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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry
Impact Factor 4.197 48 Issues per Year Indexed in Medline
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Ni Zhen, Kui Wu, Ying Wang, Qiang Li, Wenhui Gao, Dianwei Hou, Zhihua Yang, huaidong Jiang, yongjun Dong and ShiLie Pan
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01537A, Paper
Two noncentrosymmetric metal chalcogenides, BaCdSnS4 and Ba3CdSn2S8, were synthesized using a high-temperature solid-state reaction in evacuated silica tube. Although two compounds have the same building units in their structures, namely...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01064D, Paper
New cationic enamine--diimine cobalt complex [LCoBr.THF][BArF] (I) and its neutral analogue [LCoBr2] (II) where L = [(2,4,6-Me3-C6H2)NHCMe=C{CMe=(N-2,4,6-Me3(C6H2)}2] and BArF- = [{3,5-(CF3)2C6H3}4B]−, were synthesised and then characterized by single-crystal X-ray diffraction,...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01654E, Paper
C≡CFc, [3](ClO4)) were synthesized by the reactions of [(tppz)(PPh3)2RuCl](ClO4) (tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine)) with ferrocence-acetylide ligands and characterized by ESI-MS, and 1H and 31P NMR spectroscopies. The structure of [1](PF6) was...
Clémence Cheignon, Fabrice Collin, Peter Faller and Christelle Hureau
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01979J, Communication
Evaluation of the pro versus antioxidant activity of ascorbate regarding Cu(Aβ) induced Reactive Oxygen Species production in the context of Alzheimer's disease shows that a protective activity can only be...
Kyounghoon Lee, Haochuan Wei, Anastasia V. Blake, Courtney M. Donahue, Jason M. Keith and Scott R. Daly
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00200E, Paper
Ligand K-edge XAS and DFT studies of ligand variations in Rh(I) pincer complexes and correlations to small molecule reactivity.
Chad S. Smithson, Daniel J. MacDonald, T. Matt Letvenuk, Christian E. Carello, Michael Jennings, Alan J. Lough, James Britten, Andreas Decken and Kathryn E. Preuss
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01249C, Paper
A redox active ligand with three isolatable oxidations states is created by combining a thiazyl ring and an o-naphthoquinone.
Biswanath Das, Bao-Lin Lee, Erik A Karlsson, Torbjörn Åkermark, Andrey Shatskiy, Serhiy Demeshko, Rong-Zhen Liao, Tanja M Laine, Matti Haukka, Erica Zeglio, Ahmed Abdel‐Magied, Per Siegbahn, Franc Meyer, Markus Kärkäs, Eric Johnston, Ebbe Nordlander and Björn Åkermark
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01554A, Communication
The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the dinucleating ligand 2,2'‐(2‐hydroxy‐5‐methyl‐1,3‐phenylene)bis(1H‐benzo[d]imidazole‐4‐carboxylic acid) is described. The two iron complexes were...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01597B, Paper
Liquid-assisted grinding (LAG) reactions have been successfully applied to achieve a series of complexes and coordination polymers based on divalent 3d-transition metal chlorides (TM chlorides) and the aromatic ligand 1H-benzotriazole...
Javier Iglesias-Sigüenza, Cristina Izquierdo, Elena Diez-Martin, Rosario Fernández and Jose M. Lassaletta
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01700B, Frontier
The benzoannulation of the most common families of aromatic NHCs, imizadol-2-ylidenes and 1,2,4-triazol-3-ylidenes, results in heterobicyclic imidazo[1,5-a]pyridine-3-ylidenes (ImPy´s) and [1,2,4]triazolo[4,3-a]pyridin-3-ylidenes (TriPy's), characterized by a bridged N atom. These are versatile...
Evamarie Hey-Hawkins, Stefan Richter, Dijana Draca, Sushma B. Singh, Anup N. Kate, Anupa Avinash Kumbhar, Avinash S Kumbhar, Danijela Maksimovic-Ivanic, Sanja Mijatovic and Peter Lönnecke
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01782G, Paper
A series of RuII arene complexes of mono- and bidentate N-donor ligands with carboxyl or ester groups and chlorido ancillary ligands were synthesised and structurally characterised. The complexes have a...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01413E, Perspective
The advances in the synthesis and isolation of complexes that contain a group 13 element chalcogen multiple bond are accounted for.
