A copper-catalyzed borylaminomethylation of multiple carbon–carbon bonds with N,O-acetal and bis(pinacolato)diboron has been disclosed that offers efficient and expedient access to γ-amino boronates. The products contain a valuable amine and boronate, which are amenable to further elaboration, and have versatile synthetic utilities.
X. Qiu, L. Xu, S. Wang, Y. Dai, Y. Feng, C. Gong and C. Tao, Chem. Commun., 2021, 57, 3279 DOI: 10.1039/D1CC00093D
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