A new pentanuclear {Co5} cluster motif is found to have a D3h oblate trigonal bipyramidal geometry, which is extended into a 3D triangle network, forming a unique capped breathing kagomé lattice. Magnetic results confirmed a paramagnetism down to 2 K, accompanying the disappearance of two-thirds of the spin moment at low-temperature and the appearance of a 1/5 magnetization plateau.
S. Du, M. Cui and Z. He, Chem. Commun., 2021, 57, 6616 DOI: 10.1039/D1CC01987B
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