Themed collection 2024 Inorganic Chemistry Frontiers HOT articles
Luminescent iridium(III)–peptide bioconjugates for bioanalytical and biomedical applications
We describe the interactions between iridium(III) complexes and peptides and the emerging applications of iridium(III)–peptide bioconjugates in biomedical fields, summarizing and commenting on their widespread applications for bioimaging and therapy.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00625A
Surface functionalization of metal–organic framework nanoparticle for overcoming biological barrier in cancer therapy
Surface modification of MOF particle for overcoming biological barriers.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00523F
Advances in technical strategies for monitoring the reduction of platinum(IV) complexes
The reduction of Pt(IV) complexes can be monitored by various analytical techniques. These techniques hold significant promise in elucidating the mechanisms of Pt(IV) prodrug activation, aiding in the rational design of novel Pt(IV) prodrugs.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00459K
Porphyrin-based MOFs for photocatalysis in water: advancements in solar fuels generation and pollutants degradation
This review highlights the recent advances in the photocatalytic applications of porphyrin-based MOFs in aqueous environments for solar fuel generation and water remediation.
Inorg. Chem. Front., 2024,11, 2212-2245
https://doi.org/10.1039/D3QI01996A
Tailoring co-catalysts on Si photocathodes for efficient photoelectrochemical CO2 reduction: recent progress and prospects of deposition methods
This review examines recent advancements in co-catalyst design and loading strategies for photoelectrochemical CO2 reduction, emphasizing deposition methods such as physical vapor deposition, drop-casting, and photo/electrodeposition.
Inorg. Chem. Front., 2024,11, 998-1018
https://doi.org/10.1039/D3QI02293E
Constructing medium-entropy spinel oxide FeNiMnO4/CeO2 heterojunction as high-performance electrocatalyst for oxygen evolution reaction
Inorg. Chem. Front., 2024, Accepted Manuscript
https://doi.org/10.1039/D4QI00770K
RbPbPS4: a promising IR nonlinear optical material achieved by lone-pair-cation-substitution-induced structure transformation
A novel excellent IR-NLO material RbPbPS4 with superior comprehensive performances is provided, representing the first quaternary Pb-based chalcogenide breaks through the incompatibility between a large Eg and a strong deff.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI01040J
Insights into the origin of Co-based bimetallic catalysts with a para-structure exhibiting ORR and OER bifunctional activities
The development of non-precious metal catalysts with oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) bifunctional activities is of great significance for the development of fuel cells.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00793J
Calix[6]arene-Functionalized Titanium-oxo clusters for Photocatalytic Cycloaddition of Carbon Dioxide to Epoxides
Inorg. Chem. Front., 2024, Accepted Manuscript
https://doi.org/10.1039/D4QI00930D
Enhanced photocatalytic CO2 reduction to CH4 via restorable surface plasmon and Pdn–Wδ+ synergetic sites
The integration of Wδ+–Pdn synergetic sites and plasmonic properties in the preactivated Pd/W18O49 catalyst results in excellent performance for photocatalytic CO2 reduction.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00812J
An unprecedented Cu6 cluster-based bimetallic MOF with multiple open sites for high CO2 capture and efficient CO2 conversion
Through soft-hard acid-base theory, a novel bimetallic MOF (JLU-MOF108) with an unprecedented 12-connected Cu6 cluster SBU was synthesized. LAS and LBS inside JLU-MOF108 exhibited significant CO2 capture and conversion capability.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00692E
The interaction of carbon nanotubes (CNTs) with CuCoO2 nanosheets promotes structural modification and enhances their OER performance
The interaction of CNTs with CuCoO2 increases the oxygen vacancy concentration and activates lattice oxygen, which promotes the simultaneous occurrence of AEM and LOM and improves the OER performance.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00742E
Copper doping boosts the catalase-like activity of atomically precise gold nanoclusters for cascade reactions combined with urate oxidase in the ZIF-8 matrix
A biocompatible cascade system was constructed by integrating the merits of urate oxidase and atomically precise Au nanoclusters with tunable catalase-like activity in ZIF-8 for constructing potential drug delivery systems.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00573B
Narrow-band circularly polarized red electroluminescence in trinuclear clusters
R/S-PtAu2 cluster enantiomers exhibit highly efficient narrow-band red emission with a FWHM of 25–29 nm as well as excellent chiral absorption and emission characteristics with a dissymmetry factor of ±1.0 × 10−3 for CPL and ±7 × 10−4 for CPEL.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00973H
A “Flotation” Strategy for Tailoring Solid Electrolyte Interphase on 3D Composite Li Anode
Inorg. Chem. Front., 2024, Accepted Manuscript
https://doi.org/10.1039/D4QI00632A
Fullerene rotation dictated by benzene–fullerene interactions
The temperature-driven dynamics of Dy2ScN@C80 in the crystal was rigorously visualized with single crystal X-ray diffraction, indicating a surprising effect of benzene positions dictating fullerene rotation.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00831F
Designing Deep Cavity Aluminum Organic Macrocycles to Trap Dyes Generating Enhanced Non-linear Optical Performance
Inorg. Chem. Front., 2024, Accepted Manuscript
https://doi.org/10.1039/D4QI00976B
A chelating coordination modulation method for the synthesis of Ti-MOF single crystals
A chelation coordination modulation (CCM) method has been developed for the synthesis of novel Ti-MOFs.
