A photoinduced EnT-mediated generation of sulfonamidyl radicals has been accomplished using rationally designed iminophenylacetic acid oxime ester reagents under metal-free conditions. This approach offers a mild, regio- and diastereoselective synthesis of N-sulfonyl diamines via diamination of alkenes and (hetero)arenes.
Z. Sun, J. Zhang, X. Du, L. Liu, S. Gao, C. Qi, X. Li and X. Xu, Chem. Commun., 2024, 60, 7934 DOI: 10.1039/D4CC02225D
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