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Journal cover: Dalton Transactions

Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
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Rajendra Prasad Paitandi, Roop Shikha Singh, Sujay Mukhopadhyay, Ashish Kumar and Shankar Pandey
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00107J, Paper
A series of copper(II) complexes (1-9 and 3') derived from bis-dipyrrin ligands (L1-L9 and L3′) with diverse spacer lengths [-(CH2)n-] have been described. Structural diversity in these complexes have been...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00546F, Paper
B(C6F5)3-catalysed hydrosilation, heterodehydrocoupling, and demethanative coupling reactions of the Si-H bonds in poly(phenylsilane) allow the introduction of 10-40% new sidechains in this polymer. The resulting new polymers contain an unusually...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00922D, Paper
The addition of a tertiary phosphine and O2 to reaction solutions strongly affected the reactivity and selectivity of coupling reactions between transition metal complexes. The Mizoroki–Heck reaction between metal complexes...
Roman Boca, Monika Pataky Stolárová, Larry R Falvello, Milagros Tomás, Jan Titis and Juraj Černák
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00069C, Paper
The complex {[Dy2(PDOA)3(H2O)6]∙2H2O}n (1) (H2PDOA = 1,2-phenylenedioxydiacetic acid) was prepared from aqueous solution. Its crystal structure, built up of {-Dy-O-C-O-}n chains interlinked by PDOA ligands yielding a ladder-like arrangement, was...
Dominik A. Megger, Kristin Rosowski, Christian Radunsky, Jutta Kösters, Barbara Sitek and Jens Müller
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04613D, Paper
Three new metal complexes bearing a tridentate hydrazone-based ligand were synthesized and structurally characterized. Depending on the metal ion, the complexes show remarkably different antitumor activities.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04625H, Paper
Hydroxypyridinones were studied in their most simple form for the complexation of Zr(IV) which provides important data for the design of pre-organized chelators of this metal for nuclear imaging applications.
Beatriz Gil-Hernández, Antonio Jesús Calahorro, Pedro Gili and Joaquin Sanchiz
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00594F, Paper
Three new heterometallic metal-organic frameworks, namely,{(Ph4P)2[MnCu3(Hmesox)3Br(H2O)]∙H2O}n (1), {(Ph4P)2[CoCu3(Hmesox)3Br]}n (2) and {(Ph4P)2[ZnCu3(Hmesox)3Br]∙2.5H2O}n (3) were prepared and their structure and magnetic properties were investigated (H4mesox = mesoxalic acid, Ph4P+= tetraphenylphosphonium). The structure...
Paul McKeown, James Brown-Humes, Matthew G Davidson, Mary F Mahon, Timothy J Woodman and Matthew Jones
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00751E, Paper
A range of ligands based upon 2-(aminomethyl)piperidine have been successfully complexed to Mg(II), Zn(II) and group IV metal centres. These complexes have been characterised both in solution and solid state...
Weixi Fan, Chuanzhi Sun, Fang Huang, Jian-Biao Liu, Xue Zhao, Xiehuang Sheng and Dezhan Chen
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00547D, Paper
Computational studies have been applied to gain insight into the mechanism of Pd(II) catalyzed α-C-H functionalization of N-methoxy Cinnamamide. The results show that the whole catalytic cycle proceeds via sequential...
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00250E, Paper
Two novel trans-isomers of 1:2-type lanthanide-containing monolacunary Dawson-type tungstophosphates [Ln(α2-P2W17O61)2]17 (Ln = LaIII (1), CeIII (2)) have been successfully isolated and characterized by element analysis, IR, TG, and 31P NMR....
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00580F, Communication
New tetradentate Schiff base chloro complexes of U(IV) and Th(IV) are prepared by salt metathesis approaches. These complexes undergo clean salt metathesis with NaN3 to generate stable pseudo-trans azide compounds....
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT03893J, Paper
A combination of EXAFS simulations and DFT calculations, including a novel protocol to evaluate Debye–Waller factors, provide insights into the structure of the Mn(IV)/Fe(III) cofactor of Ct R2.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00389G, Perspective
Fabrication strategies for hollow MOF superstructures are classified based on the existence of external templates and the types and properties of templates, and their advantages and disadvantages are reviewed.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00509A, Paper
Dimensional reduction is used to design and synthesise Pb9[Li2(P2O7)2(P4O13)2] by using Li2O to dismantle Pb3P4O13.