Inorg. Chem. Front., 2024,11, 2876-2883
https://doi.org/10.1039/D4QI00436A
Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
Inorg. Chem. Front., 2024,11, 2863-2875
https://doi.org/10.1039/D4QI00287C
High ratios of Ni3+ and Co3+ facilitated by Mn-addition for enhanced oxygen evolution reaction and ethanol oxidation reaction
The design of dual-functional catalyst for oxygen evolution reaction and ethanol oxidation reaction is essential for improving H2 production efficiency, and one strategy to improve catalytic performance is the incorporation of high-valence metal.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00629A
Ultrathin core–shell Au@RuNi nanowires for superior electrocatalytic hydrogen evolution
Ultrathin core–shell Au@RuNi nanowires have been synthesized via the epitaxial growth of uniform fcc-structured RuNi alloy layer on the surface of ultrathin Au NWs, demonstrating remarkable alkaline HER performance and outstanding stability.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00518J
Magnifying the turn-on luminescence and electrical conductivity via the coupling effect of oxidation, metal ion adhesion and pressure within MnII-MOFs
Magnifying the turn-on luminescence and electrical resistivity of MnII2-MOFs through the coupled effect of oxidation, metal ion adhesion, and pressure.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00552J
A bimetallic CoZn metal–organic-framework derived CoZnS@NSC Co-catalyst loaded on g-C3N4 for significantly augmented photocatalytic H2 evolution
CoZnS@NSC nanoparticles derived from a CoZn-MOF were synthesized by an annealing–sulfurization strategy and used as co-catalysts for g-C3N4, which effectively augmented the photocatalytic H2 production.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00644E
Tailoring supertetrahedral cadmium/tin selenide clusters into a robust framework for efficient elimination of Cs+, Co2+, and Ni2+ ions
The elimination of radionuclides Cs+, Co2+, and Ni2+ is achieved using a supertetrahedral cluster-constructed ion exchanger CdSnSe-2K, whose soft Se component and micro-porosity synergistically contribute to the enhancement in adsorption rate, selectivity and acid resistance.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00714J
Fabrication of amorphous subnanometric palladium nanostructures on metallic transition metal dichalcogenides for efficient hydrogen evolution reaction
Metallic transition metal dichalcogenide nanosheets decorated with amorphous subnanometric Pd nanoparticles exhibit comparable HER performance to that of commercial Pt–C.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00622D
In situ formed self-embedded ion/electron conductive skeletons enabling highly stable sodium metal anodes
The NSN-3D IECF realizes fast Na+ transfer and provides enough space to suppress Na dendrites formation and accommodate metal Na deposition. The excellent affinity between metallic Na and Na15Sn4 promotes compact and uniform Na deposition.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00654B
Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups
Two outstanding UV birefringent materials SbTeO3Cl and SbTeO3Br with a honeycomb-like two-dimensional (2D) layer structure, have been successfully designed, demonstrating significant birefringence (0.281@546 nm and 0.227@546 nm, respectively).
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00791C
Incorporation of a one-dimensional electron-rich chain in viologen-based coordination polymers for super photochromic properties and improved optical applications in polyvinyl alcohol film
1D electron-rich complex chain was incorporated to the viologen complex (1), resulting in robust photochromic properties, distinct ET pathways, and applications in optics. And 1-PVA film can improve the photochromism of viologen complexes.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00200H
Defect-rich Pd@PdOs nanobelts for electrocatalytic oxidation of ethylene glycol
Reasonable design and development of catalysts with specific components and morphologies can effectively improve the catalytic performance of nanomaterials.
Inorg. Chem. Front., 2024,11, 2562-2569
https://doi.org/10.1039/D4QI00319E
An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues
The direct decomposition of nitromethane into nitrile compounds is a significant challenge due to the occurrence of severe side-reactions.
