The interactions of chelate-based ionic liquids: from the perspective of vaporization enthalpy

Abstract

The vaporization enthalpies of [C_nTPP][Cu(F₆-acac)₃] (n = 14, 16) and [C_nmim][Cu(F₆-acac)₃] (n = 8, 10), a new type of chelate-based ionic liquids (ChILs), were measured by thermogravimetric analysis (Δ^g_lH^o_m(T_av) = 73.2–83.7 kJ mol⁻¹), which decreased compared to their non-chelate counterparts (difference up to 34.1 kJ mol⁻¹). This can be explained by the fact that the increase in the polar region size by chelate ions mainly leads to the decrease in Coulomb forces based on the micro-biphasic separation in ionic liquids. Vaporization enthalpies at experimental temperatures were adjusted to a reference temperature by the Verevkin's method, and compared with the data calculated by the Kabo's method, which illustrated clear differences on ChILs. In addition, some physicochemical properties of [C_nTPP][Cu(F₆-acac)₃] (n = 14, 16) were measured including density, viscosity, conductivity, and surface tension.