Metal-mediated tunability of MOF-based optical modulators

Nikita K. Kulachenkov; Bogdan Orlioglo; Eugene S. Vasilyev; Svyatoslav A. Povarov; Alexander M. Agafontsev; Semyon Bachinin; Sergei Shipilovskikh; Artem Lunev; Denis G. Samsonenko; Vladimir P. Fedin; Konstantin A. Kovalenko; Valentin A. Milichko

doi:10.1039/D3CC02180G

Metal-mediated tunability of MOF-based optical modulators†

Nikita K. Kulachenkov,

‡^a Bogdan Orlioglo,

^b Eugene S. Vasilyev,^c Svyatoslav A. Povarov,^a Alexander M. Agafontsev,^cd Semyon Bachinin,^a Sergei Shipilovskikh,

^a Artem Lunev,^a Denis G. Samsonenko,

^e Vladimir P. Fedin,

^e Konstantin A. Kovalenko

*^e and Valentin A. Milichko

*^af

Author affiliations

* Corresponding authors

^a School of Physics and Engineering, ITMO University, St. Petersburg, Russia

^b Chemical Science Program, KAUST Catalysis Center, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, Saudi Arabia

^c Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia

^d Novosibirsk State University, 2 Pirogova St., Novosibirsk 630090, Russia

^e Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave., Novosibirsk 630090, Russia
E-mail: k.a.kovalenko@niic.nsc.ru

^f Universit de Lorraine, UMR CNRS 7198, Nancy 54011, France
E-mail: valentin.milichko@univ-lorraine.fr

Abstract

We report on the design of 1D MOFs based on a nopinane-annelated organic ligand and Co(II) or Ni(II), the variation of which allows tuning the optical modulation bandwidth. Structural and time-resolved analysis revealed the optical modulation mechanism, the rates and its endurance, thereby enriching the list of sustainable MOFs for tunable optical modulators.

Chemical Communications

Metal-mediated tunability of MOF-based optical modulators†

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