Assembly of bimetallic (Au–Ag)FON composite films at liquid/solid interfaces and their tunable optical properties

Abstract

The regular structure provided by two-dimensional (2D) structural colloidal crystals is widely accepted to provide an ideal template that ensures that plasmonic bimetallic composite nanostructures are uniform. Herein, we report an effective method for fabricating bimetallic Au–Ag composite films loaded on the surfaces of 2D polystyrene@polyacrylic acid (PS@PAA) colloidal crystals. PS@PAA particles coated with uniform Ag particle layers (AgFON) were produced by a simple and effective sputtering-deposition technique, after which the galvanic replacement (GR) reaction was used to produce a bimetallic (Au–Ag)FON composite film at the liquid/solid interface in aqueous HAuCl₄. The morphology and relative contents of the bimetallic (Au–Ag)FON composite film can be regulated by changing the kinetic factors that control the GR reaction, including the concentration and pH of the HAuCl₄ solution, and the reaction time. We demonstrated that the fabricated bimetallic (Au–Ag)FON composite has localized surface plasmon resonance (LSPR) properties that can be regulated by varying the composite structure and Ag/Au composition. On the one hand, the regular 2D colloidal crystal structure provides an ideal template for preparing Au–Ag composite films, which ensures that the optical signals of plasmonic Au–Ag composite films are reproducible. On the other hand, the synergy between Ag and Au in the bimetallic alloy composite film ensures stable and tunable LSPR performance. Furthermore, the prepared 2D ordered (Au–Ag)FON Au–Ag bimetallic material is expected to be used in sensing and catalysis applications.