Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 3.806 48 Issues per Year Indexed in MEDLINE
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Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01014K, Communication
A dinuclear Cu(II) complex [Cu2(L3)2]∙2H2O, having an unprecedented in situ formed diphenolate 2,6-piperidin-4-one derived ligand produced from the flexible Schiff-base ligand HL1, can be yielded as a side product in...
Oleg A. Varzatskii, Sergey V. Shul'ga, Alexander S. Belov, Valentin V. Novikov, Alexander V. Dolganov, Anna V. Vologzhanina and Yan Z. Voloshin
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01557F, Paper
Iron(II) dibromo- and diiodoclathrochelates undergo copper(I)-promoted reductive homocoupling to C–C conjugated dibromo- and diiodo-bis-clathrochelates.
Samadhan R. Patil, Jitendra P. Nandre, Devising Jadhav, Shilpa Bothra, S. K. Sahoo, Manisha Devi, Chullikkattil P. Pradeep, Pramod P. Mahulikar and Umesh D. Patil
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01516A, Paper
An imatinib intermediate was developed for the colorimetric sensing of Cu2+ ions in aqueous solution.
L. Wu, B. Wang, Y. Zhang, L. Li, H. R. Wang, H. Yi, Y. F. Kong and J. J. Xu
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01524J, Paper
Abnormal strong absorptions are observed in a Mg-based host KMgBO3 doped by single Mn2+ ions, which lead to a strong red emission band centered at 636 nm.
Francesco Nastasi, Fausto Puntoriero, Scolastica Serroni, Sebastiano Campagna, Jean-Hubert Olivier and Raymond Ziessel
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01127A, Paper
Complex 1 exhibits a formally forbidden energy transfer from the metal-based triplet to the fluorescent Bodipy singlet state.
Keith Gordon, Holly van der Salm, Christopher B Larsen, James R. W. McLay, Michael G Fraser and Nigel Thomas Lucas
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01415D, Paper
A series of dipyrido[3,2-a:2',3'-c]phenazine (dppz)-based ligands have been synthesised in which phenyl or phenyl-ethynyl linkers are terminated by $^{t}$Bu or CN units. The corresponding [ReCl(CO)$_3$(L)] complexes are also prepared. Electrochemistry...
Sarat Chandra Patra, Amit Saha Roy, Vadivelu Manivannan, Thomas Weyhermueller and Prasanta Ghosh
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01241K, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
A C Benniston, Michael Probert, Silvia Melnic, Constantin Ion Turta, Elena Bartolomé, Juan Bartolomé, Ana Arauzo and Ross W Harrington
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01518E, Paper
The room temperature reaction of [Mn2O2(bipy)4](ClO4)3 (bipy = 2,2’-bipyridine) with Ca(CHCl2COO)2 in methanol produced a yellow crystalline material. The X-ray determined structure comprises of a multiple calcium(II) carboxylate bridged rod-like...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01169D, Paper
Both Zeolite A/L and SBA-15 have been used to assemble novel photofunctional multi-component lanthanide hybrid materials. Microporous zeolites A/L are firstly functionalized by embedding lanthanide or zinc complexes (TTA =...
Amit Kumar, Rampal Pandey, Rakesh Kumar Gupta, Mrigendra Dubey and Daya Shankar Pandey
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01887G, Communication
The synthesis and characterization of tetranuclear copper |2 + 4| cubanes have been described. Notably, hydrated copper(II) salts/precursors reacted with various ligands to afford cubanes via copper mediated C–O bond formation, while anhydrous salt yielded the mononuclear complex.
Sourav Chakraborty, Snehasish Mondal, Sourav Bhowmick, Jianqiu Ma, Hongwei Tan, Subhadip Neogi and Neeladri Das
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01298D, Paper
New triptycene based organometallic complexes have been synthesized and subsequently used for design of the triptycene motif containing nanoscalar trigonal prisms. Flexible 3,3′-bipyridine is employed as a donor unit.
Shaobo Cui, Yongsheng Zhu, Wen Xu, Pingwei Zhou, Lei Xia, Xu Chen, Hongwei Song and Wei Han
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01792G, Paper
Three-dimensional (3D) inverse opal photonic crystals can not only modulate the emissions of the inserted emitters, they also have the advantage of a large surface to volume ratio, the concentration quenching and energy transfer process can be greatly suppressed.
