A flexible and bright surface-enhanced electrochemiluminescence film constructed from efficient aggregation-induced emission luminogens for biomolecular sensing

Abstract

A bright surface-enhanced electrochemiluminescence film (SEEF) was fabricated from an organic luminogen with aggregation-induced emission (AIEgen) features on flexible substrates. Flexible carbonous substrates including carbon fiber cloth (GCFC) and carbon fiber paper (GCFP) were decorated with gold nanoparticles (AuNPs) through electrochemical deposition methods, followed by facilely casting AIEgen solutions. The resulting SEEF had a low driving potential of +0.84 V, and its electrochemiluminescence (ECL) was readily observed by the naked eye. The systematic investigation showed that the bright ECL was associated with the promoted electrochemical oxidation and radiative decay of excited AIEgens enhanced by AuNP deposition. Intriguingly, the ECL intensity of the film was linearly enhanced by increasing AIEgen loadings, which allowed tuning of ECL brightness on demand. Moreover, the SEEF was flexible and immune to folding. The ECL intensity rarely changed even when consecutively folding the film 20 times due to the strong interaction between the AIEgen and substrate. The SEEF was further used to sense biomolecules in aqueous media. The ECL of the film was linearly quenched in the presence of dopamine (DA) in the range of 10⁻¹⁵–10⁻⁶ M with a record-low limit of detection of 3.16 × 10⁻¹⁶ M. Furthermore, a simple method based on grayscale analysis of ECL images (GAEI) was used for visual sensing of DA. This work provides a kind of novel bright ECL film, useful for the ultrasensitive monitoring of biomolecules in aqueous media.