Issue 33, 2023

Metal-free and atom-efficient protocol for diarylation of selenocyanate by diaryliodonium salts

Abstract

We developed an atom- and reaction mass efficient strategy for the preparation of diarylselenides using iodonium salts as reactants. The developed approach allows the obtaining of diarylselenides from the corresponding trimethoxyphenyl-substituted iodonium salts via a two-step one-pot reaction sequence. The proposed metal-free methodology is based on the involvement of both iodonium aryl groups for diarylation.

Graphical abstract: Metal-free and atom-efficient protocol for diarylation of selenocyanate by diaryliodonium salts

Supplementary files

Article information

Article type
Paper
Submitted
26 May 2023
Accepted
28 Jul 2023
First published
31 Jul 2023

Org. Biomol. Chem., 2023,21, 6743-6749

Metal-free and atom-efficient protocol for diarylation of selenocyanate by diaryliodonium salts

A. D. Radzhabov, N. S. Soldatova, D. M. Ivanov, M. S. Yusubov, V. Yu. Kukushkin and P. S. Postnikov, Org. Biomol. Chem., 2023, 21, 6743 DOI: 10.1039/D3OB00833A

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