Hamdi BEN YAHIA, Daisuke Mori, Masahiro Shikano, Hironori Kobayashi and Yoshiyuki Inaguma
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01418A, Paper
The new compound HP-Na2Co[PO4]F was synthesized by high pressure solid state reaction and its crystal structure was determined from single crystal X-ray diffraction data. The physical properties of HP-Na2Co[PO4]F were...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01609B, Paper
Ultrathin two-dimensional (2D) nanosheets of layered transition-metal chalcogenide are theoretically and technologically intriguing. However, it still remains a great challenge to synthesize ultrathin nanosheets because of the lack of an...
Richard O. Reithmeier, Simon Meister, Bernhard Rieger, Armin Siebel, Martin Tschurl, Ulrich Heiz and Eberhardt Herdtweck
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01717J, Paper
The photocatalytic performance for the reduction of CO2 as well as deactivation pathways of novel mono- and bimetallic Ir(III) based catalysts are outlined.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01614A, Paper
The metal binding abilities of the GCASCDNCRACKK cyclic peptide towards Zn2+, Cd2+ and Ni2+ ions were studied by potentiometric and spectroscopic methods.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01712A, Communication
In this work, the two-step sintering technique is used to realize a high piezoelectric constant (d33) and wide sintering temperature range (TS) in the 0.955(K0.42Na0.58)(Nb0.96Sb0.04)O3–0.045(Bi0.5K0.5)0.90Zn0.10ZrO3 lead-free ceramics.
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01764A, Communication
The bulky dimeric iron complex, [CpBIGFe(CO)2]2, readily activates elemental chalcogens (S8, Sered and α-Te) under mild conditions at room temperature. Six compounds containing (Q2)2- ligands (Q = S, Se) and...
Seikh Mohammad Habibur Rahman, Stefan Tommy Norberg, Christopher Knee, jordi jacas Biendicho, Stephen Hull and Sten Gunnar Eriksson
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01280A, Paper
BaTi1-xScxO3-δ (x = 0.1 - 0.8) was prepared via solid state reaction. High resolution X-ray powder diffraction was used to characterise the synthesised materials. It was found that low substitution...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01411A, Paper
Four copper(I) complexes [Cu4(3-Cl)4(-dtbpf)2] (1), [Cu6(3-Br)4(2-Br)2(-dtbpf)3] (2), [Cu4(μ2-I)2(μ3-I)2(-dtbpf)2] (3) and [Cu2(1-CN)2(2-dtbpf)2] (4) were prepared using CuX (X=Cl, Br, I, CN) and 1,1′-bis(di-tert-butylphosphino) ferrocene (dtbpf) in 2:1 molar ratio in DCM-MeOH...
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00924J, Paper
Hydrothermal precursor was first obtained by isopropyl titanate reacting with tetramethylammonium hydroxide (TMAOH), which acts as a source of nitrogen and carbon. A facile post-thermal treatment was employed to enhance...
Beata Dudziec, Monika Rzonsowska, Bogdan Marciniec, Dariusz Brząkalski and Bartosz Woźniak
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01950D, Paper
An elegant method for synthesis of a series of new mono- and diethynylsiloxysilsesquioxanes is presented. These compounds are formed via an efficient and highly selective one-pot process from silsesquioxanes with reactive Si–OH groups based on sequential condensation, hydrolysis, chlorination and substitution reactions.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01725K, Communication
A boryl scandium complex supported by the silylene-linked cyclopentadienyl-amido ligand was synthesized for the first time.
Emanuele Petruzzella, Nicola Margiotta, Giovanni Natile and James D. Hoeschele
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01474J, Paper
Interaction of kiteplatin with S-donors is investigated. Kiteplatin–glutathione adducts can further react with 5′-GMP in presence of O2. This unique reaction may account for its activity toward oxaliplatin-resistant colon cancer.
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01400F, Paper
Five new metal complexes constructed from the V-shaped ligand 2,8-di(1H-imidazol-1-yl)dibenzothiophene (DIDP) and different aromatic dicarboxylic acids have been synthesized and structurally characterized in detail. All these complexes show optical semiconductive properties.

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