Correlating the axial Zero Field Splitting with the slow magnetic relaxation in GdIII SIMs

Júlia Mayans; Albert Escuer

doi:10.1039/D0CC07474H

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Correlating the axial Zero Field Splitting with the slow magnetic relaxation in Gd^III SIMs†

Júlia Mayans

*^a and Albert Escuer

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* Corresponding authors

^a Instituto de Ciencia Molecular (ICMol), Universitat de València, Paterna, València 46980, Spain
E-mail: julia.mayans@uv.es

^b Departament de Química Inorgànica i Orgànica, Secció Inorgànica and Institute of Nanoscience (IN2UB) and Nanotecnology, Universitat de Barcelona, Martí i Franquès 1-11, Barcelona-08028, Spain

Abstract

The field-induced out-of-phase magnetic response of a Gd^III complex, selected by its good isolation in the network, has been analyzed and the behaviour of this quasi-isotropic cation has been related to its weak axial zero field splitting ∼0.1 cm⁻¹.

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Article information

DOI: https://doi.org/10.1039/D0CC07474H
Article type: Communication
Submitted: 13 Nov 2020
Accepted: 16 Dec 2020
First published: 16 Dec 2020

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Chem. Commun., 2021,57, 721-724

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Correlating the axial Zero Field Splitting with the slow magnetic relaxation in Gd^III SIMs

J. Mayans and A. Escuer, Chem. Commun., 2021, 57, 721 DOI: 10.1039/D0CC07474H

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