Issue 15, 2021
From the journal:

Chemical Communications

3-Thiolated pyrroles/pyrrolines: controllable synthesis and usage for the construction of thiolated fluorophores†

Jun Tian,‡a   Kang-Ning Yuan,‡a   Wen Liu,b   Hong-Hong Chang,a   Xing Li ORCID logo a  and  Wen-Chao Gao ORCID logo *ac  

* Corresponding authors

a College of Biomedical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
E-mail: gaowenchao@tyut.edu.cn

b School of Basic Medical Sciences, Shanxi Medical University, Taiyuan 030001, China

c Shanghai Key Laboratory of Green Chemistry and Chemical Process, East China Normal University, Shanghai, China

Abstract

Thiolation/cyclization of homopropargylic tosylamides allowed the selective synthesis of 3-thiolated pyrroles and pyrrolines controlled by solvents. Moreover, the desired 3-thiolated pyrroles were readily transformed to organic fluorophores benzothienopyrrole and bisthiolated boron dipyrromethene (S-BODIPY).

Graphical abstract: 3-Thiolated pyrroles/pyrrolines: controllable synthesis and usage for the construction of thiolated fluorophores

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Article information

DOI
https://doi.org/10.1039/D0CC07988J
Article type
Communication
Submitted
08 Dec 2020
Accepted
18 Jan 2021
First published
18 Jan 2021

Chem. Commun., 2021,57, 1943-1946

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3-Thiolated pyrroles/pyrrolines: controllable synthesis and usage for the construction of thiolated fluorophores

J. Tian, K. Yuan, W. Liu, H. Chang, X. Li and W. Gao, Chem. Commun., 2021, 57, 1943 DOI: 10.1039/D0CC07988J

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