Blowing-inspired ex situ preparation of ultrathin hydrogel coatings for visibly monitoring humidity and alkaline gas

Abstract

Compared with the in situ preparation of ultrathin hydrogel coatings through successive yet tedious steps, ex situ strategies decouple the steps and greatly enhance the maneuverability and convenience of preparing hydrogel coatings. However, the difficulty in preparing sub-micron-thick coatings limits the applicability of ex situ methods in nanotechnology. Herein, we report the ex situ preparation of centimeter-scale ultrathin hydrogel coatings by applying omnidirectional stretching toward pre-gelated hydrogels with necking behaviors. This process involves blowing a bubble directly from a pre-gelated hydrogel and subsequently transferring the resulting hydrogel bubble to different substrates. The as-fabricated coatings exhibit peak-shaped thickness variations, with the thinnest part as low as ∼5 nm and the thickest part controllable from ∼200 nm to several microns. This method can be universally applied to hydrogels with necking behavior triggered by internal particles with partial hydrophobicity. Due to the overall near- or sub-micron thickness and unique thickness distribution, the coatings present concentric rings of different interference colors. With such an observable optical characteristic, the as-prepared hydrogel coatings are applied as sensors to visibly monitor humidity changes or alkaline gas through the visibly observable expansion or contraction of concentric interferometry rings, which is triggered by adsorbing/desorbing the surrounding water or alkaline molecules and the resultant swelling/deswelling of the coatings, respectively. With the universality of the method, we believe that the ex situ strategy can be used as a simple yet efficient environmental nanotechnology to fabricate various types of nanometer-thick hydrogel coatings as detectors to sensitively and visibly monitor surrounding stimuli on demand.