A hybrid bonding strategy for tetrathiafulvalene-based hydrogen-bonded organic frameworks with electrical- and photo-conductivity†
Abstract
Two hybrid bonded hydrogen-bonded organic frameworks (namely PTP-HOF3 and PTP-HOF4) based on tetrathiafulvalene (TTF) exhibit good electrical- and photo-conductivity. PTP-HOF4 with proton transfer characteristics shows a more regular porosity with a size of 14.35 Å × 8.75 Å and better conductivity than PTP-HOF3.