Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.097 48 Issues per Year Indexed in MEDLINE
 
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Ismail Elguraish, Kelong Zhu, Leslie A Hernandez, Hazem Amarne, Jingwei Luo, Nicholas V Vukotic and Stephen J Loeb
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03198A, Communication
A new pyridine ligand based on a T-shaped 2,4,7 trisubstituted benzimidazole framework was synthesized with a 90o angle between the two nitrogen donors. When combined with convergent [Pt(dppp)]2+ corners, eight...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03208J, Communication
An organic radical cation salt, BBDTA•Au(CN)2, with a slipped π-stacking columnar structure and intercolumnar short contacts, shows ferromagnetic ordering at 8.2 K, the highest reported temperature among the BBDTA+ cation...
 
Rebecca Olivia Fuller, George Koutsantonis, Ivan Lozic, Mark Ian Ogden and Brian W. Skelton
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02952F, Paper
The structure of the oxygen-evolving complex of photosystem II, which contains a cubane-like metal-oxo cluster incorporating four manganese(III,IV) cations, along with a calcium cation, has focussed attention on synthetic analogues...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03332A, Communication
A novel 3D Co(II) coordination polymer, [Co6(4-ptz)6(N3)6]n (1) (4-ptz = 4-(pyridinyl)tetrazole), was synthesized by in situ hydrothermal reaction and characterized magnetically. Compound 1 consists of ferrimagnetic-like Co(II) layers with the...
 
Cameron Jones, Lea Fohlmeister, Kuduva Vignesh, Florian Winter, Boujemaa Moubaraki, Gopalan Rajaraman, Rainer Poettgen and Keith S. Murray
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03081H, Paper
Three neutral bis(µ-chalcogenido)diiron(III) complexes, [{(N,N’-Pipiso)Fe(-E)}2] (Pipiso- = [(DipN)2C(cis-2,6-Me2NC5H8)]-, (Dip = C6H3Pri2-2,6; E = O, S or Se) have been prepared by reactions of the iron(I) dimer [{(µ-N,N’-Pipiso)Fe}2] with O2, S8...
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02740J, Paper
A series of water-soluble Rh(I) mononuclear complexes of general formula: [Rh(sulphsal-X-R)(COD)] [sulphsal = sulphonated salicylaldimine, COD = cyclooctadiene; where R = H, Cl, CH3 and X = H, tBu] have been synthesized.
 
Tatiyana V. Serebryanskaya, Alexander S. Lyakhov, Ludmila S. Ivashkevich, Julia Schur, Corazon Frias, Aram Prokop and Ingo Ott
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03105A, Paper
Gold(I) complexes with thiotetrazolate ligands are potent TrxR inhibitors with activity in drug resistant Nalm-6 cells.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02673J, Paper
A judicious choice of palladium catalysts and conditions afforded the hydrophosphination product in >99% regioselectivity (1,4- vs. 1,6-addition).
 
Elizabeth Polido Legaria, Seda Demirel Topel, Vadim G. Kessler and Gulaim A. Seisenbaeva
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03096F, Paper
The IDA–RE3+ complexation of RE3+ on the surface of a hybrid silica adsorbent occurs under neutral or weakly acidic conditions apparently not via chelation but via the concerted action of the negatively charged carboxylate oxygen atoms, opening the possibility for enhanced selectivity.
 
