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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Shuang-Quan Zang, Min Li, Xiu-Juan Jiang, Hui-Hui Wu, Hong-Lin Lu, Hai-Yang Li, Hong Xu and Thomas C. W. Mak
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02731D, Paper
A dual functional probe L based on rhodamine was devised and synthesized. Probe L can sense Pb2+ and Cu2+ in aqueous solution through two approaches: a significant fluorescence enhancement caused...
Bala. Manimaran, S. Karthikeyan, R. Nagarajaprakash, Garisekurthi Satheesh and Chowan Ashok Kumar
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01866H, Paper
Syntheses of manganese(I)-based dinuclear metallacycles have been accomplished in facile one-pot reaction conditions at room temperature. Self-assembly of four components has resulted into the formation of M2L2-type metallacycles [Mn(CO)3Br(μ-NLN)]2 (1-5)...
Pedro T Gomes, Clara S. B. Gomes, Krishnamoorthy paramasivam, Leonel C. Silva, Sandra I. Costa, Manuel Jimenez-Tenorio, Pedro Valerga and M C Puerta
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02794B, Communication
New indenyl nickel(II) complexes containing arsine or stibine ligands synthesised by a new methodology exhibit very high activities for the oligomerisation of styrene.
Rajiv Trivedi, Rami Reddy Eda, Sarma VS Akella, Sridhar Balasubramanian, Hasitha S Anantaraju, Sriram Dharmarajan, Perumal Yogeeswari and Narayana Nagesh
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT03266K, Paper
A series of five palladium(II) pyridyl-imine Schiff base complexes 5a-e containing boronate esters with protected sugar diols derived from D-xylose, L-sorbose and D-mannitol was designed and synthesized starting from pyridyl-imines...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02755A, Paper
Reaction of 5-phenyl-2,2'-bipyridine (L) with a mixture of CuI or [Cu(CH3CN)4]BF4 and PPh3 leads to mononuclear heteroleptic complexes [CuL(PPh3)I] (1) and [CuL(PPh3)2]BF4 (2). According to X-ray diffraction, L crystallizes in...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02611C, Paper
A new category of secondary phosphine oxides (SPOs) (5a-5j) with/without benzo-fused five-membered heterocyclic substituents were prepared. These new compounds are air- and moisture-stable ligands and have the advantage for long-term...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02081F, Paper
In this study, three mixed-ligand Ru(II) complexes (Ru1–Ru3) were synthesized and developed to act as photodynamic therapy (PDT) agents. Their photophysical and photochemical properties, as well as their hydrophobic properties,...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02065D, Communication
A novel pentacoordinate mono iron dicarbonyl complex bearing a nitrogen heterocyclic carbene ligand was reported as model of [Fe]-hydrogenase active site, which exhibits interesting proton coupled CO bonding reactivity, electro-catalytic...
Destinee K. Johnson, Michael J. Stevenson, Zayed A. Almadidy, Sharon E. Jenkins, Dean. E. Wilcox and Nicholas E. Grossoehme
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02689J, Paper
A robust method for the preparation, stabilization and delivery of Cu+ for aqueous titrations, in particular ITC measurements, is described.
Tiankun Zhao, Martin Grützke, Kathrin H. Götz, Tetiana Druzhenko and Thomas Huhn
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01618E, Paper
Two sulfonamide substituted heteroleptic salan titanium(IV)-bis-chelates showed potent anticancer activity better than cisplatin against the human carcinoma cell lines HeLa S3 and Hep G2a.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02457A, Communication
Four Au–(μ-phosphinite)–In units form an unprecedented Au2In2 12-membered metallacycle which intersects at the In centres an 8-membered ring containing two In–μ-phosphinate linkages, resulting in a tricyclic structure.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02592C, Paper
Cobalt complexes incorporating ferrocene–terpyridine ligands show a reversible color change in response to redox reactions involving the cobalt centers.
Guanzhi Wang, Yuanyuan Liu, Baibiao Huang, Xiaoyan Qin, Xiaoyang Zhang and Ying Dai
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03111G, Communication
A bismuth based metal–organic framework ([Bi(BTC)(DMF)]·DMF· (CH3OH)2, Bi–BTC) with a novel topology structure is synthesized by a solvothermal method.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02420J, Paper
The introduction of S atoms to ligands induces the properties for Hg2+ recognition of POM-based compounds.
