Issue 47, 2020
From the journal:

Dalton Transactions

Mechanism and origins of regioselectivities of Rh-catalyzed alkenylation of allylbenzenes†

Tian-Qi Li,a   Jing-Yi Tan,‡a   Wei Deng*a  and  Zheng-Yang Xu ORCID logo *a  

* Corresponding authors

a School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai, PR China
E-mail: xzyang@sit.edu.cn

Abstract

Rhodium-catalyzed alkenylation of allylbenzene derivatives via C–C bond activation provides an unprecedented access to alkenylation products with remarkable regioselectivities. Using DFT calculations, we elucidate the reaction mechanism and the origins of the regioselectivity.

Graphical abstract: Mechanism and origins of regioselectivities of Rh-catalyzed alkenylation of allylbenzenes

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Article information

DOI
https://doi.org/10.1039/D0DT03704D
Article type
Paper
Submitted
27 Oct 2020
Accepted
03 Nov 2020
First published
04 Nov 2020

Dalton Trans., 2020,49, 17395-17400

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Mechanism and origins of regioselectivities of Rh-catalyzed alkenylation of allylbenzenes

T. Li, J. Tan, W. Deng and Z. Xu, Dalton Trans., 2020, 49, 17395 DOI: 10.1039/D0DT03704D

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