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Themed collection Natural Organic Matter

20 items
Open Access Critical Review

Triplet state dissolved organic matter in aquatic photochemistry: reaction mechanisms, substrate scope, and photophysical properties

Excited triplet states of chromophoric dissolved organic matter (3CDOM*) play a major role among the reactive intermediates produced upon absorption of sunlight by surface waters.

Graphical abstract: Triplet state dissolved organic matter in aquatic photochemistry: reaction mechanisms, substrate scope, and photophysical properties
Open Access Critical Review

Chromatographic methods for the isolation, separation and characterisation of dissolved organic matter

This review presents an overview of the separation techniques applied to the complex challenge of dissolved organic matter characterisation.

Graphical abstract: Chromatographic methods for the isolation, separation and characterisation of dissolved organic matter
Paper

Source tracing of natural organic matter bound mercury in boreal forest runoff with mercury stable isotopes

Terrestrial runoff represents a major source of mercury (Hg) to aquatic ecosystems.

Graphical abstract: Source tracing of natural organic matter bound mercury in boreal forest runoff with mercury stable isotopes
From the themed collection: Natural Organic Matter
Paper

The effect of probe choice and solution conditions on the apparent photoreactivity of dissolved organic matter

Probe choice, pH, and [DOC] impact the apparent photochemical production of triplet dissolved organic matter in diverse natural waters.

Graphical abstract: The effect of probe choice and solution conditions on the apparent photoreactivity of dissolved organic matter
From the themed collection: Natural Organic Matter
Paper

Photobleaching of chromophoric dissolved organic matter (CDOM) in the Yangtze River estuary: kinetics and effects of temperature, pH, and salinity

CDOM photobleaching in the Yangtze estuary is affected by its source, and water temperature and pH but not salinity.

Graphical abstract: Photobleaching of chromophoric dissolved organic matter (CDOM) in the Yangtze River estuary: kinetics and effects of temperature, pH, and salinity
From the themed collection: Natural Organic Matter
Paper

Quantifying the electron donating capacities of sulfide and dissolved organic matter in sediment pore waters of wetlands

The measured electron donating capacity of sulfidic wetland pore waters is similar for three different methods.

Graphical abstract: Quantifying the electron donating capacities of sulfide and dissolved organic matter in sediment pore waters of wetlands
From the themed collection: Natural Organic Matter
Paper

Emerging investigator series: dual role of organic matter in the anaerobic degradation of triclosan

Organic matter affects the degradation of triclosan as both a sequester and an electron shuttle.

Graphical abstract: Emerging investigator series: dual role of organic matter in the anaerobic degradation of triclosan
From the themed collection: Emerging Investigator Series
Paper

Source contributions and potential source regions of size-resolved water-soluble organic carbon measured at an urban site over one year

A year-long measurement of size-resolved WSOC was made at an urban site to elucidate sources of size resolved WSOC. Droplet mode WSOC was primarily the result of atmospheric processing during the long range transport of biogenic and anthropogenic pollutants from the eastern regions of China.

Graphical abstract: Source contributions and potential source regions of size-resolved water-soluble organic carbon measured at an urban site over one year
From the themed collection: Natural Organic Matter
Paper

Linking optical properties of dissolved organic matter to multiple processes at the coastal plume zone in the East China Sea

This study investigated the multiple processes at the coastal plume zone by water quality characteristics and dissolved organic matter optical properties.

Graphical abstract: Linking optical properties of dissolved organic matter to multiple processes at the coastal plume zone in the East China Sea
From the themed collection: Natural Organic Matter
Paper

Effects of dissolved organic matter on phototransformation rates and dioxin products of triclosan and 2′-HO-BDE-28 in estuarine water

The effects of DOM on the photolytic kinetics and dioxin yields of representative HO-PXDEs in estuarine water are revealed.

Graphical abstract: Effects of dissolved organic matter on phototransformation rates and dioxin products of triclosan and 2′-HO-BDE-28 in estuarine water
From the themed collection: Natural Organic Matter
Paper

Chemical controls on abiotic and biotic release of geogenic arsenic from Pleistocene aquifer sediments to groundwater

Co-cycling of arsenic, manganese, iron, and dissolved organic carbon govern the extent and mode of geogenic arsenic mobilization into groundwater.

Graphical abstract: Chemical controls on abiotic and biotic release of geogenic arsenic from Pleistocene aquifer sediments to groundwater
From the themed collection: Natural Organic Matter
Paper

Selectivity of solid phase extraction of freshwater dissolved organic matter and its effect on ultrahigh resolution mass spectra

Solid phase extracts of freshwater dissolved organic matter are compared to the original sample with use of complementary techniques.

