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Themed collection New Talent: Americas

62 items
Cover

Front cover

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From the themed collection: New Talent: Americas
Cover

Inside front cover

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From the themed collection: New Talent: Americas
Cover

Back cover

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From the themed collection: New Talent: Americas
Front/Back Matter

Back matter

From the themed collection: New Talent: Americas
Front/Back Matter

Contents list

From the themed collection: New Talent: Americas
Editorial

New talent: Americas

Welcome to this themed issue of Dalton Transactions entitled “New talent: Americas”

Graphical abstract: New talent: Americas
From the themed collection: New Talent: Americas
Perspective

Cycloruthenated sensitizers: improving the dye-sensitized solar cell with classical inorganic chemistry principles

A divergence from the conventional approach to chromophore design has led to the establishment of many exciting new benchmarks for the dye-sensitized solar cell (DSSC), including the first documented power conversion efficiency in excess of 12%.

Graphical abstract: Cycloruthenated sensitizers: improving the dye-sensitized solar cell with classical inorganic chemistry principles
From the themed collection: New Talent: Americas
Perspective

Synthesis and reactivity of 2-azametallacyclobutanes

2-Azametallacyclobutanes have been reported for a number of metals. This Perspective provides a brief overview of 2-azametallacyclobutanes, focusing on complexes in which the ring nitrogen is anionic (amido).

Graphical abstract: Synthesis and reactivity of 2-azametallacyclobutanes
From the themed collection: New Talent: Americas
Perspective

Perceiving molecular themes in the structures and bonding of intermetallic phases: the role of Hückel theory in an ab initio era

Modern ab initio methods have the potential to transform the way simple orbital-based Hückel calculations are used to examine new chemical bonding phenomena. In this perspective we illustrate a simple and general method for translating DFT results on crystalline phases into effective Hückel models that can reveal molecular themes at work in intermetallic phases.

Graphical abstract: Perceiving molecular themes in the structures and bonding of intermetallic phases: the role of Hückel theory in an ab initio era
From the themed collection: New Talent: Americas
Perspective

Combining form with function – the dawn of phosphole-based functional materials

The phosphole unit can provide a variety of intriguing opportunities for the design of highly functional organic materials.

Graphical abstract: Combining form with function – the dawn of phosphole-based functional materials
From the themed collection: New Talent: Americas
Frontier

Splitting water with rust: hematite photoelectrochemistry

The promise, problems and progress of photocatalytic water oxidation with iron oxide.

Graphical abstract: Splitting water with rust: hematite photoelectrochemistry
From the themed collection: New Talent: Americas
Communication

Transfer hydrogenation with a ferrocene diamide ruthenium complex

The use of a 1,1′-ferrocenediamide ruthenium complex as a mediator for base-free transfer hydrogenation is reported.

Graphical abstract: Transfer hydrogenation with a ferrocene diamide ruthenium complex
From the themed collection: New Talent: Americas
Communication

Lanthanide(III) 2-naphthoxide complexes stabilized by interligand non-covalent interactions

Lithium–lanthanide-2-naphthoxide complexes are found to have solvent dependent solution structures and related monomeric/dimeric solid state structures.

Graphical abstract: Lanthanide(iii) 2-naphthoxide complexes stabilized by interligand non-covalent interactions
From the themed collection: New Talent: Americas
Communication

A tris(2-quinolylmethyl)amine scaffold that promotes hydrogen bonding within the secondary coordination sphere

An amide-appended quinoline-based ligand was prepared that presents three hydrogen bond acceptor groups to a metal-bound substrate.

Graphical abstract: A tris(2-quinolylmethyl)amine scaffold that promotes hydrogen bonding within the secondary coordination sphere
From the themed collection: New Talent: Americas
Communication

Synthesis and characterization of a tris(2-hydroxyphenyl)methane-based cryptand and its triiron(III) complex

Reaction of tris(5-amino-2-ethoxy-3-isopropylphenyl)methane and pyridine-2,6-dicarbonyl-dichloride affords a multi-dentate cryptand in 48% yield.

