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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.177 48 Issues per Year Indexed in Medline
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Alyn Chad Edwards, Christoph Wagner, Andreas Geist, Neil A. Burton, Clint Alan Sharrad, Ralph W. Adams, Robin Pritchard, Petra J. Panak, Roger Whitehead and L Harwood
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02474B, Paper
The first examples of 4,7-disubstituted 2,9-bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-1,2,4-benzo-triazin-3-yl)-1,10-phenanthroline (CyMe4-BTPhen) ligands are reported herein. Evaluating the kinetics, selectivity and stoichiometry of actinide(III) and lanthanide(III) radiotracer extractions has provided a mechanistic insight into the...
Terry Chu, Lee Belding, Prashanth K. Poddutoori, Art van der Est, Travis Dudding, Ilia Korobkov and Georgii I. Nikonov
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02001A, Paper
Stepwise reduction of the diiminopyridine (dimpyr) complex, dimpyrZnCl2, by KC8 leads to molecular zinc compounds dimpyrZnCl (2) and dimpyrZnCl(DMAP) (3, DMAP = 4-dimethylaminopyridine), which were characterized by X-ray diffraction and...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02587K, Paper
Two new hetero-tetranuclear nickel(II)/cadmium(II) complexes, a cubane [(CH3CO2)2Ni2(L1)2Cd2(NCS)2] (1) and a linear tetramer [(DMSO)2NiL2Cd(NCS)(µ1,3-SCN)Ni(DMSO)L2Cd(NCS)2] (2) {where H2L1 = N,N'-bis(3-methoxysalicylidene)propane-1,3-diamine and H2L2 = N,N'-bis(3-ethoxysalicylidene)propane-1,3-diamine are potential hexadentate compartmental Schiff bases}, have...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02383E, Paper
A new iridium(III) complex containing coumarin derivative as the cyclometalated ligand (L) and a carbazole-functionalized β-diketonate (Cz-acac-allyl) as the ancillary ligand, namely, Ir(III) bis(3-(pyridin-2-yl)coumarinato-N,C4)(1-(9-butyl-9H-carbazol-3-yl)hept-6-ene-1,3-dionato-O,O) [Ir(L)2(Cz-acac-allyl)], was firstly synthesized as the...
Isabela Cristina Aguiar de Souza, Leticia Villafranca Faro, Daniel Tadeu Gomes Gonzaga, Carlos Basílio Pinheiro, Fernando C. da Silva, Vitor F. Ferreira, Fabio da Silva Miranda, Marciela Scarpellini and Mauricio Lanznaster
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02456D, Communication
Three novel cobalt(III)-triazole complexes with structural and redox properties suitable for hypoxia-activated drug delivery were obtained. A major influence of the ancilary ligands (TPA, py2en, py2enMe2) on the electronic properties...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02195F, Paper
Two new coordination polymers, CPO-71-Cu and CPO-72-La, were synthesized by solvothermal methods using 4,4′-dimethoxy-3,3′-biphenyldicarboxylic acid as the organic linker. The two-dimensional frameworks of both CPO-71-Cu and CPO-72-La exhibit the sql topology.
Dieter Sorsche, Markus Schaub, Frank W. Heinemann, Johannes Habermehl, Susanne Kuhri, Dirk Guldi, Julien Guthmuller and Sven Rau
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01643J, Paper
Electrostatic repulsion between gold(III) coordination spheres exceeds π-stacking for the first time in a tpphz-bridged dinuclear PMD model complex.
Mauro Carraro, Martino Gardan, Andrea Sartorel, Chiara Maccato and Marcella Bonchio
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01951J, Communication
Polyoxometalate (POM)-based polyanionic fluorosurfactants self-assemble in hexafluoroisopropanol (HFIP) and activate hydrogen peroxide (H2O2), yielding efficient epoxidation of terminal alkenes.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02535H, Communication
A chlorinated cobalt porphyrin (CoClPS) shows extremely high resistance against singlet oxygen and activity for photochemical water oxidation.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02238C, Paper
Hybrid α-Fe2O3@Co3O4 and α-Fe2O3@MnCo2O4 composites are successfully synthesized on flexible carbon cloth, respectively. These as-obtained products as the supercapacitor electrodes show enhanced discharge areal capacitance.
Amaia Iturmendi, Nestor García, E. A. Jaseer, Julen Munárriz, Pablo J. Sanz Miguel, Victor Polo, Manuel Iglesias and Luis A. Oro
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02571D, Paper
Ir(I) complexes featuring an N-heterocyclic olefin ligand (NHO) have been tested in the transfer hydrogenation reaction; this representing the first example of the use of NHOs as ancillary ligands in catalysis.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02322C, Paper
Four heteroleptic Group 12 perchlorate complexes of 2,6-bis[((2-pyridinylmethyl)oxy)methyl]pyridine with coordination numbers between six and nine were prepared and investigated.
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02023B, Paper
Using the multifunctional ligand H4L (2,2′-bipyridinyl-5,5′-diphosphonic acid), a new family of 0D-3D inorganic–organic hybrid-materials was prepared and characterized by single crystal diffraction and magnetic measurements.