Graphical abstract: Selectivity of solid phase extraction of freshwater dissolved organic matter and its effect on ultrahigh resolution mass spectra
From the themed collection: Natural Organic Matter
Paper

Mitigation in the toxicity of graphene oxide nanosheets towards Escherichia coli in the presence of humic acid

Humic acid mitigated the toxicity of graphene oxide nanosheets towards Escherichia coli via a physical barrier and weakening the oxidative stress.

Graphical abstract: Mitigation in the toxicity of graphene oxide nanosheets towards Escherichia coli in the presence of humic acid
From the themed collection: Natural Organic Matter
Open Access Paper

Phototransformation of pesticides in prairie potholes: effect of dissolved organic matter in triplet-induced oxidation

Despite the fact that triplet excited state dissolved organic matter (DOM) enhances phototransformation of pesticides by acting as a photosensitizer, it may also decrease the overall phototransformation rate through various mechanisms.

Graphical abstract: Phototransformation of pesticides in prairie potholes: effect of dissolved organic matter in triplet-induced oxidation
From the themed collection: Natural Organic Matter
Paper

Spatial and seasonal variations in the composition of dissolved organic matter in a tropical catchment: the Lower Kinabatangan River, Sabah, Malaysia

Dissolved organic matter (DOM) was characterised in water samples sampled in the Lower Kinabatangan River Catchment, Sabah, Malaysia between October 2009 and May 2010.

Graphical abstract: Spatial and seasonal variations in the composition of dissolved organic matter in a tropical catchment: the Lower Kinabatangan River, Sabah, Malaysia
From the themed collection: Natural Organic Matter
Paper

Size distribution and sources of humic-like substances in particulate matter at an urban site during winter

The highest contribution of HULIS-C to WSOC was observed to be in the particle size bins of 0.55–1.0 μm and 1.8–3.1 μm during non-Asian dust (NAD, 45 ± 6%) and Asian dust (AD, 44 ± 7%) periods, respectively. HULIS exhibited a uni-modal (@0.55 μm) distribution during the NAD and a bimodal distribution (@0.32 and 1.8 μm) during AD, respectively.

Graphical abstract: Size distribution and sources of humic-like substances in particulate matter at an urban site during winter
Paper

Effects of pH and dissolved oxygen on the photodegradation of 17α-ethynylestradiol in dissolved humic acid solution

This study explored the mechanisms responsible for pH and dissolved oxygen (DO) affecting the photodegradation of EE2 in dissolved humic acid (HA) solution.

Graphical abstract: Effects of pH and dissolved oxygen on the photodegradation of 17α-ethynylestradiol in dissolved humic acid solution
From the themed collection: Natural Organic Matter
Paper

Photoreduction of Hg(II) and photodemethylation of methylmercury: the key role of thiol sites on dissolved organic matter

Photochemical experiments demonstrate potential mechanistic differences between the photodemethylation of methylmercury and photoreduction of mercury(II) attached to dissolved organic matter.

Graphical abstract: Photoreduction of Hg(ii) and photodemethylation of methylmercury: the key role of thiol sites on dissolved organic matter
From the themed collection: Natural Organic Matter
Paper

Dissolved organic matter in Lake Superior: insights into the effects of extraction methods on chemical composition

The SPE resin choice (C18 vs. SDB-XC) affects the chemical composition of the resulting extract but differences between near and offshore dissolved organic matter samples remain clear.

Graphical abstract: Dissolved organic matter in Lake Superior: insights into the effects of extraction methods on chemical composition
From the themed collection: Natural Organic Matter
Open Access Paper

Investigations of freezing and cold storage for the analysis of peatland dissolved organic carbon (DOC) and absorbance properties

The loss of peatland dissolved organic carbon (DOC) in filtered samples under long-term storage (4 °C in the dark) can be modelled simply using a calculated half-life.

Graphical abstract: Investigations of freezing and cold storage for the analysis of peatland dissolved organic carbon (DOC) and absorbance properties
From the themed collection: Natural Organic Matter
20 items

About this collection

Natural organic matter (NOM) is a complex mixture of organic compounds which undergo further biotic and abiotic transformations in various environmental matrices. It is an important nutrient source for the microbial community, and serves as a major reservoir of carbon in the global carbon cycle; however, due to the complexity and diversity of its components understanding NOM is challenging.

Here, we have collated a selection of research articles and reviews which showcase the ongoing research on the topic of NOM – we hope you enjoy reading these papers!

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