Graphical abstract: Synthesis and characterization of a tris(2-hydroxyphenyl)methane-based cryptand and its triiron(iii) complex
From the themed collection: New Talent: Americas
Communication

One-electron Ni(II)/(I) redox couple: potential role in hydrogen activation and production

The complementary reactions of forming and activating hydrogen are studied using a nickel system with a wide bite-angle diphosphine ligand.

Graphical abstract: One-electron Ni(ii)/(i) redox couple: potential role in hydrogen activation and production
From the themed collection: New Talent: Americas
Communication

Facile synthesis of anisotropic Au@SiO2 core–shell nanostructures

A versatile method for synthesizing anisotropic Au@SiO2 core–shell nanostructures is reported, circumventing the traditional multi-step surface functionalization strategies.

Graphical abstract: Facile synthesis of anisotropic Au@SiO2 core–shell nanostructures
From the themed collection: New Talent: Americas
Communication

Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(III) species by molecular oxygen

Dioxygen reactivity of a new {Fe(NO)2}10 dinitrosyl iron complex is reported.

Graphical abstract: Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(iii) species by molecular oxygen
From the themed collection: New Talent: Americas
Communication

Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions

A supramolecular ensemble held together via synergistic π-stacking and CoIII/VI− contact ion interactions was synthesized via three different routes and represents the first subvalent, diisocyanoarene-linked polynuclear organometallics.

Graphical abstract: Diisocyanoarene-linked pentacarbonylvanadate(I−) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π–π and contact ion interactions
From the themed collection: New Talent: Americas
Communication

Complexes of Cu(I) supported by a tris(ketimine) tripod

The rigid tris(ketimine) tripod N(ArCNHPh)3 readily coordinates a number of CuI salts, generating complexes that exhibit trigonal pyramidal geometries in the solid-state.

Graphical abstract: Complexes of Cu(i) supported by a tris(ketimine) tripod
From the themed collection: New Talent: Americas
Communication

Utilizing a copper MOF as a reagent in a solvent mediated reaction to form a topologically distinct MOF

Employing a semi-rigid di-1,2,4-triazole ligand leads to the formation of new MOFs [Cu4(L)4(SO4)4]·4[Cu(H2O)6(SO4)] (3) and [Cu6(L)3(SO4)5(OH)2(H2O)6]·13H2O (4).

Graphical abstract: Utilizing a copper MOF as a reagent in a solvent mediated reaction to form a topologically distinct MOF
From the themed collection: New Talent: Americas
Communication

A heterobimetallic metal–organic framework with tunable reactive metal sites: synthesis, characterization, and reactivity

A technique for preparing heterobimetallic frameworks is demonstrated by the synthesis of an isostructural family of two-dimensional solids (Et2NH2)[Cd(H2O)][(MTCPP)], where M = H2, Fe(II), Co(II), Ni(II), Cu(II), Zn(II), and Pd(II).

Graphical abstract: A heterobimetallic metal–organic framework with tunable reactive metal sites: synthesis, characterization, and reactivity
From the themed collection: New Talent: Americas
Communication

Convenient C-alkylation of the [HCB11Cl11] carborane anion

C-alkylation of [HCB11Cl11] to [RCB11Cl11] can be conveniently accomplished with KOBut/R-I in 80–90% isolated yield.

Graphical abstract: Convenient C-alkylation of the [HCB11Cl11]− carborane anion
From the themed collection: New Talent: Americas
Communication

Nanocrystal ligand exchange with 1,2,3,4-thiatriazole-5-thiolate and its facile in situ conversion to thiocyanate

Surface-bound 1,2,3,4-thiatriazole-5-thiolate on CdSe nanocrystals decomposes under remarkably mild heating (<100 °C) to give an all-inorganic ligand shell (comprised of thiocyanate and sulfur) with loss of nitrogen gas.

Graphical abstract: Nanocrystal ligand exchange with 1,2,3,4-thiatriazole-5-thiolate and its facile in situ conversion to thiocyanate
From the themed collection: New Talent: Americas
Communication

The metal selectivity of a short peptide maquette imitating the high-affinity metal-binding site of E. coli HypB

A seven-residue peptide based on the high-affinity metal-binding site of E. coli HypB maintains the nickel-binding activity of the full-length protein.

