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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.097 48 Issues per Year Indexed in Medline
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Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01364J, Paper
Novel visible-light-driven Cd0.2Zn0.8S/g-C3N4 inorganic-organic composite photocatalysts were synthesized by a facile hydrothermal method. The prepared Cd0.2Zn0.8S/g-C3N4 composites were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared...
Shin-ichi Yamazaki, Masaru Yao, Masafumi Asahi, Hiroyasu Sato, Akihito Yamano and Tsutomu Ioroi
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01453K, Communication
To analyse the electrocatalytic oxidation of carbon monoxide by Rh porphyrins, we isolated a CO-adduct of Rh octaethylporphyrin, and examined its properties and reactivity by IR, NMR, and X-ray crystallographic...
Gwilherm Nenert, Oscar Fabelo, Kerstin Forsberg, Claire V. Colin and Juan Rodriguez-Carvajal
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02242H, Paper
We have reinvestigated the crystal structure of the low-dimensional fluoride $\beta$-FeF$_3(H_2O)_2\cdot$H$_2$O using high resolution neutron and X-ray diffraction data. Moreover we have studied the magnetic behavior of this material combining...
Rajendra S. Ghadwal, Christian J. Schürmann, G Frenking and Diego Marcelo Andrada
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02237A, Paper
Brønsted acid HNTf2 (Tf = SO2CF3) mediated dehydrogenative hydride abstraction from (L1)BH3 (3) and (L2)BH3 (4) (L1 = IPrCH2 = 1,3-(2,6-di-isopropylphenyl)imidazol-2-methylidene (1); L2 = SIPrCH2 = 1,3-(2,6-di-isopropylphenyl)imidazolidin-2-meth-ylidiene (2)) affords thermally...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01511A, Paper
Reaction of [(η5-C5Me5)CoCl]2 with two-fold excess of [LiBH4·thf] followed by thermolysis with excess Se powder produces the dicobaltaselenaborane species [{(η5-C5Me5)Co}2B2H2Se2], 1 in good yield. The geometry of 1 resembles a...
Jie Zhao, Guan-Hong Zhu, Li-Qiong Xie, Ye-Si Wu, Hai-Lun Wu, Ai-Ju Zhou, Zun-Yuan Wu, Jing Wang, Yan-Cong Chen and Mingliang Tong
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01894C, Paper
Eight isostructural lanthanide coordination polymers [Ln(bptc)(phen)(H2O)]n (Ln = Dy for 1, Eu for 2, Tb for 3, Gd for 4, Sm for 5, Nd for 6, Yb for 7, Pr...
Szymon Z. Konieczka, Michael Drisch, Katharina Fucke, Michael Hailmann and Maik Finze
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02055G, Paper
File attached.
Pengfei Shi, Qin Jiang, Sergio Sánchez, Xuesong Zhao, Qiong Zhang and Yupeng Tian
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT90118A, Correction
Zhuo Zheng, Wei-Bo Hua, Chong Yu, Yan-Jun Zhong, Binbin Xu, Jiazhao Wang, Benhe Zhong and Zhiye Zhang
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01678A, Paper
A series of xLi1.5Ni0.25Mn0.75O2.5·(1-x)Li0.5Ni0.25Mn0.75O2 (0 ≤ x ≤ 1) cathode materials have been synthesized. These compounds exhibit dramatic differences in structure, morphology and charge/discharge characteristics. As the x increases, the...
Junkuo Gao, Jianwei Miao, Yongxin Li, Ganguly Rakesh, Yang Zhao, Ovadia Lev, Bin Liu and qichun Zhang
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01769F, Paper
A simple and facile one-step method for the synthesis of organic dye-functionalized polyoxometalate (POM) hybrid with visible-light photo-response was reported. The POM hybrid was fully characterized via single crystal XRD,...
Esteban Rodriguez Arce, Maria Florencia Mosquillo, Leticia Perez, Gustavo Etcheverria, Oscar E. Piro, Alicia Merlino, E Laura Coitiño, Camila Maríngolo Ribeiro, Clarice Q.F. Leite, Fernando R. Pavan, Lucía Otero and Dinorah Gambino
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00557D, Paper
Searching for prospective agents against infectious diseases, 1,1'-bis (dipheny1phosphino) ferrocene pyridine-2-thiolato-1-oxide M(II) hexafluorophosphate compounds [M(mpo)(dppf)](PF6), where M(II) = palladium or platinum, were synthesized and fully characterized in the solid state...
