Physical Chemistry Chemical Physics
High quality research in physical chemistry, chemical physics and biophysical chemistry.
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Physical Chemistry Chemical Physics,
April 21 2012 , Issue 15,
Page 4993 to 5308
April 21 2012 , Issue 15,
Page 4993 to 5308
Phys. Chem. Chem. Phys., 2012, 14, 4993-4993
DOI: 10.1039/C2CP90045A, Cover
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP90045A, Cover
From themed collection Interfaces of Ionic Liquids
Phys. Chem. Chem. Phys., 2012, 14, 4994-4994
DOI: 10.1039/C2CP90046G, Front/Back Matter
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP90046G, Front/Back Matter
From themed collection Interfaces of Ionic Liquids
Phys. Chem. Chem. Phys., 2012, 14, 4995-5007
DOI: 10.1039/C2CP90047E, Front/Back Matter
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP90047E, Front/Back Matter
From themed collection Interfaces of Ionic Liquids
Frank Endres
Phys. Chem. Chem. Phys., 2012, 14, 5008-5009
DOI: 10.1039/C2CP90031A, Editorial
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP90031A, Editorial
From themed collection Interfaces of Ionic Liquids
Ionic Liquids show complex behaviour at the interface with vacuum, gases, liquids or solids: a field at its infancy.
Hans-Peter Steinrück
Phys. Chem. Chem. Phys., 2012, 14, 5010-5029
DOI: 10.1039/C2CP24087D, Perspective
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP24087D, Perspective
From themed collection Interfaces of Ionic Liquids
Surface orientation, enrichment effects, support interaction, growth, surface tension, cation–anion interactions, dissolved metal complexes and chemical reactions are addressed.
Martin Brehm, Henry Weber, Alfonso S. Pensado, Annegret Stark and Barbara Kirchner
Phys. Chem. Chem. Phys., 2012, 14, 5030-5044
DOI: 10.1039/C2CP23983C, Perspective
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23983C, Perspective
From themed collection Interfaces of Ionic Liquids
This perspective presents a comprehensive study of hydrogen bonding interactions in imidazolium-based acetate ionic liquids and their influence on the physicochemical properties.
Cinzia Chiappe, Christian Silvio Pomelli, Ugo Bardi and Stefano Caporali
Phys. Chem. Chem. Phys., 2012, 14, 5045-5051
DOI: 10.1039/C2CP24012B, Perspective
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP24012B, Perspective
From themed collection Interfaces of Ionic Liquids
Interfaces and surfaces are the regions where important actions happen. In this article we discuss the interface (liquid/air) properties of ionic liquids (ILs) containing dissolved metal ions and the possibility to use these surfaces in material sciences, separation procedures or as optical devices.
Susan Perkin
Phys. Chem. Chem. Phys., 2012, 14, 5052-5062
DOI: 10.1039/C2CP23814D, Perspective
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23814D, Perspective
From themed collection Interfaces of Ionic Liquids
Ionic liquids are confined to nanoscopic geometries in applications from solar cells to lubrication. This Perspective surveys and discusses recent high-resolution measurements which reveal the liquid structure and dynamics in pores and thin films.
Yuki Kohno and Hiroyuki Ohno
Phys. Chem. Chem. Phys., 2012, 14, 5063-5070
DOI: 10.1039/C2CP24026B, Perspective
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP24026B, Perspective
From themed collection Interfaces of Ionic Liquids
Suitable range of hydrophilicity for hydrophobic ionic liquids is essential to realise a dynamic phase transition after mixing with water.
Kevin R. J. Lovelock
Phys. Chem. Chem. Phys., 2012, 14, 5071-5089
DOI: 10.1039/C2CP23851A, Perspective
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23851A, Perspective
From themed collection Interfaces of Ionic Liquids
In this perspective, I describe the ionic liquid/gas surface, and relate the structure to reactions at the surface and applications.
Marcel Drüschler, Natalia Borisenko, Jens Wallauer, Christian Winter, Benedikt Huber, Frank Endres and Bernhard Roling
Phys. Chem. Chem. Phys., 2012, 14, 5090-5099
DOI: 10.1039/C2CP40288B, Discussion
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP40288B, Discussion
From themed collection Interfaces of Ionic Liquids
Dynamic processes taking place on different time scales at the Au(111)/ionic liquid interface were probed by electrochemical impedance spectroscopy and by in-situ STM measurements.
Three-dimensionally ordered macroporous silicon films made by electrodeposition from an ionic liquid
Xin Liu, Yi Zhang, Dengteng Ge, Jiupeng Zhao, Yao Li and Frank Endres
Phys. Chem. Chem. Phys., 2012, 14, 5100-5105
DOI: 10.1039/C2CP23236G, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23236G, Paper
From themed collection Interfaces of Ionic Liquids
3DOM silicon films are first made by electrodeposition from an ionic liquid, which is a feasible and effective method. It could replicate the highly-ordered structure of a polystyrene colloidal crystal. Such 3DOM silicon films have a bandgap in the near infrared regime and have the potential for electrical and optical applications.
Deborah Wakeham, Petru Niga, Christiaan Ridings, Gunther Andersson, Andrew Nelson, Gregory G. Warr, Steven Baldelli, Mark W. Rutland and Rob Atkin
Phys. Chem. Chem. Phys., 2012, 14, 5106-5114
DOI: 10.1039/C2CP23694J, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23694J, Paper
From themed collection Interfaces of Ionic Liquids
Dynamic aggregates form at the ethanolammonium nitrate surface to protect the polar regions from the gas phase.