Hang Xu, Chun-Shuai Cao, Xiao-Min Kang and Bin Zhao
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02213H, Perspective
We discuss the construction of lanthanide-based metal–organic frameworks, their applications in possible detection mechanisms, and summarize some examples of Ln-MOFs as luminescent probes.
Tatiana Spallek, Oliver Heß, Melanie Meermann-Zimmermann, Christian Meermann, Michael G. Klimpel, Frank Estler, David Schneider, Wolfgang Scherer, Maxim Tafipolsky, Karl W. Törnroos, Cäcilia Maichle-Mössmer, Peter Sirsch and Reiner Anwander
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01568A, Paper
Mono, bis, and tris(amido) derivatives are readily available applying salt metathesis protocols.
Wenna Liu, Junhong Chen, Tao Yang, Kuo-Chih Chou and Xin-mei Hou
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02049F, Paper
The coaxial nanocables (CNs) of SiC core with SiO2 shell in large scale were fabricated by a simple and low cost method. The thickness of SiO2 shell could be controlled...
Akhil R Chakravarty, Md Kausar Raza, Koushambi Mitra, Abhijith Shettar, Uttara Basu and Paturu Kondaiah
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02590K, Paper
Platinum(II) complexes, viz. [Pt(L)(cur)] (1), [Pt(L)(py-acac)] (2) and [Pt(L)(an-acac)] (3), where HL is 4,4’-bis-dimethoxyazobenzene, Hcur is curcumin, Hpy-acac and Han-acac are pyrenyl and anthracenyl appended acetylacetone, were prepared, characterized and...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02128J, Paper
The electronic structures of dinuclear copper complexes of the general formula [GFA(CuX2)2], where X = Br or Cl and GFA denotes a redox-active bridging Guanidino-Functionalized Aromatic ligand, were analysed and compared.
Mrianthi KAFENTZI, Maylis Orio, Marius Reglier, Shenglai Yao, Uwe Kuhlmann, Peter Hildebrandt, Matthias Driess, A. Jalila Simaan and Kallol Ray
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02391F, Paper
Two new heterobimetallic [LNiO2Cu(RPY2)]+ (RPY2 = N-substituted bis 2-pyridyl(ethylamine) ligands with R= Indane, 3a or R=Me; 3b) complexes have been spectroscopically trapped at low temperatures. They were prepared by reacting...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02038K, Paper
Heterostructures consisted of two semiconductors have merited considerable attention in photocatalytic applications due to the synergistic effect in the complex redox processes. The incorporation of solid solutions into such architectures...
M Concepcion Gimeno, Alejandro Gutiérrez, Antonio Laguna and Carlos Cativiela
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02000C, Paper
Unprecedented gold(I) bioconjugates bearing non-proteinogenic amino acid 4-mercaptoproline species as bioorganic ligands have been prepared. Firstly, the synthesis of Boc-Pro(SH)-OMe (1) has been accomplished by standard procedures. The subsequent reaction...
Aixiang Tian, Yan Tian, Yali Ning, Xue Hou, Huaiping Ni, Xuebin Ji, Guocheng Liu and Jun Ying
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02233B, Paper
Through using conjugate ring-riched pyrazine and quinoxaline derivatives, five new Keggin based compounds, namely, [AgI3L12(H2O)2(PMo12O40)] (1), [AgI4L15(SiMo12O40)] (2), [AgI6L26(PMo12O40)2] (3), [AgI2L22(C16H36N)2)(SiMo12O40)] (4), [CuI3L23(PMo12O40)] (5) (L1 = 2,3-diphenyl-pyrazine, L2 = 2,3-diphenyl-quinoxaline,...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02701F, Paper
The coordination chemistries of the tetradentate N2O2-type ligands N-(2-pyridylmethyl)iminodiethanol (H2pmide) and N-(2-pyridylmethyl)iminodiisopropanol (H2pmidip) have been investigated with nickel(II) and cobalt(II/III) ions. Three novel complexes prepared and characterized are [(Hpmide)2Ni3(CH3COO)4] (1),...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02469F, Paper
Dithienogermole (DTG) is a germanium-bridged bithiophene system that has been applied as a building unit of conjugated materials for organic electronic devices, including organic photovoltaics and organic light emitting diodes....
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT02415G, Communication
Photoluminescent pincer-like Pd(II) and Pt(II) complexes with a rare tridentate N^C^N ligand with a six membered NHC central core are described. Solid-state packing exhibits M(II)⋯M(II) and π–π interactions.

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95 citations
Porphyrin sensitizers have exhibited power conversion efficiencies that are comparable to or even higher than those of well-established highly efficient DSSCs based on ruthenium complexes.
DOI: 10.1039/C4DT02756F
Published: 10 Nov 2014
38 citations
Ultrasonic power was investigated as a dispersion and mixing tool to accelerate the adsorption of SO, MB, Pb2+ ions and Cr3+ ions onto the novel Fe3O4-NPs-AC composite.
DOI: 10.1039/C5DT01504A
Published: 13 Jul 2015
42 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015

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