Issue 18, 2023
From the journal:

Green Chemistry

Dehydrogenative silylation of cellulose in ionic liquid†

Daisuke Hirose, ORCID logo *a   Samuel Budi Wardhana Kusuma,ab   Akina Yoshizawa, ORCID logo a   Naoki Wadaa  and  Kenji Takahashi ORCID logo *a  

* Corresponding authors

a Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

b Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Negeri Semarang, Semarang City, Central Java 50229, Indonesia
E-mail: dhirose@se.kanazawa-u.ac.jp, ktkenji@staff.kanazawa-u.ac.jp

Abstract

A new homogenous silylation method of cellulose is developed by mixing it with monohydrosilane in an ionic liquid. In this concise reaction with high atom economy, the ionic liquid acts as both the solvent and catalyst, and the only formal by-product generated is the clean fuel of molecular hydrogen.

Graphical abstract: Dehydrogenative silylation of cellulose in ionic liquid

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Article information

DOI
https://doi.org/10.1039/D3GC02894A
Article type
Communication
Submitted
04 Aug 2023
Accepted
16 Aug 2023
First published
18 Aug 2023

Green Chem., 2023,25, 7062-7067

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Dehydrogenative silylation of cellulose in ionic liquid

D. Hirose, S. B. W. Kusuma, A. Yoshizawa, N. Wada and K. Takahashi, Green Chem., 2023, 25, 7062 DOI: 10.1039/D3GC02894A

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