Issue 22, 2021

Platinum diimine-dithiolate complexes as a new class of photoconducting compounds for pristine photodetectors: case study on [Pt(bipy)(Naph-edt)] (bipy = 2,2′-bipyridine; Naph-edt2− = 2-naphthylethylene-1,2-dithiolate)

Abstract

The photoconducting properties of platinum diimine-dithiolate complex [Pt(bipy)(Naph-edt)] (1; bipy = 2,2′-bipyridine; Naph-edt2− = 2-naphthylethylene-1,2-dithiolate) were investigated. DFT calculations on a model assembly with four complex units suggest that the high external quantum efficency measured on a prototype photodetector correlates with the intermolecular character of electronic excitations in the visible region.

Graphical abstract: Platinum diimine-dithiolate complexes as a new class of photoconducting compounds for pristine photodetectors: case study on [Pt(bipy)(Naph-edt)] (bipy = 2,2′-bipyridine; Naph-edt2− = 2-naphthylethylene-1,2-dithiolate)

Supplementary files

Article information

Article type
Communication
Submitted
19 Apr 2021
Accepted
19 May 2021
First published
19 May 2021

Dalton Trans., 2021,50, 7527-7531

Platinum diimine-dithiolate complexes as a new class of photoconducting compounds for pristine photodetectors: case study on [Pt(bipy)(Naph-edt)] (bipy = 2,2′-bipyridine; Naph-edt2− = 2-naphthylethylene-1,2-dithiolate)

M. C. Aragoni, M. Arca, M. Binda, C. Caltagirone, V. Lippolis, D. Natali, E. Podda, M. Sampietro and A. Pintus, Dalton Trans., 2021, 50, 7527 DOI: 10.1039/D1DT01288F

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