Jing Li, Wei Wei, Leanne C. Nye, Peter S. Schulz, Peter Wasserscheid, Ivana Ivanović-Burmazović and Thomas Drewello
Phys. Chem. Chem. Phys., 2012, 14, 5115-5121
DOI: 10.1039/C2CP24071H, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP24071H, Paper
From themed collection Interfaces of Ionic Liquids
Electrospray ionisation of new Brønsted acidic ionic liquids (BAILs) leads to the formation of aggregates of the types Cation[Zwitterion]n+ and Dianion[Zwitterion]n2−, the collision-induced dissociations of which are investigated.
Chariz Y. Peñalber, Zlata Grenoble, Gary A. Baker and Steven Baldelli
Phys. Chem. Chem. Phys., 2012, 14, 5122-5131
DOI: 10.1039/C2CP23920E, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23920E, Paper
From themed collection Interfaces of Ionic Liquids
The surface structure effect of an ionic liquid anion moiety at the gas–liquid interface is studied by sum frequency generation (SFG) spectroscopy.
Shiguo Zhang, Yan Zhang, Ying Wang, Shimin Liu and Youquan Deng
Phys. Chem. Chem. Phys., 2012, 14, 5132-5138
DOI: 10.1039/C2CP23675C, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23675C, Paper
From themed collection Interfaces of Ionic Liquids
Fe2O3@[EMIm][BF4] obtained by in situ ultrasonic decomposition of Fe(CO)5 in ionic liquid without any stabilizing agents finds potential application in liquid marble for magnetic transportation.
Amitesh Maiti, Arvind Kumar and Robin D. Rogers
Phys. Chem. Chem. Phys., 2012, 14, 5139-5146
DOI: 10.1039/C2CP00010E, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP00010E, Paper
From themed collection Interfaces of Ionic Liquids
Through explicit consideration of small hydrogen-bonded clusters of water we develop a more accurate theoretical method of estimating the maximum moisture content in ionic liquids.
Oliver Werzer, Emily D. Cranston, Gregory G. Warr, Rob Atkin and Mark W. Rutland
Phys. Chem. Chem. Phys., 2012, 14, 5147-5152
DOI: 10.1039/C1CP23134K, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C1CP23134K, Paper
From themed collection Interfaces of Ionic Liquids
Colloid probe atomic force microscopy has been used to study the nanotribological properties of the silica–ethylammonium nitrate–mica system.
T. Cremer, L. Wibmer, S. Krick Calderón, A. Deyko, F. Maier and H.-P. Steinrück
Phys. Chem. Chem. Phys., 2012, 14, 5153-5163
DOI: 10.1039/C2CP40278E, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP40278E, Paper
From themed collection Interfaces of Ionic Liquids
From sandwich to checkerboard: upon IL deposition on Ni(111), anions and cations change positions.
Martin Lísal, Zbyšek Posel and Pavel Izák
Phys. Chem. Chem. Phys., 2012, 14, 5164-5177
DOI: 10.1039/C2CP23572B, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23572B, Paper
From themed collection Interfaces of Ionic Liquids
Molecular dynamics simulations on the air–liquid interface of [Cnmim+][Tf2N−] (n = 4, 6, 8) are analyzed by the intrinsic method of Identification of the Truly Interfacial Molecules.
Muhammed Shah Miran, Hiroshi Kinoshita, Tomohiro Yasuda, Md. Abu Bin Hasan Susan and Masayoshi Watanabe
Phys. Chem. Chem. Phys., 2012, 14, 5178-5186
DOI: 10.1039/C2CP00007E, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP00007E, Paper
From themed collection Interfaces of Ionic Liquids
The ΔpKa dependencies of the physicochemical properties of a novel series of protic ionic liquids (PILs) based on an organic super-strong base were investigated to materialize tunable PILs with desirable chemistry.
C. Gaillard, V. Mazan, S. Georg, O. Klimchuk, M. Sypula, I. Billard, R. Schurhammer and G. Wipff
Phys. Chem. Chem. Phys., 2012, 14, 5187-5199
DOI: 10.1039/C2CP40129K, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP40129K, Paper
From themed collection Interfaces of Ionic Liquids
TBP is found to enhance acid extraction to the ionic liquid via (H3O)+(TBP)3 adducts, involving a cation exchange mechanism.
György Hantal, Iuliia Voroshylova, M. Natália D. S. Cordeiro and Miguel Jorge
Phys. Chem. Chem. Phys., 2012, 14, 5200-5213
DOI: 10.1039/C2CP23967A, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23967A, Paper
From themed collection Interfaces of Ionic Liquids
The vapour–liquid interfaces of several ionic liquids were studied in detail using molecular simulation and novel intrinsic analysis methods.
Elena Reichert, Reiner Wintringer, Dietrich A. Volmer and Rolf Hempelmann
Phys. Chem. Chem. Phys., 2012, 14, 5214-5221
DOI: 10.1039/C2CP23596J, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23596J, Paper
From themed collection Interfaces of Ionic Liquids
Vanillin is one of the many aromatic compounds which are formed upon electro-oxidative cleavage of lignin dissolved in a protic ionic liquid (PIL).
Yao Meng, Leigh Aldous, Stephen R. Belding and Richard G. Compton
Phys. Chem. Chem. Phys., 2012, 14, 5222-5228
DOI: 10.1039/C2CP23801B, Paper
From themed collection Interfaces of Ionic Liquids
DOI: 10.1039/C2CP23801B, Paper
From themed collection Interfaces of Ionic Liquids
The Hydrogen Evolution Reaction (kinetics and mechanism) has been characterised electrochemically at a range of metals in an ionic liquid for the first time.
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