Issue 96, 2023
From the journal:

Chemical Communications

Creating glassy states of dicarboxylate-bridged coordination polymers†

Zeyu Fan, ORCID logo a   Yong-Sheng Wei,b   Chinmoy Das, ORCID logo b   Kazuyoshi Kanamori,c   Hiroki Yamada,d   Koji Oharad  and  Satoshi Horike ORCID logo *bce  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

b Institute for Integrated Cell-Material Sciences, Institute for Advanced Study, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: horike.satoshi.3r@kyoto-u.ac.jp

c Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan

d Diffraction and Scattering Division, Japan Synchrotron Radiation Research Institute (JASRI), Sayo, Hyogo 679-5198, Japan

e Department of Materials Science and Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong, Thailand

Abstract

We report the direct formation of dicarboxylate-based coordination polymer glasses through thermal dehydration. The rearrangement of the coordination networks caused by dehydration was monitored by in situ powder X-ray diffraction, infrared spectroscopy, and synchrotron X-ray characterizations. The microporosity and mechanical properties of these glasses were investigated.

Graphical abstract: Creating glassy states of dicarboxylate-bridged coordination polymers

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D3CC04518H
Article type
Communication
Submitted
12 Sep 2023
Accepted
06 Nov 2023
First published
07 Nov 2023

Chem. Commun., 2023,59, 14317-14320

Permissions

Request permissions

Creating glassy states of dicarboxylate-bridged coordination polymers

Z. Fan, Y. Wei, C. Das, K. Kanamori, H. Yamada, K. Ohara and S. Horike, Chem. Commun., 2023, 59, 14317 DOI: 10.1039/D3CC04518H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements