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Polymer Chemistry Series
Phosphorus-Based Polymers: From Synthesis to Applications
By
Royal Society of Chemistry
Royal Society of Chemistry
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Edited by
Sophie Monge;
Sophie Monge
University of Montpellier 2, France
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Ghislain David
Ghislain David
Institute Charles Gerhardt of Montpellier, France
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Hardback ISBN:
978-1-84973-646-6
PDF ISBN:
978-1-78262-452-3
EPUB ISBN:
978-1-78262-151-5
Series:
Polymer Chemistry Series
No. of Pages:
318
Publication date:
07 May 2014
Book Chapter
CHAPTER 3: Phosphorus-Containing Vinyl or Allyl Monomers
By
Ghislain David
;
Ghislain David
Institut Charles Gerhardt (ICGM)/Equipe Ingénierie et Architectures Macromoléculaires (IAM)
ENSCM, 8 rue de l’école normale
34296
Montpellier
France
ghislain.david@enscm.fr
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Claire Negrell-Guirao
Claire Negrell-Guirao
Institut Charles Gerhardt (ICGM)/Equipe Ingénierie et Architectures Macromoléculaires (IAM)
ENSCM, 8 rue de l’école normale
34296
Montpellier
France
ghislain.david@enscm.fr
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Published:07 May 2014
-
Series: Polymer Chemistry Series
Citation
G. David and C. Negrell-Guirao, in Phosphorus-Based Polymers: From Synthesis to Applications, ed. S. Monge and G. David, The Royal Society of Chemistry, 2014, pp. 35-50.
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This chapter reviews the synthetic strategies that can be used for phosphonate-containing vinyl monomers, ranging from allyl-type to vinyl- and vinyl ether-type monomers. Their radical copolymerizations with electron-accepting monomers are thoroughly described and lead to materials that can be used for different applications, such as anticorrosive coatings. For instance, the free radical polymerization of 5-(allyloxymethyl)-1,3,2-dioxaphosphorinane 2-oxides with maleic anhydride affords very interesting flame retardant compounds.
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