Negar Kavoosi, Volodymyr Bon, Irena Senkovska, Simon Krause, Cesare Atzori, Francesca Bonino, Julia Pallmann, Silvia Paasch, Eike Brunner and Stefan Kaskel
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00015D, Paper
Tailoring the characteristics of gating transitions in the porous network, Ni2(ndc)2dabco, was achieved by systematically adjusting the critical synthesis parameters.
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04799H, Paper
Molecular bistable switches (electrical switches “ON” and “OFF”) represent a class of highly desirable intelligent materials due to their sensitive switchable responses, simple and environmentally friendly processing, light weight, and mechanical flexibility.
Li Zhao, Lei Wang, Peng Yu, Chungui Tian, He Feng, Zhongwei Diao and Honggang Fu
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00617A, Paper
The hierarchical structures of porous NiCo2O4 nanosheets directly grown on a conductive carbon cloth substrate were obtained by a facile in situ synthetic strategy, which could exhibit satisfactory performance with high discharge capacity, superior rate capacity and excellent reversibility.
Òscar Àrias, Kai Brandhorst, Dirk Baabe, Matthias Freytag, Peter G. Jones and Matthias Tamm
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00305F, Paper
The reactions of the molybdenum alkylidyne complex [MesC[triple bond, length as m-dash]Mo{OCMe(CF3)2}3] with the diaminoacetylenes R2NC[triple bond, length as m-dash]CNR2 (NR2 = 4-methylpiperidinyl, NEt2; Mes = 2,4,6-trimethylphenyl) afforded paramagnetic metallacyclobutadiene (MCBD) complexes with diaminodicarbene ligands.
Michael S. Bennington, Humphrey L. C. Feltham, Zoë J. Buxton, Nicholas G. White and Sally Brooker
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00295E, Paper
Four structurally characterised [CoIIILR/R′2]BF4 complexes, of four acyclic bis(triazolyl)carbazole ligands LR/R′, all show a pair of reversible one-electron redox processes which can be tuned by variation of the carbazole substituents R.
D. Jędrzkiewicz, D. Kantorska, J. Wojtaszak, J. Ejfler and S. Szafert
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00394C, Paper
New heteroleptic zinc dimeric complexes bearing an aminophenolate ligand of a single-site initiator framework were synthesized and characterized by spectroscopic methods, X-ray analysis, and DFT calculations.
Goutam Kumar Lahiri, Madhumita Chatterjee, Prasenjit Mondal, Katharina Beyer, Alexa Paretzki and W Kaim
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00055C, Paper
The reaction between indigo, H2Ind and {Ru(bpy)2(EtOH)2}2+ in EtOH/NaOH produced the compounds [Ru(bpy)2(HInd)](ClO4) [1]ClO4, rac-{[Ru(bpy)2]2(-Ind)}(ClO4)2 [2](ClO4)2, and meso-{[Ru(bpy)2]2(-Ind)}(ClO4)3 [2](ClO4)3, which were structurally characterised, the latter as the first stable, isolable...
Norbert Werner Mitzel, Martin Pieper, Jan-Hendrik Lamm, Beate Neumann and Georg Stammler
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00554G, Paper
The new geminally bonded intramolecular donor-acceptor systems Cp2LnCH2PR2 (Ln = Y, Ho, Er, R = CHMe2, CMe3) were prepared by salt elimination reactions between the dicyclopentadienylelement chlorides (Cp2LnCl, Ln =...
Stijn Raiguel, Daphne Depuydt, Tom Vander Hoogerstraete, Joice Thomas, Wim Dehaen and Koen Binnemans
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT00624A, Paper
Novel 1,2,3-triazolium ionic liquids with a high base stability were synthesized for use in solvent extraction of first-row transition elements and rare earths from chloride media. The synthesis of these...
Aimin Wu, Jing Li, Baodan Liu, Wenjin Yang, Yanan Jiang, Lusheng Liu, Xinglai Zhang, Changmin Xiong and Xin Jiang
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT90047C, Correction
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04755F, Paper
DPPA-type ligands (Ph2P)2N(p-Z)C6H4 (Z = H, SMe, OMe) led to Ag(I) complexes of various nuclearities and an unexpected influence of the para-substituent Z is observed, including for CH2Cl2 activation.

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44 citations
The emerging new solid-state LED phosphors and the methodologies for their development have been reviewed in this perspective.
DOI: 10.1039/C6DT01230B
Published: 30 May 2016
70 citations
This perspective gives an overview of what researchers want to achieve by preparing 3d–4f single-molecule magnets, the most significant results obtained so far and the challenges still ahead of us.
DOI: 10.1039/C5DT00549C
Published: 18 Mar 2015
46 citations
The versatile role of PVP in nanoparticle synthesis is discussed in this Perspective article.
DOI: 10.1039/C5DT02964C
Published: 22 Sep 2015

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