Issue 84, 2022

Luminescent magnesium complexes with intra- and inter-ligand charge transfer

Abstract

Herein, we report two 2,2′-pyridylpyrrolide (PyPyrH) ligand supported magnesium complexes (1 and 2), which demonstrate bright luminescence with a quantum yield of 22% and 14% in the solid state, respectively. Theoretical calculations reveal that their emissive properties originate from the intra- and inter-ligand charge transfer.

Graphical abstract: Luminescent magnesium complexes with intra- and inter-ligand charge transfer

Supplementary files

Article information

Article type
Communication
Submitted
25 Jul 2022
Accepted
22 Sep 2022
First published
23 Sep 2022

Chem. Commun., 2022,58, 11843-11846

Luminescent magnesium complexes with intra- and inter-ligand charge transfer

R. Kumar, S. Pahar, J. Chatterjee, S. R. Dash, R. G. Gonnade, K. Vanka and S. S. Sen, Chem. Commun., 2022, 58, 11843 DOI: 10.1039/D2CC04142A

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