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Journal cover: Chemical Communications

Chemical Communications

Urgent high quality communications from across the chemical sciences.
 
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Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00274B, Communication
Although there are numerous claims of remote group participation leading to synthesis of expected glycosides with improved anomeric geometry outcome in glycosylation, there are still lack of enough forceful evidences...
 
Atsushi Ikeda, Tomoya Mae, Masafumi Ueda, Kouta Sugikawa, Hajime Shigeto, Hisakage Funabashi, Akio Kuroda and Motofusa Akiyama
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00302A, Communication
[60]Fullerene (C60) derivatives were incorporated into liposomes using a fullerene exchange method involving the transfer of the fullerene from the cavity of two γ-cyclodextrin molecules to a liposome. A lipid-membrane-incorporated...
 
Takashi Kurogi, Patrick Carroll and Daniel J Mindiola
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00371D, Communication
Radical coupling or oxidation of the titanium(III) dimethyl precursor (PNP)Ti(CH3)2 produced the dimethyl compounds, (PNP)Ti(CH3)2(X) (X = TEMPO, OMes*, OTf), which then thermally extrude methane to cyclometallate (X = TEMPO)...
 
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00537G, Communication
We present here a rational design and fabrication for all-weather dye sensitized solar cells tailored with long persistence phosphor materials, yielding a maximized photoelectric conversion efficiency of 8.86% under simulated...
 
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00165G, Communication
Bis(sulfonamide) based synthetic carriers are reported for inversion of ion selectivity upon deviation of pH within a narrow window. A liposomal membrane potential is also generated when potassium ion is...
 
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C6CC10321A, Communication
A polypyridyl ruthenium sensitizer possessing pyridyl anchors (Ru-py) forms much stronger chemical linkages to the TiO2 surfaces compared to the conventional carboxylate and phosphonate ones. A highly stable dye-sensitized photoelectrochemical...
 
Yuhei Arai, Syoji Ito, Hajime Fujita, Yusuke Yoneda, Takahiro Kaji, Satoshi Takei, Ryota Kashihara, Masakazu Morimoto, Masahiro Irie and Hiroshi Miyasaka
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C6CC10073B, Communication
We demonstrated one-colour control of activation, excitation and deactivation of a fluorescent diarylethene derivative by using a 532-nm CW laser at a weak output power. This one-colour control method was...
 
Jaroslaw Grzegorz Osiak, Tobias Setzer, P G Jones, Christian Lennartz, Andreas Dreuw, Wolfgang Kowalsky and Hans-Hermann Johannes
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00697G, Communication
The first successful meridional to facial isomerization of homoleptic carbenic iridium(III) complexes is presented. The Brønsted-acid-mediated procedure allows the conversion of large amounts of material and additionally provides an in...
 
Lauren Grant, Seihwan Ahn, Brian Manor, Mu-Hyun Baik and Daniel J Mindiola
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00654C, Communication
The first example of a structurally characterized titanium methylidene, (PN)2Ti=CH2, has been prepared via one-electron oxidation of (PN)2Ti(CH3) followed by deprotonation or by H-atom abstraction using an aryloxyl radical. The...
 
Yi Yang Wu, Miao Meng, Gang Yi Wang, Pengju Feng and Chun Yuan Liu
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00119C, Communication
Four thienylene (C4H2S) bridged Mo2 dimers, [Mo2(DAniF)3]2(μ-OOCC4H2SCOO) (DAniF=N,N′-di(p-anisyl)formamidinate), [Mo2(DAniF)3]2(μ-N(H)SCC4H2SCN(H)S), [Mo2(DAniF)3]2(μ-OSCC4H2SCSO) and [Mo2(DAniF)3]2(μ-SSCC4H2SCSS), have been synthesized and studied in terms of electronic coupling. The subtle structural differences between these compounds vary...
 
Xiao-Lei Li, Jianfeng Wu, Lang Zhao, Wei Shi, Peng Cheng and Jinkui Tang
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00048K, Communication
A rare end-to-end azido-pinned interlocking lanthanide squares was self-assembled using ditopic Schiff-base (H2L) and NaN3 as ligands. Obvious ferromagnetic interaction and the record anisotropy barrier for any lanthanide azido-bridged SMMs...
 
Douglas R. Nevers, Curtis B. Williamson, Tobias Hanrath and Richard D. Robinson
Chem. Commun., 2017, Advance Article
DOI: 10.1039/C6CC09549F, Communication
From themed collection Frontiers in Nanocrystal Surface Chemistry
Optoelectronic properties of nanoparticles are intimately coupled to the complex physiochemical interplay between the inorganic core and the organic ligand shell.
 
