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N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools: Edition 2 Editor: Silvia Diez-Gonzalez



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This book contains 636 pages.
Print publication date: 08 Nov 2016
Copyright year: 2017
Print ISBN: 978-1-78262-423-3
PDF eISBN: 978-1-78262-681-7
ePub eISBN: 978-1-78262-903-0
Citation:

About this book

In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.

From the book series:
Catalysis Series

Author information

Silvia Diez-Gonzalez is a Senior Lecturer in the Department of Chemistry at Imperial College London, UK.