Triplet–triplet annihilation upconversion with reversible emission-tunability induced by chemical-stimuli: a remote modulator for photocontrol isomerization

Abstract

Triplet–triplet annihilation upconversion (TTA-UC) has been widely studied, but a color-tunable TTA-UC system triggered by chemical stimuli has not yet been proposed. Herein, reversible acid/base switching of the TTA-UC emission wavelength is achieved for the first time by a simple platform, composed of a direct singlet–triplet (S₀–T₁) absorption photosensitizer, and proton-responsive 9,10-di(pyridin-4-yl)anthracene (DPyA) as an acceptor. The photosensitizer–acceptor pair exhibits efficient UC emission (quantum yield up to 3.3%, and anti-Stokes shift up to 0.92 eV) with remarkable contrast upon base/acid treatment (Δλ_em,max = 82 nm, 0.46 eV). In a proof-of-concept study, the color-adjustable TTA-UC emission was applied as a remote modulator to photo-control reversible chemical reactions for the first time. This platform enriches the portfolio of color-switchable TTA-UC, and the mechanism would inspire further development of smart UC systems and extend the application field of upconversion.