Callum Giles Maxwell Benson, Valdislav Vasilenko, Raul Garcia-Rodriguez, Andrew David Bond, Silvia Gonzalez Calera, Dominic S Wright and Lutz H Gade
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02069G, Paper
The reactions of the chloro-phosph(III)azane dimers [ClP(μ-NR)]2 with LiSH give the dimers [S=(H)P(μ-NR)]2 (III), which are potential new building blocks for inorganic macrocycles of the type [{P(μ-NR)}2(μ-S)]n. NMR spectroscopic studies...
Marco Taddei, Phuong Viet Dau, Seth Mason Cohen, Marco Ranocchiari, Jeroen van Bokhoven, Ferdinando Costantino, Stefano Sabatini and Riccardo Vivani
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01838B, Paper
A highly efficient and scalable synthesis of zirconium-based metal-organic framework UiO-66 was developed. In order to identify the best conditions for optimizing the process, a wide range of parameters was...
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02176F, Paper
Four FeLn heterometallic coordination polymers with the H4pmida ligand were ionothermally synthesized and characterized. Their catalytic properties in the Knöevenagel condensation reaction were investigated.
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02279G, Communication
Axially linked trifluoroethoxy (TFEO)-coated subphthalocyanine (SubPc) homo- and heterodimers were synthesized by two different axial ligand substitution methods. TFEO-SubPc homodimers were obtained directly from TFEO-SubPc boron chloride with o-, m-,...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01963J, Paper
The redox-active metalloligand (RML) (Et3NH)3[CrIII(F4Cat)3] (F4Cat = perfluorocatecholato) (1) was synthesized and its interactions with the guest metal ions Li+, Mn2+, Fe2+, Co2+, Cu2+, and Zn2+ were examined. Cyclic voltammetry...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02189H, Paper
Reaction of the in situ deprotonated N-thiophosphorylated thiourea 2-MeO(O)CC6H4NHC(S)NHP(S)(OiPr)2 (HL) with MCl2 (M = ZnII, CdII) in aqueous ethanol leads to complexes of the formula [ML2]. Both compounds crystallise in...
Tânia S.M. Oliveira, Ana C. Gomes, Andre D Lopes, João P. Lourenço, Filipe Alexandre Almeida Paz, Martyn Pillinger and Isabel S. Goncalves
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02165K, Paper
Treatment of the solvent adduct [MoO2Cl2(THF)2] with either 2 equivalents of N,N-dimethylbenzamide (DMB) or 1 equivalent of N,N'-diethyloxamide (DEO) gave the dioxomolybdenum(VI) complexes [MoO2Cl2(DMB)2] (1) and [MoO2Cl2(DEO)] (2). The molecular...
Catherine R. Munteanu and Kogularamanan Suntharalingam
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02101D, Perspective
This perspective describes the advances in cobalt-containing compounds as anticancer agents. Cobalt, being an essential trace element, offers a less toxic alternative to traditional platinum-based anticancer drugs.
Ke-zhao Du, Apoorva Chaturvedi, Xing-zhi Wang, Yi Zhao, Ke-ke Zhang, M. Iqbal Bakti Utama, Peng Hu, Hui Jiang, Qi-hua Xiong and Christian Kloc
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01858G, Communication
CdS and other II–VI compounds were synthesized and crystallized in sealed quartz ampoules by plasma-enhanced microwave vapor transport.
Juan Xia, Le Xin Song, Wei Liu, Yue Teng, Li Zhao, Qing Shan Wang and Mao Mao Ruan
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01645B, Communication
1D, 2D and 3D nanostructures of CMOHs were successfully constructed through a pH-dependent dimensional transformation of ACM.
Péter Baranyai, Gábor Marsi, Csaba Jobbágy, Attila Domján, Laura Oláh and Andrea Deák
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01795E, Communication
A gold(I)–diphosphine exhibits an intriguing dual-response (mechanochromism and mechanochromic luminescence) to mechanical stress as a consequence of the reversible neutral-to-ionic phase transition.
Di Zhu, Arzoo Z. Sharma, Christopher R. Wiebe and Peter H. M. Budzelaar
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02218E, Communication
Oxidation of (MeBDI)Rh(cyclooctene) (MeBDI = [2,6-Me2C6H3NCMe]2CH) with Br2 or I2 produces paramagnetic halide-bridged RhII dimers [(MeBDI)Rh]2(μ-X)2 without a direct Rh–Rh bond.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01487E, Paper
An unusual antiferromagnetic interaction was observed in a Gd–radical complex with tridentate chelating nitronyl nitroxide. The Tb complex displays slow magnetic relaxation.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01848J, Paper
A 1D anionic lanthanide complex has been prepared that can serve as a potential functional material to selectively remove cationic dyes from wastewater, especially methylene blue.

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