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CrystEngComm

Design and understanding of solid-state and crystalline materials
Impact Factor 3.858 48 Issues per Year
 
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CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE00926J, Communication
We demonstrate a simple, rapid, one-pot exfoliation of h-boron nitride for generating surfactant-free nanosheets from a supercritical mixture of iso-propanol and water. The product was characterized by powder X-ray diffraction,...
 
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE00862J, Paper
In our efforts toward rational design and systematic synthesis of porous 3D MOFs, three 3D frameworks of Zn-MOFs ([Zn(BDC)(TIB)]n (Zn-MOF-1) (TIB = 1, 3, 5-tri (1H-imidazol-1-ly) benzene and H2BDC =...
 
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE01004G, Paper
Conformational polymorphism of a series of 2,5-bis(N,N-dibenzylamino)-3,6-dicyanopyrazine dyes, with high molecular flexibility in a non-hydrogen-bonding system, is described. Three derivatives having a substituent at the 4-position of the benzyl groups...
 
Wei Liu, Tao Yang, Chengxiang Li, Ping Che and Yongsheng Han
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE01005E, Paper
Controllable synthesis of materials with designed structure is a long term dream of scientists and engineers. The challenge faced by dreamers is the complexity of material formation and the diversity...
 
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE00659G, Paper
Galvanic replacement is a versatile synthetic strategy for the synthesis of alloy and hollow nanostructures. The structural evolution of single crystalline and multiply twinned nanoparticles < 20 nm in diameter...
 
Santiago Cañellas, Antonio Bauza, Aida Lancho, Angel garcia-raso, Juan J Fiol, Elies Molins, Pablo Ballester and Antonio Frontera
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE01009H, Paper
In this manuscript we report the synthesis and X-ray characterization of several complexes of Cu(II), Co(II) and Ni(II) with 2-(N-benzimidazolyl)-pyrimidine (L) and nitrate co-ligands. Complexes 1 and 2 are, respectively,...
 
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE00598A, Paper
Self-standing enamel-like films consisting of c-axis-oriented hydroxyapatite nanorods were fabricated by a two-step controlled crystal growth method with the monolayer of a specific artificial peptide binding to the c face of hydroxyapatite.
 
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE00029G, Paper
Thermal behaviour for the two polymorphic forms of 2,4-dinitroanisole (24DNAN) and phase transition of the β-form were studied by variable-temperature single-crystal X-ray diffraction. 24DNAN shows an unusual biaxial NTE after phase transition temperature.
 
Ashwini Nangia and T. N. Guru Row
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE90116B, Editorial
Welcome to this CrystEngComm themed issue on Polymorphism.
 
Zhanbing He, Hung Tran Nguyen, Le Duc Toan and Didier Pribat
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE00773A, Paper
The turning angles of kinked Si nanowires are governed by the different combinations of three types of {111} twins, where TBs are normal to (Twin I), inclined to (Twin II) or parallel to (Twin III) the axes of Si nanowires.
 
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE00768B, Paper
By tuning N-donor sites of 1-benzyl-1H-triazole, four polyoxometalate (POM)-based compounds modified by mono-nuclear metal–organic subunits and two POM-based compounds containing linear and cycle-like tri-nuclear clusters have been obtained.
 
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE00778J, Paper
The aggregation of a series of strained dehydrobenzoannulene derivatives with methyl ester groups is revealed.
 
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE00816F, Paper
The relationship between the two-photon absorption (TPA) properties and the coplanarity of the cations of LI2, L(BPh4)2 and L[Eu(TTA)4]2, was investigated. L[Eu(TTA)4]2 exhibits larger TPA cross-section and can be successful application in TPE microscopy.
 
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE00809C, Paper
Three copper(II) Schiff base complexes have been synthesized and characterized. Supramolecular assemblies in the solid state are analyzed by DFT calculations.
 
Linyan Yang, Yanping Zhang, Rui Lv, Jingyao Wang, Xin Fu, Wen Gu and Xin Liu
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE00911A, Communication
A self-assembled functionalized metal-organic nanotubes, compound 1 has been hydrothermally synthesized using 5-(3-methyl-5-phenyl-4H-1, 2, 4-triazol-4-yl) isophthalic acid (H2L) with Zn(II) ions. Compound 1 possesses one dimensional (1D) nanotubular architecture. Luminescent...
 
