Issue 45, 2024

Photocatalytic α-arylation of cyclic ketones by a thermally activated delayed fluorescence molecule

Abstract

α-Arylation of cyclic ketones via an organophotocatalytic route has been described utilizing PXZ-TRZ, a molecule displaying thermally activated delayed fluorescence (TADF). Using this route, a plethora of cyclic ketones including cyclohexanone, cyclopentanone and even cyclooctanone can be effectively arylated with many aryl iodides or bromides under mild conditions.

Graphical abstract: Photocatalytic α-arylation of cyclic ketones by a thermally activated delayed fluorescence molecule

Supplementary files

Article information

Article type
Communication
Submitted
20 Mar 2024
Accepted
01 May 2024
First published
02 May 2024

Chem. Commun., 2024,60, 5852-5855

Photocatalytic α-arylation of cyclic ketones by a thermally activated delayed fluorescence molecule

B. Mandal, S. Mandal, S. Halder and D. Adhikari, Chem. Commun., 2024, 60, 5852 DOI: 10.1039/D4CC01287A

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