Experimental and theoretical insights into Co–Ln magnetic exchange and the rare slow-magnetic relaxation behavior of [Co II2Pr]2+ in a series of linear [Co II2Ln]2+ complexes

Abstract

We herein report a series of near-linear trinuclear complexes [Co₂Ln(HL)₄(NO₃)](NO₃)₂ (where HL = (2-methoxy-6-[(E)-2′-hydroxymethyl-phenyliminomethyl]-phenolate) with Ln(III) = La (1), Ce (2), Pr (3)). For the comparative study, we have also included the recently reported analogous complexes of Gd(III), Tb(III), and Dy(III) (complexes 4–6) with the same H₂L ligand. The experimental nature of the dc magnetic susceptibilities profile and an empirical approach revealed that the magnetic exchange interaction between Co(II) and Ln(III) having <4f⁷ (complexes 2 and 3) is antiferromagnetic while the dominant interaction between Co(II) and Ln(III) having ≥4f⁷ (complexes 4–6) is ferromagnetic. Dynamic magnetic relaxation studies on complexes 1–3 revealed the field induced single-molecule magnetic (SMM) behavior of 1 and 3 with effective energy barriers of 10.65 K and 15.03 K respectively, for magnetic relaxation. To the best of our knowledge, 3d-Pr(III) based zero or field induced SMMs have not been reported to date. CASSCF/SO-RASSI/SINGLE_ANISO based ab initio calculations on the X-ray structures of complexes 1–6, followed by POLY_ANISO simulations, estimated the magnetic exchange coupling constants J_Co–Ln and J_Co–Co and also rationalized our experimental findings for the dynamic magnetic properties.