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01773D, Paper
In biology, aromatic hydroxylation is carried out by a family of heme and nonheme oxygenases, such as cytochrome P450, toluene monooxygenases (TMOs) , methane monooxygenases (MMO). In contrast, a vast...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01982F, Paper
A solvothermal method has been widely used to synthesize different kinds of materials. However, only little is known about how precursor solutions react to form solid precipitates by using this...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01459J, Paper
A new series of Pr1-xCexScO3 (0.0 ≤ x ≤ 1.0) compounds was synthesized by a two-step synthesis route, involving combustion reaction followed by reduction while heating in low partial pressure...
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02853A, Paper
The current work revealed the comparative analysis of bare and surface functionalized tungsten trioxide (WO3) nanoparticles that can be successfully utilized as competent photocatalyst for the degradation of organic dye...
A Schulz, Alexander Villinger, Jonas Bresien, Kirill Faust, Christian Hering and Julia Rothe
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02757H, Paper
Different reactions of Mes* substituted phosphanes (Mes* = 2,4,6-tri-tert-butylphenyl) led to the formation of the bicyclic tetraphosphane Mes*P4Mes* (5) and its unknown Lewis acid adduct 5·GaCl3. In this context, the...
Go Nakamura, Mio Kondo, Meredith Crisalli, Sze Koon Lee, Akane Shibata, Peter C Ford and Shigeyuki Masaoka
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02994E, Paper
Four novel phosphine-substituted ruthenium(II) polypyridine complexes with nitrogen oxides—trans(P,NO2)-[Ru(trpy)(Pqn)(NO2)]PF6 (trans-NO2), cis(P,NO2)-[Ru(trpy)(Pqn)(NO2)]PF6 (cis-NO2), [Ru(trpy)(dppbz)(NO2)]PF6 (PP-NO2), and cis(P,NO)-[Ru(trpy)(Pqn)(NO)](PF6)3 (cis-NO)—were synthesised (trpy = 2,2’:6’,2”-terpyridine, Pqn = 8-(diphenylphosphanyl)quinoline, and dppbz = 1,2-bis(diphenylphosphanyl)benzene). The influence...
I. Gryca, Joanna Palion, Barbara Machura, Mateusz Penkala, Rafał Kruszynski, Joan Cano, Francesc Lloret and Miguel Julve
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02522B, Paper
Two new Re(IV) compounds of formula H2tppz[ReCl6] (1) and [Cu(bpzm)2(µ-Cl)ReCl3(µ-ox)Cu(bpzm)2(µ-ox)ReCl3(µ-Cl)]n (2) [tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine and bpzm = bis(pyrazolyl-1-yl)methane] have been prepared and their crystal structures determined by X-ray diffraction on...
Dietrich Gudat, Markus Blum, Oliver Puntigam, Sebastian Plebst, Fabian Ehret, Johannes Bender and Martin Nieger
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT02854J, Paper
The homolytic P–P bond fission in a series of sterically congested tetraaminodiphosphanes (R2N)2P–P(NR2)2 ({4}2 – {9}2, two of which were newly synthesized and fully characterized) into diaminophosphanyl radicals (R2N)2P• (4...
Laurence J. Taylor, Brian A. Surgenor, Piotr Wawrzyniak, Matthew J. Ray, David B. Cordes, Alexandra M. Z. Slawin and Petr Kilian
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT02539G, Paper
Borane adducts of peri-substituted bis(phosphines) eliminate hydrogen at room temperature, without the presence of catalysts. These reactions are the first examples of “spontaneous” phosphine–borane dehydrocoupling.
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02861B, Communication
Three different indium building blocks, from a positive trimer to a negative monomer, lead to In-MOFs with tunable framework charge.
Aleksei O. Tolpygin, Tatyana A. Glukhova, Anton V. Cherkasov, Georgy K. Fukin, Diana V. Aleksanyan, Dongmei Cui and Alexander A. Trifonov
Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02570B, Paper
The introduction of a pendant Ph2P(O) group into an amidinate ligand resulted in high 1,4-cis selectivity (96.6%) while maintaining very high activity.

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