Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.097 48 Issues per Year Indexed in MEDLINE
 
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Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01428F, Perspective
The spectroscopies of a range of porphyrinic compounds performed under a magnetic field are reviewed focusing on the molecular functions of the compounds. Characteristic molecular magneto-optical effects, such as the...
 
María Alonso, M. Angeles Alvarez, M. Esther García, Daniel García-Vivó and Miguel A. Ruiz
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01942C, Paper
S-Alkylation of the title complexes is orbital-favoured, but alkylation at the terminal O atom of the phosphorus ligand is thermodynamically preferred.
 
M. Angeles Alvarez, M. Esther García, Daniel García-Vivó, Miguel A. Ruiz and M. Fernanda Vega
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01915F, Paper
The title anion adds metal-based electrophiles at the ditungsten site, but its protonation gives mixtures of isomers with either bridging or terminal hydrides (W = WCp; P = PCy2).
 
Panagiota S Perlepe, Angeliki Athanasopoulou, Konstantina Alexopoulou, Catherine Raptopoulou, Vassilis Psycharis, Albert Escuer, Spyros Perlepes and Dr Theocharis Stamatatos
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02434F, Communication
Three structurally and magnetically different tetranuclear NiII complexes have been isolated and magnetically characterized, emphasizing the effect of reaction solvent and organic ligand substitution on the chemical identity of cluster...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02322F, Paper
By combination of different metal salt and solvent, four unprecedented in-situ reactions have been discovered for heterocyclic disulfide of 2-ppds (2-ppds = di[4-(pyridin-2-yl)pyrimidinyl]disulfide). In the CH3CN/DMF solvent, reaction of 2-ppds...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01907E, Paper
A new diMnIII complex, Na[Mn2(5-SO3-salpentO)(μ-OAc)(μ-OMe)(H2O)].4H2O, where 5-SO3-salpentOH = 1,5-bis(5-sulphonatosalicylidenamino)pentan-3-ol, has been prepared and characterized. ESI-mass spectrometry, paramagnetic 1H NMR, EPR and UV-visible spectroscopic studies on freshly prepared solutions of the...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02162B, Perspective
Lithium ion batteries exhibit the highest energy densities of all battery types and are therefore an important technology for energy storage in every day life. Today’s commercially available batteries employ...
 
Miroslaw Maczka, Adam Pietraszko, L. Macalik, Adam Sieradzki, Justyna Trzmiel and Adam Pikul
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02586E, Paper
We report the synthesis, crystal structure, thermal, dielectric, Raman, infrared, and magnetic properties of [(CH3)2NH2][Na0.5Fe0.5(HCOO)3] (DMNaFe), the first metal formate framework templated by organic cations, presenting an ABO3 perovskite architecture...
 
Indranath Chakraborty, Shrabani Mahata, Anuradha Mitra, Goutam De and T. Pradeep
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02476A, Communication
A stable, Ag55 cluster protected with 4-(tert-butyl) benzyl mercaptan (BBSH) was synthesized which exhibits two prominent absorption bands with maxima at 2.25 and 2.81 eV. A molecular ion peak at...
 
Erik Østreng, Henrik Hovde Sønsteby, Sigurd Øien, Ola Nilsen and Helmer Fjellvåg
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01930J, Paper
Thin films of sodium and potassium oxides have for the first time been deposited using atomic layer deposition. Sodium and potassium complexes of tert-butanol, trimethylsilanol and hexamethyldisilazane have been evaluated...
 
Antonio Otero, manuel honrado, juan fernandez, LUIS FERNANDO SÁNCHEZ-BARBA MERLO, andres garces, agustin lara and Ana María Rodríguez
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02178A, Paper
The reaction of bpzbeH, bpzteH (racemic mixture) or (R,R)-bpzmmH (enantiopure) with the amide complexes Zn{N(SiMe3)2}2 or Zn{N(SiHMe2)2}2 in a 1:1 molar ratio in toluene afforded the mononuclear amide zinc complexes...
 
Jitendra Gangwar, BIPIN KUMAR GUPTA, Pawan Kumar, Surya Kant Tripathi and Avanish kumar Srivastava
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01831A, Paper
Herein, we have demonstrated the high yield facile growth of uniform morphology with different polymorphs phases (e.g. γ, δ and θ) of Al2O3 nanowires via a hydrothermal method with varying...
 
Matthieu Virot, Laurent Venault, Philippe Moisy and Sergey Nikitenko
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02330G, Paper
The behavior of Pu(IV) and Pu(III) was investigated in aqueous nitric solutions under ultrasound irradiation (Ar, 20 kHz). In the absence of anti-nitrous reagents, ultrasound has no effect toward Pu(IV)...
 
