Facile synthesis of multiphase cobalt–iron spinel with enriched oxygen vacancies as a bifunctional oxygen electrocatalyst

Abstract

The multiphase cobalt–iron spinel was firstly synthesized via a facile cold plasma method and applied as a bifunctional electrocatalyst for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Compared with the single-phase obtained by the traditional calcination method, the CoFe₂O₄ and Co₃O₄ phase were obtained by the plasma method. The multivalence states of cobalt and iron facilitated electron transport in electrochemical reactions. The plasma sample had a small particle size (5 nm) due to the low operation temperature. Notably, electron impact produced more oxygen vacancies and a larger surface area on Co_xFe_yO₄, which increased the active sites and electronic conductivity. Electrochemical investigations indicated that the multiphase spinel obtained with a quasi-four-electron transfer process showed an onset potential of 0.76 V versus the RHE for the oxygen reduction reaction. In the oxygen evolution reaction, the potential of current density at 10 mA cm⁻² was 1.53 V versus RHE. As for the overall electrocatalytic activity, the multiphase spinel had a ΔE (the difference between E₁₀(OER) and E_1/2(ORR)) of 0.89 V, exhibiting greater bifunctional activity than the other prepared catalysts.