(SiHPh)2}Mo(H)(SiH2Ph)(PMe3)2 (3), formation of which proceeds via a series of silanimine and Si–HMo agostic species.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C3DT53561D, Paper
Doughnut-like, concave hierarchical structures of orthorhombic Sb2WO6 were firstly prepared and were found to exhibit excellent visible-light-driven photocatalytic performance.
Lijuan Yu, Wenye Shi, Li Lin, Yuwen Liu, Renjie Li, Tianyou Peng and Xingguo Li
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00411F, Paper
Novel highly asymmetric zinc tetraazaporphyrin (TAP) derivatives (Zn-tri-TAPNc and Zn-tri-PcNc) with one carboxyl and three tert-butyl peripheral substituent groups for dye-sensitized solar cells were synthesized.
Albert Poater, Sai Vikrama Chaitanya Vummaleti and Luigi Cavallo
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00321G, Paper
The formation of an oxoiron(IV) complex is achieved from iron(II) just pumping electrons and oxygen, with a particular innocent role of Sc3+.
Zhiqiang Ye, Run Zhang, Bo Song, Zhichao Dai, Dayong Jin, Ewa M. Goldys and Jingli Yuan
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00179F, Paper
A functional ruthenium(II) complex that can specifically respond to hypochlorous acid with remarkable luminescence enhancement has been successfully developed.
Ai-xiang Tian, Yang Yang, Jun Ying, Na Li, Xiao-ling Lin, Ju-wen Zhang and Xiu-li Wang
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00107A, Paper
Four POM-based compounds with different structures have been synthesized. The existence of –CH3 or not of ligands H2bhpe and H2bdpm plays the key role on these structures.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C3DT53641F, Paper
A novel diamine-functionalized mesoporous SBA-15 was developed for the colorimetric detection and removal of Cu2+ ions from water.
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00688G, Paper
Cu2ZnSnSe4 is a prospective material as absorber in thin film solar cells due to its many advantages including direct band gap, high absorption coefficient, low toxicity, and relative abundance (indium-free)...
Athanasia Kostopoulou, Sabareesh K. P. Velu, Kalaivani Thangavel, Francesco Orsini, Konstantinos Brintakis, Stylianos Psycharakis, Anthi Ranella, Lorenzo Bordonali, Alexandros Lappas and Alessandro Lascialfari
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00024B, Paper
1 H-NMR relaxometric experiments over an extended frequency range show that ferrimagnetic colloidal nanoclusters exhibit enhanced transverse relaxivity, r2.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00613E, Perspective
The combination of surface modification and intercalation chemistry of inorganic layered materials allows for the design of nanoparticles for specific applications.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00318G, Paper
Self-assembly occurs spontaneously through π-stacking in solution for calix[4]arenes derivatised at both rims with pendant aromatic rings. Zinc ion titration studies, carried out on 3, up to a 1 : 4 ligand to metal ratio, did not disrupt the self-assembly process.
Toby J. Blundell, Fiona R. Hastings, Benjamin M. Gridley, Graeme J. Moxey, William Lewis, Alexander J. Blake and Deborah L. Kays
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00647J, Paper
The analysis of three series of two-coordinate Group 12 bis-terphenyl complexes highlights how subtle changes to ligand properties, particularly sterics, and, to a smaller extent, electronics have a large effect on the solid state structures adopted.

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