Yun-Wu Li, Da-Cheng Li, Jian Xu, Hong-Guo Hao, Su-Na Wang, Jian-Min Dou, Tong-Liang Hu and Xian-He Bu
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02321H, Communication
A synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect was successfully applied to tune two CuII-based MOFs. 1 represents a cds topology, while 2 is built by three distinct {Cu4} clusters as SBUs.
 
Elisa Deponti, Alessandra Luisa, Mirco Natali, Elisabetta Iengo and Franco Scandola
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02269F, Paper
The ability of a new pentapyridine cobalt(II) complex to power photochemical hydrogen evolution from water is investigated in detail.
 
Jun Yoshida, Keisuke Sugawara, Hidetaka Yuge and Jun Okabayashi
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02331E, Paper
The octahedral Ru(III) complex acts as a redox-active scorpionate ligand.
 
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02088J, Paper
Ellestadites are silicate–sulphate apatite matrices for the immobilization of toxic metal waste. Phosphate-rich chlorellestadite, Ca10[(SiO4)x(PO4)6−2x(SO4)x]Cl2 (0 ≤ x ≤ 1) show promise as ceramic waste forms for hazardous fly ashes rich in sulphur and chlorine.
 
Siddhartha Kolay, Mukesh Kumar, Amey Wadawale, Dasarathi Das and Vimal K. Jain
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02200A, Paper
Reactions of telluro ethers with common cyclopalladation precursors gave a variety of palladium complexes ranging from mononuclear, trans-[PdCl2(TeR2)2] to binuclear [Pd2(μ-Cl)2Cl2(TeRR′)2], cyclopalladated [Pd2(μ-OAc)2{RTeCH2C6H2(4,6-Me2)}2] and products formed by Te–C bond cleavage.
 
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01547A, Paper
Well-defined highly active pincer-ligated palladium complexes have been developed for the direct arylation of heteroarenes through C–H bond functionalization using aryl iodides as electrophiles with impressive reactivity.
 
Zoe R. Greenburg, Dong Jin, Paul G. Williard and Wesley H. Bernskoetter
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01221F, Paper
Nickel pyridyl-phosphine species couple CO2 with olefins and can produce cyclic anhydrides and ketoacids with alkyl zinc and/or carbon monoxide.
 
Carl Redshaw, Jing Ma, Keqing Zhao, Mark Walton, Joseph A Wright, David L. Hughes, Mark Robert James Elsegood, Xinsen Sun and Kenji Michiue
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01448K, Paper
Reaction of the ligand 2,4-tert-butyl-6-[(2-methylquinolin-8-ylimino)methyl]phenol (L1H) with [VOCl3] in the presence of triethylamine afforded the complex [VOCl2L1] (1), whereas use of [VO(OnPr)3] led to the isolation of [VO2L1] (2) or...
 
Jian Ping Wang, Hong-Xin Ma, Lan-Cui Zhang, wansheng You and Zaiming Zhu
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02571G, Paper
Two novel Strandberg-type organophosphomolybdate hybrid compounds [(Cu(H2O))2(-bipy)2(C6H5PO3)2Mo5O15]n (1) and [(Cu(H2O)2)2(-bipy)(C6H5PO3)2Mo5O15]n (2) (bipy =4,4'-bipyridyl) were prepared by mild hydrothermal conditions and structurally characterized by physico-chemical and spectroscopic methods. Single crystal X-ray...
 
M Concepcion Gimeno, Alejandro Gutiérrez, Lucía Gracia-Fleta, Isabel Marzo, Carlos Cativiela and Antonio Laguna
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02299H, Paper
Several gold(I) complexes containing a thiolate ligand functionalised with several amino acid or peptide moieties of the type [Au(SPyCOR)(PPh2R´)] (where R = OH, amino acid or dipeptide and R´ =...
 
sophie louise Benjamin, Yao-Pang Chang, Chitra Gurnani, Andrew L Hector, Michelle Huggon, W Levason and Gillian Reid
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02694B, Paper
A series of pentavalent niobium and tantalum halide complexes with thio-, seleno- and telluro-ether ligands, [MCl5(EnBu2)] (M = Nb, Ta; E = S, Se, Te), [TaX5(TeMe2)] (X = Cl, Br,...
 
Julia Matussek, Regine Herbst-Irmer, Ina Objartel and Dietmar Stalke
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01995D, Paper
Three novel metal complexes [(acac)2Cu2(NtBu)4S] (3), [Li(thf)4]2[I4Cd2(NtBu)4S] (4) and [(thf)2Li{(SiMe3)2N}Zn(NtBu)4S] (5) are prepared from the intended transmetalation of the dilithium complex of N,N′,N′′,N′′′-tetrakis(tert-butyl)tetraimidosulfate [(thf)4Li2(NtBu)4S] (1).
 

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