Hyunsoo Ryu, Yanyan Mulyana, In-Hyeok Park, Jinhee Kim, Lenard F. Lindoy and Shim Sung Lee
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE01127B, Paper
The macrocyclic pillar ligand, dipyridyldibenzotetraaza[14]annulene (H2L), in the absence and presence of the dicarboxylate coligands, biphenyl-4,4′-dicarboxylic acid (H2bpdc) or benzene-1,3-dicarboxylic acid (H2bdc), reacts with nickel(II), cobalt(II), and zinc(II) to yield...
 
Xiaohui Su, Xianfeng Yang, Lin Yu, Gao Cheng, Huanhua Zhang, Ting Lin and Feng-Hua zhao
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE00707K, Paper
Branched α-MnO2 nanorods are synthesized using a facile hydrothermal method without surfactants or templates. The formation of α-MnO2 with different morphologies, including branched nanorods and nanorods with controllable length, is...
 
Xingxuan Huang, Hongkang Wang, Chunming Niu and Andrey L. Rogach
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE00867K, Highlight
Design and synthesis of SnO2 nanoarrays on versatile substrates and their applications in energy storage and conversion are reviewed.
 
German Montes-Hernandez, Francois Renard, Nathaniel Findling and Anne-Line Auzende
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C4CE01598C, Paper
This study reports a simple, innovative and fast method to synthesize porous calcite mesocrystals with high specific surface area from Ca(OH)2-water-CO2 slurry in the presence of common domestic drinks (soluble...
 
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE01042J, Paper
Propeller-shaped molecules with 2,4,5-trisubstituted-1,3-thiazole as hub and tunable blades (B1-B3) were synthesized as trivariant scaffolds. B1-B3 were modulated by varying hydrazone capping in B1, isothiocyanate in B2 and α-haloketone in...
 
Shinji Yamada, Nodoka Sako, Kazuhiko Yamada, Kenzo Deguchi and Tadashi Shimizu
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C4CE02517B, Communication
4-Nitrostyrylpyridine hydrochloride forms porous crystals stabilized by cation-π and NO2···Cl- interactions that involve water clusters with a T5(2) motif in the channels. The crystals reversibly release and re-uptake water molecules....
 
Yuuya Yoshii, Ken-ichi Sakai, Norihisa Hoshino, Takashi Takeda, Shin-ichiro Noro, Takayoshi Nakamura and Tomoyuki Akutagawa
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C4CE02519A, Paper
The Brønsted acid-base reaction between 3-hydroxy-2-quinoxalinecarboxylic acid (Hhqxc) and imidazole (Im) in acetone-H2O yielded two 1:1 salts: anhydrous (HIm+)(hqxc-) (1) and hydrated (HIm+)(hqxc-)•(H2O) (2), where HIm+ and hqxc- are imidazolium...
 
Amelia R Perry, Robert Alexander Lazenby, Maria Adobes-Vidal, Massimo Peruffo, Kim McKelvey, Michael E Snowden and P R Unwin
CrystEngComm, 2015, Accepted Manuscript
DOI: 10.1039/C5CE00138B, Paper
Dissolution kinetics of the (110) face of salicylic acid in aqueous solution is determined by hopping intermittent contact-scanning electrochemical microscopy (HIC-SECM) using a 2.5 µm diameter platinum ultramicroelectrode (UME). The...
 
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE00828J, Communication
A pyridinedicarboxylate-containing Zn-MOF structure was modulated using pyridine and 4,4′-bipyridine to generate highly porous N-doped carbon adsorbents for CO2 capture.
 
CrystEngComm, 2015, Advance Article
DOI: 10.1039/C5CE00767D, Paper
Nine new compounds were synthesized from a terpyridine-based ligand containing sulfo groups, H2DSPTP. The structural diversity, crystalline–amorphous–crystalline phase transition and the luminescence properties of selected compounds were explored.
 

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