Graphical abstract: The metal selectivity of a short peptide maquette imitating the high-affinity metal-binding site of E. coli HypB
From the themed collection: New Talent: Americas
Communication

Thermally stable rare earth dialkyl complexes supported by a novel bis(phosphinimine)pyrrole ligand

A novel bis(phosphinimine)pyrrole based ligand has been prepared and used to support thermally stable and base free dialkyl rare earth (Er, Lu, Sc) complexes.

Graphical abstract: Thermally stable rare earth dialkyl complexes supported by a novel bis(phosphinimine)pyrrole ligand
From the themed collection: New Talent: Americas
Communication

Generation of [(IPr)Pd(PR2Cl)] complexes via P–Cl reductive elimination

We report the preparation and isolation of the first well-defined [(NHC)Pd(PR2Cl)] complexes, which are formed by way of an unusual P–Cl bond reductive elimination process.

Graphical abstract: Generation of [(IPr)Pd(PR2Cl)] complexes via P–Cl reductive elimination
From the themed collection: New Talent: Americas
Paper

Aluminum complexes of the redox-active [ONO] pincer ligand

Aluminum(III) complexes with two different redox-active ligands show evidence of non-innocent behavior.

Graphical abstract: Aluminum complexes of the redox-active [ONO] pincer ligand
From the themed collection: New Talent: Americas
Paper

Reaction of carbon dioxide with a palladiumalkyl complex supported by a bis-NHC framework

Reaction of a cis-dimethylpalladium complex supported by a bis-NHC ligand framework with wet CO2 leads to formation of the corresponding κ2-carbonato complex.

Graphical abstract: Reaction of carbon dioxide with a palladium–alkyl complex supported by a bis-NHC framework
From the themed collection: New Talent: Americas
Paper

Changes in the heme ligation during folding of a Geobacter sulfurreducens sensor GSU0935

The capture and release of a non-native His ligand to the heme during folding of a Geobacter sulfurreducens sensor GSU0935 demonstrates the flexibility of the heme environment which may relate to the domain sensor function.

Graphical abstract: Changes in the heme ligation during folding of a Geobacter sulfurreducens sensor GSU0935
From the themed collection: New Talent: Americas
Paper

Oxidation of dimethyldi(2-pyridyl)borato PtIIMen complexes, n = 1, 0, with H2O2: tandem B-to-Pt methyl group migration and formation of C–O bond

New dimethyldi(2-pyridyl)borato (dmdpb) platinum(II) complexes, (dmdpb)PtIIMe(SMe2) (1), (dmdpb)PtII(L)(SMe2)+, L = MeOH (2), MeCN (3), supported by dimethylsulfide ligand and featuring one (1) or no hydrocarbyls at the metal (2, 3) were prepared and their oxidation with hydrogen peroxide was studied.

Graphical abstract: Oxidation of dimethyldi(2-pyridyl)borato PtIIMen complexes, n = 1, 0, with H2O2: tandem B-to-Pt methyl group migration and formation of C–O bond
From the themed collection: New Talent: Americas
Paper

Rigid NON- and NSN-ligand complexes of tetravalent and trivalent uranium: comparison of U–OAr2 and U–SAr2 bonding

Uranium(III) and (IV) complexes of extremely rigid, dianionic NON-donor and NSN-donor ligands have been prepared, and the extent of covalency in U–SAr2versus U–OAr2 bonding was assessed using DFT and Atoms in Molecules calculations.

Graphical abstract: Rigid NON- and NSN-ligand complexes of tetravalent and trivalent uranium: comparison of U–OAr2 and U–SAr2 bonding
From the themed collection: New Talent: Americas
Paper

Synthesis, spectroscopic analysis and photolabilization of water-soluble ruthenium(III)–nitrosyl complexes

The syntheses and spectroscopic properties of a series of {RuNO}6 complexes with TPA as the coligand are reported, and the photolability of the bound NO ligand in these systems is investigated in comparison to analogous edta complexes.

Graphical abstract: Synthesis, spectroscopic analysis and photolabilization of water-soluble ruthenium(iii)–nitrosyl complexes
From the themed collection: New Talent: Americas
Paper

Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru)

The synthesis, activation, and heats of CO2 adsorption for the M3(BTC)2 (HKUST-1) isostructural series with M = Cr, Fe, Ni, Zn, Ni, Cu, Mo were investigated to gain insight into the impact of CO2–metal interactions for CO2 storage/separation.

