Issue 1, 2022
From the journal:

Dalton Transactions

High-spin carbonyl complexes of iron(i) and cobalt(i)†

Christian Schneider,a   Lukas Guggolza  and  C. Gunnar Werncke ORCID logo *a  

* Corresponding authors

a Chemistry department, Philipps-University Marburg, Hans-Meerwein-Straße 4, D-35032 Marburg, Germany
E-mail: gunnar.werncke@chemie.uni-marburg.de

Abstract

Metal carbonyl complexes are almost exclusively found in a low-spin state due to the strong-field nature of the CO ligand. Here the characterisation of highly labile three-coordinate metal(I) monocarbonyl complexes of iron and cobalt is presented. Experimental and quantum chemical examinations reveal their high-spin configuration.

Graphical abstract: High-spin carbonyl complexes of iron(i) and cobalt(i)

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Article information

DOI
https://doi.org/10.1039/D1DT03924E
Article type
Paper
Submitted
19 Nov 2021
Accepted
30 Nov 2021
First published
30 Nov 2021

Dalton Trans., 2022,51, 179-184

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High-spin carbonyl complexes of iron(I) and cobalt(I)

C. Schneider, L. Guggolz and C. G. Werncke, Dalton Trans., 2022, 51, 179 DOI: 10.1039/D1DT03924E

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