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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.097 48 Issues per Year Indexed in Medline
 
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Huang YU, Jun Chen, Wei Zou, Linxing Zhang, Hu Lei, Ranbo Yu, Jinxia Deng and Xianran Xing
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01269D, Paper
Hollow spheres of multicomponent (CuIn)xZn2(1-x)S2 solid solutions have been rapidly synthesized by a salt-assisted aerosol decomposition method. (CuIn)0.2Zn1.6S2 hollow spheres with a band gap of 2.53 eV exhibit an excellent...
 
Farooq Ali Shah, Shaista Sabir, Kaneez Fatima, Saqib Ali, Ishtiaq Qadri and Corrado Rizzoli
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00862J, Paper
Three new organotin(IV) carboxylates (1–3) of 3,5-dimethylcarboxylate, have been synthesized and characterized by elemental analysis, FT-IR, multinuclear NMR (1H, 13C and 119Sn), mass spectrometry and single crystal X-ray structural analysis....
 
Jerome Kretzschmar, Norbert Jordan, Erica Brendler, Satoru Tsushima, Carola Franzen, Harald Foerstendorf, Madlen Stockmann, Karsten Heim and Vinzenz Brendler
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00730E, Paper
The aqueous speciation of selenium(IV) was elucidated by a combined approach applying quantum chemical calculations, infrared (IR), Raman, and 77Se NMR spectroscopy. The dimerization of hydrogen selenite (HSeO3−) was confirmed...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00444F, Paper
This paper presents the electrical properties, complex impedance analysis and dielectrical behavior of La0.5Ca0.5-xAgxMnO3 manganites with the composition below the concentration limit of silver solubility in perovskites (0 ≤ x...
 
Carlos Alberto Fernandez, Satish Kumar Nune, Harsha V. R. Annapureddy, Liem X Dang, B. Peter McGrail, Feng (Richard) Zheng, Evgueni Polikarpov, David King, Charles Freeman and Kriston Brooks
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00606F, Paper
Metal-organic frameworks (MOFs) have proved to be very attractive for applications including gas storage, separation, sensing and catalysis. In particular, CO2 separation from flue gas in post-combustion processes is one...
 
Xicheng Wang, Zhengyan Zhao, Quansheng Wu, Yanyan Li, Chuang Wang, Aijun Mao and Yuhua Wang
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00800J, Paper
A series of SrSiAl2O3N2: Eu2+(0.005≤x≤0.05) phosphors were successfully synthesized through a pressureless, facile, and efficient solid state route. The crystal structure, band structure, and their photoluminescence or cathodoluminescence properties were...
 
Norbert Werner Mitzel, Leif Arne Körte, Robin Warner, Yury V Vishnevskiy, Beate Neumann and Georg Stammler
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01068C, Paper
Deprotonation of the methylpyridines 2,6-lutidine, 2-picoline, 4-dimethylamino-2,6-dimethyl¬pyridine as well as 2,6-dimethyl-4-(piperidine-1-yl)pyridine with n-butyllithium or n-butyl¬lithium/KO-t-Bu at the methyl positions led to the corresponding organolithium or -potassium compounds. Treatment with ClB(C6F5)2...
 
Moumita Pait, Michael Shatruk, Jeff Lengyel, Silvia Gómez-Coca, Antonio Bauzá, Antonio Frontera, Valerio Bertolasi and Debashis Ray
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT90077H, Correction
 
Francesco Endrizzi, Andrea Melchior, Marilena Tolazzi and Linfeng Rao
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00261C, Paper
Glutarimidoxioxime forms a bidentate complex with UO22+ via the oxime and imino groups. Hydrogen bonding between water and the carbonyl group helps to stabilize the complex. The complex is much weaker than that of glutarimidedioxime previously studied.
 
Francesc Teixidor, Isabel Romero, Mònica Fontanet, Montserrat Rodríguez, Xavier Fontrodona and Clara Vinas
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00305A, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00903K, Paper
Through utilizing two kinds of pendent organic ligands, four new Keggin-based compounds, [AgI3(bpz)2(pz)(H2O)(H3PMo12O40)2] (1), [AgI2(bpz)2(H3PMo12O40)]•2H2O (2), [AgI3(btz)4(PMo12O40)] (3) and [AgI3(btz)3(PMo12O40)]·H2O (4) (bpz = 4-butyl-1H-pyrazole, pz = pyrazole, btz = 1-benzyl-1H-(1,2,4)triazole),...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01151E, Paper
A pair of 3-D homochiral metal-organic frameworks (HMOFs) based on mixed semi-rigid 5-(2-carboxypyrrolidine-1-carbonyl)isophthalate (PIA) ligand and rigid 4,4’-bipyridine (bipy), [Co3((R)-PIA)2(bipy)3].6H2O (1-D) and [Co3((S)-PIA)2(bipy)3].6H2O (1-L), are synthesized and structurally characterized. They...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01241D, Paper
The dinuclear lanthanide complexes [Ln2(L)2(THF)n] (Ln=Nd (1) n=4, Gd (2) n=3, Lu (3) n=2) supported by carbon bridged triphenolate ligand [LH3 = tris(3,5-di-tert-butyl-2-hydroxyphenyl)methane] were synthesized via salt metathesis reaction between...
 