Graphical abstract: Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru)
From the themed collection: New Talent: Americas
Paper

Electronic structure and solution behavior of a tris(N,N′-diphenylhydrazido)manganese(IV) propeller complex

The solution-phase magnetic susceptibility of the tris(κ2-hydrazide)manganese(IV) propeller complex varies with temperature and concentration. The variable solution phase magnetic susceptibility is explained by a dimerization mechanism whereby the monomeric S = 3/2 complex is in equilibrium with an antiferromagnetically coupled S = 0 binuclear complex in solution.

Graphical abstract: Electronic structure and solution behavior of a tris(N,N′-diphenylhydrazido)manganese(iv) propeller complex
From the themed collection: New Talent: Americas
Paper

Elucidating the structure-dependent photocatalytic properties of Bi2WO6: a synthesis guided investigation

The photocatalytic properties of Bi2WO6 microspheres and microplates prepared by ultrasonic spray pyrolysis have been evaluated.

Graphical abstract: Elucidating the structure-dependent photocatalytic properties of Bi2WO6: a synthesis guided investigation
From the themed collection: New Talent: Americas
Paper

A responsive particulate MRI contrast agent for copper(I): a cautionary tale

The relaxivity of particulate MRI contrast agents does not increase continuously with increasing aggregation induced by increasing concentration of analyte.

Graphical abstract: A responsive particulate MRI contrast agent for copper(i): a cautionary tale
From the themed collection: New Talent: Americas
Paper

Cyclometalated platinum(II) diimine complexes: synthetically tuning the photophysical and electrochemical properties

A family of phosphorescent, cyclometalated Pt(II) complexes was synthesized and their photophysical and electrochemical properties were investigated.

Graphical abstract: Cyclometalated platinum(ii) diimine complexes: synthetically tuning the photophysical and electrochemical properties
From the themed collection: New Talent: Americas
Paper

Cyclopentadienyl chromium diimine and pyridine-imine complexes: ligand-based radicals and metal-based redox chemistry

Organochromium complexes with anionic radical diimine and pyridine-imine ligands were synthesized, characterized, and investigated using theoretical calculations.

Graphical abstract: Cyclopentadienyl chromium diimine and pyridine-imine complexes: ligand-based radicals and metal-based redox chemistry
From the themed collection: New Talent: Americas
Paper

Metallomacrocycles as ligands: synthesis and characterisation of aluminium-bridged bisglyoximato complexes of palladium and iron

Dialuminiummacrocycles based on bisglyoximato moieties were prepared and their coordination chemistry with FeII and PdII was investigated.

Graphical abstract: Metallomacrocycles as ligands: synthesis and characterisation of aluminium-bridged bisglyoximato complexes of palladium and iron
From the themed collection: New Talent: Americas
Paper

Coordination and structural properties of encumbering 6-mesityl-2-picolinate complexes

The coordination and structural properties of a new class of encumbering picolinate ligands for transition-metal and main-group ions are presented.

Graphical abstract: Coordination and structural properties of encumbering 6-mesityl-2-picolinate complexes
From the themed collection: New Talent: Americas
Paper

Two-step hydrothermal synthesis of submicron Li1+xNi0.5Mn1.5O4−δ for lithium-ion battery cathodes (x = 0.02, δ = 0.12)

A facile two-step hydrothermal method is developed for the large-scale preparation of lithium nickel manganese oxide spinel as a cathode material for lithium ion batteries.

Graphical abstract: Two-step hydrothermal synthesis of submicron Li1+xNi0.5Mn1.5O4−δ for lithium-ion battery cathodes (x = 0.02, δ = 0.12)
From the themed collection: New Talent: Americas
Paper

Dissecting the role of DNA sequence in Helicobacter pylori NikR/DNA recognition

Helicobacter pylori NikR recognizes DNA with high affinity when thymine is present at a specific position on the DNA sequence.

Graphical abstract: Dissecting the role of DNA sequence in Helicobacter pylori NikR/DNA recognition
From the themed collection: New Talent: Americas
Paper

sp 2 C–H activation of dimethyl fumarate by a [(Cp*Co)2-μ-(η4 : η4-toluene)] complex

Well defined, sp2 C–H bond activation of dimethyl fumarate is mediated by a [(Cp*Co)2-μ-(η4 : η4-toluene)] complex.