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00837F, Communication
o-Phenylenediamido Pb(II) and Sn(II) complexes react with mesityl azide in analagous C-H activation reactions. The Pb(II) complex forms a Lewis pair with ONMe3. The Sn(II) analogue reacts with AgOTf yielding...
 
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00784A, Communication
A dihydroxy-substituted benzothienobenzothiophene, BTBT(OH)2, was synthesized, and its charge-transfer (CT) salt, β-[BTBT(OH)2]2ClO4, was successfully obtained. Thanks to the introduced hydroxy groups, a hydrogen-bonded chain structure connecting the BTBT molecules and...
 
Sophie R Harvey, Yang Liu, Wen Liu, Vicki H Wysocki and Arthur Laganowsky
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C6CC09606A, Communication
Native ion mobility mass spectrometry (MS) and surface induced dissociation (SID) are applied to study the integral membrane protein complexes AmtB and AqpZ. Fragments produced from SID are consistent with...
 
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00108H, Communication
A highly diastereoselective palladium catalyzed cinnamylation of N-tert-butanesulfinyl imines with cinnamyl acetates has been established to provide enantioenriched β-aryl homoallylic amines. The synthetic application of this stragety has been successfully...
 
Tile Gieshoff, Anton Kehl, Dieter Schollmeyer, Kevin D. Moeller and Siegfried R Waldvogel
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00927E, Communication
A novel electrochemical method for the synthesis of benzoxazoles from readily available anilides is reported. Various functionalities are tolerated and good yields can be achieved. By employing common electrode materials...
 
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00678K, Communication
A visible light driven catalytic cycle for hydrocarboxylation of alkenes with CO2 was established using a combination of Rh(I) complex as a carboxylation catalyst and [Ru(bpy)3]2+ (bpy = 2,2’-bipyridiyl) as...
 
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC00269F, Communication
Regio- and stereoselective β-mannosylations using 1,2-anhydromannose and diol sugar acceptors in the presence of a boronic acid catalyst proceeded smoothly to give the corresponding β-mannosides with high regio- and β-stereoselectivities...
 
Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C6CC10319G, Communication
A self-repairing metal-enzyme hybrid nanocatalyst with sodium alginate (SA) coating was reported in this study. Compared with free enzyme, immobilized chloroperoxidase (CPO) has similar Km and Kcat values. SA-coated CPO@Ca3(PO4)2...
 
Irene Arrata, Anna Barnard, Darren C. Tomlinson and Andrew J. Wilson
Chem. Commun., 2017, Advance Article
DOI: 10.1039/C6CC09395G, Communication
Selection methods are used to identify Affimers that recognise α-helix mimicking N-alkylated aromatic oligoamides.
 
Wouter Engelen, Kayleigh M. van de Wiel, Lenny H. H. Meijer, Bedabrata Saha and Maarten Merkx
Chem. Commun., 2017, Advance Article
DOI: 10.1039/C6CC10032E, Communication
From themed collection Biological optical imaging
Bioluminescent molecular beacons have been developed using a modular design approach that relies on BRET between the bright luciferase NanoLuc and a Cy3 acceptor.
 
Yeong-Eun Kim, Jin Kim, Joon Woo Park, Kiyoung Park and Yunho Lee
Chem. Commun., 2017, Advance Article
DOI: 10.1039/C6CC10139A, Communication
Introduction of weak σ-SiH coordination to a copper(I) center leads to a highly emissive copper complex to minimize geometry relaxation in MLCT excited states.
 
Chem. Commun., 2017, Advance Article
DOI: 10.1039/C7CC00783C, Communication
X-ray crystallography reveals key interactions in the pharmacophore of the antibiotic teixobactin.
 
Albert Gandioso, Anna Massaguer, Núria Villegas, Cándida Salvans, Dani Sánchez, Isabelle Brun-Heath, Vicente Marchán, Modesto Orozco and Montserrat Terrazas
Chem. Commun., 2017, Advance Article
DOI: 10.1039/C6CC10287E, Communication
Efficient click siRNA–peptide conjugation for targeted delivery into tumor cells.
 

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232 citations
A collaborative sensitization by silyl-anchor and carboxy-anchor dyes (ADEKA-1 + LEG4) in dye-sensitized solar cells realized a high light-to-electric energy conversion efficiency of over 14% under one sun illumination.
DOI: 10.1039/C5CC06759F
Published: 14 Sep 2015
37 citations
This feature article discusses the rational control of nano-scale metal catalysts for catalytic biomass transformation.
DOI: 10.1039/C6CC00336B
Published: 14 Mar 2016
110 citations
Neutron diffraction shows the methylammonium cation in the photovoltaic [CH3NH3]PbI3 demonstrates increasing positional disorder on heating from 100 K to 352 K.
DOI: 10.1039/C4CC09944C
Published: 23 Jan 2015

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