Shu Zhang, Wen-Chao Zhang, Dan-Dan Shang, Zhi-Qian Zhang and Yixian Yixian Wu
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00675A, Paper
Various vanadium complexes containing N-heterocyclic carbenes, VOCl3[1,3-R2(NCH=)2C:] (V1, R = 2,6-Me2C6H3; V2, R = 2,6-Et2C6H3; V3, R = 2,6-iPr2C6H3; V4, R = 2,4,6-Me3C6H2), have been synthesized and employed as catalyst...
 
Aleksandra Schejn, Thomas Mazet, véronique falk, Balan Lavinia, lionel aranda, ghouti medjahdi and Raphaël Schneider
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01191D, Communication
A simple methodology for encapsulating ca. 10 nm-sized superparamagnetic Fe3O4 nanoparticles in zeolitic imidazolate frameworks (ZIF-8) crystals was developed. The corresponding Fe3O4@ZIF-8 heterostructured material exhibits bifunctional properties with both high...
 
Navaneethan Mani, Santhanakrishnan Harish, Archana Jayaram, Silambarasan A, Ponnusamy S, Muthamizhchelvan C and Y. Hayakawa
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01572C, Paper
Zinc oxide (ZnO) nanostructures were synthesized and their photocatalytic activity was evaluated using methylene blue (MB) as a model pollutant. Ethylenediamine (EDA) was used as a passivating agent to control...
 
Daniela Marasco, Luigi Messori, Tiziano Marzo and Antonello Merlino
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01279A, Paper
The model protein hen egg white lysozyme was challenged with Oxaliplatin and Cisplatin. ESI mass spectrometry, surface plasmon resonance and thermal shift analyses demonstrate the formation of a bis-platinum adduct,...
 
Ge Wang, Marites Guino-o, David S Glueck, James A. Golen, Christopher John Anthony Daley and Arnold L Rheingold
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00520E, Paper
Metal-mediated synthesis of a new heterocycle, 1-phenyl-phosphapyracene (Ph-4, Ph-PyraPhos), by tandem phosphination/cyclization of peri-substituted 5-bromo-6-chloromethylacenaphthene (3) was investigated for comparison to Pt-catalyzed formation of 1-phosphaacenaphthenes (2, AcePhos) from the analogous...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01260K, Paper
Fe3O4-graphene oxide nanocomposite has been synthesized via a chemical reaction with magnetite particle size of 18-25 nm. The resulting nanocomposite can be easily manipulated by an external magnetic field, exhibit...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01125F, Paper
MoS2@CuO heterogeneous structure nanoflowers were synthesized through two-step hydrothermal method for the first time. The valence band offset (VBO) and conduction band offset (CBO) of MoS2@CuO heterojunction, the bases for...
 
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00813A, Paper
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01147G, Communication
By integrating two different electronegative metal cations into a metallocavitand, the electrostatic potential of the latter and thus its selective recognition towards the substituted benzene derivatives can be modulated.
 
Mohammad Mahdi Najafpour, Foad Ebrahimi, Mojtaba Amini, Mohammad Rahimi, Abdelhamid El-Sawy and Steven L. Suib
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01130B, Communication
We propose that nano-sized Mn oxides are true catalysts for the oxidation of some alcohols to aldehydes in the presence of a mononuclear manganese(II) complex, and Oxone as an oxidant.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01022E, Paper
Utilising Sn(II) and Sn(IV) precursors allowed the synthesis of diamido Sn(IV) compounds with synthetically useful halide and amide substituents.
 
Francesco Isaia, Maria Carla Aragoni, Massimiliano Arca, Alexandre Bettoschi, Claudia Caltagirone, Carlo Castellano, Francesco Demartin, Vito Lippolis, Tiziana Pivetta and Elisa Valletta
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00917K, Paper
The Zn-bound chelating anion methimazole reveals a different reactivity towards the electrophilic addition of H+ and CH3+.
 

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