Inorg. Chem. Front., 2024,11, 2590-2597
https://doi.org/10.1039/D4QI00343H
Modulating Mn self-reduction and multimodal luminescence in CaSb2O6 through La3+ doping for quadruple-mode dynamic anti-counterfeiting and optical temperature sensing applications
The co-doping La3+strategy was employed to modulate Mn self-reduction and multimodal luminescence in CaS2O6:Mn. CaS2O6:Mn has potential application in optical anti-counterfeiting and high-sensitivity temperature sensing applications.
Inorg. Chem. Front., 2024,11, 2570-2589
https://doi.org/10.1039/D4QI00493K
Tailoring two magic number Au13 nanoclusters with N-containing diphosphine ligands: a classical icosahedral core vs. an unprecedented UFO- shaped core
Two magic number Au13 nanoclusters were tailored using two N-containing multidentate phosphine ligands with a classical icosahedral core and an unprecedented “UFO”-shaped polyhedral core, respectively.
Inorg. Chem. Front., 2024,11, 2553-2561
https://doi.org/10.1039/D4QI00334A
Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH−. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH−, and accelerated the kinetics of HMFOR.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00519H
Energetic copper(II) quadridentate chelate: a novel green laser-sensitive primary explosive
A copper(II)-based quadridentate chelate [Cu(BNATE)·2H2O] has been prepared and systematically studied. It has excellent near-infrared laser sensitivity and detonation performance, and low mechanical sensitivity.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00489B
A composite electrolyte based on aluminum oxide filler/polyester polymer via in situ thermal polymerization for long-cycle sodium metal batteries
The introduction of Al2O3 regulates the solvation structure of Na+, which is conducive to the formation of inorganic-rich SEI. Na|THFA-5|Na cell maintains low polarization voltage, indicating that uniform Na depositions was successfully achieved.
Inorg. Chem. Front., 2024,11, 2300-2311
https://doi.org/10.1039/D4QI00391H
sp2–sp cross-carbanion coupling at a rare-earth center leading to the formation of carbon–carbon double bonds
The reaction of rare-earth azametallacyclopentadienes with terminal alkynes provides rare-earth metallacycles with cumulated double bonds in three steps: alkynyl C–H bond activation, sp2–sp cross-carbanion coupling and subsequent isomerization.
Inorg. Chem. Front., 2024,11, 2312-2318
https://doi.org/10.1039/D4QI00178H
Structural phase transition drives outright photoluminescence quenching and dielectric duple bistable switching
(TECA)PbBr3 and (TEBA)PbBr3 have a wide range of photoluminescence signals and undergo coupling of the structural phase transition and photoluminescence quenching.
Inorg. Chem. Front., 2024,11, 2290-2299
https://doi.org/10.1039/D4QI00303A
Boosting structural variety and catalytic activity of porphyrinic metal–organic frameworks by harnessing bifunctional ligands
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
Inorg. Chem. Front., 2024,11, 2281-2289
https://doi.org/10.1039/D4QI00314D
Selenium doping induced phase transformation and interlayer expansion boost the zinc storage performance of molybdenum disulfide
This work synthesized Se-doped MoS2 nanosheets as a cathode for aqueous zinc-ion batteries, and they exhibited largely improved electrochemical performance owing to their high content of the 1T phase (64%) and expanded interlayer spacing (0.65 nm).
Inorg. Chem. Front., 2024,11, 2272-2280
https://doi.org/10.1039/D4QI00344F
Carboxylate trapping engineering to fabricate monodispersed dual-atom iron sites for efficient oxygen reduction
Atomically dispersed catalysts with dense accessible Fe–Fe binary active sites supported on hierarchically ordered porous N-doped carbon are prepared via a general carboxylate-assisted strategy and they display drastically enhanced ORR activity.
Inorg. Chem. Front., 2024,11, 2260-2271
https://doi.org/10.1039/D4QI00124A
Hysteretic magnetism–dielectricity switching in 2D Hofmann type spin-crossover compounds
Two 2D Hofmann type compounds {Fe(3,4-bpt)2[M(CN)4]} were synthesized. They showed reversible switching in magnetism, dielectricity, and thermochromism actuated by the spin transition of Fe(II).
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D3QI02660D
Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs
The long-neglected stereochemically active lone pair groups ClO3− and BrO3− are demonstrated to be important UV NLO functional motifs based on the fact that AClO3 and ABrO3 possess high SHG effects and short λPM and are promising UV NLO materials.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00462K
Sodium ion pre-intercalation regulates the electron density and structural stability of vanadium oxide nanowires for Ca–ion batteries
Benefiting from the abundant resource, low cost, and high operating potential, calcium–ion batteries (CIBs) have attracted great attention as emerging energy storage devices over lithium-based systems.
