Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
 
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Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT04270H, Paper
Nine coordination polymers based on dinuclear metal units/metal-carboxylate chains and 1,1′:4′,1′′-terphenyl-2′,4,4′′,5′-tetracarboxylic acid have been synthesized and structurally characterized. Complexes 2 and 9 show the weak ferromagnetic interactions.
 
Zoi G. Lada, Amaia Soto Beobide, Aikaterini Savvidou, Catherine P. Raptopoulou, Vassilis Psycharis, George A. Voyiatzis, Mark M. Turnbull and Spyros P. Perlepes
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03595G, Paper
A novel CuII-assisted transformation of acetylacetone dioxime to coordinated quinoxaline has been discovered.
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04207D, Paper
An integrated package that uses structural, first principles and thermodynamic approaches is expected to play a significant role in advancing our knowledge of nanocatalysts.
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03944H, Paper
This report describes the synthesis and characterization of a family of unsymmetrical NCN pincer Ni(II) complexes 2-8 with NHC-triaizole arms. All of these complexes have been fully characterized by X-ray...
 
Anette Petuker, stephan mebs, Nils Schuth, Philipp Gerschel, Matthew L. Reback, Bert Mallick, Maurice van Gastel, Michael Haumann and Ulf-Peter Apfel
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04048A, Paper
Herein, we report on the versatile reactions of CH3C(CH2PPh2)3 as well as CH3Si(CH2PPh2)3 derived Nicomplexes. While Ni[CH3C(CH2PPh2)3] complexes reveal high stability, the Ni[CH3Si(CH2PPh2)3] analogs showed rapid decomposition at room temperature...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03948K, Communication
A quinoline-based heptadentate ligand, N,N,N’,N’-tetrakis(2-quinolylmethyl)-2,6-bis(aminomethyl)pyridine (TQLN), exhibits a Zn2+-specific fluorescence increase at 428 nm, which is assigned to excimer emission (IZn/I0 = 38, ICd/IZn = 24%, φZn = 0.069). In...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03638D, Paper
We report a study on the structure directing effects of functional groups and counterions. The aim was to find a facile and high yielding synthetic procedure to obtain polyoxometalate (POM)...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04474C, Paper
By the combination of carboxylate and phosphonate ligands, we herein report a nanosized H2[Ti18(μ3-O)14(μ2-O)6(O3P-Phen)2(PA)16(OPri)14] (PTC-51) (HPA = propionic acid, O3P-Phen = phenyl phosphonate), whose structure can be seemed as the...
 
Yan Mei, Yanhui Su, Zheng Li, Shiqi Bai, Mengyu Yuan, Lu Li, Zheng Yan, Jun Wu and Lian-Wen Zhu
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03887E, Paper
A novel BiOBr@TiO2/carbon hybrid framework as a continuous flow sunlight water purification system has been reported in the present work.
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04091H, Paper
Four Ir(III) complexes have been prepared, showing structural and luminescence modulation upon varying their substituent groups or protonation/deprotonation state.
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04059D, Paper
Complexes HL1 and HL2 and 1–4 exhibit a stronger ECL emission and complexes 1–4 exhibit higher stability.
 
Banashree Deka, Tukki Sarkar, Samya Banerjee, Arun Kumar, Sanjoy Mukherjee, Sasanka Deka, Kandarpa K. Saikia and Akhtar Hussain
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03660K, Paper
Mixed-ligand ferrocenyl copper(II) complexes target the mitochondria of cancer cells showing remarkable cytotoxicity against HeLa and MCF-7 cancer cells while being much less toxic to MCF-10A normal cells.
 
Jiahui Zhu, Qi Liu, Zhanshuang Li, Jingyuan Liu, Hongsen Zhang, Rumin Li, Jun Wang and G. A. Emelchenko
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03227C, Paper
A novel composite adsorbent, consisting of three-dimensional honeycomb-like porous carbon and MnO2 nanowires (HLPC/MnO2), has been successfully synthesized and is an excellent adsorbent for removing uranium(VI) ions from aqueous solutions.
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04118C, Communication
Two novel core-shell Ni-Ln nanosized clusters, Na4(H3O)4[Nd38Ni42.5(ID(A)42(OA(c)4(CH3CH2OH)2(CO3)18(μ3-OH)62(μ3-O)6(H2O)12]Cl6•26H2O (1) and Na[Pr42Ni38(μ3-OH)71(μ3-O)4(ID(A)38(NH2CH2COO)2(OA(c)2(CH3CH2OH)2(CO3)16(H2O)6Cl7]Cl3•37H2O (2) (IDA=iminodiacetat(e), were successfully prepared using Cl- anion and the flexible ligand iminodiacetic acid. Structural analysis indicates that the discrete...
 
