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Chemical Communications

Urgent high quality communications from across the chemical sciences.
Impact Factor 6.567 100 Issues per Year Indexed in Medline
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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05735G, Communication
A novel protocol for synthesis of polycyclic compounds from linear diynes and diaryliodonium salts has been realized. The reaction proceeded through Cu-catalyzed arylation of alkyne to generate vinyl carbocation intermediates...
Janine Ackermann, Adelheid Hagenbach and Ulrich Abram
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05811F, Communication
Reactions between [TcI(NO)X2(PPh3)2(CH3CN)] complexes (X = Cl, Br) and KCp form the pseudotetrahedral organotechnetium compounds [TcI(NO)(Cp)(PPh3)X]. The halide ligands can readily be replaced by other halides or organometallic ligands giving access...
Felix Hanke, Sarah Hindley, Anthony Jones and Alexander Steiner
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05851E, Communication
The solid state structure of dimethylcadmium, a classic organometallic compound with a long history, has remained elusive for almost a century. X-ray crystallography and density functional theory reveal similar phase...
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04949D, Communication
White luminescence composite films containing Dy-polyoxometalate (Dy-POM) were firstly constructed by layer-by-layer assembly method for realization of electrically controlled luminescence switching, additionally, blue-white luminescence could be switched by choice of...
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04516B, Communication
Linker free molecular design based on 1-carbazolylcarbazole was effective in improving delayed fluorescence characteristics and device performances.
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC03943J, Communication
An ion-gating nanochannel system was built by immobilizing a Cu2+-responsive self-cleaving DNAzyme, which could control the ion transport by regulating the surface charge density of the channels.
Rapeepat Sangsuwan, Allie C. Obermeyer, Phum Tachachartvanich, Krishnan K. Palaniappan and Matthew B. Francis
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04575H, Communication
A convenient two-step method is described for the detection of nitrotyrosine-containing proteins.
M. Elsayed Moussa, B. Attenberger, E. V. Peresypkina, M. Fleischmann, G. Balázs and M. Scheer
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC05224J, Communication
The selective synthesis of a series of new 1D organometallic–organic coordination polymers is shown. They are obtained from the reaction of the diphosphorus complex [Cp2Mo2(CO)42-P2)] with Cu[CH3CN]4BF4 and flexible bipyridyl linkers.
Takuma Yamaguchi, Yadagiri Kommagalla, Yoshinori Aihara and Naoto Chatani
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC05330K, Communication
The reaction of aromatic amides with unactivated olefins in the presence of Co(OAc)2 gave allylated products, not vinylated products.
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04919B, Communication
A fluorescence switch based on a pH-sensitive dye and a cationic pillar[5]arene was employed in fluorescence indicator displacement detection of phenolic contaminants.
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04823D, Communication
A spherical assembly containing a perylene stack, prepared from a rigid tribranched scaffold and perylene, exhibits unusual Y-emission in water at room temperature. In contrast, an analogous assembly from a flexible scaffold and perylene shows E-emission under the same conditions.
Reiner Sebastian Sprick, Baltasar Bonillo, Michael Sachs, Rob Clowes, James R. Durrant, Dave J. Adams and Andrew I. Cooper
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC03536A, Communication
Conjugated microporous polymers (CMPs) have been used as photocatalysts for hydrogen production from water in the presence of a sacrificial electron donor.
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC03530B, Communication
C1-Benzoyl isoquinolines can be generated via a palladium(II)-catalyzed C–C and C–O coupling of isoquinoline N-oxides with aromatic nitroalkenes.
Huan Sun, Yan Ren, Weijie Hou, Lin Li, Fanqi Zeng, Sisi Li, Yongfen Ma, Xiao Liu, She Chen and Zhiyuan Zhang
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04030F, Communication
BTC-ABPP was developed by converting the reactants of a click conjugation from proteins (biochemistry) to peptides (chemistry) to identify the modified peptides.