M. Ramos Silva, P. Martín-Ramos, J. T. Coutinho, L. C. J. Pereira, V. Lavín, I. R. Martín, P. S. Pereira Silva and J. Martín-Gil
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02767A, Paper
The magnetic properties of two similar Er3+ complexes have been investigated.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03211J, Communication
An unprecedented azido-bridged chair-like [CoII10] SMM containing both tetra- and octahedral Co(II) ions was prepared through an in situ [2 + 3] cyclo-addition reaction in a sealed system. Magnetic study showed that it exhibited overall intracluster ferromagnetic couplings and slow magnetic relaxation at both zero and non-zero applied fields.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02940B, Paper
The Pt-loaded g-C3N4 demonstrated high visible-light photoactivity of CO2 reduction to CH4, which was attributed to the efficient interfacial electron transfer from g-C3N4 to Pt.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02954B, Paper
Triple-armed cyclens bearing three aromatic side-arms were prepared, and the Ag+-ion-induced 1H NMR and UV-vis spectral changes and X-ray structures suggested that the new armed cyclens behave like an insectivorous plant (Venus flytrap).
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03161J, Paper
The Cp*IrIII(NHC)-based precatalyst does not compromise on its efficiency in catalytic C–H oxidation activity when templated on a coordination platform.
 
Mannar R. Maurya, Nikita Chaudhary, Fernando Avecilla, Pedro Adão and João Costa Pessoa
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02474E, Paper
VV-polymer-supported compounds, their neat analogues and the corresponding peroxido-complexes are prepared and applied as catalyst precursors for the oxidation of isoeugenol.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02714K, Paper
MIL-124 has been synthesized by solvothermal approach, and the luminescence was tuned by doping Ln3+ into the channels. With adjustment of the excitation wavelength and concentration of Ln3+, dichromatic (MIL-124@Eu3+) and trichromatic (MIL-124@Eu3+/Tb3+) white-light-emission can be achieved.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03005B, Paper
For the first time it is shown that a subtle change in the N-alkyl group (methyl or ethyl) of a tridentate ancillary ligand, bis(2-pyridylmethyl)alkylamine, is responsible for the diversity of product formation under similar conditions. Through their water vapor adsorption study, a structure-property correlation is established.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02643H, Paper
La1−xLnxH(O3PCH3)2 (0 < x ≤ 1; Ln = Eu, Tb) is a red, blue to green, cyan to green or white phosphor.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02922D, Paper
Ir(pdpit)(pppo)(bptz) complex (3) reveals a PO–H–N inter- ligand H-bond from which proton transfer takes place.
 
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02292K, Paper
BeH2 and BH3 association with unsaturated bases of group 15 increases their acidity and changes the trend. Ethynyl : BeH2 complexes unexpectedly behave as Be acids.
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02268H, Perspective
Density functional theory (DFT) results on the geometry, energies and charges of selected Rh-β-diketonato reactants, products and transition states are discussed. Various DFT techniques are used to increase our understanding...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02827A, Communication
The [RuV=O]3+ and [RuVI=O]4+ generated from [RuII(NCN-Me)(bpy)(H2O)](PF6)2 (NCN-Me is the neutral N-methyl-3,5-di(2-pyridyl)pyridinium iodide after deprotonation of the C-H bond), plays the selective role in C-H bond oxidation of 2-(pyridin-2-yl)-9,10-dihydroacridine (PADHH)...
 
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02657H, Paper
Theoretical calculations (density functional theory with the scalar relativistic ZORA Hamiltonian) have been performed to obtain the energy and Gibbs free energy of formation of cationic 1:3 complexes of americium(III)...
 
JingQuan Sha, Liang Li, Jingwen Sun, Guangming Li, Pengfei Yan, Cheng Wang and Lian Yu
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02960G, Paper
Two polyoxometalates based coordination polymers (POMCPs) constructed form Keggin POMs and Ag+ with pyttz were synthesized, [Ag4(H2pyttz-I)(H2pyttz-II)(Hpyttz-II)][HSiW12O40]•4H2O (1) and [Ag4(H2pyttz-II)(Hpyttz-II)2][H2SiW12O40]•3H2O (2). (H2pyttz-I = 3-(pyrid-2-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl; H2pyttz-II = 3-(pyrid-4-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl). Both compounds have...
 
weibin liang, Ravichandar Babarao, Michael J Murphy and Deanna Michelle D'Alessandro
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03183K, Communication
This work reports the first example of a Zr-based MOF which is exclusively constructed from the monocarboxylate ligand formate. Despite the low surface area, the new material exhibits an unexpectedly...
 

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