Schirin Hanf, Raul Garcia-Rodriguez, Sascha Feldmann, Andrew David Bond, Evamarie Hey-Hawkins and Dominic S Wright
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04390A, Paper
In the current work a range of multidentate pyridyl-phosphine ligands are synthesised with tuneable electronic and steric character, through the incorporation of a variety of alcohols into (amino)pyridyl-phosphine frameworks. The...
 
Douglas W. Crandell, Haiyang Zhu, Xiaofan Yang, John Hochmuth and Mu-Hyun Baik
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03894H, Paper
The copper-exchanged aluminosilicate zeolite SSZ-13 is a leading catalyst for the selective catalytic reduction of NO.
 
Brain Abeykoon, Jean-Marc Grenèche, Erwann Jeanneau, Dmitry Chernyshov, Christelle Goutaudier, Aude Demessence, Thomas Devic and alexandra fateeva
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04208B, Paper
Two new 3D porphyrin-based metal organic frameworks were obtained by solvothermally reacting iron (III) chloride, a free base (5,10,15,20-Tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrin) (H2TTPP) and either pyrazine or DABCO. Both MOFs displayed a 3-D...
 
Stephan R Mathis (II), Saki T Golafale, John Bacsa, Conrad Wayne Ingram, Alexander Steiner, F. Patrick Doty, Elizabeth Auden and Khalid Hattar
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT03755K, Paper
Ultra large pore isostructural metal organic frameworks (MOFs) which exhibit both photoluminescence and scintillation properties, were synthesized from trans - 4, 4’-stilbenedicarboxylic acid (H2L) and trivalent lanthanide (Ln) metal salts...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04512J, Paper
The paper reports the formation of unprecedented iridium(III)-derived topological macrocycles. Discrete molecular Borromean rings 1 and 3 in pure form are synthesized via coordination-driven self-assembly of acceptor [(Cp*Ir)2(OO∩OO)](OTf)2 ( Cp*=...
 
Ana Arauzo, Elena Bartolomé, A C Benniston, Silvia Melnic, Sergiu Sova, Javier Luzón, Pablo Javier Alonso, Anne-Laure Barra and Juan Bartolomé
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT02509A, Paper
In this paper we present the characterization of the complex with formula [Mn2Ca2(hmp)6(H2O)4(CH3CN)2](ClO4)4 (1), where hmp-H = 2-(hydroxymethyl)pyridine. Compound 1 crystallizes in the monoclinic space group C2/c with the cation...
 
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT04268F, Paper
Two new dysprosium complexes, [Dy(H5L)(NO3)2(CH3OH)2]∙4CH3OH (1), [Dy2(H5L)2(NO3)4(H2O)2]∙10CH3OH (2) were isolated from the reaction of a novel 1,8-naphthalenediol-based ligand N,N'-((1,8-dihydroxynaphthalene-2,7-diyl)bis(methanylylidene))bis(2-hydroxybenzohydrazide), H6L with dysprosium(III) nitrate upon crystallization at different temperatures. Because of...
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04266J, Communication
A unique dysprosium selenoarsenate(III) contains large oligomeric cluster [As3Se6]3− anions with binuclear dysprosium complexes as counterions, and exhibits a photocurrent response and slow magnetic relaxation behavior.
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03488H, Paper
Reported are the syntheses, structures and magnetic properties, also by NMR spectroscopy in solution, of a series of 13 linear trinuclear 3d–4f compounds with a lanthanide(III) surrounded by two NiII ions, NiII2LnIII, where the central LnIII is hexacoordinate.
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03814J, Paper
Comparison of the results of EDA-NOCV for the M←C bond in [NHC(R) → MR′] and [{P(Ph)3CHR} ← MCl] complexes reveals that the phosphorus ylides are slightly better σ-donors and weaker π-acceptors than the corresponding NHC(R).
 
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03872G, Paper
Octaaminospherosilicates have been synthesized using hydrogenation over Pd/C and were reacted in situ with propyl isocyanate to give octafunctional hydrogen bond bearing spherosilicates [CnH2n(NHCONH)C3H7]; (n = 4, 5, 6, 11).
 

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23 citations
The emerging new solid-state LED phosphors and the methodologies for their development have been reviewed in this perspective.
DOI: 10.1039/C6DT01230B
Published: 30 May 2016
135 citations
Porphyrin sensitizers have exhibited power conversion efficiencies that are comparable to or even higher than those of well-established highly efficient DSSCs based on ruthenium complexes.
DOI: 10.1039/C4DT02756F
Published: 10 Nov 2014
59 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015

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