Graphical abstract: sp 2 C–H activation of dimethyl fumarate by a [(Cp*Co)2-μ-(η4 [ ] : [ ] η4-toluene)] complex
From the themed collection: New Talent: Americas
Paper

A mechanistic investigation of carbon–hydrogen bond stannylation: synthesis and characterization of nickel catalysts

The isolation of a catalyst for C–H bond stannylation allows for insight into the mechanism of this novel functionalization reaction.

Graphical abstract: A mechanistic investigation of carbon–hydrogen bond stannylation: synthesis and characterization of nickel catalysts
From the themed collection: New Talent: Americas
Paper

Non-innocent ligand behaviour of a bimetallic Cu complex employing a bridging catecholate

The oxidation chemistry of a bimetallic Cu complex employing a non-innocent dioxolene bridge is explored.

Graphical abstract: Non-innocent ligand behaviour of a bimetallic Cu complex employing a bridging catecholate
From the themed collection: New Talent: Americas
Paper

Synthesis of U(IV) imidos from Tp*2U(CH2Ph) (Tp* = hydrotris(3,5-dimethylpyrazolyl)borate) by extrusion of bibenzyl

A family of uranium(IV) imido species, Tp*2U(NR), have been synthesized by loss of bibenzyl from the uranium(III) alkyl, Tp*2UCH2Ph.

Graphical abstract: Synthesis of U(iv) imidos from Tp*2U(CH2Ph) (Tp* = hydrotris(3,5-dimethylpyrazolyl)borate) by extrusion of bibenzyl
From the themed collection: New Talent: Americas
Paper

Substituent effects on Ni–S bond dissociation energies and kinetic stability of nickel arylthiolate complexes supported by a bis(phosphinite)-based pincer ligand

Effects of ligand substituents on Ni–S bond lengths, bond dissociation energies, and nucleophilicity of a series of nickel thiolate complexes have been investigated.

Graphical abstract: Substituent effects on Ni–S bond dissociation energies and kinetic stability of nickel arylthiolate complexes supported by a bis(phosphinite)-based pincer ligand
From the themed collection: New Talent: Americas
Paper

Cycloaddition reactivity studies of first-row transition metal–azide complexes and alkynes: an inorganic click reaction for metalloenzyme inhibitor synthesis

The cycloaddition reaction between first-row transition metal–azide complexes and alkynes was investigated and the metal–triazolate products were structurally characterized.

Graphical abstract: Cycloaddition reactivity studies of first-row transition metal–azide complexes and alkynes: an inorganic click reaction for metalloenzyme inhibitor synthesis
From the themed collection: New Talent: Americas
Paper

A redox series of gallium(III) complexes: ligand-based two-electron oxidation affords a gallium–thiolate complex

Two-electron oxidation of [(IP2−)2Ga] by MeSSMe yields (IP)2Ga(SMe) via a ligand-based change in oxidation state.

Graphical abstract: A redox series of gallium(iii) complexes: ligand-based two-electron oxidation affords a gallium–thiolate complex
From the themed collection: New Talent: Americas
Paper

Synthesis, characterization and thermal properties of trimetallic N3–Cr[quadruple bond, length as m-dash]Cr⋯M–N3 azide complexes with M = Cr, Mn, Fe, and Co

Described here are two novel synthetic pathways toward the preparation of Cr2M(dpa)4(N3)2 complexes, and characterization of these compounds.

Graphical abstract: Synthesis, characterization and thermal properties of trimetallic N3–Cr [[quadruple bond, length as m-dash]] Cr⋯M–N3 azide complexes with M = Cr, Mn, Fe, and Co
From the themed collection: New Talent: Americas
Paper

Yttrium (amidate) complexes for catalytic C–N bond formation. Rapid, room temperature amidation of aldehydes

An yttrium (amidate) complex can catalyze the room temperature amidation of aldehydes with amines in only 5 min.