Inorg. Chem. Front., 2024, Advance Article
https://doi.org/10.1039/D4QI00218K
Te doped 1T/2H-MoSe2 nanosheets with rich defects as advanced anode materials for high-rate sodium ion half/full batteries
MoSe2 with a two-dimensional layer-like structure has been considered a promising anode material for sodium-ion batteries (SIBs) on account of its high capacity and rich reserves on Earth.
Inorg. Chem. Front., 2024,11, 2017-2028
https://doi.org/10.1039/D4QI00259H
Efficient catalysis of Knoevenagel condensation by 1D copper-containing heteropolyoxoniobate at room temperature
A 1D copper-containing organic–inorganic hybrid heteropolyoxoniobate catalyst for efficient catalysis of Knoevenagel condensation at room temperature.
Inorg. Chem. Front., 2024,11, 1993-1997
https://doi.org/10.1039/D4QI00260A
Highly stable chiral Cr(III)-based metal–organic frameworks for enantioadsorption separation of aromatic alcohols
Highly stable Cr-HMOFs Cr-HMOF-1 and Cr-HMOF-2 were synthesized for the first time directly using enantiomerically pure chiral ligands, showing excellent enantioselective separation performance for aromatic alcohol racemates.
Inorg. Chem. Front., 2024,11, 1998-2006
https://doi.org/10.1039/D4QI00113C
An interface-engineered Co2P/CoMoP2 heterojunction with greatly improved electrocatalytic activity in water/seawater splitting
In this work, an interface-engineered Co2P/CoMoP2 heterojunction has been prepared with greatly improved electrocatalytic activity in both water and seawater splitting.
Inorg. Chem. Front., 2024,11, 1978-1992
https://doi.org/10.1039/D4QI00098F
Highly efficient bifunctional nanofiber catalysts with 3D hierarchical nanostructures as building blocks for rechargeable Zn–air batteries
The well-distributed cobalt nanoparticles, coupled with the large specific surface area and high conductivity of the catalyst, expand the effective number of active sites to achieve high catalytic activity toward both the ORR and OER.
Inorg. Chem. Front., 2024,11, 2007-2016
https://doi.org/10.1039/D3QI02624H
A defective bismuth–indium catalyst promotes water dissociation for selective carbon dioxide electroreduction to HCOOH
A defective BiIn bimetallic catalyst derived from a P-doped BiIn pre-catalyst is developed, which enables CO2 conversion to HCOOH with high activity and selectivity.
Inorg. Chem. Front., 2024,11, 1703-1709
https://doi.org/10.1039/D4QI00053F
Straightforward construction of a rare-earth diphosphanato complex from white phosphorus: synthesis and reactivity
A straightforward and atom-economical route from P4 to polyfunctional diphosphine ligands has been developed, revealing the versatile reactivity of the RPPR moiety.
Inorg. Chem. Front., 2024,11, 1742-1753
https://doi.org/10.1039/D3QI02680A
High-density accessible Ru–Se–Ni moieties boost the hydrogen evolution reaction by optimizing H absorption
Ru-doped NiSe2 enhances HER, achieving 36 mV overpotential and exceptional durability in alkaline electrolytes, showcasing a novel approach to catalyst design.
Inorg. Chem. Front., 2024,11, 1733-1741
https://doi.org/10.1039/D3QI02668J
Boosting the high rate and durability of lithium–sulfur batteries using a bidirectional catalyst of a polyoxometalate-cyclodextrin supramolecular compound
PW12 and CD in PW12-CD supramolecular compound synergetically anchor polysulfides. PW12 bidirectionally catalyzes polysulfides conversion, accompanied by reversible transformation between reduction and oxidation states.
Inorg. Chem. Front., 2024,11, 1710-1723
https://doi.org/10.1039/D3QI02696E
Exploring multi-stimuli-responsive Pt(II) complexes: supramolecular self-assembly, lysosome-specific targeted photodynamic therapy and photodegradation of organic pollutants
Developing novel luminescent materials with multi-stimuli-responsiveness and multi-functional properties is vital.
Inorg. Chem. Front., 2024,11, 1693-1702
https://doi.org/10.1039/D3QI02584E
Hydrogen production from complete dehydrogenation of hydrazine borane on carbon-doped TiO2-supported NiCr catalysts
C-doped mesoporous TiO2-supported Cr(OH)3 modified Ni nanoparticles (Ni–Cr/CTO) with different morphologies were synthesized by a simple wet-chemical method and used as efficient catalysts for hydrogen production from hydrazine borane.
