Bobbing chemical garden tubes: oscillatory self-motion from buoyancy and catalytic gas production

Abstract

Chemical reactions can induce self-propulsion by the production and ejection of gas bubbles from micro-rocket like cylindrical units. We describe related micro-submarines that change their depth in response to catalytic gas production. The structures consist of silica-supported CuO and are produced by utilizing the self-assembly rules of chemical gardens. In H₂O₂ solution, the tube cavity produces O₂(g) and the resulting buoyancy lifts the tube to the air–solution interface, where it releases oxygen and sinks back down to the bottom of the container. In 5 cm deep solutions, the resulting bobbing cycles have a period of 20–30 s and repeat for several hours. The ascent is characterized by a vertical orientation of the tube and a constant acceleration. During the descent, the tubes are oriented horizontally and sink at a nearly constant speed. These striking features are quantitatively captured by an analysis of the involved mechanical forces and chemical kinetics. The results show that ascending tubes increase their oxygen-production rate by the motion-induced injection of fresh solution into the tube cavity.