Water-assisted spin-flop antiferromagnetic behaviour of hydrophobic Cu-based metal–organic frameworks

Arif I. Inamdar; Batjargal Sainbileg; Saqib Kamal; Khasim Saheb Bayikadi; Raman Sankar; Tzuoo Tsair Luo; Michitoshi Hayashi; Ming-Hsi Chiang; Kuang-Lieh Lu

doi:10.1039/D1DT00673H

Water-assisted spin-flop antiferromagnetic behaviour of hydrophobic Cu-based metal–organic frameworks†

Arif I. Inamdar,

^abc Batjargal Sainbileg,

^de Saqib Kamal,^afg Khasim Saheb Bayikadi,^h Raman Sankar,

^h Tzuoo Tsair Luo,^a Michitoshi Hayashi,

*^de Ming-Hsi Chiang

*^aci and Kuang-Lieh Lu

*^aj

Author affiliations

* Corresponding authors

^a Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan
E-mail: kllu@gate.sinica.edu.tw, chiangmh@gate.sinica.edu.tw

^b Department of Applied Chemistry, National Yang Ming Chiao Tung University, Hsinchu 300, Taiwan

^c Sustainable Chemical Science and Technology, Taiwan International Graduate Program, Academia Sinica, Taipei 115, Taiwan and National Yang Ming Chiao Tung University, Hsinchu 300, Taiwan

^d Center for Condensed Matter Sciences, National Taiwan University, Taipei 106, Taiwan

^e Center of Atomic Initiative for New Materials, National Taiwan University, Taipei 106, Taiwan

^f Molecular Science and Technology, Taiwan International Graduate Program, Institute of Atomic and Molecular Science, Academia Sinica, Taipei 115, Taiwan

^g Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan

^h Institute of Physics, Academia Sinica, Taipei 115, Taiwan

ⁱ Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 807, Taiwan

^j Department of Chemistry, Fu Jen Catholic University, New Taipei City 242, Taiwan

Abstract

Solvent-dependent magnetism in Cu-based metal–organic frameworks (MOFs) is reported. Spin-flop magnetic behaviour occurs at different dehydrated states of MOFs. The oxygens of guest and coordinated water molecules are responsible as water removal tunes the coordination geometry around the Cu centre and the electronic structure of the framework.

Supplementary files

Article information

DOI: https://doi.org/10.1039/D1DT00673H
Article type: Communication
Submitted: 05 Feb 2021
Accepted: 10 Mar 2021
First published: 10 Mar 2021

Download Citation

Dalton Trans., 2021,50, 5754-5758

Permissions

Request permissions

Water-assisted spin-flop antiferromagnetic behaviour of hydrophobic Cu-based metal–organic frameworks

A. I. Inamdar, B. Sainbileg, S. Kamal, K. S. Bayikadi, R. Sankar, T. T. Luo, M. Hayashi, M. Chiang and K. Lu, Dalton Trans., 2021, 50, 5754 DOI: 10.1039/D1DT00673H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Dalton Transactions

Water-assisted spin-flop antiferromagnetic behaviour of hydrophobic Cu-based metal–organic frameworks†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Water-assisted spin-flop antiferromagnetic behaviour of hydrophobic Cu-based metal–organic frameworks

Social activity

Search articles by author

Spotlight

Advertisements