Graphical abstract: Yttrium (amidate) complexes for catalytic C–N bond formation. Rapid, room temperature amidation of aldehydes
From the themed collection: New Talent: Americas
Paper

Synthesis and electronic properties of a pentafluoroethyl-derivatized nickel pincer complex

A pentafluoroethyl-derivatized nickel pincer complex was synthesized, and its electronic properties were evaluated by electrochemical and computational methods.

Graphical abstract: Synthesis and electronic properties of a pentafluoroethyl-derivatized nickel pincer complex
From the themed collection: New Talent: Americas
Paper

Quantifying factors that influence metal ion release in photocaged complexes using ZinCast derivatives

Two generations of nitrobenzhydrol-based photocages for Zn2+ have been prepared and characterized.

Graphical abstract: Quantifying factors that influence metal ion release in photocaged complexes using ZinCast derivatives
From the themed collection: New Talent: Americas
Paper

Effects of ligand tuning on dinuclear indium catalysts for lactide polymerization

Functionalized diaminophenols were investigated as ligands for dinuclear indium catalysts for the ring-opening polymerization of racemic lactide. Changes in ligand sterics have a significant impact on the structure and reactivity of the complexes. The dissociation of these catalysts in the presence of lactide was investigated.

Graphical abstract: Effects of ligand tuning on dinuclear indium catalysts for lactide polymerization
From the themed collection: New Talent: Americas
Paper

Gas sorption and luminescence properties of a terbium(III)-phosphine oxide coordination material with two-dimensional pore topology

PCM-15 is a terbium(III)-triphenylphosphine oxide coordination polymer that exhibits reversible tuning of the luminescence quantum yield, based on desolvation and resolvation of the metal centres. It also has a large capacity for low-temperature small molecule sorption.

Graphical abstract: Gas sorption and luminescence properties of a terbium(iii)-phosphine oxide coordination material with two-dimensional pore topology
From the themed collection: New Talent: Americas
Paper

Chemistry of the heavy group 15 elements with the pyridyl tethered 1,2-bis(imino)acenaphthene “clamshell” ligand

A new redox route utilizing cobaltocene to generate a Pn(I) synthon from Pn(III) was developed. Subsequent 4 + 2 cycloaddition with a α-diimine gives N-heterocyclic chloropnictine. In the absence of a reductant a donor–acceptor complex is formed.

Graphical abstract: Chemistry of the heavy group 15 elements with the pyridyl tethered 1,2-bis(imino)acenaphthene “clamshell” ligand
From the themed collection: New Talent: Americas
Paper

Copper-catalyzed oxidation of azolines to azoles

We report herein convenient, aerobic conditions for the oxidation of thiazolines to thiazoles and data regarding the oxidation mechanism.

Graphical abstract: Copper-catalyzed oxidation of azolines to azoles
From the themed collection: New Talent: Americas
Paper

First structural evidence for multiple alkali metals between sandwich decks in a metallocene

A tetralithio salt (1) derived by treating 1,4-bis(trimethylsilyl)-cyclooctatriene with nBuLi serves as the first structural evidence for a multi-alkali metallocene.

Graphical abstract: First structural evidence for multiple alkali metals between sandwich decks in a metallocene
From the themed collection: New Talent: Americas
Paper

Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(I)

Imido coordination to Group V metals in Nb–Co and Ta–Co heterobimetallic complexes decreases metal–metal interactions.

Graphical abstract: Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(i)
From the themed collection: New Talent: Americas
Paper

Is histidine dissociation a critical component of the NO/H-NOX signaling mechanism? Insights from X-ray absorption spectroscopy

Structural analysis of H-NOX domains reveals incomplete histidine dissociation upon NO binding, challenging this widely hypothesized requirement for NO/H-NOX signaling.

Graphical abstract: Is histidine dissociation a critical component of the NO/H-NOX signaling mechanism? Insights from X-ray absorption spectroscopy
From the themed collection: New Talent: Americas
Paper

Synthesis and computational studies of Mg complexes supported by 2,2′:6,2′′-terpyridine ligands

Through the reactions of substituted terpy ligands with Grignard reagents, we have prepared rare examples of Mg complexes supported by terpy ligands.

Graphical abstract: Synthesis and computational studies of Mg complexes supported by 2,2′:6,2′′-terpyridine ligands
From the themed collection: New Talent: Americas
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