A tin porphyrin axially-coordinated two-dimensional covalent organic polymer for efficient hydrogen evolution

Abstract

Herein, we demonstrate a facile strategy for constructing an efficient and stable hydrogen evolution reaction (HER) catalyst, i.e. a tin porphyrin axially-coordinated 2D covalent organic polymer (SnTPPCOP). SnTPPCOP exhibits promising HER activity with a low overpotential of 147 mV at 10 mA cm⁻² due to its unique structural properties, ranking among the best records reported recently.