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Journal cover: Chemical Communications

Chemical Communications

Urgent high quality communications from across the chemical sciences.
Impact Factor 6.567 100 Issues per Year Indexed in Medline
 
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Guang Yang, Zdravko Kochovski, Zhongwei Ji, Yan Lu, Guosong Chen and Ming Jiang
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04250C, Communication
From themed collection Host–guest chemistry
In this report, orthogonal non-covalent interaction strategy based on specific recognition between sugar and protein, and host-guest interaction, was employed to construct artificial three dimensional (3D) protein assemblies in laboratory.
 
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04882J, Communication
We report the design and synthesis of a photoactivatable azido-acyl oxazine fluorophore. Photoactivation is achieved cleanly and rapidly with UV light, producing a single fluorescent oxazine photoproduct. We demonstrate the...
 
Zuolun Zhang, Zheng Wang, Martin Haehnel, Antonius Eichhorn, Robert M Edkins, Andreas Steffen, Anke Krueger, Zhenyang Lin and Todd B Marder
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04831E, Communication
The (B-Cl)-chloroboroles 2-chloro-1,3-di(4-R-phenyl)-2,4,5,6-tetra-hydrocyclopenta[c]borole (R = H, Br) undergo a novel dimerization process in CH2Cl2 solution. The resulting unsymmetric dimers are highly fluxional in solution via reversible enantiomerization through an intermediate...
 
Yousoon Lee, Khalil A. Abboud, Ricardo García-Serres and Leslie J. Murray
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04671A, Communication
A μ3-sulfide bridged triiron cluster(II,II,III) supported by a cyclophane ligand undergoes metal-based reduction to yield an all-ferrous species.
 
Jianchao Liu, Xiaobing Xu, Jiuyi Li, Bo Liu, Huanfeng Jiang and BiaoLin Yin
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04298H, Communication
.A protocol for Pd-catalyzed intra- and intermolecular 2,5-alkoxyarylation reactions of furans to diastereospecifically synthesize two series of spirooxindoles is reported. This protocol likely involves an intramolecular dearomatizing Heck-type α-arylation of...
 
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04735A, Communication
A convergent, transition-metal-free synthesis of 2-aryl-azaindoles enabled by carbene catalysis is reported with high yields and a wide substrate scope featuring previously inaccessible azaindoles.
 
Qing Pan, Leon Freitag, Tanja Kowacs, Jane C. Falgenhauer, Jeroen P. Korterik, Derck Schlettwein, Wesley R. Browne, Mary T. Pryce, Sven Rau, Leticia González, Johannes G. Vos and Annemarie Huijser
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC05222C, Communication
The contrasting early-time photodynamics of two related Ru/Pt photocatalysts are reported.
 
Xin Zhang, Lin Chen, Xiang-Yu Chen, Hanzhi Zhang, Liuqing Yang and Fengchun Yang
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04139F, Communication
The electrochemical behaviors of m- and s-SWNTs obtained from as-prepared SWNTs using a novel binaphthyl based separation agent were very different, and can be further interconverted through changing the DOS via electron or hole doping.
 
Yu-Teng Zhang, Xin-Long Wang, Shuang-Bao Li, Ya-Ru Gong, Bai-Qiao Song, Kui-Zhan Shao and Zhong-Min Su
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04583A, Communication
A series of vanadium-based metal–organic polyhedra were obtained through the self-assembly of Anderson-like alkoxo-polyoxovnadate {V6S} clusters with different carboxylate ligands.
 
Onkar S. Nayal, Maheshwar S. Thakur, Vinod Bhatt, Manoranjan Kumar, Neeraj Kumar, Bikram Singh and Upendra Sharma
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04381J, Communication
Reductive N-alkylation through a carbocationic pathway.
 
Ya-Lan Chu, Yen-An Chen, Wei-Chin Li, Jean-Ho Chu, Chun-Hu Chen and Chao-Ming Chiang
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC02618D, Communication
Graphene acts as a photosensitizer to induce decomposition of t-butyl peroxybenzoate, and solid matrix permitting radicals to be trapped and characterized.
 
Yao-Yu Xiao, Xiao-Lei Gong, Yang Kang, Zhi-Chao Jiang, Sheng Zhang and Bang-Jing Li
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC03587F, Communication
Light-, pH- and thermal-responsive hydrogels with the triple-shape memory effect.
 
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC01251E, Feature Article
With significant development in the computational methods applied to open-shell systems and tremendous improvements in computing resources, molecular modelling has become an integral part of the study of molecular magnetism. In this feature study, we have attempted to provide a bird's-eye view of the modelling of various spin Hamiltonian parameters of molecular nanomagnets.
 