Xun Wang, Azhar Mahmood, Faisal Saleem, Haifeng Lin and Bing Ni
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04079A, Communication
Crystallinity offers countless opportunities for the controlled synthesis of multimetallic 2D and 3D nanomaterials. Herein we have successfully synthesized 2D Pt-Ag ultrathin nanosheets through the oxidative etching of twin seeds...
Qianrong Fang, Daliang Zhang, Dan Xu, Houbing Zou, Liangkui Zhu, Ming Xue and Shilun Qiu
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05366A, Communication
A series of in-situ hot stage experiments in transmission electron microscopy (TEM) were studied to directly observe the transition of a Ni-MOF to Ni nanoparticles (NPs) over the temperature range...
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05359A, Communication
Herein we report the synthesis and structural characterization of a series of novel Zr(IV)salan complexes. The initial metalation product [(L1)2Zr] is highly water sensitive while ligand exchanged [L1Zr(dipic)] hydrolyses slowly...
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05074C, Communication
Rh(III)/Cu(OAc)2 catalyzed, one-pot reactions of aryl ketones, acrylate esters and ammonium acetate or a-substituted benzylamines under microwave irradiation conditions produce 1H-isoindoles bearing a quarternary carbon center.
Xiaolan Chen, Jian Han, Yan Zhu, Chunchen Yuan, Jingyu Zhang and Yingsheng Zhao
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05560E, Communication
Direct Transformation of directing group to important synthetic units would provide a high atom efficiency synthetic approach in synthetic chemistry. Herein, a convenient protocol in synthesis of o-aminobenzaldehyde and benzoxazole...
Lu Liu, Daniel D Taylor, Efrain E Rodriguez and Michael Zachariah
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC01997H, Communication
The selection of highly efficient oxygen carriers (OCs) is a key step necessary for the practical development of chemical looping combustion (CLC). In this study, a series of ABO3 perovskites,...
Makoto Saikawa, Takashi Nakamura, Junji Uchida, Masaki Yamamura and Tatsuya Nabeshima
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05439K, Communication
A macrocyclic bisBODIPY (bis(boron-dipyrromethene)) complex [1B2] with a figure-of-eight helicity was synthesized and successfully resolved. [1B2] was proven to be one of the most efficient red-emitting CPL (circularly polarized luminescence)...
Venkatachalam Rajeshkumar and Mihaiela C. Stuparu
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04910A, Communication
Conjugated aromatic units of choice can be fused to corannulene in an efficient manner through a photo-induced oxidative cyclization process.
Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05514A, Communication
A pillar[5]arene-based pseudo[2]rotaxane was synthesized using a slippage method by only heating an axle with bulky valine derivative ends in a cyclic host liquid (CHL), which is liquid at room...
David E. Stephens, Johant Lakey-Beitia, Jessica E. Burch, Hadi D. Arman and Oleg V. Larionov
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04816A, Communication
N-Heterobiaryls can be prepared directly from heterocyclic N-oxides, or N-heterocycles in a scalable, transition metal-free, KOt-Bu-mediated process.
M. Al Hareri, E. L. Gavey, J. Regier, Z. Ras Ali, L. D. Carlos, R. A. S. Ferreira and M. Pilkington
Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC03578G, Communication
The magnetization dynamics of an emissive [Dy(OH2)8]3+ complex with local pseudo D4d symmetry encapsulated within a supramolecular cage have been unraveled by magneto-optical and ab initio studies.

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95 citations
A collaborative sensitization by silyl-anchor and carboxy-anchor dyes (ADEKA-1 + LEG4) in dye-sensitized solar cells realized a high light-to-electric energy conversion efficiency of over 14% under one sun illumination.
DOI: 10.1039/C5CC06759F
Published: 14 Sep 2015
88 citations
This Feature Article covers recent research endeavors of the marriage between pillararene-based host–guest pairs and supramolecular polymeric assemblies.
DOI: 10.1039/C4CC03170A
Published: 11 Jul 2014
87 citations
In this feature article, we address the synthesis and design strategies for the development of fluorescent probes for H2S, based on the reaction type between H2S and the probes.
DOI: 10.1039/C4CC03312D
Published: 06 Jun 2014

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