Issue 94, 2023
From the journal:

Chemical Communications

Influence of solvent on cyclic polynorbornene tacticity†

Sung-Min Hyun, ORCID logo a   Arkadios Marathianos, ORCID logo b   Parker T. Boeck, ORCID logo ac   Ion Ghiviriga,a   Daniel W. Lester,b   Brent S. Sumerlin ORCID logo c  and  Adam S. Veige ORCID logo *a  

* Corresponding authors

a University of Florida, Department of Chemistry, Center for Catalysis, P.O. Box 117200, Gainesville, FL, USA
E-mail: veige@chem.ufl.edu

b Polymer Characterization Research Technology Platform, University of Warwick, Coventry CV4 7AL, UK

c University of Florida, Department of Chemistry, George and Josephine Butler Polymer Research Laboratory, Center for Macromolecular Science and Engineering, Gainesville, FL 32611, USA

Abstract

Tacticity is critical to polymer properties. The influence of solvent on tacticity in the catalytic synthesis of cyclic polynorbornene (c-PNB) is reported. In toluene cis,syndiotactic c-PNB forms; in THF, cis,syn/iso c-PNB forms.

Graphical abstract: Influence of solvent on cyclic polynorbornene tacticity

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Article information

DOI
https://doi.org/10.1039/D3CC04167K
Article type
Communication
Submitted
28 Aug 2023
Accepted
21 Oct 2023
First published
31 Oct 2023

Chem. Commun., 2023,59, 13993-13996

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Influence of solvent on cyclic polynorbornene tacticity

S. Hyun, A. Marathianos, P. T. Boeck, I. Ghiviriga, D. W. Lester, B. S. Sumerlin and A. S. Veige, Chem. Commun., 2023, 59, 13993 DOI: 10.1039/D3CC04167K

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