Jose Luis Jimenez Blanco, Fernando Ortega-Caballero, Laura Blanco-Fernández, Thais Carmona, Gema Marcelo, María Martínez-Negro, Emilio Aicart, Elena Junquera, Francisco Mendicuti, Conchita Tros de Ilarduya, Carmen Ortiz Mellet and Jose Manuel Garcia Fernandez
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04791B, Communication
A convergent preparation of Janus molecular nanoparticles by thiourea-“clicking” of ,’-trehalose halves has been implemented; the strategy let access macrocyclic derivatives with seggregated cationic and lipophilic domains that in the...
 
Yaxin Chen, Zhiwei Huang, Meijuan Zhou, Pingping Hu, Chengtian Du, Lingdong Kong, JM Chen and Xingfu Tang
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC03097A, Communication
Surface silver atoms with upshifted d-orbitals are identified as the catalytically active sites of formaldehyde oxidation by correlating activity with the number of the surface silver atoms, and the degree...
 
Rajkumar Misra, Rahi M Reja, Narendra L V, Gijo George, S Ragothama and Hosahudya N Gopi
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04502B, Communication
We are reporting the influence of foldamer structures on their self-assembled architectures. In a sharp contrast to ordered alpha,gamma-hybrid 12-helix obtained from 1:1 alternating Aib and gamma-Phe, the alpha,gamma-hybrid peptides...
 
Youn Jeong Jang, Jaegeon Ryu, Dongki Hong, Soojin Park and Jae Sung Lee
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04775K, Communication
3D multi-stacked hyperporous silicon flake (MHSF) are prepared via selective chemical reduction of natural clay minerals bearing MgO negative catalyst layers. The resultant MHSFs are used as a photocatalyst for...
 
Shanchao Wu, Na Liu, Guoqiang Dong, Lin Ma, Shengzheng Wang, Wencai Shi, Kun Fang, Shuqiang Chen, Jian Li, WN Zhang, Chunquan Sheng and Wei Wang
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC03071H, Communication
An efficient redox-amination-aromatization-Friedel-Crafts acylation cascade process from trans-4-hydroxyproline and 2-formylbenzoic acids has been developed for the synthesis of pyrrolo[1,2-b]isoquinolin-10(5H)-ones. Compound 3h was identified as a new potent dual topoisomerase I/II...
 
Leonardo Degennaro, Daniela Maggiulli, Claudia Carlucci, Flavio Fanelli, Giuseppe Romanazzi and RENZO LUISI
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04588J, Communication
Tertiary butyl esters find large applications in syntetic organic chemistry. A straightforward method for the direct introduction of the tert-butoxycarbonyl group into a variety of organic compounds has been developed...
 
Wei Hou, Ya-Xi Yang, Yunxiang Wu, Huijing Feng, Yuan-Chao Li and Bing Zhou
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC03846H, Communication
A Rh(III)-catalyzed intermolecular chelation-assisted insertion of carbenes derived from α-diazocarbonyl compounds into non-acidic primary sp3 C-H bonds, for the first time, is reported under mild reaction conditions, thus affording a...
 
Jin Kim, Yujeong Kim, Indranil Sinha, Koeun Park, Sun Hee Kim and Yunho Lee
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC03983A, Communication
A paramagnetic cobalt-SiH intermediate possessing a Co–(η1-H–Si) moiety was studied using various spectroscopic techniques. Frozen solution ENDOR experiments show a Co–H distance of ~1.53 Å and Si–Co–H angle of ~15°,...
 
Debora Ressnig, Simona Moldovan, Ovidiu Ersen, Patricia Beaunier, David Portehault, Clement Sanchez and Sophie Carenco
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04157D, Communication
An expeditious synthesis of metal carbide nanoparticles onto various carbon supports is demonstrated. The procedure is versatile and readily yields TiC, VC, Mo2C and W2C nanoparticles on different types of...
 
Xiao-Lei Li, Jianfeng Wu, Jinkui Tang, Boris Le Guennic, Wei Shi and Peng Cheng
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05326B, Communication
A unique Dy6 complex with planar Dy3+Dy3 structure was assembled by delicately modifying the axial ligands. Single-molecule magnet behavior, and meanwhile the toroidal magnetic moment in the ground state have...
 
Toyoharu Kobayashi, Ryuta Shioi, Ai Ushie, Hideki Abe and Hisanaka Ito
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04828E, Communication
The first total synthesis of (+)-artalbic acid has been accomplished using asymmetric allylation of an acetoacetate derivative with a phase-transfer catalyst. This synthetic work was completed in 12 steps from...
 
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04721A, Communication
An adjustable broadband reflector based on a polymer stabilized chiral nematic liquid crystal has been fabricated.
 

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DOI: 10.1039/C4CC03312D
Published: 06 Jun 2014

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