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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.097 48 Issues per Year Indexed in MEDLINE
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Niamh S. Murray, Sarah Keller, Edwin C. Constable, Catherine E. Housecroft, Markus Neuburger and Alessandro Prescimone
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00517E, Paper
Synthesis, structural, NMR spectroscopic and photophysical properties of the first [Cu(N^N)(POP)]+ complexes with 2,2′:6′,2′′-terpyridines as the N^N domain are described (POP = bis(2-(diphenylphosphino)phenyl)ether).
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03679D, Paper
Silver–N-heterocyclic carbene complexes derived from natural xanthine products have been prepared. Chemosensitivity studies indicate a correlation between cytotoxicity, ligand sterics and hydrophilicity.
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03950E, Paper
In this paper, we report the synthesis and characterization of a novel hybrid inorganic–organic structure formulated as [[Nd2(L1)2(L2)(H2O)7][H2SiW12O40]]n.4H2O (1), in which HL1= nicotinic acid and H2L2=2–hydroxynicotinic acid. Interestingly, L1 and...
María Cecilia Blanco, Sergio Alexis Paz, Vivian M. Nassif, Julio J. Guimpel and Raúl E Carbonio
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03880K, Paper
BaLaCuSbO6 double perovskite has been successfully synthesized by solid state reaction in air atmosphere. Its structure was refined using powder neutron diffraction in the monoclinic space group I 2/m with...
Ying Yang, Rijia Lin, Lei Ge, Lei Hou, P Bernhardt, Tomas Rufford, Shaobin Wang, Victor Rudolph, Yao-Yu Wang and Zhonghua Zhu
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03927K, Paper
The incorporation of Lewis base sites and open metal cation sites into metal-organic frameworks (MOFs) is a potential route to improve selective CO2 adsorption from gas mixture. In this study,...
Sunder N. Dhuri, Yong-Min Lee, Mi Sook Seo, Jaeheung Cho, Dattaprasad D. Narulkar, Shunichi Fukuzumi and Wonwoo Nam
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00809C, Paper
Valuable insights into the hydride-transfer mechanism and C–H bond activation reactions by high-valent trans-dioxoruthenium(VI) species is provided.
Sarote Boonseng, Gavin W. Roffe, John Spencer and Hazel Cox
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00031A, Paper
A method validation, formation reaction via C–H bond activation, and an Atoms in Molecules analysis of symmetrical pincer palladacycles.
Adilson L. Chinelatto, Khalid Boulahya, Domingo Pérez-Coll, Ulises Amador, Corina Tabacaru, Simon Nicholls, Markus Hoelzel, Derek C. Sinclair and Glenn C. Mather
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00170F, Paper
The solid solution Sr3NdNb3−xTixO12−δ (0 ≤ x ≤ 0.06) crystallises with a 12R-type hexagonal perovskite structure and exhibits increasing proton conductivity with x.
Yonggang Wang, Ting Wen, Lingyun Tang, Liuxiang Yang, Wenge Yang and Yusheng Zhao
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00426H, Paper
Structural and photoluminescence behaviors of Mn4+-doped BaTiF6 phosphor under hydrostatic pressure have been studied using in situ XRD, Raman and spectroscopy techniques.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00614G, Communication
A zinc tetrazolate approach to solid-state photochemical [2 + 2] cycloaddition and in situ fluorescence study.
R. Haiges, G. Bélanger-Chabot, S. M. Kaplan and K. O. Christe
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00888C, Paper
3,5-Dinitro-1H-1,2,4-triazole was isolated as an impact and friction sensitive solid, and fully characterized for the first time. The compound decomposes explosively upon heating to 170 °C. Impurities might lower the decomposition temperature and increase the sensitivity of the material.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00723B, Paper
Colorless and stable metal-containing ionic liquids were prepared from cationic Ru(II) sandwich complexes, and their liquid properties were investigated in detail.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03774J, Paper
Single-crystal tetragonal α-MnO2 nanorods with different amounts of gold nanoparticles (NPs) attached were successfully prepared by a facile sputtering deposition technique.
Debabrata Chatterjee, Namita Jaiswal and Papiya Sarkar
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00472A, Paper
[RuIII(EDTA)(pz)] (EDTA4− = ethylenediaminetetraacetate), pz = pyrazine) mediates two-electron reduction of O2 to produce H2O2 using H2S as a reducing agent.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00162E, Paper
Covalent tethering of a P2N2 ligand to a planar, azide-terminated glassy carbon electrode surface was accomplished using a CuI-catalyzed “click” reaction, followed by metallation with NiII.
Shuojue Wang, Hui-Ling Ma, Jing Peng, Youwei Zhang, Jian Chen, Liangliang Wang, Ling Xu, Jiuqiang Li and Maolin Zhai
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00101C, Paper
A novel polymeric ionic liquid gel was prepared by gamma radiation at room temperature and showed a preeminent adsorption ability toward Cr(VI).
Bhausaheb Dhokale, Thaksen Jadhav, Shaikh M. Mobin and Rajneesh Misra
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00565E, Paper
We report the synthesis of meso enyne substituted BODIPYs by the reaction of 8-chloro BODIPY with terminal alkynes under Sonogashira coupling conditions, and by Pd–Cu catalyzed hydroalkynylation reaction of terminal alkynes, across the –C[triple bond, length as m-dash]C– bond of meso alkynylated BODIPYs.
Jean-Claude Berthet, Pierre Thuéry and Michel Ephritikhine
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00692A, Perspective
By using the cyanide ligand, actinide compounds with unprecedented structures, UIII–CN vs. CeIII–NC and UIII–CN vs. UIV–NC coordination modes, and novel high-valent uranium complexes were revealed.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00678C, Paper
Novel mesoporous structures on TiO2 nanotube arrays were achieved for enhancing electrochemical performance.
Claudia Guanci, Giovanni Giovenzana, Luciano Lattuada, Carlos Platas-Iglesias and Loïc J. Charbonnière
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00077G, Paper
Anchoring three picolinate units on a AMPED scaffold affords a strongly pre-organized ligand for the formation of luminescent lanthanide complexes.
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03360D, Paper
According to the Ligand Polyhedral Model (LPM) the complete interchange of all CO ligands in [Rh6(CO)16] takes place by a single step low energy (soft) breathing mode of the CO...
Enrique Garcia-Espana, Javier Pitarch-Jarque, Raquel Belda, Laura García-España, José Miguel Llinares, FangFang Pan, Kari Rissanen and Pilar Navarro
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00763A, Communication
We report on a novel 1-D helical coordination polymer formed by protonated polyamine 1H-pyrazole cryptands interconnected by Cu2+ metal ions able to encapsulate anionic species behaving as a multianion receptor....
Yongqiang Feng, Jie Li, Zhuxia Zhang, bo wu, Yongjian Li, Li Jiang, Chun-Ru Wang and Taishan Wang
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00432B, Communication
A kind of Gd@C82 salt, Gd@C82/TBPA, was prepared through chemical oxidation. The Gd@C82/TBPA was characterized to be paramagnetic with effective magnetic moment of 9.68 μB. The Gd@C82/TBPA can dissolve in...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01026H, Communication
A new vanadium sulfate, [H2N(CH3)2]6.34(en)[V5O5(μ3-O)4(SO4)4](SO4)0.67[HN(CH3)2]1.5 1, constructed from novel umbrella-like [VV(μ3-O)4VIV4O5(SO4)4(en)]5- anions was synthesized and structurally characterized using single-crystal X-ray analysis. While the magnetic studies of 1 indicate the title...
Jiang Liu, Yan-Cong Chen, Zhong-Xia Jiang, Jun-Liang Liu, Jian-Hua Jia, Long-Fei Wang, Quan-Wen Li and Mingliang Tong
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00880H, Paper
The perturbation to ligand field around the lanthanide ion may significantly contribute to the magnetic dynamics of single molecule magnet. This can be demonstrated by two typically Dy4 cluster-based single...

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