Inorg. Chem. Front., 2024,11, 1683-1692
https://doi.org/10.1039/D3QI02633G
Boosting the thermoelectric performance of Yb-filled skutterudites through the incorporation of YSb nanoprecipitates
In this work, a ZTmax of ∼1.35 at 873 K is obtained for a Y0.05Yb0.2Co4Sb12 alloy, attributed to the synergistic effects of well-formed nanoscale YSb precipitates and Yb as effective fillers.
Inorg. Chem. Front., 2024,11, 1724-1732
https://doi.org/10.1039/D3QI02439C
Last piece of the puzzle: lead-assisted assembly of an arsenopalladate nanostar as an antitumor metallodrug
Access to the long-sought nanostar of arsenopalladate is workable via host–guest assembly. The arsenate functions of such POP metallodrugs drive the ROS-induced apoptosis with great antitumor potential.
Inorg. Chem. Front., 2024,11, 1413-1422
https://doi.org/10.1039/D4QI00026A
Dearomatized diimines for nickel(II) and palladium(II) catalyzed ethylene polymerization and copolymerization
Dual steric enhancement was achieved through the combination of a dearomatized acenaphthyl backbone and bulky ortho substituents. The role of this bulky backbone in metal-catalyzed ethylene (co)polymerization was investigated.
Inorg. Chem. Front., 2024,11, 1394-1412
https://doi.org/10.1039/D4QI00005F
Spin configuration modulation of Co3O4 by Ru doping for boosting the overall water splitting and hydrazine oxidation reactions
Co-based spinel oxides with unique crystal structures have been identified as a class of promising candidates for alkaline water oxidation catalysis in oxide structural families.
Inorg. Chem. Front., 2024,11, 1381-1393
https://doi.org/10.1039/D3QI02533K
An efficient oxygen evolution reaction by Ru(II) polypyridyl complex-based AIEgen
The present study reports on Ru-4, an AIE-active Ru(II) polypyridyl compound for effective electrocatalytic OER. Ru-4 has great feasibility for OER with a wide exposed surface, as evidenced by TOF and Tafel slope values.
Inorg. Chem. Front., 2024,11, 1048-1060
https://doi.org/10.1039/D3QI02380J
Ultra-stable Cu-ion-exchanged cobalt hexacyanoferrate(II) in aqueous copper-ion storage
CuCoFe(CN)6 prepared by coprecipitating and ion-exchanging exhibits high initial discharge capacity, long term cycling life, and excellent rate performance in aqueous copper ion batteries.
Inorg. Chem. Front., 2024,11, 1108-1116
https://doi.org/10.1039/D3QI02392C
Configuration-regulated highly luminescent hydrogen–organic frameworks for detection of phenelzine and propofol
By modulating the configuration of a fluorophore via hydrogen bonding, a highly luminescent HOF (TPPA-BDC) is successfully constructed that achieves the efficient sensing of phenelzine (psychotropic drug) and propofol (controlled substance).
Inorg. Chem. Front., 2024,11, 1099-1107
https://doi.org/10.1039/D3QI02083E
Exploring the use of rigid 18-membered macrocycles with amide pendant arms for Pb(II)-based radiopharmaceuticals
Large 18-membered macrocycles functionalised with amide pendants show great potential for the complexation of Pb(II) radioisotopes, particularly when incorporating rigid cyclohexyl units into the macrocyclic scaffold.
Inorg. Chem. Front., 2024,11, 1070-1086
https://doi.org/10.1039/D3QI02354K
Harnessing ligand design to develop primary and self-calibrated luminescent thermometers with field-induced single ion magnet behaviour in Dy3+ complexes
Magneto-luminescent studies on Dy+3 complexes of N6 macrocycles lead to a unique [Dy(LN6prop)(OAc)2](NO3)·CHCl3 luminescent primary thermometer based on 2 thermally coupled levels, which in addition shows field-induced single ion magnet behaviour.
Inorg. Chem. Front., 2024,11, 1087-1098
https://doi.org/10.1039/D3QI02374E
An alkoxyborate-bridging Dy2 single-molecule magnet with ferromagnetic coupling
An alkoxyborate-bridging Dy2 single-molecule magnet featuring ferromagnetic coupling exhibits an over 100-fold increase in the zero-field relaxation time at 2 K compared to its Y(III)-diluted analogue.
Inorg. Chem. Front., 2024,11, 1061-1069
https://doi.org/10.1039/D3QI02230G
About this collection
Read our on-going collection of the hottest research published as advance article from Inorganic Chemistry Frontiers in 2024. These articles are recommended by reviewers as being of significant novelty and interest. Congratulations to all the authors whose articles are featured!