Sahan R. Salpage, Avishek Paul, Bozumeh Som, Tanmay Banerjee, Kenneth Hanson, Mark D. Smith, Aaron K. Vannucci and Linda S. Shimizu
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01377E, Paper
Structural, photophysical, and electrochemical characterization of a bridged exo-diruthenium compound [(bpy)2RuLRu(bpy)2]Cl4·6H2O and use as a recyclable SET catalyst.
Qiang Zheng, Roman Gumeniuk, Horst Borrmann, Walter Schnelle, Alexander A. Tsirlin, Helge Rosner, Ulrich Burkhardt, Michael Reissner, Yuri Grin and Andreas Leithe-Jasper
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01164K, Paper
Nb7Fe3B8 and Ta7Fe3B8 feature Fe atoms occupying a planar Kagome-type framework.
Pedro R. Florindo, Diane M. Pereira, Pedro M. Borralho, Paulo J. Costa, M. F. M. Piedade, Cecília M. P. Rodrigues and Ana C. Fernandes
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01571A, Communication
Ruthenium glycoconjugates, with privileged passage through HCT116 colon cancer cell membranes via glucose transporters, are reported.
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01148A, Paper
The co-ordination chemistry of a tristhiourea tris(2-pyridylmethyl)amine ligand (L1) with a series of transition metal ions has been investigated. Crystallographic data show that large metal ions, with no geometrical preferences...
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT01414C, Perspective
Do we really know how “dual action” Pt(IV) work?
Florian Wittkamp, Christoph Nagel, Paul Lauterjung, Bert Mallick, Ulrich Schatzschneider and Ulf-Peter Apfel
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01209D, Paper
Here we present the syntheses and structural, spectroscopic, as well as electrochemical properties of dinitrosyl iron complexes (DNICs), which are based on silicon- and carbon-derived di- and tripodal phosphines. Whereas...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01323F, Paper
Two series of well-defined palladium(0) complexes with phosphine-functionalized N-heterocyclic carbene ligands were prepared. In the first series, the palladium(0) complexes featured six-member chelate rings, but seven-member chelate complexes were formed...
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01248E, Paper
Highly asymmetric A2BC type zinc phthalocyanine (Zn-di-PcNcTh) has been designed and synthesized. The Zn-di-PcNcTh used π electron rich thiophene ring in place of the benzenoid rings of phthalocyanine which was...
Richard Layfield, Liviu Chibotaru, Thomas Pugh, Richard Grindell and Veacheslav Vieru
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01763K, Communication
The synthesis, structure and magnetic properties of the HAN-bridged tri-dysprosium complex [{(thd)3Dy}3HAN] (1) are described. The complex is an SMM that shows two relaxation processes owing to the presence of...
Panagiota Perlepe, Luis Cunha-Silva, Vlasoula Bekiari, Kevin J Gagnon, Simon Teat, Albert Escuer and Theocharis Stamatatos
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01162D, Paper
The employment of the fluorescent bridging and chelating ligand N-naphthalidene-2-amino-5-chlorobenzoic acid (nacbH2) in NiII cluster chemistry has led to a series of pentanuclear and hexanuclear compounds with different structural motifs,...
Morgan C Allison, Maxim Avdeev, Siegbert Schmid, Samuel Liu, Tilo Soehnel and Christopher D. Ling
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01074A, Paper
Fe4Si2Sn7O16 has a unique crystal structure that contains alternating layers of Fe2+ ions octahedrally coordinated by O (oxide layer) and Sn (stannide layer), bridged by SiO4 tetrahedra. The formula can...
Stella A Gonsales, Ion Ghiviriga, Khalil A Abboud and Adam Steven Veige
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01049K, Communication
see attached
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01674J, Paper
The one-pot synthesis of 1,2-disubstituted benzimidazoles by transfer hydrogenation of azobenzene, using benzylamine as hydrogen donor, sequential rearrangement of hydrazobenzene to semidine and further condensation with N-benzylideneamine is reported, catalyzed...
Li Li, Yingjie Zhang, Maxim Avdeev, Lenard F. Lindoy, David Harman, Rongkun Zheng, ZX Cheng, Janice Rae Aldrich-Wright and Feng Li
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT01651K, Communication
We present the synthesis and characterization of a unique, slightly distorted square prismatic, box-like coordination cage of type [Cu6Dy8L8(MeOH)8(H2O)6](NO3)12•χsolvent obtained via the supramolecular assembly between a non-centrosymmetric Dy(III) metalloligand and...

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